12.04.07 Arlypon TT Incosmetics

Arlypon
TT
A turbo thickener that tames surfactants

Keriman Albaha and Werner Seipel 17th of April 2007
Chart no. 1
OUR THICKENING
Turbo Thickener that tames surfactants
Chart no. 2
OUR THICKENING
INTRODUCTION
Performance profile of thickeners Thickeners today Arlypon TT the synergistic thickener Temperature / viscosity relationship with Arlypon TT Sensorial benefits of Arlypon TT on Skin Frame formulations body / hair Summary
Chart no. 3
Performance profile of thickeners
High thickening power for all clear and pearlescent surfactant systems Effective even at low surfactant concentration Easy to handle Cold processable Liquid pumpable Good compatibility with shampoo and body wash ingredients
Chart no. 4
OUR THICKENING
Chart no. 5
Thickeners Today
Micellar thickener
A micellar thickener forms rod micelles and stabilizes these.
From Sphere to Rod Like Micelle

Chart no. 6
Thickeners Today
Micellar thickener
20000 18000 16000 14000 12000 10000 8000 6000 4000
Viscosity adjustment with NaCl

[mPa s ] viscosity 10% as SLES
useful for:
standard surfactant combinations
viscosity adjustment with low amount of electrolytes
stabilizing heterogeneous systems by

2000 0
0 0,5 1 1,5 2 2,5 3 3,5 4 4,5 5 5,5 6 6,5 7 7,5 [%] NaCl
adjustment of the density e.g. pearl shine waxes

Thickening by NaCl only
Thickening by Fatty Alcohol EO and NaCl
Chart no. 7
Thickeners Today
Micellar thickener
[mPas] viscosity
100000
Viscosity adjustment with Laureth-2 and NaCl
12600
10000
5800 1800
1000
100
10 +23C +30C +40C
temp.
Advantages: Easy to handle = liquid Sufficient temperature viscosity stability
Disadvantages: For standard surfactant systems only Limited viscosity potential
Chart no. 8
Thickeners Today
Associative thickener
ilic h op r yd h
r hyd
ic hob op
PEGs PEG
micelle micelle
general chemical structure
water
An associative thickener links micelles and builds up an agglomerate of thickener and micelles.
Chart no. 9
Thickeners Today
Associative thickener
[mPas] viscosity
100000
Standard surfactant formulation with associative thickener

useful for: alternative and standard surfactant combinations
PEG-120 Methyl Glucose Dioleate

10000
8900
low surfactant concentrations difficult to thicken ingredients

1425
1000
100
50
Stable pearl shine formulations at least need a viscosity of 200 mPas at +40C.
temp.
10 +23C +30C +40C
Advantages:
Sufficient thickening potential useful for low surfactant concentrations and difficult to thicken ingredients Additional benefits e.g. skin and hair conditioning
Disadvantages:
No sufficient temperature / viscosity stability at +40C (Temperature stability is important for heterogeneous systems) Rheological behavior = newtonian viscosity
Chart no. 10
OUR THICKENING
Chart no. 11
Technical Data
INCI
PEG/PPG-120/10 Trimethylolpropane Trioleate (and) Laureth-2
Appearance Water pH value (1% in water /IPA 1:1) Density (20C, g/cm) cold processable preservative free
: : : :
clear liquid 9 11 % 5.0 6.5 0.95 1.00
Chart no. 12
The Synergistic Thickener

Arlypon TT combines the advantages of different mechanisms
PEG/PPG-120/10 Trimethylolpropane Trioleate as an associative thickener
(and)
Laureth-2 as a micellar thickener
An associative thickener links micelles and builds up an agglomerate of thickener and

ic hil op r yd
A micellar thickener forms rod micelles and stabilizes these.

