1. The live organism is: // a closed system. // + open system. // an isolated system. // homogeneous system. // heterogeneous system.

*** 2. The first law of thermodynamics: // + expresses the indestructibility and the equivalence of different forms of energy in the mutual transformation. // indicates the direction of spontaneous ongoing process. // allows calculating the change in free energy for this process. // determine the conditions for chemical equilibrium. // indicates spontaneous process. *** 3. Possibility of spontaneous flow of the process is determined by the value of G. For what value of G process spontaneously possible: // + G <O. // G = O. // G> O. // G = H. // G O. *** 4. The closed ampoule represents:// + the closed system.// open system.// the isolated system.// homogeneous system.// heterogeneous system. *** 5. Process assimilation in the body of sucrose can be written in the form of the equation of thermo-chemical oxidation: S12N22O11 (K) + 11O2 (D) 12 CO 2 (r) + 11N2O (M), H = - 5650,69 kJ / mol. Based on the values of H make output: // + exothermic reaction . // endothermic reaction. // H does not determine the thermal effect. // exothermic and endothermic reaction. // proceeds with the absorption of energy. *** 6. A thermos is: // a closed system. // open system. // + isolated system . // a homogeneous system. // heterogeneous system. *** 7. To functions of a condition of system carry://

temperature and pressure. // concentration and mass. // + enthalpy and entropy . // pressure and volume. // concentration and volume. *** 8.Entropiya increases with: // + increase of temperature . // decreasing of temperature. // decreasing of concentration.// reducing the volume. // increasing of pressure. *** 9. Enthalpy (order) increases: // the melting of the ice. // the decomposition of complex substances into simple substances. // during the transition from liquid to gaseous state. // + in the transition from liquid to solid state . // during the formation of simple substances complex substances. *** 10. Mathematical expression of the first law of thermodynamics (process isobar):// Q = U + V. // +Q = . // Q = U - V.// U = Q + .// Q = U. *** 11. By what formula can calculate the thermal effect of chemical reaction on the tabulated data in the heats of formation: // + . . = 0298 - 0298 .
Reaction initial

. .

product 0298 initial

substances .// 0298. reaction product// 0 298.

. .

substances 0298 + Reaction

initial

. .

product 0298 initial substances

substances

//
0 298.

reaction product//

. .

0 298 initial

298.

reaction product

substances ***

12. The mathematical expression of the second law of thermodynamics: // +G = H S .//

G = H.// Q = U + V. // G = H + S.// Q = U. *** 13. The reaction of the hydrolytic cleavage adenosine triphosphate (ATP) leads to the formation adenozindifosfornoy acid (ADP) with allocation of 29.3 kJ \ mol. Thermochemical equation for this reaction is of the form: // + ATP + H 2O ADP + phosphate ions; H = -29, 3 kJ /mol .// H does not characterize the thermal effect of reaction. // ATP hydrolysis is not associated with the release of energy. // ATP + H 2O ADP + phosphate; H = 29 3 kJ \ mol. // ATP + H 2O ADP; H = 29 3 kJ/mol. *** 14. Entropiya (S) is: // the degree of ordering system. // heat of reaction. // the equilibrium condition of the system. // + degree of disorder the system . // motion of particles. *** 15. Standard state in thermodynamics implies: // + 25, with the temperature (298o C), gas pressure 1 atm .// the temperature of 273o C, any pressure gas. // gas pressure is 1 atmosphere, any temperature. // temperature of 273 K. // temperature of 273 K, NU gas. *** 16. Free energy (Gibbs energy) can be calculated based on the known values of enthalpy (delta entropy (delta S) and temperature of the formula:// + G = H - T S// G = H. // Q = U + p V. // G = H + T S. // Q = U. *** 17. Without performing calculations, determine the sign of entropy change in the reaction: 2H2 (D) + O2 (G) = 2 H2O (M) // +entropy decreases . // entropy increases. // +decreases and increases. // the entropy does not change. // the entropy remains constant. ***

18. Deacreases or increases the entropy in the transition of water vapor in the ice:// entropy increases. // the entropy does not change. // +entropy decreases. // may increase and decrease. // the entropy remains constant *** 19. What is a sign of equilibrium system: // +G = 0. // G <0. // G> 0. // H0 = 0. // Q = H. *** 20. Direction of spontaneous processes: // +reduction in energy. // increase in the order. // decrease of disorder. // increase in internal energy. // increase in the Gibbs energy. *** 21.In the process of melting: // increases the internal energy. // decreases mess. // increases the order. // + increasing disorder. // increase in the Gibbs energy. *** 22. Direction of spontaneous processes: // from the simple to the complex. // from cold to hot. // +from hot to cold . // to increase order and reduce the clutter. // from the complex to the simple. *** 23. Velocity of chemical reactions - is: / / interest in the way a unit of time. / / the time during which the substance would react to the end. / / +concentrations of the reactants in unit of time . / / the path traversed per unit time. / / temperature change.

