CBSE TEST PAPER-06 Class XI Chemistry Time :-3 Hrs. General Instructions: (i) All questions are compulsory.

. (ii) Q. No. 1 to 8 carry 01 mark each. (iii) Q No. 9 to 18 carry 02 marks each. (iv) Q No. 19 to 27 carry 03 marks each. (v) Q. No. 28 to 30 carry o5 marks each. (vi) Use log table if necessary, calculator is not permitted. Q1. Q2. How many inner transition series are present in the f-block? Give the general electronic configuration of the members of the carbon family. Q3. Q4. Q5. Q6. Write Charless law. When is bond energy equal to bond dissociation energy? What are conjugate acid and conjugate base of H2O? Write formula of Kc for following equilibrium. N2 + O2 2NO Q7. Balance the following reaction in acidic medium. NO3- NO2 Q8. Q9. Give one use of dihydrogen (H2). Give reasons: (i) Water can extinguish most fires but petrol fire. (ii) Temporary hard water becomes soft on boiling. Q10. Calculate the molar mass of water if water sample contains 50% heavy water (D2O). Q11. State as to why: (i) The hydroxide of alkali metals are strong bases. (ii) Sodium is stored in kerosene oil. Q12. Define disproportionate with suitable example. [3] [3] [2] [2] [2] [2] [1] [1] [1] [2] [1] [1] M.M.70

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Q13.

Write short notes on any two. (i) Adiabatic process (ii) Extensive properties (iii) Entropy (iv) Isolated system

[3]

Q14.

Same mass of diamond and graphite (both being carbon) are burnt in oxygen. Will the heat produced be same or different? Why?

[3]

Q15.

Calculate the no. of atoms in 64 g of SO2 at N. T. P. (S = 32, O = 16)

[3]

Q16.

Sodium Chloride (NaCl) gives white ppt with AgNO3 solution but chloroform doesnt. Explain.

[5]

Q17.

Explain the following: (i) Fluorine is most electronegative element. (ii) Cesium is used in photoelectric cell.

[5]

Q18.

Give the electronic configuration of the following ions: (i) CO3+ (At No. of CO = 27) (ii) Fe2+ (at. No. of Fe = 26)

Q19.

Chorine is prepared by action of HCl on MnO2. 4HCl + MnO2 MnCl2 + 2N2O + Cl2 How many grams of HCl react with 3.84 g. (At mass of Mn = 55)

Q20.

The mass of an electron is 9.1 x 10-31 kg. If its K.E. is 3 x 10-25 J. Calculate its wavelength.

Q21.

(a) What is the basic differences between the terms electron gain enthalpy and electro negativity. (b) In terms of period and group, where would you locate the element with atomic number 10.

Q22.

Calculate No. of sigma and pi bond in following: (i) CH2 = CH CH3 (ii) CH3C CCH2OH
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(iii) CH3CH2CH3 Q23. Predict the type of hybridization and shape of the following molecules on the basis of VSEPR theory. (i) BF3 (ii) SF4 (iii) CH4 Q24. Calculate the total pressure in a mixture of 8 g of oxygen and 4 g of hydrogen confined in a vessel of 1 dm3 at 270 C. (R = o.o83 bar dm3 K-1 mol-1) Q25. Balance the following equation by used oxidation number method in basic medium. P4 + OH- PH3 + H2PO-2 Q26. What do you mean by solubility product. Calculate Ksp of AgCl at 270 C. It its solubility in a saturated solution is 1.435 x 10-3gL-1 at same temperature. (Ag = 108, Cl = 35.5) Q27. Q28. What are hydrides. Write different types of hydrides with examples. What transition in the hydrogen spectrum would have same wavelength as Balmer transition n = 4 to n = 2 of He+ spectrum. OR The work function for calcium atom is 1.9 e.v. Calculate: (a) The threshold wavelength (b) the threshold frequency If the metal is irradiated with a wavelength 500 nm. Calculate Kinetic energy and the velocity of the ejected photoelectrons. Q29. (a) State the law governing entropy and temperate. (b) Define enthalpy of formation under standard conditions. Calculate the enthalpy of formation of methane at 298 K. If enthalpies of combustion of methane, graphite and hydrogen at 298 K are 890.2 KJ, 393.4 KL and 285 mol-1 respectively.

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OR (a) State and explain first law of thermodynamics with its mathematical form. (b) H for the reaction

Is 150 KJ. Calculate the bond energy of C N bond. Bond energy of C H = n414 KL mol-1, H H = 435 KJ mol-1, C N = 293 KJ mol-1, N H = 396 KJ mol-1 Q30. (a) For a general reaction, derive a relation between Kc and Kp with absolute temperature and gas constant Rx is aA + bB cC + dD. (b) What is the importance of HCl during the precipitation of sulphide of 2nd group. OR (a) What do you mean by Le-Chateliers principle. By using it identify the suitable conditions for good yield of ammonia. N2 + 3H2 2NH3. (b) For reaction: 2A B + C the equilibrium constant Kc is 2.0 x 10-3. In which direction the reaction will proceed if the composition of the reaction mixture at any time is: [A] = [B] = [C] = 3.0 x 12 mol L-1.

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