Beruflich Dokumente
Kultur Dokumente
Other Names
Centre Number
Candidate Number
Candidate Signature
9.00 am to 11.00 am
Instructions
Use blue or black ink or ball-point pen.
Fill in the boxes at the top of this page.
Answer all questions in Section A and Section B in the spaces
provided. All working must be shown.
Do all rough work in this book. Cross through any work you do not
want to be marked.
The Periodic Table/Data Sheet is provided on pages 3 and 4. Detach
this perforated sheet at the start of the examination.
Section B questions are provided on a perforated sheet. Detach this
sheet at the start of the examination.
Information
The maximum mark for this paper is 120.
Mark allocations are shown in brackets.
This paper carries 20 per cent of the total marks for Advanced Level.
You are expected to use a calculator where appropriate.
Your answers to the questions in Section B should be written in
continuous prose, where appropriate. You will be assessed on your
ability to use an appropriate form and style of writing, to organise
relevant information clearly and coherently, and to use specialist
vocabulary, where appropriate.
Mark
Question
Mark
3
4
5
6
7
8
Total (Column 1)
Total (Column 2)
TOTAL
Examiners Initials
Advice
You are advised to spend about 1 hour on Section A and about
1 hour on Section B.
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CHM5
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SECTION A
Answer all questions in the spaces provided.
1 Consider the incomplete BornHaber cycle and the table of data below.
Mg(s) + Cl2(g)
MgCl2(s)
Name of standard enthalpy
change
Substance to which
enthalpy change refers
Enthalpy of atomisation
Enthalpy of atomisation
Enthalpy of formation
First ionisation enthalpy
Electron affinity
Enthalpy of lattice formation
chlorine
magnesium
magnesium chloride
magnesium
chlorine
magnesium chloride
(a) Complete the Born-Haber cycle above by writing the appropriate chemical formulae,
with state symbols, on the dotted lines.
(4 marks)
(b) Use the cycle and the values given in the table to calculate the second ionisation
enthalpy of magnesium.
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(3 marks)
APW/Jun07/CHM5
APW/Jun07/CHM5
89
90 103 Actinides
Actinium
Ac
227
57
Lanthanum
La
138.9
39
Yttrium
88.9
21
Scandium
Sc
45.0
Lanthanides
88
* 58 71
87
Ra
Radium
Fr
223.0
Francium
56
226.0
55
Ba
Barium
132.9
Cs
38
137.3
37
Caesium
Sr
Strontium
Rb
85.5
Rubidium
20
87.6
19
Ca
Calcium
39.1
Potassium
12
40.1
11
Mg
Magnesium
Na
Sodium
24.3
23.0
Beryllium
Lithium
Be
9.0
II
72
Hafnium
Hf
178.5
40
Zirconium
Zr
91.2
22
Titanium
Ti
47.9
24
25
Tc
98.9
26
Ru
101.1
Iron
Fe
55.8
43
Nd
144.2
75
Rhenium
Re
186.2
44
Pm
144.9
76
Osmium
Os
190.2
Sm
150.4
77
Iridium
Ir
192.2
45
Rhodium
Rh
102.9
27
Cobalt
Co
58.9
Pa
Protactinium
Th
Thorium
91
231.0
232.0
92
Uranium
238.0
60
93
Neptunium
Np
237.0
61
94
Plutonium
Pu
239.1
62
Pr
140.9
74
Tungsten
183.9
42
Mo
95.9
59
90
Mn
54.9
Li
Lithium
6.9
Chromium Manganese
Cr
52.0
58
Cerium
Ce
140.1
73
Tantalum
Ta
180.9
41
Niobium
Nb
92.9
23
Vanadium
50.9
atomic number
Key
95
Americium
Am
243.1
63
Europium
Eu
152.0
78
Platinum
Pt
195.1
46
Palladium
Pd
106.4
28
Nickel
Ni
58.7
47
96
Curium
Cm
247.1
64
Gadolinium
Gd
157.3
79
Gold
Au
197.0
Silver
Ag
107.9
29
Copper
Cu
63.5
30
Al
Cf
252.1
66
Dysprosium
Dy
162.5
81
Thallium
Tl
204.4
49
Indium
In
114.8
31
Gallium
Ga
13
69.7
Aluminium
50
Es
(252)
67
Holmium
Ho
164.9
82
Lead
Pb
207.2
Tin
Sn
118.7
32
Germanium
Ge
14
72.6
Silicon
Si
28.1
Carbon
12.0
IV
97
98
99
Bk
247.1
65
Terbium
Tb
158.9
80
Mercury
Hg
200.6
48
Cadmium
Cd
112.4
Zinc
Zn
65.4
5
27.0
Boron
10.8
III
100
Fermium
Fm
(257)
68
Erbium
Er
167.3
83
Bismuth
Bi
209.0
51
Antimony
Sb
121.8
33
Arsenic
As
15
74.9
Phosphorus
31.0
Nitrogen
14.0
The atomic numbers and approximate relative atomic masses shown in the table are for use in the examination unless stated
otherwise in an individual question.