*** 24. Velocity of chemical reactions depends: // only on the concentration of the reactants. // only on the nature of the reactants. // + on many factors: the nature of the reactants, reagent concentration, process temperature, the presence of catalysts .// grinding, pH. // on the pressure. *** 25. General wording of influence of concentration on the rate of chemical reactions gives:// Law Avagadro. // the law of equivalents. // +the law of mass action Guldberg-Waage . // Henry's Law. // Law Ostwald. *** 26.Activation energy - is: // the average energy of molecules. // temperature at which the reaction. // +is the energy that is necessary for turning the average molecule in the active . // Reaction temperature. // pressure reaction. *** 27.Influence of temperature on the rate of chemical reaction formulates: // +rule van't Hoff . // the law of mass action. // the law of equivalents. // Law Avagadro. // Henry's Law. *** 28. Increasing of velocity of catalyzed reaction is related: // with a greater activation energy of the new way of reaction. // +with a lower activation energy of the new way of reaction. // effect of catalysts is not related to the energy of activators.// with increasing velocity of the molecules. // with increasing energy. *** 29. Enzyme - is: // +biological catalysts of protein nature. // non-organic catalysts.//

steroid hormones. // inhibitors. // promoters *** 30. Opportunity of rapid digestion of the products in living organisms at relatively low temperature (370 C) is carried out through: // + cells in the presence of specific biological catalysts-enzymes . // the presence of hydrochloric acid of gastric juice. // a constant pH of the blood. // effects of vitamin. // inorganic catalysts. *** 31. According to the mass action law, rate of a chemical change in a gaseous fluid or solution: // It is enlarged in 2-4 times at rise in temperature on 100 // Depends on presence of accelerators // + Proportional to product of concentration of reactants . // It is enlarged in 4-8 times at rise in temperature on 100 C // It is enlarged concentrations of reactants *** 32. Molecularity of reactions is determined: // On applicability to them of those or other forms of the equations of kinetics of reactions // + By the number of the molecules which have entered chemical interaction in the elementary act of reaction. // Molarities of reactants // Number of the molecules forming during reaction // Number of molecules, dissociated during reaction *** 33. Define molecularity of reaction of thermal decomposition of vapours of Aether : // 3- 3 4+ 2+ + Monomolecular reaction. // A termomolecular reaction // Polymolecular // Bimolecular // Quinquemolecular *** Order of reaction is determined by : // Number of the molecules entering chemical interaction in The elementary act of reaction // +No applicability to them of those or other forms of the equations of kinetics, as the sum of degrees of concentration. // On temperature of a reaction mixture // Number of the molecules forming during reaction *** 35. Equation of Michaelis-Menthon has view: //

__ [S] ___ + V = VMAX KM + [S] .// __ Vmax __ V = KS + [S] // V = KS + [S] // + [S] V = Vmax // __ S max __ V = KS + [V] *** 36. In what direction there will be a shift of equilibrium 2 4++ if in system enter some ions of +?: // +To the side of reverse reaction . // A forward reaction // Equilibrium does not shift // Aside thermo positive // Aside thermo negative *** 37. An equilibrium constant of a homogeneous system CO (g) + 2 (g) (g) + 2 (g) It is expressed by the equation like: // [CO] [H2] K eq. = [CO2] [H2] //
KS

24 ,

[CO2] [H2] + eq. = [CO] [H2O] . // K EQ. = [CO] [H2O] // K EQ. = [CO2] [H2O] // K EQ. = [CO2] / [H2O] *** 38. The equation 2 / 1 = t2 - t2/10 corresponds: // To the Oswalds law of dilution // To Vander-Vails law // To the Henry's law // + To the Vann-Goff law. // To Avogadros law *** 39. An equilibrium constant reflecting process of a dissociation of weak electrolyte, is called // A constant of fastness // A kinetic constant // + A constant of dissociations. // A constant of instability //

