Time : 2 hours Note : The marking scheme is (+3, 1) for all questions Section : I For question number 1 to 10 choose

the correct/most appropriates. Only one option should be chosen 1. The rms velocity of hydrogen is gas, then (a) T(H 2 ) = T( N 2 ) (c) T(H 2 ) < T( N 2 ) Therefore, (a) Vm > 22.4 litres (c) Vm = 22.4 litres (b) Vm < 22.4 litres (d) Vm = 44.8 litres (b) T(H 2 ) > T( N 2 ) (d) T(H 2 ) = 7 T( N 2 )

V(L)

(30.61, 373K)

(c)

(22.4L, 273K) T(K) V(L)

7 times the rms

(d)

(22.4L, 273K) (14.21, 373K) T(K)

velocity of nitrogen. If T is the temperature of the

6. When the temperature is increased, surface tension of water

(a) Increases (b) Decreases (c) Remains constant (d) Shows irregular behaviour

2. The compressibility of a gas is less than unity at S.T.P.

3. At 100 o C and 1 atm, if the density of liquid water is

7. Positive deviation from ideal behaviour takes place because of

(a) Molecular interaction PV/nRT>1 (b) Molecular interaction PV/nRT<1 between atoms and

1.0 gcm 3 and that of water vapour is 0.0006 gcm 3 ,

then the volume occupied by water molecules in 1 litre of steam at that temperature is (a) 6cm 3 (c) 0.6cm 3 (b) 60cm 3 (d) 0.06cm 3

between

atoms

and

(c) Finite size of atoms and PV/nRT>1 (d) Finite size of atoms and PV/nRT<1

4. The root mean square velocity of an ideal gas at

constant pressure varies with density (d) as (a) d 2 (c) (b) d

8. The root mean square velocity of one mole of a monoatomic gas having molar mass M is U r .m.s. . The
relation between the average kinetic energy (E) of the gas and U r .m.s. is (a) ur .m.s. =

(d) 1 / d

5. Which of the following volume (V) - temperature (T)

plots represents the behaviour of one mole of an ideal gas at one atmospheric pressure
V(L) (38.81, 373K)

3E 2M 2E M

(b) ur .m.s. =

2E 3M E 3M

(a) (22.4L,
273K) T(K) V(L) (22.4L, 273K) (28.61, 373K)

(c) ur .m.s. =

(d) ur .m.s. =

9. The ratio of the rate of diffusion of helium and methane under identical condition of pressure and temperature will be
(a) 4 (b) 2 (d) 0.5

(b)
T(K)

(c) 1

10. When one mole of monoatomic ideal gas at T K undergoes adiabatic change under a constant extenal pressure of 1 atm changes volume from 1 litre to 2 litre. The final temperature in Kelvin would be
(a)

15. Which of the following graphical represents Boyles law correctly

presentations

T 2
( 2 / 3)

(b) T + (d) T

2 0.0821 3 2 0.0821 3

(a) V
P

(b)

(c) T

Section II For question number 11 to 20 choose all the correct options. Your answer will be denote correct only, If all the correct options and no incorrect option is chosen 11. If a gas is expanded at constant temperature
(a) The pressure decreases (b) The kinetic energy of the molecules remains the same (c) The kinetic energy of the molecules decreases (d) The number of molecules of the gas increases

(c)

(d)
1/V

1/V

16. The gas constant R has the unit

(a) L atm K 1 mol 1 (b) L atm1 K 1mol (c) atm cm3 K 1 mol 1 (d) erg K 1 mol 1

12. Energy of sublimation of solid helium is much lower than that of ice because
(a) A large part of sublimation energy of ice is used to overcome hydrogen bonding (b) Ice melts at much higher temperature (c) In solid helium, there is Vander Waals force of attraction between helium atoms (d) None is true

17. Which of the following statements is/are incorrect?

(a) The volume of a gas always increases when the temperature is increased (b) Equal volumes of gases under the same conditions of temperature and pressure contain the same number of molecules (c) The kinetic energy of a molecule is zero at 0 o C (d) A gas in a closed container exerts higher pressure at the bottom than at the top due to gravity

13. Which of the following are correct statements

(a) Vander Waal's constant a is a measure of attractive force (b) Vander Waal's constant b is also called co-volume or excluded volume (c) b is expressed in L mol 1 (d) a is expressed in atm L2 mol 2

