Beruflich Dokumente
Kultur Dokumente
K
+
BO
3
3
Mg
2+
Ca
2+
Mn
2+
Ni
2+
3000
3000
3000
3000
200
200
200
200
citrate
oxalate
tartarate
Al
3+
Cd
2+
Ba
2+
Co
2+
Zn
2+
500
500
500
500
500
500
500
500
Cu
2+
*
Ce
4+
*
Fe
3+
*
Sn
2+
*
Pb
2+
*
Hg
2+
*
W
6+
*
Mo
6+
*
25
25
25
25
25
25
25
25
* Masked by masking agent
TABLE 2.5B: EFFECT OF DIVERSE IONS ON THE DETERMINATION OF
CHROMIUM (3 gmL
1
) USING DNPH - u-NAPHTHOL REAGENTS
Diverse
ions
Tolerance
limit(gmL
1
)
Diverse
ions
Tolerance
limit(gmL
1
)
Diverse
ions
Tolerance
limit(gmL
1
)
K
+
BO
3
3
Na
+
CHCOO
tartarate
citrate
oxalate
Ba
2+
2500
2500
2500
2500
2500
2500
2500
500
Co
2+
Zn
2+
Al
3+
Cd
2+
Mn
2+
Ni
2+
Mg
2+
Ca
2+
500
500
100
100
100
100
100
100
Sn
2+
*
Pb
2+
*
W
6+
*
Mo
6+
*
Hg
2+
*
Cu
2+
*
Ce
4+
*
Fe
3+
*
50
50
50
50
50
50
50
50
* Masked by masking agent
TABLE 2.5C: EFFECT OF DIVERSE IONS ON THE DETERMINATION OF
CHROMIUM (3 gmL
1
) USING DNPH-PYROCATECHOL REAGENTS
Diverse
ions
Tolerance
Limit(gmL
1
)
Diverse
ions
Tolerance
limit(gmL
1
)
Diverse
ions
Tolerance
limit(gmL
1
)
Na
+
K
+
CHCOO
Citrate
Oxalate
Tartarate
BO
3
3
Al
3+
> 3000
> 3000
> 3000
> 3000
> 3000
2500
1000
500
Cd
2+
Ba
2+
Co
2+
Zn
2+
Mg
2+
Ca
2+
Mn
2+
Ni
2+
500
500
500
500
300
300
300
300
Sn
2+
*
Pb
2+
*
Fe
3+
*
W
6+
*
Mo
6+
*
Cu
2+
*
Ce
4+
*
Hg
2+
*
50
50
50
50
50
20
20
50
* Masked by masking agent
TABLE 2.5D: EFFECT OF DIVERSE IONS ON THE DETERMINATION OF
CHROMIUM (2 gmL
1
) USING DNPH-NEDA REAGENTS
Diverse
ions
Tolerance
limit(gmL
1
)
Diverse
ions
Tolerance
limit(gmL
1
)
Diverse
ions
Tolerance
limit(gmL
1
)
Na
+
K
+
CHCOO
citrate
oxalate
tartarate
BO
3
3
> 3000
> 3000
> 3000
> 3000
> 3000
> 3000
2000
SO
4
2
Al
3+
Cd
2+
Ba
2+
Co
2+
Zn
2+
Mg
2+
1000
800
800
800
500
500
200
Ca
2+
Mn
2+
Ni
2+
Cu
2+
*
Ce
4+
*
Hg
2+
*
200
200
200
25
25
25
* Masked by masking agent
FIGURE II.1A: ABSORPTION SPECTRA OF AZO DYES: DNPH-
-NAPHTHOL COUPLE VS REAGENT BLANK (a), DNPH- u-NAPHTHOL
COUPLE VS REAGENT BLANK (b) AND REAGENT BLANK VS DISTILLED
WATER (c)
FIGURE II.1B: ABSORPTION SPECTRA OF AZO DYES: DNPH- NEDA VS
REAGENT BLANK (a), DNPH- PYROCATECHOL COUPLE VS REAGENT
BLANK (b) AND VS REAGENT BLANK VS DISTILLED WATER (c)