From Sphere to Rod Like Micelle
+ +
micelles.
c obi oph r hyd
Both components are linked to an effective thickener compound with synergistic effects.
anionic
micelle micelle
water
cationic ion
nonionic
Chart no. 13
Performance in SLES - Free Surfactant Systems

SLES free surfactant combination:
Sodium Cocoamphoacetate (and) Glycerin (and) Lauryl Glucoside (and) Sodium Cocoyl Glutamate (and) Sodium Lauryl Glucose Carboxylate
12% WAS + 1% Arlypon TT
14000
11300
en i ck d h to t blen lt icu tant diff rfac su
8500
Measurement: Brookfield spindle LV2 / LV4 speed 6 / 12 / 60 rpm room temperature
5000
[mPas] viscosity
Chart no. 14
10000
15000
Viscosity improvement in SLES - Free formulations
PEG/PPG-120/10 Trimethylolpropane Trioleate [and] Laureth-2
8500
PEG-200 Hydrogenated Glyceryl Palmate [and] PEG-7 Glyceryl Cocoate
25
20
8% WAS
Surfactant combination that contains
without
5000
[mPas] viscosity
10000
15000
thickener 1% as is
Chart no. 15
Specific Mild Shower Bath for Sensitive Skin

Ingredient Plantapon LGC Sorb Dehyton MC Dehyton PK 45 Cetiol LDO Arlypon TT perfume preservative Citric Acid 50% water pH-value viscosity mPas WAS
Chart no. 16
INCI
weight % (as is) (active) 32.3 6.0 4.1 0.3 0.97 0.3 0.1 0.56 55.37 5.5 8800 13.5% 10.0 2.0 1.5
function Surfactant Surfactant Surfactant Emollient Thickener Fragrance Preservative pH adjustment
Sodium Lauryl Glucose Carboxylate (and) Lauryl Glucoside Sodium Cocoamphoacetate Cocamidopropyl Betaine Dicaprylyl Ether (and) Lauryl Alcohol
fragrance preservative Citric Acid
(no.: HB-DE/06/146/13)
Viscosity Performance in SLES - Free surfactant systems
Very good thickening power without additional NaCl
Arlypon TT shows better viscosity in SLES-free surfactant systems than benchmarks
Chart no. 17
Performance in SLES - Poor Surfactant Systems
Ingredient
INCI
weight % (as is)
Plantapon LGC Sorb Sodium Lauryl Glucose Carboxylate(and) Texapon Dehyton N70 MC SB 3KC Texapon Plantapon LC7 Gluadin WQTM Cetiol LDO Polymer JR 400 Arlypon TT perfume preservative MgCl26H2O water
Lauryl glucoside 15.0 Sodium Laureth Sulfate 6.0 Sodium Cocoamphoacetate 6.0 Disodium Laureth Sulfosuccinate 6.0 Laureth-7 Citrate 2.0 Hydroxypropyltrimonium Hydrolyzed Wheat Protein 1.5 Dicaprylyl Ether (and) Lauryl Alcohol 0.3 Polyquaternium-10 0.05 PEG/PPG-120/10 Trimethylolpropane Trioleate 0 - 3.0 [and] Laureth-2 Fragrance 0.3 Preservative 0.1 Magnesium Chloride 0.4 water add to 100.0
pH-value washing active substance
5.5 11.9% (no.: HB-DE/06/090/....)

Chart no. 18
Viscosity improvement in a SLES - Poor formulation

[mPas] viscosity
80000 60000 40000

19200
20000
5000
0 without
Measurement: Brookfield spindle no 4 / TE speed 4 / 10 rpm room temperature
spindle no TE, 4 rpm spindle no 4, 10 rpm
0,5
1,5
2,5
[%] Arlypon TT
(no.: HB-DE/06/090/....)
Chart no. 19
Thickening behavior in a formulation with low SLES content

Viscosity adjustment of 5000 mPas
1,63
[%] Thickener
(no.: HB-DE/06/090/....)
Chart no. 20

Thickening behavior in a formulation with low SLES content different pH adjustments
[mPas] viscosity
20000
15000
15800
10000
10200 6800
5000
3200 3400 1400
0 5,0 6.0 7,0