A constant of resistance *** 40. Heat-absorbing reaction of decomposing pentachloride phosphorus runs on the equation: PCl5 (g) PCl3 (g) + Cl2 (g); H = + 92 kJ. How decrease of pressure in system will affect? // In the revertive side {party} // + Equilibrium shifts to the right. // Equilibrium shifts to the left // The side of heat-absorbing reaction // The side of exothermal reaction *** 41. The temperature coefficient of rate of a chemical change is peer 3. As the speed of response will change at warming a reaction mixture on 300C: // Will increase in 3 times // Will increase in 9 times // +Will increase in 27 times. // Will decrease in 3 times // Will decrease in 9 times *** 42. As the augmentation of pressure at an equilibrium chemical admixture will affect 2 NO (g) + O 2 ( ) 2 NO2 (g): // Results in augmentation of temperature // Equilibrium shifts to the right. // +Equilibrium shifts to the left // Results in decrease of temperature // Equilibrium does not shift *** 43. The temperature coefficient of rate of a chemical change is peer 2. As the speed of response will change at warming a reaction mixture on 400C: // Will increase in 3 times // Will increase in 9 times // Will increase in 27 times // +Will increase 16 times. // 3 times will decrease *** 44. For what from reactions which schemas are given below, build-up of pressure will not affect shift of equilibrium?: // CaCO3 CaO + CO2 // 2H2 + O2 2H2O // N2 +3H2 2NH3 // + CO + H2O CO2 + H2. // CaO + CO2 CaCO3 *** 46. Reduction of concentration of one of reacting substances in equilibrium system leads to balance displacement in side: // reactions of an expenditure of this substance. //

+the reaction going with absorption of heat. // the reaction going with reduction of number of molecules of gas. // reactions of formations of this substance //. the reaction going with increase of number of molecules of gas *** 47. The pressure increase, in equilibrium system of a containing molecule of gases, results balance displacement in side: // the reaction going with increase of number of molecules of gas. // the reaction going with absorption of heat. // + reactions, going with reduction of number of molecules of gas . // the reaction going with allocation of heat. // the reaction going with increase pressure. *** 48. Pressure reduction, in equilibrium system of a containing molecule of gases, results balance displacement in side:// +reactions, going with increase in number of molecules of gas. // the reaction going with absorption of heat. // the reaction going with reduction of number of molecules of gas. // reactions of formation of reacting substances. // the reaction going with increase pressure. *** 49. Percentage concentration shows: // the quantity of moles substances contains in 1 liter of a solution. // the quantity of moles substances contains in 100 ml of a solution. // the quantity of grammas of substance contains in 1litre of a solution. // +the quantity substance grammas contains in 100 grammas of a solution . // the quantity of moles substances contains in 1000 ml of a solution. *** 50. Molar concentration shows: // +quantity of moles substances contains in 1litre of a solution. // the quantity moles substances contains in 100 ml of a solution. // the quantity of grammas of substance contains in 1litre of a solution. // the quantity of grammas of substance contains in 100 grammas of a solution. // the quantity of grammas of substance contains in 1000 grammas of a solution. *** 51. Molar concentration of an equivalent shows: // + how much grammar the substance equivalent contains in 1 litre of a solution . // how many moles substances contains in 100 ml of a solution. // how many moles substances contains in 100 g. A solution. // how many substance grammas contain in 1 litre of a solution. // how many moles substances contains in 1000 g. A solution. *** 52. Interaction of ions of the dissolved salt with protons or hydroxylic groups neutral (non- dissociated) water molecules are called: // coagulation. // a dialysis. // + hydrolytic decomposition . //

peptization. // neutralisations . *** 53. To 240 grammas 15 %-s' solutions of sulphate have added 60 grammas of water. A sulphate mass fraction of potassium in the received solution composes: // +12 % . // 11 %.// 13 %.// 14 %.// 10 %. *** 54. From 400g 50 % of a solution (on weight) solution 2SO4 evaporation have removed 100g waters. A mass fraction of sulfuric acid in the remained solution equal:// 50 %.// +66, 6 %. // 40 %.// 30 %.// 20 %. *** 55. For reception 1 a solution of sulfuric acid in volume of 1 l it is necessary to take the following weight of sulfuric acids: // + 98g //. 49g. // 100g. // 10g. // 0,98g. *** 56. In 100 ml 0,1n a solution of sulfuric acid contains this acid: // 0,17g. // 0,81g. // 0,98g. // + 0,49g // 49g. *** 57. To find weight of nitrate of the sodium, 300 ml necessary for preparation 0,2 solution// + 5,1g . // 51g// 2,65. // 26,5g. // 25g. *** 58. In 100 ml 0,1n a solution of sulfuric acid contains this acid: // 0,17g. // 0,81g. // 0,98g. //

+ 0,49g . // 49g. *** 59. To find weight of nitrate of the sodium, 300 ml necessary for preparation 0,2 solution. // + 5,1g . // 51g. // 2,65g. // 26,5g. // 25g. *** 60 How many grammas of sulphate of sodium is required for preparation 5 8 % of the solution (the solution density is equal to 1,075g/ml)?// 0,43g. // 400g. // + 430g . // 4,3g. // 0,4g. *** 59. To find weight (g) the glucose, necessary for preparation 900 12 %-s' of solution: // 54g. // 105g. // + 108g //. 81g//. 0,81g. *** 60.5 % a physiological solution of glucose prepares: // + from 5g glucose and 95g waters . // from 15g glucose and 95g waters. // from 5g glucose and 100g waters. // from 5g glucose and 95g a solution. // from 95g glucose and 5g waters. *** 61. In HNO3 oxidation of nitrogen is equal to: // -5. // + +5.// +3.// +4.// -3. *** 62. To oxidation belongs the following process: // MnO4- Mn +2.// MnO4- MnO2.// MnO4- MnO2.// + Mn0 MnO- .// MnO4-2 Mn +7.

