Beruflich Dokumente
Kultur Dokumente
Operation Start: November, 1959 Facilities: Manufacturing of boiler plants, desulfurization plants (DESOx), nuclear power plant equipment, industrial plants and incineration facilities
ISO9001 Established quality program and succeeded to get the initial certi cate of approval on July 12, 1994.
DESOx R&D
Tray Tower R&D Spray Tower R&D Advanced Spray Tower Commercialization
DENOx
R&D
R&D Catalyst Composition Catalyst Con guration Pellet type Catalyst Con guration Plate type Commercialization
Operation Start: March, 1987 Facility: Continuous automatic manufacturing process of catalyst Site Area: 127,000 m2
CCS
Global Network
As a core company of the Hitachi, Power & Industrial group, we provide boiler and AQCS services globally.
l l l l
l Babcock-Hitachi K.K. l Babcock-Hitachi (Philippines) Inc. l Babcock-Hitachi Dongfang Boiler Co.,Ltd l Hitachi Power Europe GmbH l Hitachi Power Systems America, Ltd.
DESOX
Flue Gas Desulfurization Systems
In the early 1960s, before other commercial enterprises got on the bandwagon, Babcock-Hitachi K.K. (BHK) began developing Flue Gas Desulfurization systems (FGD). Our rst commercial system went into operation in April, 1974. Then, as a result of continuous technical improvements, our rst 1,050 MW plant started up in 2000. FGD system technology of BHK is contributing to the prevention of air pollution not only in Japan but also in European countries, the USA and Asian countries.
ESP Boiler
Fan
Limestone Silo
Gas-Gas Heater
Process Input
Mist Eliminator
SO2 Flow
Gypsum Dewatering
pH
Oxidation Blower
Absorber
Electric Power Development Co., Ltd. (Japan) Tachibanawan Power Station, No. 2 Unit
The largest DESOx plant in Japan
Boiler Fuel: Size: Gas Capacity: Conc. of Inlet SO2: SO2 Removal Ef ciency: FGD Con guration: Absorber Type: Gas Reheating System: Placed in Operation: Coal 1,050 MW 3,300,000 m3N/h 809 ppm 94% or more New Flue Gas Treatment System Advanced Spray Tower Non-Leakage Gas-Gas Heater Dec., 2000
Control Signal
Gypsum
DESOX
Summary of Latest Technology Improvement
The following design concepts are adopted in our advanced FGD systems: 1. Higher gas velocity 2. Decrease of spray stages and better liquid/gas contact. 3. Higher slurry concentration 4. Effective in-situ forced oxidation
Droplet
Pressure Drop
Gas Velocity
Slurry Gas
Low Concentration
High Concentration
BHK is capable to offer the advanced FGD system containing the following features adopting technology improvement. 1. Excellent advanced spray tower absorber featuring ; 1) High SO2 and dust removal ef ciency 2) Low utility consumption due to excellent liquid / gas contact and lower pressure drop 3) Higher oxidation performance 2. Full support by R&D facility 3. Proven FGD technology and high reliability
No Plugging
DESOX
Non-Leakage Gas-Gas Heater
Typical Con guration
Untreated Gas Heat Recovery Section
Reheat Section
Stack
GGH IDF
(Heat Recovery)
DESOx
GGH
(Reheat)
Treated Gas
Stack
Auxiliary Steam
The new system has the following features: 1. Improved ESP performance and lower dust emission 2. Increased gypsum purity
3. Higher SO3 removal performance 4. Lower ID-fan capacity and power consumption
Untreated Gas
( cm)
High
A Coal
B Coal
Conventional system
Treated Gas
Low
Gas Temperature
Adsorption of SO3 into the dust The fall of Temp. (By GGH)
Heat Transfer Medium Recirculation Pump
SO3(Vapor)
SO3(humid)
Applications
DESOX
Applications
Soma Kyodo Power Co., Ltd. (Japan) Shinchi Power Station, No. 1
Boiler Fuel: Size: Gas Capacity: Conc. of Inlet SO2: SO2 Removal Ef ciency: Absorber Type: Absorption System: Gas Reheating System: Placed in Operation: Coal 1,000 MW 3,040,400 m N/h
3
Shikoku Electric Power Co., Inc. (Japan) Sakaide Power Station, No. 3
Boiler Fuel: Size: Gas Capacity: Conc. of Inlet SO2: SO2 Removal Ef ciency: Absorber Type: Absorption System: Gas Reheating System: Placed in Operation: Heavy Oil 450 MW 1,279,000 m3N/h 1,217 ppm 96% or more Advanced Spray Tower Dust Mixing System Regenerative Type Gas-Gas Heater Mar., 2003
920 ppm 90% or more Advanced Spray Tower Dust Separation System Non-Leak Gas-Gas Heater Jun., 1994
Hokkaido Electric Power Co., Inc. (Japan) Shiriuchi Power Station, No. 2
Boiler Fuel: Size: Gas Capacity: Conc. of Inlet SO2: SO2 Removal Ef ciency: Absorber Type: Absorption System: Gas Reheating System: Placed in Operation: Orimulsion 350MW 1,071,000 m3N/h 2,465 ppm 94% or more Advanced Spray Tower Dust Mixing System Regenerative Type Gas-Gas Heater Sep., 1997
Hydro Electrical del cantabrico S.A. (Spain) Abono Power Station, No. 2
Boiler Fuel: Size: Gas Capacity: Conc. of Inlet SO2: SO2 Removal Ef ciency: Absorber Type: Absorption System: Gas Reheating System: Placed in Operation: Coal 556 MW 2,362,604 m N/h
3
736 ppm 95% or more Advanced Spray Tower Dust Mixing System Regenerative Type Gas-Gas Heater Oct., 2007
DENOX
NOx Removal Systems
In the 1960s, when air pollution emerged as a major global concern, BHK started research and development for the reduction of NOx emissions from power plants. BHK rst developed a pellet type DENOx catalyst. Based upon this original catalyst, BHK developed a low-pressure drop plate type catalyst, which is presently one of our major products. Contributing to global environmental preservation, the DENOx catalysts have been adopted throughout the world, North America, Europe and Asia, as well as in Japan, and have maintained an excellent reputation for high performance.