[pH value]
(no.: HB-DE/06/090/....)
Chart no. 21
SLES poor Mild Shampoo
Ingredient Plantapon LGC Sorb N70 MC SB 3KC Texapon Plantapon LC7 Gluadin WQTM Dehyton LDO Polymer JR 400 Arlypon TT perfume preservative MgCl26H2O NaOH 50% water Cetiol Texapon
INCI
weight % (as is)
active
function
Sodium Lauryl Glucose Carboxylate (and) Lauryl Glucoside 15.0 Sodium Laureth Sulfate 6.0 Sodium Cocoamphoacetate 6.0 Disodium Laureth Sulfosuccinate 6.0 Laureth-7 Citrate 2.0 Hydroxypropyltrimonium Hydrolyzed Wheat Protein 1.5 Dicaprylyl Ether (and) Lauryl Alcohol 0.7 Polyquaternium-10 0.05 PEG/PPG-120/10 Trimethylolpropane Trioleate [and] Laureth-2 1.1 Fragrance 0.3 Preservative 0.1 Magnesium Chloride 0.4 Sodium Hydroxide water 0.12 60.73 5.5 5400
4.7 4.2 1.0 2.0
surfactant surfactant surfactant surfactant conditioning agent conditioning agent emollient conditioning agent viscosity adjustment
complexing agent and viscosity adjustment
pH-value viscosity mPas washing active substance
11.9%
(no.: HB-DE/06/146/17)
Chart no. 22
Thickening behavior in a formulation with low SLES content
Very effective even at low surfactant concentrations
Superior viscosity profile compared to benchmarks
Chart no. 23
Performance in SLES / CAPB Surfactant System
Viscosity adjustment in a standard SLES formulation

SLES : CAPB ratio 10:2 1% Arlypon TT
12% WAS with 8000 mPa.s
Viscosity adjustment
1,31
1,53
1,95
3 [%] NaCl
Chart no. 24
Viscosity adjustment of 4000 mPas

SLES : CAPB 8% WAS ratio 6,7:1,3 thickener 1% as is
1,95
1,85
2,23
without
5,42
6 [%] NaCl
Chart no. 25

Viscosity Profile in Standard Surfactant System at different NaCl concentrations
31000 22500
30000 25000
12% WAS
10% WAS [mPas] viscosity with 1% Arlypon TT
50000 40000 30000
[mPas] viscosity with 1% Arlypon TT

40000
28000 22000
20000 15000
20000 10000
1375 9000 2600
11200
10000
8400
5000
1800
0
0 0
20000
[%] NaCl
[mPas] viscosity 8% WAS with 1% Arlypon TT
Surfactant ratio SLES : CAPB 10 : 2 AS
[% ] NaCl
15000
[mPas] viscosity 6% WAS with 1% Arlypon TT
15000
13400
10000
11500
10000
Measurement:
5600 1200
5000
4200
Brookfield spindle LV2 / LV4 speed 6 / 12 / 60 rpm room temperature
5200
5000
3300 770
0 0 1 2 3 4 5
1200
6 7
[% ] NaCl
0 0 1 2 3 4 5 6 7
[% ] NaCl
Chart no. 26
Standard Surfactant / Clear Shower Bath
Clear Shower Bath

Ingredient Texapon N 70 Dehyton PK 45 Arlypon TT Dehyquart 701/NA perfume preservative Citric Acid 50% NaCl water pH-value viscosity mPas WAS INCI Sodium Laureth Sulfate Cocamidopropyl Betaine
weight % (as is) (active) 11.9 4.6 1.0 1.7 0.3 0.1 0.08 1.5 78.82 5.5 9000 10.0% 8.3 1.7
function Surfactant Surfactant Thickener Conditioner Fragrance Preservative pH adjustment viscosity adjustment
Polyquaternium-7 fragrance preservative Citric Acid Sodium Chloride
(no.: HB-DE/06/146/05)
Chart no. 27
Standard Surfactant / Care Shampoo
Super Care Shampoo

Ingredient Texapon N 70 Plantacare 818 UP Cetiol LDO Arlypon TT Polymer JR 400 perfume preservative Citric Acid 50% NaCl water pH-value viscosity mPas WAS INCI weight % (as is) (active) 14.3 3.8 0.7 1.0 0.2 0.3 0.1 0.22 1.5 77.88 5.5 5600 12.0% 10.0 2.0 function Surfactant Surfactant Emollient Thickener Conditioner Fragrance Preservative pH adjustment viscosity adjustment Sodium Laureth Sulfate Coco-Glucoside Dicaprylyl Ether (and) Lauryl Alcohol
(no.: HB-DE/06/146/02)
Chart no. 28
Thickening in Standard Surfactant System
The synergistic thickening effect of Arlypon TT enables to build up sufficient viscosity in all standard surfactant formulations
Chart no. 29
OUR THICKENING
Chart no. 30
Temperature / Viscosity behavior