*** 63. Acid on the theory Barnstead - Lowry is the connection: // dissociation into hydrogen cathion and anion balance of acid.// which has a hydrogen atom. // which has a hydrogen molecule. // + having the ability to give protons .// acceptor. *** 64. According to the theory of Barnstead -Lowry base is: // NH4 +.// H3O +.// H2S.// + NH3.// OH-. *** 65. Connection of sulfur, which shows only oxidizing properties: // + sulfuric acid . // free sulfur. // sulfurous acid .// hydrogen sulfide. // oxide, sulfur. *** 66. Connection of sulfur, which shows only reducing properties: // sulfuric acid// sulfur oxides (IV).// sulfurous acid.// + hydrogen sulfide.// sulfur *** 67. Connection of sulfur, which shows oxidation and reduction properties: // sulfuric acid.// hydrogen sulfide.// sulfur oxides (VI).// + sulfurous acid .// sulfur *** 68. Which item VII A group in the form of simple substance is the only oxidant?// + fluorine .// chlorine.// bromine.// iodine.// astatine *** 69. To reduction process corresponds to the transformation: // + Cl +1 Cl-1 .// Cl0 Cl +. // S-2 S0.// P +3 P +5.//

+1

*** 70. The degree of oxidation of chlorine in KClO3 is: / / + +5 .// +3.// +1.// +7 .// -1. *** 71. Which process is oxidation?: // K2CrO4 K2Cr2O7.// Cr2O3 Cr(OH)3.// Cr (OH) 3 NaCrO2.// + Cr2O3 CrO3 . // CrO3 K2Cr2O7. *** 72. Which of these processes is the reduction?// MnO2 KMnO4.// K2MnO4 KMnO4.// Mn(OH)3 MnO2.// + KMnO4 MnSO4 .// MnO2 K2MnO4 *** 73. Buffer system: // + CH3COOH + CH3COONa .// NaOH + HNO3.// NaOH + Na2SO4.// CH3COOH + NaOH.// H2CO3 + NaOH. *** 74.The factor of affecting the buffer capacity: // temperature. // + ratio of the components . // pH of the solution./ / pressure.// volume. *** 75. Show the formula indicator of hydroxyl group: // + pOH =-lg [H +] . I // pOH = ---------. lg [H +] // pOH =-lg [OH-].// pOH = - lg [CK-you].// pOH = [H +]. *** 76. PH value in blood acidosis: // 7,5.//

+ 7,25 .// 7,4.// 7,45// 5,6. *** 77. pH of gastric juice with high acidity:// +0,8 .// 2.// 2,1.// 3,5.// 4,2. *** 78. What you need to add water to pH was equal to 3?:// alkali.// water.// +acid .// solution of NaCl.// salt. *** 79. What is the pH of gastric juice indicates the absence of pathology: // + 2,5 .// 3.// 4.// 1,2.// 5. *** 80. What is the significance of blood pH indicates the absence of pathology: / / 7,6.// 7,2.// 7,1.// + 7,4 .// 7,0. *** 82. The expression for the ionic product of water is: // KW = [H +] * [OH-] / [H2O].// KW = [H +] / [OH-].// KW = [H +].// + KW = [H +] [OH-] .// KW = [H2O] / [H +] [OH-] *** 83. How does the structure of atoms of elements in a small period of the periodic system in the transition from element to element?: // increases the number of electronic layers.// nuclear charge remains constant.// + the number of electrons on the last layer of the electronic atom increases.// the number of electrons on the penultimate electron layer atom increases.// the number of electronic layers decreases ***

84. How to change the properties of elements with increasing atomic number elements in the period?:// metallic and nonmetallic increase.// metal decrease, increasing non-metallic.// + metallic and nonmetallic decrease.// metal increases, reduced non-metallic.// metallic and nonmetallic properties are not changed. *** 85. On what basis elements are combined in the s-, p-, d-, f-group?// the number of energy levels.// +for filling the energy sublevels .// the number of electrons in the outer energy level.// number of the period in which the element.// in decreasing the energy sublevels. *** 86. What distinguishes the great periods of low periods?// the presence of alkali metal.// the absence of inert gas.// + the presence of d-and f-elements.// the presence of non-metals.// the presence of metals. *** 87. What form of higher oxide is responsible elements of the electronic configuration of outer electrons ns2 np3?// EO.// E2O3.// + E2O5 .// E2O7.// EO2 *** 88. What elements are always begins and ends every time?// s-and f-elements.// p-and d-elements.// s-and d-elements.// + s-and p-elements .// p-and f-elements. *** 89. Molar mass equivalent of Fe(OH)3 is // 107.// +35,6 .// 53,5.// 72,3.// 108. *** 90. What of halogen is in the solid aggregate state? // F2 // Cl2 // Br2 //