14. Which of the following statements are incorrect

(a) Molar volume of every gas at STP is 22.4 L (b) Under critical states compressibility factor is 1 (c) All gases will have equal value of average KE at a given temperature (d) At absolute zero, KE is

18. A 5-L flask containing 1.0g of hydrogen is heated from 300K to 600K. Which of the following statements is/are correct
(a) The pressure of the gas increases (b) The rate of collision increases (c) The energy of the gaseous molecules increases (d) The number of moles of the gas increases

3 R 2

19. Which of the following is/are the characteristic / s of a real gas

(a) The molecules attract each other. (b) It shows deviations from the ideal gas law (c) It obeys the gas law at low temperature and high pressure (d) The mass of the molecules is negligible

23. If intermolecular forces vanishes among water molecules, then volume occupied by 1.8 g H 2O(l ) at
STP is (a) 2.24 litre (c) 1.8 mL
27 o C is

(b) 22.4 litre (d) 2.24 mL

24. The average kinetic energy of 1.6g CH 4 molecules at

(a) 6.21 10 15 erg (c) 6.21 10 15 calorie (b) 6.21 10 15 joule (d) None of these

20. The compressibility factor for an ideal gas is

(a) Unity at all temperatures (b) Unity at all pressures (c) Unity at the critical temperatures (d) Unity at Boyle temperature

25. The urms of SO2 at 27o C is

(a) 3.42 10 2 m sec 1 (c) 11.69 10 4 m sec 1 (b) 10.82 m sec 1 (d) None of these

Section : III Comprehension I Directions: Question 21 to 25 Answer these question with the help of the following passage.
The behaviour of gases has been expressed in terms of various gas laws obtained experimentally i.e., Boyles law, Charless law, Pressure-temperature law, Daltons law of partial pressure, Grahams law of diffusion and Avogadros hypothesis. Later on 1 Maxwell derived kinetic equation PV = mnu 2 , 3 theoretically by assuming the concept of molecules and their motion. The term u represents root mean square speed of molecule

Comprehension - II Directions: Question 26 to 30 Answer these question with the help of the following passage.
The ideal gas behaviour has been expressed in terms of ideal gas equation : PV = nRT. Since none of the gas in universe is ideal one and deviations are noticed from ideal gas nature. The deviations from ideal gas nature has been PV explained in terms of compressibility factor Z Z = . nRT Usually when Z > 1 repulsive forces among molecules predominates and when Z < 1 attraction forces predominates. However almost all the gases show ideal gas behaviour within Boyles temperature range. The numerical value of Z for 1 mole of gas at critical conditions 3 is . 8

21. For one mole of an ideal gas

26. The gas which always shows predominative repulsive forces

(a) He (c) Ar (b) Ne (d) Kr

P V V . . is equal to T V T P P T
(a)

R2

(b)

R2 P
2

27. The numerical value of Z for gases within Boyles temperature range is
(a) > 1 (c) = 1 (b) < 1 (d) > 1 <

(c) +1

(d) -1

22. The intercept of plots of log V vs log T curves at constant pressure P for 1 mole gas will be
(a) log

28. The compressibility factor for SO2 is 0.711, then

(a) SO2 is more compressible than ideal gas (b) SO2 is less compressible than ideal gas (c) SO2 is equally compressible (d) SO2 can not be compressed

P R

(b) log

P R

R (c) log P

R (d) log P

29. The numerical value of Z is greater than 1 for gases

usually at (a) Very high pressure (c) High temperature (b) Low pressure (d) None of these

Section V

Match the following columns. * In each of the following question two columns A, B, C, D and P, Q, R, S are given. You are supposed to write the correct choice (es) from the second column (P,Q,R,S) against A, B, C, D of the first column. Marks will be awarded for any if and only if all the correct options and no wrong option has been chosen. The expressions/ results in the first column are valid only under certain condition. List the appropriate condition from the second column.

30. The ratio of Z at Boyles temperature and at critical

conditions for 1 mole of a given gas is (a) 8/3 (c) 5/8 (b) 3/8 (d) 8/5

Section : IV

Write the answers of following question 31. For

the reaction,

N 2O5 (g) = 2 NO2 (g) + 0.5 O2 (g) ,

calculate the mole fraction of N 2O5 (g) decomposed at a constant volume and temperature, if the initial pressure is 600 mm Hg and the pressure at any time is 960 mm Hg. Assume ideal gas behaviour.