Stability
The viscosity / temperature behavior of a formulation with pearlized wax
Formulation no.: DE-HB/06/159/ Texapon N70 Dehyton PK 45 Dehyquart 701/NA Lamesoft PO 65 Arlypon TT PEG-200 Hydrogenated Glyceryl Palmate [and] PEG-7 Glyceryl Cocoate PEG-120 Methyl Glucose Dioleate Wax dispersion perfume preservative NaCl water pH value viscosity mPas ----2.0 0.3 0.1 0.5 1.0 --2.0 0.3 0.1 0.6 --1.0 2.0 0.3 0.1 0.5 10 11 12 ------------------- weight % --------------13.9 13.9 13.9 5.2 1.5 1.0 1.0 5.2 1.5 1.0 --5.2 1.5 1.0 ---
--------------- add to 100% --------------5.6 5.6 5.6 7100 8000 5200
Chart no. 31

Stability
The viscosity / temperature behavior of a formulation with pearlized wax
aft ble a St
k ee w 12 r
Arlypon TT
PEG-200 Hydrogenated Glyceryl Palmate(and) PEG-7 Glyceryl Cocoate 11 8000 < 100 1.0242
PEG-120 Methyl Glucose Dioleate 12 5200 < 100 1.0256
Formulation no.: DE-HB/06/159/ viscosity mPas 23C viscosity mPas 40C density g/cm 20C
10 7100 200 1.0245
Chart no. 32
Arlypon TT maintains sufficient viscosity also at higher temperature in pearlized formulations
Chart no. 33
OUR THICKENING
Chart no. 34
Sensory benefits on Skin Skin Sensory Assessment

Formulation no.: DE-HB/06/146/ Texapon N70 Dehyton PK 45 Dehyquart 701/NA Arlypon TT perfume preservative citric acid 50% NaCl water pH value viscosity mPas 35 37 ------- weight % ------11.9 11.9 4.6 1.7 --0.3 0.1 0.08 2.2 4.6 1.7 1.5 0.3 0.1 0.08 0.6
------ add to 100% ----5.5 8000 5.5 6600
Chart no. 35
Sensory benefits on Skin

Pairwise comparison of developed formulation 06/146/037 with reference 06/146/35 in different variables
[easy] Distribution Flash foam [easy] Flashfoam Amount of foam [more] Amountof foam [much] Foam cushion [small] Foam bubble size [high] Foam stability [more] Body [more] Creaminess [easy] Rinse off Softness (after 8min) [more] Softness (after 8min) Softness (after 30min) [more] Softness (after 30min) [more] Smoothness (after 8min) [more] Smoothness (after 30min) [less] Dryness (after 8min)
n = 11 p-Value >=0,1 <0,1 <0,05 <0,01 -1 -0,5 0 0,5 1
1.5% Arlypon TT significantly improves the foam parameters and the softness of the skin
[less] Dryness (after 30min) [high] Acceptance Acceptance
placebo with 1.5% Arlypon TT Chart no. 36
Sensory benefits on Skin
Additional benefits for Arlypon TT
Sensorial Assessment showed that Arlypon TT improves skin softness
Sensorial Assessment showed perceivable foam improvement
Chart no. 37
Additional information
The dermatological behavior was tested by HET-CAM and RBC tests
The results showed that Arlypon TT has a neutral influence The Arlypon TT wasnt tested on animals
Chart no. 38
OUR THICKENING
Chart no. 39
Frame Formulations
Specific Mild Shower Bath for Sensitive Skin HB-DE/06/146/13 Super Mild Shampoo Clear Shower Bath Super Care Shampoo Soft Care Shower Bath Extra Care Shampoo HB-DE/06/146/17 HB-DE/06/146/05 HB-DE/06/146/02 HB-DE/06/146/37 HB-DE/06/146/04
Chart no. 40
Performance in standard Surfactant Systems
Soft Care Shower Bath