FIGURE II.2A: ADHERENCE TO BEERS LAW FOR THE DETERMINATION
OF CHROMIUM USING DNPH- -NAPHTHOL REAGENTS
FIGURE II.2B: ADHERENCE TO BEERS LAW FOR THE DETERMINATION
OF CHROMIUM USING DNPH- u -NAPHTHOL REAGENTS
FIGURE II.2C: ADHERENCE TO BEERS LAW FOR THE DETERMINATION
OF CHROMIUM USING DNPH- PYROCATECHOL REAGENTS
FIGURE II.2D: ADHERENCE TO BEERS LAW FOR THE DETERMINATION
OF CHROMIUM USING DNPH- NEDA REAGENTS
REACTION SCHEMES 2.1
O
2
N
NH
NH
2
NO
2
+
Cr
2
O
7
2- O
2
N
N
+
N
NO
2
+
Cr(III) + H
2
O
O
2
N
N
+
N
NO
2
+
OH
OH
-
O
2
N
N
N
NO
2
O H
O
2
N
N
+
N
NO
2
OH
O
2
N
N
N
NO
2
OH
+
OH
-
Cl H
Cl
-
Cl
-
Cl
-
O
2
N
N
+
N
NO
2
+
NH
NH
2
O H
-
O
2
N
N
+
N
NO
2
OH
OH
O
2
N
N
N
NO
2
OH
OH
+
O H
-
O
2
N
N
N
NO
2
NH
NH
2
Cl
-
Cl
-
2HCl
2.9 REFERENCES
1. M. J. Udy, History of Chromium, Reinhold, New York, (1956).
2. R. Chadwick, New Extraction Processes for Metals, Oxford University
Press, London. (1958).
3. F. E. Bacon, Chromium and Chromium Alloys, p. 451; W. H. Hartford and
R. L. Copson, Chromium Compounds, p. 473; Encyclopedia of Chemical
Technology, Interscience, New York, 2
nd
Edn., (1964).
4. V. Bencko, J. Hyg. Epidemiol Microbiol Immunol, 29 (1985) 37.
5. M.D. Cohen, B. Kargacin, C.B. Klein and M. Costa. Crit. Rev. Toxicol, 23
(1993) 255.
6. L. Teleky, Dtsch. Med. Wochenschr, 62 (1936) 1353.
7. S. Langard and T. Vigander, Br. J. Ind. Med., 40 (1983) 71.
8. K. Satoh, Y. Fukuda, K. Torii, M. Eng and N. Katsuno, J. Occup. Med., 23
(1981) 835.
9. E. Lindberg and G. Hedenstierna. Arch. Environ. Health, 38 (1983) 367.
10. A. A. Fisher. Cutis, 18 (1976) 21.
11. M. C. Udy, Physical Properties of Chromium, its Alloys and Metallurgical
use in Chromium, Reinhold, New York. (1956).
12. W. Mertz and K. Schwarz, Arch. Biochem. Biophys., 58 (1955) 504.
13. W. Mertz, Physiol. Reviews, 49 (1969) 163.
14. Agency for Toxic Substances and Disease Control. ATSDRs Toxicological
Profiles: Chromium. Boca Raton, Florida: Lewis Publishers, CRC Press, Inc.,
(1997).
15. A. Zhitkovich, V. Voitkun and M. Costa, Biochem., 35 (1996) 7275.
16. W. Mertz, Nutr. Rev., 33 (1975) 129.
17. R. H. Rosen and S. Freeman, Contact Dermatitis, 29 (1993) 88.
18. J. Vertick, and R. Cornelis, Anal. Chim. Acta, 116 (1980) 217.
19. J.M. Eckert, R.J. Judd, P.A. Lay and A.D. Symons, Anal. Chim. Acta, 255
(1991) 31.
20. M. Kamburova, Talanta, 40 (1993) 713.
21. S. Harita, Y. Umezaki and M. Ikeda, Anal. Chem, 58 (1986) 2602.
22. R. R. Greenberg, R. Zeisler, H. M. Kingston and T.M. Sullivan, Fresenius J.
Anal. Chem., 332 (1988) 652.
23. R. E. Shaffer, J. O. Cross, S. L. Rose-Pehrsson and W. T. Elam, Anal. Chim.
Acta, 442 (2001) 295.
24. C. M. Davidson, R. P. Thomas, S. E. McVey, R. Perala, D. Littlejohn and
A. M. Ure, Anal. Chim. Acta, 291 (1994) 277.
25. G. H. Jeffery, J. Bassett, J. Mendham, and R. C. Denney, A. I. Vogel, A
Textbook of Quantitative Inorganic Analysis, 5
th
Edn., Longmans, (1989).
26. Q. Wei, C. Duan, J. Wang, H. Ma and B. Du, Annali di Chimica, 96 (2006)
451.
27. M. Kaneko, M. Kurihara, S. Nakano and T. Kawashima, Anal. Chim. Acta,
474 (2002) 167.
28. Y. Luo, S. Nakano, D.A. Holman, J. Ruzicka and G.D. Christian, Talanta 44
(1997) 1563.
29. W. Jianya and X. Bin, Anal. Sci., 22 (2006) 1233.
30. Y. Xiang, L. Mei, N. Li and A. Tong, Anal. Chim. Acta, 581 (2007) 132.
31. U. Divrikli, M. Soylak and L. Elci, Environ. Monit. Assess., 138 (2008) 167.
32. H. J. Cahnmann and B. Ruth, Anal. Chem., 24 (1952) 1341.
33. D. O. Miller. Dwight and J. H. Yoe, Clin. Chim. Acta, 4 (1959) 378.
34. K. Motojima and H. Hashitani, Anal. Chem., 33 (1961) 239.
35. N. Todorovska, I. Karadjova, S. Arpadjan and T. Stafilov, Cent. Eur. J. Chem.,
5 (2007) 230.