+ J2 // H2 *** 91. Show number of electrons in the outer level of the ion S2- // 3 // 5 // 6 // +8 // 7 *** 92. In the subgroup of the periodic system of elements of D.I. Mendeleyev with increasing ion radius at the metal hydroxides occurs: // + reduction in the basic properties // increase in acidic properties // decrease in the number of electronic levels // increase in the basic properties // unchangeable *** 93. Complex formed can be: // + atoms of metals and nonmetals // anions // protons // atoms of inert elements // nonmetals *** 94. Founder the theory of complex compounds is: // Zinin // Kolrausch // + Werner // Van't Hoff // Avogadro *** 95. What is equality charge of the complex-complex compound [Al(OH)(H2O)5] Cl2?: // -2 // + +3 // +4 // +5 // -3 *** 96. Show charge of the complex ion in K2 [HgI4]: // -4 // + -2 // -1 // +2 // +4 *** 97. Show instability constants K2 [HgI4]: //

[K +] 2 [Hg2 +] KH = ______________ [I-]4 // [Hg2 +] [I-] 4 + KH = ________________ [[HgI4] -2] // [K] [I] KH = ____________ [Hg2 +] // [[HgI4] 2 -KH = ____________ [Hg2+] [I-] 4 // KH = [K] [I] *** 98. Constant dissociation of HCN will be: // [HCN] + K =__________ [H +] [CN-] // [H +] [CN-] K = ____________ [HCN] // I K = _________ [H +] [CN-] // K = [H +] [CN-] // K = [H +] / [CN-] *** 99. Show to calculate the Nernst equilibrium potential of the metal electrode has the form: // 2,3 RT + E = E + _______ lg [met + n] nF //  2,3 RT [Oxid] E = ______ lg_______ nF [Red]//
0

F = F C / (K + C) // X = C2n / (Cv +2CL) // X = (CH2 Cv) / C2n *** 100. What conditions the potential of the standard hydrogen electrode is zero?: //

p = any, t = 250C, [H +] - 1g-ion / l // p = 1 atm, t = 250C, [H +] - any // p = 1 atm // + p = 1 atm, t = 25C, [H +] - 1g-ion / l // p = 10atm *** 102.What called aqueous colloidal solutions?: // + hydrozole // alkozole // waterzole // eterozole // liquidzole *** 103. Which methods available colloidal dispersion system? // + dispersion and condensation // disperse condensation // the dispersion of the condensation // condensation and coagulation // by evaporation of the dispersion liquid *** 104. Aldehydes and ketones contain a functional group: // OH// COOH//. Hal. // + - COH// . - SH. *** 105. Formic aldehydes - is: // .// 3 .// .// 2 5 + .//
3 3.

*** 106. When aldehydes interact with alcohol, is formed: // ether. // aldol. // + acetal. // diatomic alcohol. // Imin. *** 107. The oxidation of acetaldehyde is formed: // + ethanoic acid. // oxinitril. // acetic anhydride. // ethanol. // Acetone. ***

108. During the decarboxylation of oxalic acid is formed: // propionic acid. // oxalic anhydride. // + formaldehyde .// formic acid. // acetic anhydride. *** 109. Aldehydes are oxidized to: // alcohol. // + carboxylic acid.// ketones.// alkanes. // amines. *** 110. During the restoration of acetone is formed: // acetic anhydride. // propanol-1. // propionic acid. // acetic acid. // + propanol -2 . *** 111. 40% water solution of metanal is called: // paraform. // + formalin. // aldol. // croton. // formamide. *** 112. Hydroxyacid - it heterofunctional compound containing in its composition: // hydroxyl and carbonyl groups. // amino and hydroxyl groups. // + hydroxyl and carboxyl groups. // halogen, and carboxyl group. // carbonyl and carboxyl groups. *** 113. For the carboxylic acid functional group is characterized by: // OH.// + - COOH.// Hal.// COH.// SH. *** 114. Formula of butyric acid: // .// 3 .// 6 5 .// + 3 2 2 .// ( 3 )2 .