Ingredient Texapon N 70 Dehyton PK 45 Arlypon TT Dehyquart 701/NA perfume preservative Citric Acid 50% NaCl water pH-value viscosity mPas WAS INCI Sodium Laureth Sulfate Cocamidopropyl Betaine
weight % (as is) 11.9 4.6 1.5 1.7 0.3 0.1 0.08 0.6 79.22 5.5 6600
(active) function 8.3 1.7 Surfactant Surfactant Thickener Conditioner Fragrance Preservative pH adjustment viscosity adjustment
10.0%
(no.: HB-DE/06/146/37)
Chart no. 41
Performance in standard Surfactant Systems
Extra Care Shampoo

Ingredient Texapon N 70 Dehyton PK 45 Arlypon TT Polymer JR 400 perfume preservative Citric Acid 50% NaCl water pH-value viscosity mPas WAS INCI Sodium Laureth Sulfate Cocamidopropyl Betaine
weight % (as is) 11.9 4.6 1.0 0.2 0.3 0.1 0.1 1.0 80.8 5.5 6800
(active) function 8.3 1.7 Surfactant Surfactant Thickener Conditioner Fragrance Preservative pH adjustment viscosity adjustment
10.0%
(no.: HB-DE/06/146/04)
Chart no. 42
OUR THICKENING
Chart no. 43
Turbo Thickener Our thickening that tames surfactants
Applicational Summary
Easy to handle Cold processable Liquid pumpable Preservative free Synergistic combination for all types of surfactants
Chart no. 44
Turbo Thickener that tames surfactants Performance Summary
Excellent thickening power Very effective even at low surfactant concentrations Better stabilization of viscosity at higher temperature (pearlized systems) Perceivable skin softness improvement
Chart no. 45
OUR THICKENING
Turbo Thickener that tames surfactants
Chart no. 46
OUR THICKENING
Chart no. 47
[All products in the text marked with an are trademarks of the Cognis Group] The information on product specifications provided herein is only binding to the extent confirmed by Cognis in a written Sales Agreement. COGNIS expressly disclaims any responsibility for the suitability of the products for any specific or particular purposes intended by the user. Suggestions for the use and application of the products and guide formulations are given for information purposes only and without commitment. Such suggestions do not release Cognis customers from testing the products as to their suitability for the customers intended processes and purposes. Cognis does not assume any liability or risk involved in the use of its products as the conditions of use are beyond its control. The user of the products is solely responsible for compliance with all laws and regulations applying to the use of the products, including intellectual property rights of third parties.
BACK-UP CHARTS

Viscosity proof in SLES - Free formulations
14000
5600
8100
12% WAS Plantapon SF
without
10
5000
[mPas] viscosity
10000
15000
thickener 1% as is
Chart no. 51

Thickening behavior in a SLES - Poor formulation temperature influence
[mPas] viscosity
20000
19600
15000
10000
10400
5000
3000
0 5 23 30
400
40
[C] Temperature
(no.: HB-DE/06/090/....)
Chart no. 52
Performance in Standard Surfactant System

Performance Thickening behavior in a standard SLES formulations with different salt concentrations
100000
[mPas] viscosity
76000 78500
80000
60000
SLES : CAPB ratio 10:2 without thickener

53000
40000 21600 20000
0 0 1 2 3 4 5 6 7
[%] NaCl
[mPas] viscosity
50000
SLES : CAPB ratio 8.3:1.7 without thickener
[mPas] viscosity
50000
SLES : CAPB ratio 6.7:1.3 without thickener
[mPas] viscosity
50000
40000
40000
40000
SLES : CAPB ratio 5:1 without thickener
30000
30000
30000
20000
20000
20000
10000
2500
0 0 1 2 3
4350 5700
7800
7000
10000
4700 5400 2800 3500

0 1 2 3 4 5 6 7
[% ] NaCl
10000
2500 3300 1325 1900

0 0 1 2 3 4 5 6 7
[% ] NaCl
0
4 5 6 7
[% ] NaCl
Chart no. 53
Foam Behavior in a Standard Surfactant System
Foam properties measured by the Rotor-Foam-Test

1000 900 800 700 600 500 400 300 200 100 0 0 10 20 30 40 50 Shower Bath with 1,5% Arlypon TT Shower Bath with 1% Arlypon TT
foam volume [ml]

