Beruflich Dokumente
Kultur Dokumente
| 02 |
Advanced Ceramics
Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .04 Experienced Material Specialist . . . . . . . . . . . . . . . . . . . . . . . . . . . . .04 Development . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .05 Innovative Power and Support . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .05 Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .06 Value-Added Product Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . .06 Product Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .07 Boron . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .07 Borides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .08 Carbides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .09 Nitrides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11 Oxides, Silicon and Silicides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13 AMPERPRESS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14 AMPERGY Solid Oxide Fuel Cell Powders . . . . . . . . . . . . . . . . . . .15
| 03 |
Materials
Development
>
Materials stands for H.C. Starcks material competence which is unique the world over and extends throughout the company both vertically and horizontally.
>
Development stands for the innovation potential and expertise that makes us a driving force behind new products, applications and global markets.
Solutions
>
Solutions stands for the ability to support our customers with appropriate or even customized product solutions across their entire value chain.
| 04 |
| Materials |
| 05 |
| Development |
Customized Products
Through our Applications Engineering you also have access to H.C. Starck's Central Laboratory in Goslar, one of the largest industrial laboratories in Germany for inorganic element analysis and powder characterization. Our laboratories will contribure to the sucess of our products by providing world class processing methods.
Central Laboratory
Powder Characterization
> > > > > > High resolution imaging, using scanning electron and optical microscopes Elemental analyses XRD analyses, providing chemical and structural information Physical properties testing (PSD, BET, density, tap density, etc.) Full metallographic tools, including sample preparation techniques Zeta potential measurement
Ceramic Laboratory
> > > > > > Various milling equipment Laboratory spray dryer Hydraulic pressing unit CIP facility Gas pressure sintering furnace Microhardness measurement
| 06 |
| Solutions |
Distribution
H.C. Starck is represented by its own sales offices and agencies in many different countries throughout the world. A cooperation agreement was concluded with the company ABCR specially for research institutes, universities and other interested parties having small volume requirements in order to offer these customers appropriate care and support. ABCR GmbH & Co. KG Im Schlehert 10 76187 Karlsruhe/Germany www.abcr.de hcstarck@abcr.de ABCR is responsible for small quantities of ceramic powders from a few grams up to 100 kg. The documentation, i.e. works report of H.C. Starck, is in place.
All datasheets (following pages) within this brochure are available for download at www.hcstarck.com
H.C. Starck produces also Thermal Spray Powders. The trademark AMPERIT stands for high-grade spray powders (carbides, oxides, pure metals, alloys & blends) for a variety of applications. From powder development to complete coating solutions, H.C. Starck's experts provide customers with technical help and advice based on their extensive know-how in materials and coatings technology. Brochures are available in printed form and can also be downloaded at www.amperit.info
Solutions | 07 |
BORON
n Av er a Si ge ze Pa Di / r ffr La tic ac se le tio r n d Sp 50 m ec i ti o
Ar fic ea Su m 2 (BE rfac /g T ) e
Ty pe
Pr od
Amorphous Boron
Grade I(e) Grade II(e) Grade III(e)
min. 95 % Boron, Mg max. 0.8 % min. 90 % Boron, Mg max. 6.0 % min. 86 % Boron, Mg max. 12.0 %
Sh or
tD
uc
es c
ri p
Typical Applications
automotive (igniter in airbags and belt tighteners) additive in pyrotechnic mixtures (flares, igniters and delay compositions) additive in solid rocket propellant fuels and explosives preparation of refractory metal borides sintering additive for SiC advanced ceramics reducing additive in fluxes for soldering stainless steel neutron absorber in nuclear technology
Crystalline Boron
Grade K1 Grade K2 Grade KT 1 Grade P1(e)
min. 99.4 % Boron, lumpy, main particle size 1 20 mm min. 99.4 % Boron, lumpy, main particle size 3 8 mm min. 98.0 % Boron, lumpy, main particle size 1 20 mm min. 98.0 % Boron, fine powder less than 38 m
25.0
0.6 2.0
Other grades, i.e. fine and coarse powders are available on request.
Typical Applications
> neutron shields and absorbers in nuclear reactors > thermistors > filaments > preparation of high-purity metal borides > metallurgy (deoxidizing agent)
The values in above tables are typical values only and do not constitute a specification.
| 08 |
BORIDES
n Av er a Si ge ze Pa Di / r ffr La tic ac se le tio r n d 50 Sp m ec
O max. 0.3 % O max. 0.6 % O max. 1.5 %
ti o
Pr od
Sh or
8 12 4 7 2 3
Other grades, i.e. coarse and fine powders, are available on request.