36. Match the following Column-I

(A)

Column-II
(P) Pressure

32. One mole of nitrogen gas at 0.8 atm takes 38S to

diffuse through a pinhole, whereas one mole of an unknown compound of xenon with flourine at 1.6 atm takes 57S to diffuse through the same hole. Calculate the molecular formula of the compound.

PV = constant, when T is a constant

(B) Rate of diffusion (Q) of a gas (C) Velocity of a gas (D) Vapour pressure of a liquid (R) (S)

Closed container

Temperature Molecular mass

33. The pressure exerted by 12 g of an ideal gas at

temperature t C in a vessel of volume V litre is one atm. When the temperature is increased by 10 degrees at the same volume, the pressure increases by 10%. Calculate the temperature t and volume V. (Molecular weight of the gas = 120.)
o

(a) (A) Q,S; (B) P,R; (C) P,Q,S; (D) P (b) (A) Q ; (B) P,R,S; (C) R,S; (D) R,Q (c) (A) P, R; (B) Q,R; (C) P,Q ; (D) P,Q (d) (A) P,Q,S; (B) P,R; (C) Q, (D) P,R,S

34. Calculate the pressure exerted by one mole of CO2

gas at 273 K if the Vander Waal's constant

a = 3.592 dm6 atm mol 2 . Assume that the volume

occupied by CO2 molecules is negligible.

37. Match the following Column-I

(A) Efficiency of tooth paste and mouth wash (P)

Column-II
Is the molar volume of the liquid at a temperature when its surface tension is in unity

35. The compression factor (compressibility factor) for one

mole of a Vander Waal's gas at 0 o C and 100 atmohpheric pressure is found to be 0.5. Assuming that the volume of a gas molecule is negligible, calculate the Vander Waal's constant a.

(B)

If n1 and n2 are number of drops of equal volume of two liquids of density D1 and D2 then

(Q)

The downward force due to the weight of water column equals the upward force exerted by surface tension Lower surface tension
surface tension 1 n2D1 = surface tension 2 n1D2

39. Match the following Column I

(A) Dalton's Law

Column II
(P)

V1 = V2

M1 M2

[at

constant temperature and pressure] (B) (C) (D) Dulong Petit's law Grahm's law Henry's law and (Q) (R) (T) At wt.sp. heat 6.4

(C) (D)

Parachore of a liquid The water rises upward when a capillary tube is inserted in water

(R) (S)

Pgas = X gas K H

PA = Mole fraction
Total pressure

(a) (A) P; (B) R; (C) P; (D) S (b) (A) Q; (B) S; (C) P; (D) R (c) (A) S; (B) Q, R; (C) S; (D) Q (d) (A) R; (B) S; (C) P; (D) Q

(a) (A) Q ; (B) P ; (C) R ; (D) S (b) (A) S ; (B) Q ; (C) P ; (D) R (c) (A) P ; (B) R ; (C) Q ; (D) S (d) (A) R ; (B) P ; (C) S ; (D) Q

38. Match the following Column I

(A) Root mean square velocity Most velocity probable

40. Match the following Column I Column II

(P) (A) (B) Excluded molar volume Higher the compressibility factor At Boyles temperature At extremely low pressure

Column II
(P) (Q)

Z =1 b

3 RT 2 8P d 3P d 2RT M

(B)

(Q)

(C) (D)

(R) (S)

(C)

Average velocity

(R)

All gases ideally Easy is the

behave

(D)

K.E. of gas mol1

(S)

liquification of gas (T) Difficult is the liquification of gas

(a) (A) S ; (B) R ; (C) P ; (D) Q (b) (A) Q ; (B) S ; (C) P ; (D) R (c) (A) P ; (B) Q ; (C) S ; (D) R (d) (A) R ; (B) S ; (C) Q ; (D) P

(a) (A) Q ; (B) T ; (C) P,R ; (D) P,R (b) (A) S,T ; (B) Q,R ; (C) P ; (D) R (c) (A) P ; (B) R,S ; (C) Q,T ; (D) S,T (d) (A) P,R ; (B) P,Q ; (C) S,T ; (D) Q,S