Mock Test Iit - Jee..Paper 1

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Mumbai (H.O.) : 77-A, 1uhu Supreme Shopping Centre, Gulmohur Cross Road 9, 1VPD Scheme, Mumbai-49.
MOCK TEST 4 (IIT 1EE 2008)
PAPER 1
Time: 3 hours Marks: 270
Each question has only one correct answer. For every correct answer 3 marks will be
awarded. For every wrong answer 1 mark will be deducted.
Physics
1. A balloon starts Irom rest on the ground with constant acceleration .
8
A ball is dropped
Irom the balloon when the balloon is at a height h` meter. The time taken by the ball to
reach the ground is
(a) 2
(b)
(c)
2
(d)
2

2. According to previous problem, the velocity acquired by the ball just beIore it strikes the
earth is,
(a) 2 (b) (c)
2
3
(d)
2

3. A car is moving with a speed :
` see a truck at a distance S` ahead Irom the car on the

same track moving with a speed :
2
` . Driver oI the car now puts on the break and gives a
constant acceleration a`. The car will collide with the truck when,
(a)
,
: :
$
2
) (
2
2

(b)
,
: :
$
2
) (
2
2

(c)
,
: :
$
2
2
) (
(d)
,
: :
$
) (
2
2
2

4. A particle is moving along a curved path. Its velocity is directed
(a) normally to the tangent (b) parallel to the radial acceleration but outwardly
(c) tangentially (d) none oI these.
5. The acceleration oI a particle various with distance as a .
2
3
2
x Then the distance
covered by the particle, ). , 0 ( : ; 9 hen its speed becomes 2u is,
(a)
2
3: (b)
4
3
2
:
(c)
3 / 2
) 3 ( : (d)
3 / 2
3:
. Two balls are simultaneously projected vertically towards each other one Irom top oI the
building and the other Irom the bottom with a speed oI 5 meter/sec. II 00 meter be the
height oI the building then the time aIter which both the balls meet each other is,
(a) 0 sec (b) 5 sec (c) 2 sec (d) 8 sec.

7. A body Ialling Ireely Irom a height H` hits a inclined plane in its path at a height h`. As
a result oI this impact the direction oI the velocity oI the body becomes horizontal.
The ratio oI
H
Ior which the body will take maximum time to reach the ground is
(a)
2
(b)
3
(c)
2
(d)
4

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8. II the pulleys are Iixed then the upward speed oI mass m`
is

(a) 7 cos ;

(b)
7 cos
;

(c)
7 sin
;
(d)
7 cos
;

9. A rod oI length L` and mass m` iI acted by Iorces 2F` and F` as shown. The tension in
the rod at its middle point is

(a)
m
F
2
(b)
m
F
2
3

(c)
2
3F
(d)
2
F

10. A block oI mass m` rests on a rough horizontal Iloor. It is desired to make the block
move by applying the minimum possible Iorce F` at an angle 7 `. The minimum value
oI F` is given by
(a)
2
3
m
(b)
2
3
3
m

(c) m 3 (d) m
2
3

11. The coeIIicient oI volume expansion Ior an ideal gas at constant pressure is
(a) % (b) % / (c)
2
/ % (d) %

12. A ball is thrown up in a liIt with a velocity v relative to the liIt. II t` be the time oI Ilight
then the acceleration with which the liIt is going up
(a)
9
9 ; 2
(b)
9
9 ;
(c)
9
9 ; 2
(d)
9
9 ;

13. An upward Iorce oI 325 N is applied at the centre
as shown. The accelerations oI 7 kg and 0 kg
blocks are given by (g9.8)

(a) .8 m/sec
2
, 0
(b) .8 m/sec
2
, .8 m/ sec
2

(c) .8 m/sec
2
, .6 m/sec
2

(d) .8 m/sec
2
, -.6 m/sec
2

v
v
7
a
L
F 2F
B A
325 N
7 kg
m
2

m
0 kg

14. The molar heat capacity oI a certain substance varies with temperature according to the
given equation. % ) 0 4 ( 2 . 27
3
L .The heat necessary to change the temperature
oI 2 mol. oI the substance Irom 300K to 700K is
(a)
4
0 46 . 3 L (b)
3
0 33 . 2 L (c)
3
0 46 . 3 L (d)
4
0 33 . 2 L

15. A massless wire oI length 90 m is Iastened between two points. A bird oI mass 500 gm
lands on the wire midway between the two given points and depress the wire by 00 cm.
The tension in the wire is equal to, (g9.8)
(a) 0.25 N (b) 00 N (c) 90.5 N (d) 80 N