H2O N2
NOx
NH3
Tokyo Electric Power Co., Inc. (Japan) Hitachinaka Power Station, No. 1 Unit
Boiler Fuel: Size: Gas Capacity: Conc. of Inlet NO2: NOx Removal Ef ciency: Placed in Operation: Coal 1,000 MW 3,280,000 m3N/h 225 ppm 85% or more Dec., 2003
Seminole Electric Cooperative, Inc. (USA) Seminole Generating Station, Units No.1 & No.2
Boiler Fuel: Size: Gas Capacity: Conc. of Inlet NOx: Placed in Operation: Coal 650 MW 2,238,000 m3N/h 306.5 ppm Spring, 2009
BHK DENOx catalyst has been applied to many types of boilers, HRSGs and heaters that use various fuels. In particular, BHK DENOx catalyst has gained a superb reputation in the eld of coal- red boilers. Very low plugging potential and extremely high erosion resistance are some of the reasons for this reputation. An additional unique feature of the BHK catalyst is the adjustable plate size that enables the product to t any ue size.
Ammonia
Air
DENOX
Catalyst Manufacturing
All of BHK DENOx catalysts are produced in its own manufacturing facility, currently in Akitsu, Japan. Over the past 40 years, the manufacturing has been continuously improved as a result of ongoing research into the product to increase its effectiveness. The present high quality, high performance and highly competitive DENOx catalyst is the culmination of four (4) decades of experience and continuous development.
Gas Gas Dust Hg Hg (Oxide)
Dust
Spray Hg (Oxide)
SCR Catalyst
Ash Particulate Particulate Hg Catalyst Center Metal Plate Plate Type Catalyst Catalyst
Absorption
Hg
Elemental Hg
Solid Material Catalyst
Oxidized Hg (HgCI2)
TRACTM
Hitachi is providing Triple Action Catalyst (TRAC) having high mercury oxidation, high NOx removal and low SO2 to SO3 oxidation rate.
Before operation After 50,000 hours operation
Hg Oxidation
Space for Added Catalyst
Conventional TRAC
Reactor
Catalyst Block (1-stage Model) Compact reactor using stacked plate type catalyst (5-stage Model) Multistage reactor
NOx Removal
0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6
DENOX
Applications
Electric Power Development Co., Ltd. (Japan) Matsuura Power Station, No. 1 Unit
Boiler Fuel: Size: Gas Capacity: Conc. of Inlet NOx: NOx Removal Ef ciency: Placed in Operation: Coal 1,000 MW 3,029,000 m3N/h 250 ppm 80% or more Jun., 1990
Zhejiang Guohua Zheneng Power Generation Co., Ltd. (China) Ninghai Power Plant, No.4 Unit
Boiler Fuel: Size: Gas Capacity: Conc. of Inlet NOx: NOx Removal Ef ciency: Placed in Operation: Coal 600 MW 1,924,795 m3N/h 250 ppm 80% or more Nov., 2006
Tokyo Electric Power Co., Inc. (Japan) Futtsu Power Station, No. 3 Unit
Gas Turbine Type: Fuel: Size: Gas Capacity: Conc. of Inlet NOx: NOx Removal Ef ciency: Placed in Operation: GE Frame 9 FA++ LNG 380 MW 1,870,000 m3N/h 45 ppm (16% O2) 90% Jul., 2001
CCS
CO2 Capture Systems
In the 1990s, when aimed call for protection of global warming, BHK, being ahead of the times, started research & development for CO2 capture technology. In the development of tchnology and continuous investment through pilot plant test treating actual ue gas from power plant, BHK created advanced CO2 capture system utilizing his originated solvent as amine basis (H3 series solution). Also BHK has been developing oxyfuel system simultaneously. BHK de nitely contributes to global protection as a leading player of CO2 capture technology.
CCS Pilot Plant Test Facility in Power Station Tokyo Electric Power Co., Inc. (Japan)
Boiler Fuel: Fuel Gas Volume:
Desorber Absorber
COM (Coal and Oil Mixture) 1,000 Nm3/h 90% 4.5 ton/day Dec. 1999 Mar. 1995
Absorber
Desorber
Steam
Chemical Principle
Exothermic + R-NH2 + CO2 + H2O R-NH3 + HCO3 Endothermic (Solution)
Reboiler Solvent
Akihabara UDX Bldg.10F, 4-14-1 Sotokanda, Chiyoda-ku, Tokyo 101-0021, Japan Tel : +81-3-5209-7314 Fax: +81-3-5209-7763 www.bhk.co.jp
Printed in Japan (HB) 01.2011
Babcock-Hitachi K.K.