*** 115. Tautomerism - is: // structural isomers. // optical isomers. // + equilibrium dynamic isomerism.// stereo isomers. // cis-trans isomer. *** 116. Qualitative reaction to glycerol with:// sulphate of copper (II). // sodium hydroxide. // chloride iron (III). // + copper hydroxide (II . // iodine. *** 117. Diacid - is: // formic acid. // crotonic acid. // acetic acid. // sulfanilic acid. // + oxalic acid. *** 118. The general formula of hydrocarbon homologous series of benzene:// 2 // +CnH2n-6// 2n-2// CnH2n+2// .-2nH2n+2 *** 119. Diatomic alcohol: // + ethylene glycol. // phenol. // methyl alcohol. // glycerin. // ethyl alcohol. *** 120. Connection CH3CH (OH) COOH is called // + lactic acid. // oxalic acid. // glycolic acid. // malic acid. // pyruvic acid. *** 121. Oxalic acid is: // + etandiol acid // ethane acid; // butane acid; //

amber acid; // Epropandiol acid; *** 122. Amino acid containing sulphur is: // serine // lysine // + cysteine // glutamine // phenylalanine *** 123.Uracil this: // 2 - hydroxy, 4-aminopirimidin // 2,4-dihydroxy-5 metilpirimidin // +2,4 - dioksipirimidin // 6-aminopurine; // 2-amino-6-oksipurin; *** 124.Citozin this: // 2,4 - dioksipirimidin // +2- hydroxy, 4-aminopirimidin // 2,4-dihydroxy-5 metilpirimidin // 6-aminopurine; // 2-amino-6-oksipurin; *** 125. Guanine is: // +2- amino-6-oksipurin // 2 - hydroxy, 4-aminopirimidin // 2,4-dihydroxy-5 metilpirimidin // 6-aminopurine; // 2,4 - dioksipirimidin; *** 126.Amino acid is: // glucose // + glycine // aminoethanol // aminoetanal // kolamin *** 127. . not synthesized at phenylketonuria in the body: // glutamate // aspartate // + Tyrosine // glycine // serine *** 128. Complimentary to adenine: // guanine; // cytosine; //

uracil; // + thymine; // adenine; *** 129. When decarboxylation of lactic acid is formed: // + ethanol // ethylene glycol // ethane // glycerol // ethanal *** 130. When oxidation of dairy acid produced // Amber // acetic // + pyruvic // propionic // Oil *** 131. Final breakdown product of purine bases in the body: // guanine; // + adenine; // xanthine; // uric acid; // hypoxanthine; *** 132. . participate in formation of secondary structure of proteins// + hydrogen bond// peptide // disulfide // ion // ester *** 133. In the formation of the primary structure of protein is involved link: // hydrogen // + peptide . // disulfide// ion // ester *** 134. Complimentary to guanine: // guanine; // thymine; // +cytosine; // uracil; // adenine; *** 135. Third structure of the protein stabilizes the link: // hydrogen //

peptide // +between the radicals of amino acids . // Phosphodiester // Eglycosidic *** 136. Indispensable aminoacid: // Proline // + Lysine //. Histidine // Glycine // Glutamine *** 137. Nucleotides are: // glitserolphosphaty // nucleoside triphosphates; // +nukleozidmonophosphaty . // ribose 5 phosphate; // nukleoziddiphosphaty; *** 138. In the composition of DNA: // glucose; // fructose; // +deoxyribose; // ribose // sucrose *** 139. When the hydrolysis of AMP formed: // adenine and phosphate; // +adenine, ribose, phosphate . // adenine, glucose, phosphate // adenine and ribose; // adenine and pyrophosphate; *** 140. In the composition of RNA: // +ribose. // glucose; // fructose; // deoxyribose; sucrose *** 141. Glycerin is: // +propantriol-1, 2,3 . // ethanediol-1, 2 // resorcinol // hydroquinone // kreozol *** 142. With copper hydroxide interacts: //

+glycerol . // propanol // ethanol// phenol // butanol *** 143. Optical activity has acid.// +diary.// oxalic acid.// pyruvic acid.// vinegar acid.// malonic acid *** 144. Fats - are esters of higher fatty acids and.// ethanol .// propanol. // +glycerol .// butanol .// ethanediol *** 145. Nukleozid consists of.// +nitrogen bases and ribose.// nitrogen bases and fructose.// nitrogen base and glucose.// glucose and fructose.// ribose and ethanol *** 146. Fructose is.// +Hexoses.// Pentoses.// Ketopentoza.// Ketogeksoza.// Aldotrioza *** 147. Lewis acids.// +acceptors of an electronic pair.// donors of positive protons. // donors of an electronic pair.// acceptors of positive protons. // oxonium basis *** 148. The greatest basic properties shows.// +triethylamine.// ethoxy ethanes.// diethylsulfede.// diethylamines.// ethylamine ***