1. During a catch practice session in cricket, player throws a ball upwards catches it himselI
aIter 4 second. The maximum height attained by the balls is equal to (g0)
(a) 20 m (b) 25 m (c) 30 m (d) 5 m

17. Two masses are connected as shown. The
Iorce F` causes acceleration a` in mass
m
`, then the acceleration oI mass m

2
`,

(a)
2
m
F
(b)
2
m m
F
(c)
2
m
, m F
(d)
) (
2
m m
, m

18. A block oI mass 0. kg is held against a wall by applying a horizontal Iorce oI 5 N on the
block. II the coeIIicient oI Iriction between the block and the wall is 0.5, the magnitude
oI the Irictional Iorce acting on the block is
(a) 2.5 N (b) 0.98 N (c) 4.9 N (d) 0.49 N

19. Two blocks are kept as shown. Mass m
` is tied to the wall through a horizontal string.

The horizontal Iorce F` is
necessary to move the block oI
mass m
2
`,(g0)

(a) 500 N
(b) 800 N
(c) 2000 N
(d) None oI these

20. A particle is projected with kinetic energy K. II it has the maximum possible horizontal
range, the kinetic energy oI the particle at the highest point is
(a) K (b)
4
(c)
2
(d) 2

21. A thin metal square plate oI length L is heated Irom
0
0 to
0
00 , its length increases
by 2 the increase in the area oI the plate is

(a) .04 (b) 2.04 (c) 3.04 (d) 4.04

F
m
200 kg
4
3
5 /
2
3
m
2
300 kg
F m
1
m
2

a

22. A metallic sphere oI radius R has a cavity oI radius oI r at its centre. II the sphere is
heated, the radius oI the cavity will
(a) increase (b) decrease (c)remain same (d) increase iI
2
#
7
23. A one litre Ilask contains some mercury. It is Iound that at diIIerent temperatures the
volume oI the air inside the Ilask remains the same. The volume oI Hg in the Ilask,

4
Hg
-6
0 8 . , 0 9 glass

L L
3 3
-
(a) 000 litre (b) 00 cm
3
(c) 50 cm
3
(d) 200 cm
3

24. M` gram oI ice at -
0
4 is mixed with 200 gm oI water at 25
0
C . Final temperature oI
the system is 0
0
C. ( /gm). cal 80 L , cal/gm 5 . 0
ice I
0
ice
$ Then M is equal to
(a) 3 gm (b) 35 gm (c) 39 gm (d) 42 gm

25. An ideal gas with pressure P, volume V, and temperature T, is expanded isothermally to a
volume 2V and a Iinal pressure P
i.
II the same gas is expanded adiabatically to a volume
2V, the Iinal pressure is P
a
. The ratio oI speciIic heats Ior the gas is .67
The ratio
,
!
!
is
3 . 0
2
, 8 . 3 2 , 5 . 0
3
, 26 . 6 3
67 .
67 .
67 .
67 .
;03
(a) 0.4835 (b) 0.6285 (c) 2.069 (d) 6.825

2. In the given process on an ideal gas, d 0 and . 0 /" Then, Ior the gas
(a) The pressure will increase (b) The temperature will increase
(c) The temperature will decrease (d) The pressure will decrease

27. A given mass oI an ideal gas is at pressure P and absolute temperature T. The isothermal
bulk modulus oI the gas is
(a) P (b) 2P (c) P
3
2
(d) P
2
3

28. The molar heat capacity oI an ideal gas (c)

(a) must equal either C
p
or C
V

(b) cannot be negative
(c) may have any value lying between C C and
(d) must lie in the range starting Irom C
V
and terminating at
! !
A A
V
C e., i

29. In a certain region oI space there are 5 molecules per cm
3
on an average at 3K
temperature. The average pressure oI this gas is
(a) Pa 0 07 . 2
0
L (b) Pa 0 05 . 3
7
L
(c) Pa 0 07 . 2
6
L (d) Pa 0 05 . 5
5
L

30. An ideal gas is Iound to be obey the low J !
2
Constant.
The gas is initially at temperature T and volume V. II the gas now expands to a volume
2V then its new temperature will be
(a) T (b)
2
%
(c)
2
%
(d) % 2


CHEMIS1RY

1. Hardness oI water is measured in terms oI ppm (parts per million) oI CaCO
3.
It is the
amount (in g) oI CaCO
3
present in 0
6
g H
2
O. in a sample oI water, 0 L required 0.56 g
oI CaO the remove temporary hardness oI HCO
-
3

O H ,O ,O HO ,
2 3 2 3
2 ) ( PF P
Temporary hardness is:
(a) 200 ppm CaCO
3
(b) 00 ppm CaCO
3