Grade A
Other grades, i.e. coarse and fine powders, are available on request.
90 % less than 45 m
O max. 0.6 %
10.0 15.0
Other grades, i.e. coarse and fine powders, are available on request.
powder for hot pressing, technical grade powder for sintering, 90 % < 4.5 m higher N, O, Fe contents
High purity powders, coarse and doped powders are available on request.
> hot-pressed composites of excellent electrical conductivity, e.g., evaporation boats (TiB2-BN or TiB2-BN-AlN) for continuous aluminum metallizing > crucible material for non-ferrous metals (Al, Cu, Mg, Zn, etc.) > ceramic shapes to be used in production of Al in Hall-Hroult cells > hot pressed TiB armor plates > cutting tools and cermets, used for machining aluminium > Metal Matrix Composites (MMCs)
2
> see TiB2 > antioxidant in carbon-bonded refractories > burnable absorbers for neutrons
Other Borides:
CrB, CrB2 , CrB2+Ni and other borides are available on request. AlB2, HfB2 and other borides are available on request.
The values in above tables are typical values only and do not constitute a specification.
Ty pe
tD
uc
es c
ri p
Solutions | 09 |
CARBIDES
n Av er a Si ge ze Pa Di / r ffr La tic ac se le tio r n d Sp 50 m ec i
B:C ratio 3.8 3.9 B:C ratio 3.7 3.8 B:C ratio 3.8 4.0 B:C ratio 3.6 3.9 B:C ratio 3.7 3.9
ti o
Pr od
Grade HP(e) Grade HS(e) Grade HD 07(e) Grade HD 15(e) Grade HD 20(e) Typical Applications
Sh or
06.0 09.0 15.0 20.0 6.0 9.0 15.0 21.0 22.0 27.0
abrasive grit or powder (grinding, lapping, polishing) wear resistant engineering components (e.g. sand-blasting and water jet nozzles) light weight ceramic armor metal infiltration boron source to produce other boron compounds high-temperature thermoelements sintering additive for SiC advanced ceramics neutron shielding material
15.0 25.0
for brake pad formulations corrosion resistance parts hot working tools grain growth inhibitor
4.0 6.0 09.0 11.0 14.0 16.0 23.0 26.0 11.0 13.0 16.0 18.0 4.0 6.0
For AMPERPRESSTM SiC premix grades see page 14. Other grades, i.e. doped and fine SiC powders, are available on request.
Typical Applications
sliding bearings seal rings wear parts kiln furniture, crucibles, heating elements, burner nozzles, heat exchangers semiconductor handling parts components for wafer processing (susceptors, chucks, carriers) electronic applications (varistors, diodes)
The values in above tables are typical values only and do not constitute a specification.
Ty pe
tD
uc
es c
ri p
| 10 |
CARBIDES
n ti o io ct La s d er D 50 m iff ra
free C free C free C free C O max. 1.3 % O max. 0.8 % O max. 1.0 % O max. 0.5 %
Ty pe
ri p
Typical Applications
> hardmetals (tooling and machining) > cermets > black ceramics, e.g. (Al2O3-TiC)
Typical Applications
> additive for hard metals > additive in powder metallurgy (TZM Titanium-Zirconium-Molybdenum) > moderator in solid fuel propellant
Other Carbides
Al4C3(4), Mo2C, NbC, TaC, VC, WC and other carbides are available on request. Al4C3(4), Cr3C2, HfC, Mo2C and other carbides are available on request.
The values in above tables are typical values only and do not constitute a specification.
Pr od
Sh or
tD
uc
es c
Solutions | 11 |
NITRIDES
n Av er a Si ge ze Pa Di / r ffr La tic ac se le tio r n d Sp 50 m ec i
O < 1.0 % O < 1.5 % O < 2.0 % O < 1.3 %
ti o
Pr od
Sh or
Coarse and fine powders and experimental grades are available on request.
high thermally conductive ceramics composite ceramics, e.g. evaporation boats SiAlONs heat sinks electrically insulating packages for electronics crucibles for metals and salt melts thermally conductive filler for polymers components for wafer processing (susceptors, chucks, carriers)
Boron Nitride BN
Grade A 01 Grade B 50 Grade C Grade F 15
white powder white powder white powder for hot-pressing (min. lot size 100 kg) very fine white powder BO
2 3
BO
2
BO
2
BO
2
max. 0.3 %
Coarse and fine powders and experimental grades are available on request.