149. The Basis of Lewis are: // +donors of an electronic pair;// acceptors of an electronic pair;// compounds with a free orbital.// donors of positive protons.// acceptors of positive protons *** 150. To the greatest acidic properties exhibits.// thanol.// ethane thiol.// phenol.// +paraftorophenol.// para-aminophenol *** 151. Quantitatively acidity of organic compounds is valued.// stability of an ion.// +constant of an acidity ( ).// constant of a basicity (Kb).// H+ OH-.// electronegativity of atom in acid center *** 152. The greatest basicity shows the compound below.// CH3 NH2.// CH3-OH.// CH3- NH CH3.// CH3- SH.// +CH3- N CH3 | CH3 *** 153. Bronsted-Lowry acids are.// +donor of positive protons.// donor of electrons.// acceptor of positive protons.// acceptors of electrons.// neutral molecule, in which one atom with paired electrons *** 154. The greatest basicity has.// Methylamine.// Dimethylamine.// +triemethylamine.// Aniline.// para-methylaniline *** 155. In order of basicity increase the compounds are arranged in a row.// +C2H5 - O C2H5 , C2H5 - S C2H5 , C2H5 - NH C2H5.// C2H5 - S C2H5 , C2H5 - O C2H5 , C2H5 - NH C2H5.// there is no right answer.//

C2H5 - NH C2H5 , C2H5 - O C2H5 , C2H5 - S C2H5.// C2H5 - NH C2H5 , C2H5 - S C2H5 , C2H5 - O C2H5 *** 156. To the least acidic properties exhibits.// +ethanol.// ethane thiol.// phenol.// paraftorophenol.// para-aminophenol *** 157. The greatest acidity shows// acid.// +SH acid.// NH acid.// CH acid.// the compounds listed are not acids *** 158. The least acidic properties shows.// Ethanol.// diethyl ether.// ethane thiol.// methyl amine.// + dimethylamine *** 159. The least acidity shows the following compound// acetic acid.// chloroacetic acid.// Dichloroacetic acid.// trichloroacetic acid.// +aminoacetic acid *** 160. Alkenes are the bases.// Ammonium.// Oxonium.// Sulfonium.// pi-bases.// +neutral *** 161. In the following reaction HCOOH + H2O m HCOO- + H3 + conjugated acid is.// formic acid.// water.// formiate ion.// +hydroxonium ion.// there is no conjugated acid in this reaction *** 162. In the following equation of the reaction CH3-COOH + H2O m CH3-COO- + H3O+ the base is.//

acetic acid.// +water molecule.// acetate ion.// hydroxonium ion.// there is no base in this reaction *** 163. In order of basicity increase the following compounds are places in the row.// 3- N- CH3, CH3- NH- CH3, CH3- NH2.// | CH3 CH3- NH2, CH3- N- CH3, CH3- NH- CH3.// | CH3 CH3- NH- CH3, CH3- NH2, CH3- N- CH3.// | CH3 +CH3- NH2, CH3- NH- CH3, CH3- N- CH3.// | CH3 there is no correct answer *** 164. The acidity of the following organic compounds decreases in the row.// +H-COOH, CH3-COOH, CH3-CH2-COOH.// CH3-CH2-COOH, CH3-COOH, H-COOH.// CH3-CH2-COOH, H-COOH, CH3-COOH.// CH3-COOH, H-COOH, CH3-CH2-COOH.// H-COOH, CH3-CH2-COOH, CH3-COOH *** 165. The least basicity shows.// Diethylamine.// methyl amine.// diethyl ether.// +diethylsulfide.// ethanol *** 166. The less the Ka of the organic compound the.// + more is acidity.// less is acidity.// less is basicity.// more stable the anion.// more is electronegativity of atom in the acid centre *** 167. The least acidity shows.// acid.// SH acid.// NH acid.// +CH acid.// the compounds listed are not acids

*** 168. The glyoxilic acid has a following structure.//

+H - C - COOH || O.// CH3 COOH. // CH3 - C - COOH .// || O HOOC - C - COOH.// || O HOOC - C CH2 - COOH || O *** 169. Lactic acid the is.// +molecules of hydroxyacids.// molecules - hydroxyacids and alcohol.// molecules of alcohol and carboxylic acid.// of two molecules of alcohol.// there is no right answer *** 170. Ketoacids are the compounds containing.// aminogroup and carboxyl group. // two hydroxyl groups.// amino and carboxyl group.// ketogroup and carboxyl group.// +hydroxyl and carboxyl group *** 171. The formula of -hydroxyvaleric acid is.// CH3 - CH - COOH.// | OH HOOC - CH CH2 - COOH.// | OH +CH3 CH2 CH CH2 - COOH.// | OH CH3 - CH CH2 - COOH.// | OH CH2 CH2 CH2 - COOH ***

172. The name of the compound is.// .// | | OH OH hydroxy-butanedioic acids lactic acids.// citric acids.// +tartaric acids.// acetic acid *** 173. The name of the compound is. // O || CH3 -C CH2 - COOH.// glyoxilic acid.// pyrotartaric an acid.// +acetoacetic acids. // acetic acid. // oxalacetic acids *** 174. Hydroxyacids are the heterofunctional compounds containing.// aminogroup and carbonyl group. // two hydroxyl groups.// aminogroup and carboxylic group.// ketogroup and carboxylic group. // +hydroxyl and carboxylic group *** 175. The formula of D-lactic acid is.// + COOH | H - C - OH | CH3 .// COOH | HO - C - H | CH3 . // COOH | H - C NH2 | CH3.// COOH |