Shower Bath without Arlypon TT
Test Design: solution 10 g/l water hardness 255 ppm CaCO3 15dH = 2,68 mmol/Ca2+ temperature = 30C time intervals = 10 sec rotation speed: 1300 r.p.m.
m oa f sh fla
Shower Bath with 0,5% Arlypon TT
stirring time [s]
Chart no. 54
Standard Surfactant / Care Shampoo
Ingredient Texapon N 70 Dehyton PK 45 Cetiol LDO Arlypon TT Polymer JR 400 perfume preservative Citric Acid 50% NaCl water pH-value viscosity mPas WAS
INCI
weight % (as is) 14.3 4.1 0.7 1.0 0.2 0.3 0.1 0.11 1.0 78.19 5.5 7700
(active) function 10.0 1.5 Surfactant Surfactant Emollient Thickener Conditioner Fragrance Preservative pH adjustment viscosity adjustment
Sodium Laureth Sulfate Cocamidopropyl Betaine Dicaprylyl Ether (and) Lauryl Alcohol
11.5%
(no.: HB-DE/06/146/01)
Chart no. 55
Additional Benefits / Hair Conditioning Hair Combing Test

Formulation no.: DE-HB/06/146/ Texapon N70 Dehyton PK 45 Polymer JR 400 Arlypon TT perfume preservative citric acid 50% NaCl water pH value viscosity mPas 31 32 4 --------- weight % --------11.9 11.9 11.9 4.6 0.2 --0.3 0.1 0.05 1.5 4.6 0.2 0.5 0.3 0.1 0.07 1.4 4.6 0.2 1.0 0.3 0.1 0.1 1.0
-------- add to 100% -----5.5 6200 5.5 7800 5.5 6800
Chart no. 56
Additional Benefits / Hair Conditioning Combing test on hair strands

[%] residue in wet combing work
Shampoo HB-DE/06/146/31 with 0.2% PQ-10
89%
Shampoo HB-DE/06/146/32 with PQ-10 + 0.5%Arlypon TT
86%
Shampoo HB-DE/06/146/04 with PQ-10 + 1% Arlypon TT
77%
0
WS9
20
40
60
80
100
120
Chart no. 57
Folie 57 WS9 Report: AH 2006/017 A.Huhn CTPP 06-00329 05.12.2006
Seipel; 22.01.2007
Temperature / Viscosity behavior in a standard Surfactant System
Formulation no.: DE-HB/06/159/ Texapon N70 Dehyton PK 45 Dehyquart 701/NA Arlypon TT PEG-120 Methyl Glucose Dioleate PEG-200 Hydrogenated Glyceryl Palmate [and] PEG-7 Glyceryl Cocoate Euperlan PK 3000 OK perfume preservative NaOH 10% NaCl water pH value viscosity mPas 23C density g/cm 20C
05 06 07 ------------------------ weight % ---------13.9 13.9 13.9 5.2 1.5 1.0 ----2.0 0.3 0.1 --0.5 5.2 1.5 --1.0 --2.0 0.3 0.1 0.4 0.3 5.2 1.5 ----1.0 2.0 0.3 0.1 0.03 0.3
The viscosity / temperature behavior of a Pearlized formulation with different thickeners
---------------------- add to 100% ---------5.5 13.000 1.0268 5.5 5000 1.025 5.5 8300 1.0273
Chart no. 58
Temperature / Viscosity behavior in a standard Surfactant System
[mPas] viscosity at +40C

10000 1800
Viscosity behavior at +40C
1000
400
100
<50
A higher viscosity
<50
[at +40C] has a positive influence
10
Laureth-2 PEG-200 Hydrogenated Glyceryl Palmate [and] PEG-7 Glyceryl Cocoate PEG-120 Methyl PEG/PPG-120/10 Glucose Dioleate Trimethylolpropane Trioleate [and] Laureth-2
on the stability.
DE-HB/06/159/5, 6, 7, 9
Chart no. 59