(c) 50 ppm CaCO
3
(d) 25 ppm CaCO
3

2. In the Iollowing reaction (unbalanced), equivalent weight oI As
2
S
3
is related to
molecular weight M by:

F
2
4
3
4 2 3 3 2
$O AsO O H NO NO H $ As
(a)
2
M
(b)
4
M
(c)
28
M
(d)
24
M

3. mol oI FeC
2
O
4
is oxidise by x mol oI
2
7 2
O 7 in acidic medium, x is:
(a) 3 (b) .5 (c) 0.5 (d) .0

4. For the reaction between
4
M3O and
2
4 2
O in basic solution, the unbalanced equation
is:

F
2
3 2
2
4 2 4
) ( O s M3O O M3O In a balanced equation, the number oI OH
-
ions is:
(a) 0 (b) 4 on the right (c) 4 on the leIt (d) 2 on the leIt

5. hich is not a disproportionation reaction?

(a) 2

(b)

(c)

(d) All oI these

. In the Iollowing redox reactions, NH
3
appears either in reactant or product. In which case
equivalent weight oI NH
3
is maximum?
(a)
3 2 2
2 3 NH H N F (b)
2 2 3
6 4 5 4 H NO O NH F
(c)
2 2 3
4 2 2 H N,NH N, NH F (d) equal in all cases

7. Maximum Number oI mol oI PbSO
4
that can be precipitated by maxing 20.00 mL oI
0. M Pb (NO
3
)
2
and 30.00 mL oI 0. M Na
2
SO
4
will be:
(a) 0.002 (b) 0.003 (c) 0.005 (d) 0.00

8. 00 mL oI a mixture oI NaOH and Na
2
SO
4
is neutralised by 0 mL oI 0.5 M H
2
SO
4.

Hence, amount oI NaOH in 00 mL mixture is
(a) 0.2g (b) 0.4g (c) 0.6 g (d) .0 g
CHO P P P F P
3
) (OE9 AI
COOCH
2

CHO CH
2
OH COO
-

COOH COO
-
COO
-

OH
-
NaH H2O
2
H NaOH PF P
F

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9. Volume oI 0.50 M NaOH solution required to react with 40.0 mL oI 0.05 M H
2
SO
4

solution is:
(a) 40.0 mL (b) 80.0 mL (c) 20.0 mL (d) 8.0 mL

10. A 20.0 mL solution oI Na
2
SO
3
required 30 mL oI 0.0 M K
2
Cr
2
O
7
solution Ior the
oxidation to Na
2
SO
4
Hence, molarity oI Na
2
SO
3
Solution is:
(a) 0.05 M (b) 0.045 M (c) 0.030 M (d) 0.0225 M

11. The hybridisation scheme Ior the central atom includes a /- orbital contribution in:
(a)
-
3
I (b) PCl
3
(c)

3
NO (d) H
2
Se
12. Relative stability oI O
2
,
- 2
2
O and O
2,
O
-
2
is in order:
(a)
2
O
2
O
2
2
O
-
2
O
(b)
2
O
2
O
2
O
- 2
2
O

(c)

2
2
O
-
O O
2
O
2 2
(d)
2
2
O
-
O
2
O
2
O
2

13. Some oI the Iollowing properties are important in determining whether an element has
metallic properties :
I: Atomic number II: atomic weight
III: number oI valance electrons IV: number oI vacant atomic orbitals
V: total number oI electronic shells in the atom
Select correct properties Irom the codes given below:
(a) I, II, III, IV (b) I, III, IV, V (c) III, IV (d) III, IV, V

14. In terms oI polar character, which one oI the Iollowing order is correct?
(a) NH
3
H
2
O HFH
2
S (b) H
2
S NH
3
H
2
O HF
(c) H
2
O NH
3
H
2
SHF (d) HF H
2
O NH
3
H
2
S
15. How many unpaired electrons are present in a ground state gaseous
2
Ni ions?
(a) 0 (b) 2 (c) 4 (d) 6

1. hich oI the Iollowing statements is correct?
(a) (n -) d subshell has lower energy than ns subshell
(b) (n -) d subshell has higher energy than ns subshell
(c) (n ) d subshell has lower energy that nI subshell
(d) nI subshell has lower energy than (n2)s subshell

17. Suggest two transitions in the spectrum oI atomic hydrogen Ior which the wave number
ratio is 08:7
(a) First lyman and Iirst brackett transitions
(b) First and second lyman transitions
(c) First lyman and Iirst balmer transitions
(d) First lyman and Iirst paschen transitions

18. The emission spectrum oI the hydrogen atom
(a) is caused by the removal (ionisation) oI the electron.
(b) is continuous because the electron can emit any Irequency oI light during a
transition.
(c) is caused by the absorption oI light at characteristic Irequencies the electron to be
excited into higher energy levels.
(d) is a result oI the excited electron undergoing transitions to lower energy levels
and emitting photons oI light at speciIic Irequencies.