H - C - OH | HO - C - H | HO - C - H | COOH.// COOH | C=O | CH3.// *** 176. Organic compounds, having in their structure several different functional groups, are called.// Esters.// +heterofunctional compounds. // Aldehydes. // carboxylic acids. // polyatomic alcohols *** 177. General formula H2N- R - OH corresponds to.// +amino acids.// amino alcohols.// hydroxyacids.// ketoacids. // hydroxyaldehyde *** 178. The hydroxy-butandioic acid has structure. // .// 3| OH CH3 CH2 COOH.// HOOC CH2 - CH - COOH.// | OH CH3 - CH - COOH.// | NH2 +CH3 CH2 - CH COOH | OH *** 179. The formula is called.// 3|| O glyoxalic acid.// pyrotartaric acid.//

+acetoacetic acid.// acetic acid.// oxalic acids *** 180. The amino acids are compounds having.// +aminogroup and carboxyl group.// two hydroxyl groups.// aminogroup and carbonyl group.// aminogroup and ketogroup.// hydroxyl and carboxylic group *** 181. The name CH3 2 - COOH is.// | OH - hydroxyvaleric acid.// + - hydroxybutyric acid.// - hydroxybutyric acid. // - hydroxypropionic acid.// 3 - aminopropanoic acid *** 182. The name HOOC 2 - COOH is.// - hydroxyvaleric acid.// - hydroxybutyric acid. // - hydroxybutyric acid.// - hydroxypropionic acid.// +malic acid *** 183. The name HOOC - COOH is.// acetoacetic acid..// glutamic acid.// malonic acid.// +oxalic acid.// malic acid *** 184. Not natural polymer is.// protein.// nucleic acid.// ctllulose.// starch.// +kapron *** 185. Tioly have a functional group:// - OH.// +- SH.// - COOH.// - S -.// -S S ***

186. Aminy have a functional group:// - OH.// - SH.// - COOH.// +- NH2.// -CN *** 187. For aldehydes and ketones to typical following reactions:// - SN.// - SE.// +- AN.// - AE.// - SR *** 188. Ketoacids are the compounds containing:// aminogroup and carboxyl grou.//p two hydroxyl groups.// amino and carboxyl group.// +ketogroup and carboxyl group.// hydroxyl and carboxyl group *** 189. The heterofunctional compounds are all the compounds in the row.// aldehydes, amino acids, lipids.// aldehydes, alcohols, unsaturated carboxylic acids.// lipids, alcohols, esters.// ketones, aldehydes, carbohydrates.// +amino alcohols, hydroxyacids, amino acid, aldehydoacids, ketoacids *** 190. The reactions the most typical for carbon atom of the carbonyl group.// nucleophilic substitution .// electrophilic substitution.// electrophilic addition.// +nucleophilic addition .// elimination *** 192. At the hydrolysis propylacetoate the following compounds form.// , 2 5 .// 2 5 + 3 , 3 7 .// , 2 5 .// 2 5 , 3 7 .// 2 5 , .// 3 3 *** 193. Substitution of hydroxyl group of the carboxyl group into ammonia results in formation of.// amino acids.// salts of carboxylic acids (carboxylates).// anhydrides.// +amides.//

imins *** 194. Product of aldehydes reduction is:// +primary alcohols.// secondary alcohols.// aldehydes.// carboxylic acids.// ketones *** 195. The general formula R - C - S - R corresponds to the following class.//: || O amides.// acid anhydrides.// aldol.// +thioethers.// ethers *** 196. Not natural polymer is:// protein.// nucleic acid.// cellulose.// starch.// +kapron *** 197. Denaturation of protein it is:// +the destructions of all structures of a protein including the primary structure.// the reversible sedimentation of a protein.// irreversible processes of destruction of tertiary and secondary structures of a protein at the influence of different factors.// destructions of all structures of a molecule.// irreversible processes of destruction of tertiary structures of a protein. *** 198. The molecules of high-molecular compounds may be obtained:// reaction of a hydrolysis.// oxidation reactions.// +reaction of polymerization and polycondensation.// exchange reactions.// reaction of an etherification *** 199. The molecules of HMC are formed by the following reaction:// hydrolysis.// oxidation-reduction.// substitution.// etherification.// +polymerization and polycondensation ***

200. The state of the protein when the number of the ionized carboxylic groups is equal to amount of amino groups and the general charge of the protein is equal to zero is called:// +isoelectric state.// thermodynamic parameter.// oxidation.// reduction.// buffer capacity