Viscosity improvement in a surfactant system with SLES
Test formulation Texapon N70 Plantacare 818 UP Dehyton PK45 Arlypon TT DE/06/084/.... Sodium Laureth Sulfate Coco-Glucoside Cocamidopropyl Betaine -------- weight % ------12.8 2.9 3.8
PEG/PPG-120/10 Trimethylolpropane Trioleate 1.0 / 2.0 (and) Laureth-2 Citric Acid Sodium Chloride water ~ 1 6% ---- add to 100% ---5.5 12.0 ~
Citric Acid (20%) NaCl water pH value WAS % viscosity mPas
Chart no. 60

Thickening behavior in a surfactant system with SLES
SLES : APG : CAPB ratio 9 : 1.5 : 1.5 Arlypon TT 1% / 2%
70000 60000 50000 40000 30000 20000
[mPa.s] viscosity
Arlypon TT 1% Arlypon TT 2%
Measurement: Brookfield RVF spindle 4 / 5 speed 4 / 10 rpm room temperature +23C
10000 0 0 1 2 3 4 5 6
no. HB-DE/06/084/....
[%] NaCl
Chart no. 61

Arlypon TT Dermatological Behavior
Formulation no.: DE-HB/06/146/ Texapon N70 Dehyton PK 45 Dehyquart 701/NA Arlypon TT perfume preservative citric acid 50% NaCl water pH value viscosity mPas
35 36 5 37 ------------------------ weight % ---------------------11.9 11.9 11.9 11.9 4.6 1.7 --0.3 0.1 0.08 4.6 1.7 0.5 0.3 0.1 0.09 4.6 1.7 1.0 0.3 0.1 0.08 4.6 1.7 1.5 0.3 0.1 0.08
---------------------- add to 100% -------------------5.5 8000 5.5 9600 5.5 9000 5.5 6600
Chart no. 62
Hens egg test chorionallantoic membrane (HET-CAM)

Classification of the mucous membrane irritation potential based on the relative irritation potential Q
High irritation potential
3 2,5 2 1,5
Q Classification slightly irritating moderately irritating irritating severely irritating Q [relative irritation score]
1 0,5 0
Low irritation potential
< 0.8 > 0.8 < 1.2
> 0.12 < 2.0
DEHB/06/146/35
DEHB/06/146/36
DEHB/06/146/05
DEHB/06/146/37
> 2.0
without thickener
with 0,5% Arlypon TT
Test concentration: 3% as is pH appr. 6.5
The test results show no significant difference

Chart no. 63
WS4
Folie 63 WS4 Study report Schrader no 857-CCT-06-000-06-551 15. December 2006

Seipel; 03.01.2007

Arlypon TT Dermatological Behavior vs. Benchmarks
Formulation no.: DE-HB/06/146/ Plantapon SF Arlypon TT Antil 200 Glucamate DOE120 Perfume preservative citric acid 50% water pH value viscosity mPas
38 14 40 39 ------------------ weight % -----------------33.3 33.3 33.3 33.3 ------0.3 0.1 0.58 0.43 ----0.3 0.1 0.7 --0.8 --0.3 0.1 0.58 ----0.6 0.3 0.1 0.58
------------------ add to 100% -------------5.5 <100 5.5 5600 5.5 5200 5.5 5000
Chart no. 64
Hens egg test chorionallantoic membrane (HET-CAM)

Classification of the mucous membrane irritation potential based on the relative irritation potential Q
High irritation potential
3 2,5 2 1,5 1 0,5 0
Low irritation potential Q < 0.8 > 0.8 < 1.2 Classification slightly irritating moderately irritating irritating severely irritating Q [relative irritation score]
> 1.2 < 2.0 > 2.0
DEHB/06/146/38
DEHB/06/146/14
DEHB/06/146/40
with PEG-200 HGP PEG-7 GC
DEHB/06/146/39
with PEG-120 MGD
Test concentration: 2,5% AS pH appr. 6.5
without thickener
with Arlypon TT
The test results show no significant difference

Chart no. 65
WS8
Folie 65 WS8 Study report Schrader no 857-CCT-06-482 14. November 2006