Li
1
6.9
Hydrogen
1.0
101
Mendelevium
Md
(258)
69
Thulium
Tm
168.9
84
Polonium
Po
210.0
52
Tellurium
Te
127.6
34
Selenium
Se
16
79.0
Sulphur
32.1
Oxygen
16.0
VI
102
Nobelium
No
(259)
70
Ytterbium
Yb
173.0
85
Astatine
At
210.0
53
Iodine
126.9
35
Bromine
Br
17
79.9
Chlorine
Cl
35.5
Fluorine
19.0
VII
He
10
103
Lawrencium
Lr
(260)
71
Lutetium
Lu
175.0
86
Radon
Rn
222.0
54
Xenon
Xe
131.3
36
Krypton
Kr
18
83.8
Argon
Ar
39.9
Neon
Ne
2
20.2
Helium
4.0
Table 1
Proton n.m.r chemical shift data
Type of proton
/ppm
RCH3
0.71.2
R2CH2
1.21.4
R3CH
1.41.6
RCOCH3
2.12.6
ROCH3
3.13.9
RCOOCH3
3.74.1
ROH
0.55.0
Table 2
Infra-red absorption data
APW/Jun07/CHM5
Bond
Wavenumber/cm1
CH
28503300
CC
7501100
16201680
16801750
CO
10001300
OH (alcohols)
32303550
OH (acids)
25003000
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(c) The standard enthalpies of hydration of the Mg2+ and the Cl ions are 1920 kJ mol1
and 364 kJ mol1, respectively. Use this information and data from the table in part (a)
to calculate the enthalpy of solution of magnesium chloride.
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(3 marks)
(d) The standard enthalpy of solution of ammonium chloride, NH+4Cl, is +15 kJ mol1.
(i) Explain why ammonium chloride dissolves spontaneously in water even though
this process is endothermic.
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(2 marks)
(ii) A 2.0 g sample of ammonium chloride is dissolved in 50 g of water. Both
substances are initially at 20 C.
Calculate the temperature change and the final temperature of the solution.
Assume that the specific heat capacity of the solution is 4.2 J K1 g1.
Temperature change .................................................................................................
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Final temperature of solution ...................................................................................
(5 marks)
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2 Data for the following reaction, which represents the reduction of aluminium oxide by
carbon, are shown in the table below.
Al2O3(s) + 3C(s) 2Al(s) + 3CO(g)
Substance
Hf / kJ mol1
S / J K1 mol1
Al2O3(s)
1669
51
C(s)
Al(s)
28
CO(g)
111
198
(a) Calculate the values of H , S and G for the above reaction at 298 K and
suggest why this reaction is not feasible at 298 K.
H .....................................................................................................................................
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S ......................................................................................................................................
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G .....................................................................................................................................
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Reason why this reaction is not feasible at 298 K .............................................................
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(8 marks)
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+ 0.77
Cr3+(aq) + e Cr2+(aq)
0.41
Fe2+(aq) + 2e Fe(s)
0.44
Zn2+(aq) + 2e Zn(s)
0.76
Cr2+(aq) + 2e Cr(s)
0.91
(a) Predict the products, if any, when the following substances are mixed. In each case
use E values from the table to explain your answer.