19. The circumIerence oI the 4th Bohr`s orbit in hydrogen atom is 5.32 nm. The de Broglie
wavelength oI the electron is:
(a) 0.33 nm (b) 3.3 nm (c) .33 nm (d) 33 nm

20. hat is the diIIerence in wavelengths oI the 4th and 5th lines oI the Balmer series in the
spectrum oI atomic hydrogen?
(a)
3
A 3
(b)
3
A 520 (c)
3
A 390 (d)
3
A 262

21. The energy required to melt g ice is 33J. The number oI quanta oI radiation oI Irequency
sec
3
0 67 . 4

L that must be observed to melt 0g ice is
(a)
22
0 065 . L (b)
23
0 205 . 3 L (c)
20
0 076 . 9 L

(d)None oI these

22. hat should be the velocity oI an electron so that its momentum becomes equal to that oI
a photon oI wavelength
3
A 5200
(a) 700 m/s (b) 000 m/s (c) 400 m/s (d) 2800 m/s

23. hich oI the Iollowing samples contains the largest number oI atoms?
(a) g oI Ni(s) (b) g oI Ca(s) (c) g oI N
2
(g) (d) g oI B(s)

24. A compound was Iound to contain 5.37 nitrogen. hat is the minimum molecular wt.
oI compound
(a) 26.07 (b) 2.607 (c) 260.7 (d) None

25. hich oI the Iollowing will contain same number oI atoms as 20g oI calcium?
(Atomic mass : Ca 40)
(a) 24g magnesium (b) 2g carbon
(c) 8g oxygen gas (d) 6 g oxygen atom

2. A compound
3
O
2
X contains 3.58 oxygen by weight. The atomic weight oI x is
(a) g/mol. 34.66 (b) . / 0 . 45 mol
(c) 52.00 g/mol. (d) 04.0 g/mol.

27. A 000 gram sample oI NaOH contains 3 moles oI O atoms, what is the purity oI
NaOH
(a) 4 (b) 00 (c) 2 (d) 24

28. The volume oI water which must be added to 40 cc. oI 0.25M Oxalic acid solution to
make it exactly decimolar (0.M) is:
(a) 40 c.c. (b) 30 c.c. (c) 60 c.c. (d) 25 c.c.

29. 8 gms NaOH is dissolved in one litre oI solution, the molarity oI the solution is
(a) 0.2 M (b) 0.4 M (c) 0.02 M (d) 0.8 M.

30. 0.g oI KNO
3
are dissolved in 500 g oI water. How many grams oI Ba(NO
3
)
2
should be
added to this solution to gat a molality oI 0.3 Ior the nitrate ion?
|At. t. oI Ba 37.4|

(a) 6.535 (b) 5.365 (c) 3.655 (d) 7.535

MATHS

1. The set oI all values oI 7 in | 2 , 0 | " Ior which the equation
0 sin ) cos 2 ( ) sin (
2
7 7 7 x x has real roots.
(a) ) 3 / , 0 ( " (b)
"
"
"
"
2 ,
6
,
6

(c) )
"
"
" 2 ,
6
5
6 / , 0 (d)
" "
2
3
,
3

2. The general solution oI the equation 0 cos 2 sin 2 2 sin x x x is
(a)
4
3
"
" 3 (b)
4
2
"
" 3
(c)
"

3
sin ) ( 2
3
3 (d)
4
"
" 3
3. The number oI solutions oI the equation x x 6 sin ) 3 tan( in
" "
"
2
,
6 6
, 0 is
(a) 5 (b) 4 (c) 3 (d)
4. The equation 7 2 cos sin
2
7 7 possesses a solution iI
(a) 6 2 A A (b) 2 (c) 6 (d) 2

5. II 2 / ) ( sin 2 ) ( sin

"

x x then
(a)
2
, 0 x (b)
2
x (c) 0 x only (d) none

. II tan ) ( tan cot( ) cot( x x then x
2
sin is equal to
(a)
" ) 2 (
2
3
(b)
" ) 2 (
4
3
(c)
" ) (
2
3 3
(d)
" ) (
4
3 3