36. R. M. Cespon and M.C. Yebra, Microchim. Acta, (2008) DOI 10.1007/s00604-
007-0916-7.
37. S. Hoshi, K. Konuma, K. Sugawara, M. Uto and K. Akatsuk, Talanta, 47
(1998) 659.
38. H. D. Revanasiddappa and T. N. Kiran Kumar, Talanta 60 (2003) 1.
39. B. Narayana and T. Cherian, J. Braz. Chem. Soc., 16 (2005) 197.
40. B. Narayana and T. Cherian, Oxid. Commun., 28 (2005) 923.
41. K. L. Cheng, Talanta, 14 (1967) 875.
42. A. A. Mohamed and M. F. El-Shahat, Anal. Sci., 16 (2000) 151.
43. K. Girish Kumar and R. Muthuselvi, J. Anal. Chem., 61 (2006) 28.
44. M. A. Zaitoun, Intern. J. Environ. Anal. Chem. 85 (2005) 399.
45. L. S. de Carvalho, A. C. S. Costa, S. L. C. Ferreira and L. S. G. Teixeira, J.
Braz. Chem. Soc., 15 (2004) 153.
46. G. den-Boef and B. C. Poeder, Anal. Chim. Acta, 30 (1964) 261.
47. U. Katsuya and K. Yukiteru, Bull. Chem. Soc. Japan, 38 (1965) 2010.
48. E. Jacobsen and W. Lund, Anal. Chim. Acta, 36 (1966) 135.
49. J. R. Johnston and W. J. Holland, Microchim. Acta, 60 (1972) 321.
50. T. Yotsuyanagi, Y. Takeda, R. Yamashita and K. Aomura, Anal. Chim. Acta,
67 (1973) 297.
51. H. S. Gowda and J. B. Raj, J. Indian Chem. Soc., 59 (1982) 1398.
52. G. H. Rizvi, B. P. Gupta and R. P. Singh, Microchim. Acta, 60 (1972) 459.
53. R. K Hussain and R. D. Venkata, Analyst, 108 (1983) 1247.
54. P. Nagaraj, N. Aradhana, A. Shivakumar, A. K. Shrestha and A. Gowda,
Environ.Monit. and Assess., (2008) DOI: 10.1007/s10661-008-0557-2
55. P. Ram, B. Reeta, K. Ajit and S. K. Rehani, Talanta, 38 (1991) 1163.
56. D. T. Burns, M. Harriott and S. A. Barakat, Anal. Chem. Acta, 259 (1992) 33.
57. F. A. S. Fabiyi, and A. Z. Donnio, Synth. Reactivity Inorg. Met-Org. Nano-
Met. Chem., 37 (2007) 809.
58. M. Kamburova, Talanta, 40 (1993) 707.
59. M. Kamburova, Talanta, 40 (1993) 713.
60. M. Kamburova, Chem. Anal, (Warsaw), 38 (1993) 189.
61. S. Yoshiaki, T. Shoji, M. Yoshiko and N. Hiroaki, Anal Sci., 10 (1994) 71.
62. S. P. Arya and B. Anvita, Fresenious J. Anal. Chem., 348 (1994) 772.
63. J. B. Raj and H. S. Gowda, Analyst, 120 (1995) 1815.
64. A. Rosa, M. Hector and O. Roberto, Anal. Sci., 11 (1995) 431.
65. V. Maheswari and N. Balasubramanian, Chem. Anal., (Warsaw), 41 (1996)
569.
66. S. Ressalan, R. S. Chauhan, A. K.Goswami and D. N. Purohit, Asian J. Chem.,
10 (1998) 1004.
67. S. Ressalan, R. S. Chauhan, A. K.Goswami and D. N. Purohit, Oriental J.
Chem., 14 (1998) 345.
68. M. B. Melwanki and J. Seetharamappa, Indian J. Environ. Protection, 20
(2000) 801.
69. M. B. Melwanki and J. Seetharamappa, Indian J. Chem., 40A (2001) 659.
70. H. D. Revanasiddappa and T. N. Kiran Kumar, Chem. Anal. (Warsaw), 47
(2002) 311.
71. L. M. Lourenco, F. G. Martins, V. R. Balbo, A. C. Pimenta, J. R. M. Castro
and J. F. Andrade, Ecl. Quim., 31 (2006) 31.
72. H. D. Revanasiddappa and T. N. Kiran Kumar, J. Anal. Chem., 56 (2001)
1084.
73. T. Cherian and B Narayana, Indian J. Chem. Tech., 12 (2005) 596.
74. P. K. Tarafder, S. B. Singh and D. P. S, Rathore, Fresenius' J. Anal. Chem.,
354 (1996) 124.