(i) iron metal with aqueous zinc(II) ions
Products, if any .........................................................................................................
Explanation ..............................................................................................................
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(ii) aqueous iron(III) ions with aqueous chromium(II) ions
Products, if any .........................................................................................................
Explanation ..............................................................................................................
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(5 marks)
(b) Calculate the e.m.f. of the following standard cell and deduce an equation for the
overall cell reaction.
Zn(s)|Zn2+(aq)||Cr3+(aq),Cr2+(aq)|Pt
e.m.f. ...................................................................................................................................
Equation .............................................................................................................................
(2 marks)
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(c) Chromium(III) ions are weakly acidic in aqueous solution as shown by the following
equation.
[Cr(H2O)6]3+(aq)
[Cr(H2O)5(OH)]2+(aq) + H+(aq)
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(i) Name the main type of bonding in each of the oxides MgO and P4O10
Bonding in MgO .......................................................................................................
Bonding in P4O10 .....................................................................................................
(ii) Explain how the type of bonding in P4O10 can be predicted by a consideration of
electronegativity.
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(3 marks)
(d) Write equations for the reaction of Na2O and of SO2 with water.
Equation for Na2O .............................................................................................................
Equation for SO2 ................................................................................................................
(2 marks)
(e) Write an equation for the reaction of MgO with dilute hydrochloric acid.
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(1 mark)
(f) Write an equation for the reaction of P4O10 with an excess of aqueous sodium
hydroxide.
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(1 mark)
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SECTION B
Detach this perforated sheet.
Answer all questions in the spaces provided on pages 13 to 20 of this booklet.
(a) Explain why the ester methyl ethanoate has a lower boiling point than its isomer,
propanoic acid.
(2 marks)
(b) A polyester is formed when ethane-1,2-diol reacts with butanedioic acid. Draw the
structure of the repeating unit of this polymer.
Suggest why this polyester begins to melt at a higher temperature than poly(ethene)
which has molecules of a similar size to those in the polyester.
(4 marks)
(c) Outline a mechanism for the formation of an ester by the reaction between ethanoyl
chloride and an alcohol.
(4 marks)
(d) The ester ethyl ethanoate is hydrolysed when it is heated with water in the presence of
an acid catalyst. An equilibrium is established.
CH3COOCH2CH3(l) + H2O(l)
CH3COOH(l) + CH3CH2OH(l)
A 0.50 mol sample of ethyl ethanoate was heated with 4.0 mol of water. At equilibrium,
70 % of the ester was hydrolysed. Calculate a value of Kc for this reaction. (5 marks)
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Reaction 2
BrCH2CH2Br
H2NCH2CH2NH2
(a) Suggest a reagent for Reaction 1. Name and outline a mechanism for this reaction.
(5 marks)
(b) Suggest a reagent for Reaction 2. Name the type of mechanism involved and write an
equation for the overall reaction.
(3 marks)
(c) Draw the structure of the complex ion formed when aqueous cobalt(II) ions react with
an excess of ethane-1,2-diamine.
(2 marks)
(d) Ethane-1,2-diamine can be converted into the EDTA4 ion shown below.
OOCCH2
CH2COO
NCH2CH2N
OOCCH2
CH2COO
(a) The compounds CH3CH2Cl and CH3CHCl2 can be distinguished by comparing their
proton n.m.r. spectra.
For each compound, describe its proton n.m.r. spectrum by giving the number of
peaks, the integration ratio and the splitting patterns.
(6 marks)
(b) The following pairs of compounds can be distinguished using the reagents indicated.
Each compound is in a separate aqueous solution. For each one of the compounds,
describe what you would observe and write equations for any reactions that occur.
(i) KBr and KI using chlorine water
(ii) BaCl2 and MgCl2 using dilute sulphuric acid
(iii) CoCl2 and CuCl2 using concentrated hydrochloric acid
(9 marks)
END OF QUESTIONS
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