7. II x x x A A

) ( tan ) ( cos ) ( sin

, then
(a) " , 0 (b)
2
, 0
"
(c) "
"
,
2
(d) none
8. iven . 30 , 3 , 2
0
\ A c b , then in-radius oI AB is
(a)
2
3
(b)
2
3
(c)
2
3
(d) none
9. The value oI ) ) ( sin ) ( cos 2 cos

x x

at 5 / x where " A A

) ( cos 0

x and
2
) ( sin
2
"
A A
"

x
(a)
25
6
(b) 6
5
2
(c)
5
20
(d) none
10. In a triangle ) sin( : ) sin( sin : sin B B A A Then
2 2 2
: : c b , are in

(a) AP (b) P (c) HP (d) none

11. In a triangle AB,
0
90 \ then
2 2
2 2
b ,
b ,
is equal to
(a) ) ( sin B A (b) ) sin( B A (c) ) ( cos B A (d)

2
sin
B A

12. II ) tan( ) tan( 7 - 7 - 3 then
) 2 sin(
) 2 sin(
-
7
is equal to
(a)
3
3
(b)
3
3
(c)
3
3
(d)
3
3

13.
,b c, bc
c b ,
log
log
log
is equal to

(a) 0 (b) 3 (c) 2 (d)
14. II , 27 log
2
then 6 log
6
is
(a)
,
,
3
3
(b)
,
,
3
) 3 ( 4
(c)
) 3 ( 4
/ 3
,
,
(d) none
15. II A 2 log 2 256 log log log
2
4 2 2
then A equals
(a) 2 (b) 3 (c) 5 (d) 7
1. II ) ( log ), ( log , ) ( log ,b : c, bc x
c b ,
then x:
(a) : x (b) : x
(c) 2 : x (d) 3 : x

17. II . - , , are the roots oI the equation
0
2
2
0
3
5 x 5 x 5 x then ) ( ) ( ) (
2 2 2
. - is equal to.
(a)
2
2 0
2
) ( ) ( 5 5 5 (b)
2
2 0
2
) ( ) ( 5 5 5
(c)
2
2 0
2
) ( ) ( 5 5 5 (d) none
18. The domain oI the Iunction ) 8 5 ( log cos
2
2
x x is
(a) | 2, 3| (b) |-3, -2| (c) |-2, 2 | (d) |-3, |
19. II - and . are the roots oI , 0
2
x x then
3 3 3 3
2 3 and 3 2 . - . - are the
roots oI
(a) 0
2
x x (b) 0 7 5
2
x x
(c) 0 7 5
2
x x (d) 0 7 5
2
x x

20. II . -, are roots oI 0
2
c bx ,x then roots oI equation
0 ) ( ) (
2 2
x c x bx ,x are
(a) , . - (b) ,
,
.
.
-
-
(c)
.
.
-
-
,

(d) none
21. II , 4
6 2
3 5 6
2
2
A

x x
x x
the least and the highest values oI
2
4x are
(a) 0 and 8 (b) 9 and 8 (c) 36 and 8 (d) none

22. The sixth term oI the series 3, 29, 69, 8, 509, is
(a) 484 (b) 486 (c) 488 (d) 485

23. II
b , , c c b
are in AP then ) 0 ( , ,

x q q q
cx bx ,x
are in

(a) AP (b) P only iI x 0 (c) P only iI x~ 0 (d) none
24. The coeIIicient oI
9
x in the polynomial given by
) ( ) 3 ( ) 2 ( ) 0 ( ) 2 ( ) ( x x x x x x
) 20 ( ) 2 ( ) ( x x x is
(a) 55 (b) 55 (c) 55 (d) 55

25. The sum oI the series C
3 2
5
0
5
7
5
4
is
(a)
35
6
(b)
8
(c)
6
35
(d)
6
8

2. The sum oI 3 series oI the sequence 0, 003, 0005,

(a) ) 0 (
9
0
3
(b) 0
9
00
3

(c)
2
0
9
00
3
3
(d) 0
9
00
2
3
3

27. II 0 at then
2
2
tan
2
x
/x
/
x
x
is
(a) (b) 2 (c) log2 (d) none

28. The derivative oI ) ( sin w.r.t
tan
-
x
x
x
is
(a) (b)
2

(c)
2
(d) none
29. The maximum value oI the Iunction 0 , 0
2 2

b ,
x ,
b
x
,
in (0, , ) is
(a) b , (b)
b ,
(c)
,
b ,
2
) (
(d)
2
,
b ,

30.
/x
x
x
3

(a) c
x x

4 3
4 3
(b) c x x
x x
) log(
2 3
2 3

(c) c x x
x x
) ( log
2 3
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` see a truck at a distance S` ahead Irom the car on the

`, then the acceleration oI mass m

` is tied to the wall through a horizontal string.

x (c) 0 x only (d) none

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