Homework 3, Chemistry 1211, Mrs. Denton Due November 3 at the beginning of class.

Multiple choice, each question has only one correct answer. Question 21 is a problem to be worked. 1. The body heat of a person is responsible for emitting electromagnetic waves that have a wavelength of approximately 8.0 * 10 7 m. What is the frequency associated with these electromagnetic waves in Hz? A. 5.30 * 10-40 D. 3.75 * 10
14

B. 4.17 * 10-3

C. 240 E. 2.67 * 1015

2. . As you go from left to right on the periodic table, which of the following is true regarding atomic size of atoms? A. atoms get smaller because the nucleus gets stronger B. atoms get smaller because the valence electrons are at a larger n quantum number C. atoms get larger because the nucleus gets stronger D. atoms get larger because the valence electrons are at a larger n quantum number E. atoms get larger because the atomic mass increases

3. . How many valence electrons are in Arsenic (As)? A. 1 B. 3 C. 5 D. 13 E. 15

4. Which of the following orders the atoms Beryllium, Boron and Carbon in increasing ionization energy?

A. Beryllium < Boron < Carbon B. Carbon < Boron < Beryllium C. Carbon < Beryllium < Boron D. Boron < Beryllium < Carbon E. Boron < Carbon < Beryllium

5. . Which answer below has both a set of quantum numbers that represent the 4d-orbital? A. n =4, l = 4 D. n = 5, l = 4 B. n = 4, l = 3 C. n = 4, l = 2 E. n = 3, l = 3

6. . Which set of quantum numbers is not possible? A. n = 4, l = 3, ml = -3

B. n = 17, l = 6, ml = 0 C. n = 1, D. n = 2, E. n = 3, l = 0, ml = 0 l = 2, ml = 2 l = 1, ml = -1

7. . Which quantum number describes the orientation of an orbital in regards to the x, y and z-axis? A. n B. l C. ml D. ms E.

8. . Which atom would have an electron configuration of [Kr] 5s24d105p2 A. Ge B. Se C. Sn D. Ba E. Te

9. . Which pair of reactions below demonstrates both the ionization energy and electron affinity for Calcium? A. Ca Ca+ + e and B. Ca + e Ca+ and Ca Ca + e Ca + e Ca + e Ca + e Ca Ca Ca+

C. Ca Ca+ + e and D. Ca Ca + e and E. Ca + e Ca+ and

Ca Ca + e

10. What is the electron configuration for Cd2+? A. [Kr] 5s24d8 B. [Kr] 5s24d105p2 C. [Kr] 4d8 D. [Kr] 5s24d10 E. [Kr] 4d10 11. A compressor tank holds 20.0 L of a gas at 715 torr with a temperature of 30.0 Celsius. How many moles of gas are in the tank? (760 torr = 1 atm)

A. 575 mol

B. 45.9 mol

C. 7.64 mol

D. 0.756 mol

E. 0.0621 mol

12. What is the identity of a gas that has a density of 3.48 g/L and a volume of 12.8 L at a pressure of 1.61 atm and with a temperature of 349.6 Kelvin. A. H2 B. NO3 C. SO2 D. N2 E. Cl2

13 . For a sealed gas chamber, if the volume remains constant, and temperature increases from 125 Celsius to 250 Celsius, what is the final pressure of the chamber if the initial pressure is 1.25 atm? A.0.609 atm D. 1.64 atm B. 0.675 atm E. 2.50 atm C. 1.25 atm

14. Which of the following gases would effuse slowest down a tube? A. O2 B. Ar C. Br2 D. Ne E. CH4

15. A sample of Kr diffuses down a long, narrow tube at a rate of 1.31 m/s. What rate would N2 diffuse down the same long, narrow tube? A. 0.438 m/s B. 2.27 m/s C. 3.20 m/s D.3.92 m/s E. 11.7 m/s

16. In the chemical reaction: 2 NO3 (l) N2 (g) + 3 O2 (g) what is the partial pressure of N2 that results from 61.2 g of NO2 reacting in a sealed chamber of 15.2 L and a constant temperature of 344.35 Kelvin? A. 0.917 atm D. 3.67 atm B. 1.83 atm E. 7.34 atm C. 2.75 atm

17. Which of the following atoms would have the greatest first ionization energy? A. Oxygen B. Potassium C. Iron D. Neon E. Boron

18. According to Graham s law times of effusion are directly proportional to the molar masses of gases, thus;
     

(Note that rates of effusion are inverse.)

Calculate the molar mass of an unknown gas if it takes 163 sec. to effuse into a vacuum, and it takes 103 sec. for an equal amount of N2 under the same conditions of temperature and pressure. A. 44.3 g/mol B. 70.2 g/mol c. 35.2 g/mol D. 17.7 g/mol E.495 g/mol

19. A period 3 element has the following ionization energies in kJ/mol; 1st 1012 What is its identity? A. Aluminum B. Silicon C.Phosphorus D. Sulfur E. Chlorine 2nd 1903 3rd 2910 4th 4956 5th 6278 6th 22,230

20. Which of the following ions is not isoelectronic with Argon? A. ClB. K+ C. S2D. Na+ E. Ca 2+

21. Extra credit problem: The De Broglie equation describes the wavelengths of particles relative to their mass (m) and velocity (v)using Planck s constant. (h = 6.626 * 10-34 J-s). Find the wavelength of an object that has a mass of 9.11 * 10-31 kg moving at a speed of 1.55 * 107 m/s? Joules are a derived unit equaling 1 kg m2/s2