Seipel; 03.01.2007
Soft Care Body Wash
Ingredient 1. 2. 3. 4. 5. 6. 7. 8. 9. Aqua Edenor C 12-98 Edenor C 14-98 Glycerine Aqua KOH [95%] Dehyton ML Comperlan KD T Arlypon TT
INCI
weight % (as is)
function
10. perfume 11. preservative
water 52.6 Lauric acid 11.6 Myristic Acid 5.3 Glycerine 2.0 water 9.0 Potassium Hydroxide 4.5 Sodium Lauroamphoacetate 6.0 Cocamide DEA 6.0 PEG/PPG-120/10 Trimethylolpropane Trioleate [and] Laureth-2 3.0 fragrance q.s. preservative q.s.
Soap Soap Moisturizer/solvent pH adjustment Surfactant Surfactant Thickener Fragrance Preservative
pH-value viscosity mPas
9.3 2000
(no.: HB-KR/07/027/01)
1. Heat 1, 2, 3, 4 to 75~80, premix solution of 5 and 6 slowly add while stirring at 75~80 2. Neutralization step. Keep the temp. stirring until homogenous, Adjust the pH around 9.5 3. Cool down to 50, add 7, 8, 9, and cool down to 40, add other raw materials
Chart no. 66

12.04.07 Arlypon TT Incosmetics

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12.04.07 Arlypon TT Incosmetics

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Arlypon

A turbo thickener that tames surfactants

Turbo Thickener that tames surfactants

Performance profile of thickeners

A micellar thickener forms rod micelles and stabilizes these.

From Sphere to Rod Like Micelle

20000 18000 16000 14000 12000 10000 8000 6000 4000

Viscosity adjustment with NaCl

standard surfactant combinations

viscosity adjustment with low amount of electrolytes

stabilizing heterogeneous systems by

adjustment of the density e.g. pearl shine waxes

Thickening by Fatty Alcohol EO and NaCl

Viscosity adjustment with Laureth-2 and NaCl

10 +23C +30C +40C

Advantages: Easy to handle = liquid Sufficient temperature viscosity stability

Disadvantages: For standard surfactant systems only Limited viscosity potential

general chemical structure

Standard surfactant formulation with associative thickener

PEG-120 Methyl Glucose Dioleate

low surfactant concentrations difficult to thicken ingredients

10 +23C +30C +40C

PEG/PPG-120/10 Trimethylolpropane Trioleate (and) Laureth-2

clear liquid 9 11 % 5.0 6.5 0.95 1.00

The Synergistic Thickener

PEG/PPG-120/10 Trimethylolpropane Trioleate as an associative thickener

Laureth-2 as a micellar thickener

An associative thickener links micelles and builds up an agglomerate of thickener and

A micellar thickener forms rod micelles and stabilizes these.

c obi oph r hyd

Performance in SLES - Free Surfactant Systems

12% WAS + 1% Arlypon TT

10% WAS + 1% Arlypon TT

en i ck d h to t blen lt icu tant diff rfac su

Performance in SLES - Free Surfactant Systems

Viscosity improvement in SLES - Free formulations

PEG/PPG-120/10 Trimethylolpropane Trioleate [and] Laureth-2

PEG-200 Hydrogenated Glyceryl Palmate [and] PEG-7 Glyceryl Cocoate

PEG-120 Methyl Glucose Dioleate

Performance in SLES - Free Surfactant Systems

Specific Mild Shower Bath for Sensitive Skin

function Surfactant Surfactant Surfactant Emollient Thickener Fragrance Preservative pH adjustment

fragrance preservative Citric Acid

The Synergistic Thickener

Viscosity Performance in SLES - Free surfactant systems

Very good thickening power without additional NaCl

Arlypon TT shows better viscosity in SLES-free surfactant systems than benchmarks

Performance in SLES - Poor Surfactant Systems

weight % (as is)

pH-value washing active substance

5.5 11.9% (no.: HB-DE/06/090/....)

Performance in SLES - Poor Surfactant Systems

Viscosity improvement in a SLES - Poor formulation

80000 60000 40000

spindle no TE, 4 rpm spindle no 4, 10 rpm

Performance in SLES - Poor Surfactant Systems

Thickening behavior in a formulation with low SLES content

PEG/PPG-120/10 Trimethylolpropane Trioleate [and] Laureth-2

PEG-200 Hydrogenated Glyceryl Palmate [and] PEG-7 Glyceryl Cocoate

PEG-120 Methyl Glucose Dioleate

Performance in SLES - Poor Surfactant Systems

0 5,0 6.0 7,0

SLES poor Mild Shampoo