Typical Applications
solid lubricant for high-temperature applications mold release for die casting and injection molding raw material for cubic BN thermally conductive filler for polymers composite ceramics, e.g. evaporation boats starting material for hot-pressed BN parts refractories
Other powders with low oxygen and high purity are available on request.
ceramic cutting tools heavy duty components in automotive engines high-performance parts for mechanical engineering bearing components, like high precision balls SiAlONs metallurgy (thermocouple protection tubes, stalk tubes, crucibles) chemical engineering, e.g. heat exchangers functional parts in textile machinery releasing agent in Silicon ingot production
The values in above tables are typical values only and do not constitute a specification.
Ty pe
tD
uc
es c
ri p
| 12 |
NITRIDES
ti o n io
N2 10.5 11.5 % 10.5 11.5 % 10.3 11.3 %
Ty pe
ri p
La s d er D 50 m iffr a
Typical Applications
> hardmetals (tooling and machining) > cermets > black ceramics
> additive for ceramic parts to increase electrical conductivity > constituent of cermets and black ceramics > raw material for TiN sputter targets (PVD)
Other Nitrides
CrN1-x, Cr2N, Li3N(4+9+15), TaN, ZrN and other nitrides are available on request. CrN1-x, Cr2N, ZrN and other nitrides are available on request.
NOTES
Hazards identification in advertising (Directive 67/548/EEC Article 26 and Directive 1999/45/EC Article 13)
Please refer to our safety data sheet for details. (4) highly flammable (8) harmful (9) corrosive (15) dangerous for the environment (e) This product is under export control. Please contact H.C. Starck for more details.
(x) Purchaser agrees to indemnify and hold harmless H.C. Starck from any and all liability, damages, loss or expense connected with any claim of patent infringement arising out of production and delivery by seller of product in accordance with Purchaser's specification pursuant to this transaction and all related transactions.
The values in above tables are typical values only and do not constitute a specification.
Pr od
Sh or
tD
uc
es c
ct
Solutions | 13 |
ti o
Pr od
Sh or
15.0 17.0
sintering additive for Si3N4 and AlN stabilizer for zirconias (PSZ) and insulating coatings (TBCs) catalyst carrier yttria stabilized zirconia electrolytes for solid oxide fuel cells (SOFC) luminescent materials (phosphors) constituent of high-temperature superalloys and ODS materials additive in special glass (Yttralox)
composite ceramics heating elements constituent of glow plugs for engines raw material for MoSi2 sputter targets (PVD)
The values in above tables are typical values only and do not constitute a specification.
Ar ic ea Su m 2 (BE rfac /g T ) e
Ty pe
tD
uc
es c
ri p
| 14 |
NEW: AMPERPRESSTM
New Product Line
Under the tradename AMPERPRESSTM H.C. Starck is offering a new product line with powder formulations including processing and sintering additives. > granulated by using spray-drying technology > ready-to-press systems
sliding bearings > seal rings > wear parts kiln furniture, crucibles, heating elements, burner nozzles, heat exchangers semiconductor handling parts components for wafer processing (susceptors, chucks, carriers) electronic applications (varistors, diodes)
ceramic cutting tools heavy duty components in automotive engines high-performance parts for mechanical engineering bearing components, like high precision balls SiAlONs metallurgy (thermocouple protection tubes, stalk tubes, crucibles) chemical engineering, e.g. heat exchangers functional parts in textile machinery
The values in above tables are typical values only and do not constitute a specification.
tio
Pr od
Sh
14 16 14 16
12 14 12 14
max. 0.1
15 17
Ar ic S ea u m 2 (BE rfac /g T ) e
Ty pe
or
tD
uc
es c
rip
Solutions | 15 |
ia
ie
Ra tio
GDC
Fe K Na Si Al K Na Si Al Fe K Na Si Al K Na Si Al K Na Si Al Fe Na Si
Im
500 ppm 50 ppm 200 ppm 100 ppm 300 ppm 10 ppm 100 ppm 150 ppm
0.1 10 m/g
MCF 2)
0.1 5 m/g
LSM 3)
(La+Sr)0.95MnO3
< 100 ppm < 1000 ppm < 10 ppm < 100 ppm < 150 ppm < < < < < < < < < < < < 300 ppm 10 ppm 100 ppm 150 ppm 300 ppm 10 ppm 100 ppm 150 ppm 200 ppm 100 ppm 100 ppm 100 ppm
0.1 8 m/g
LSCM 2)
La0.8Sr0.2Co0.5Mn0.5O3 La0.8Sr0.2Co0.2Mn0.8O3
0.1 10 m/g
LSCF 2)
La0.58Sr0.4Co0.2Fe0.8O3
0.1 10 m/g
YSZ
15 17 m/g
PRELIMINARY SPECIFICATIONS (The products described are still under test. Amendments of all technical data are possible. Special care has to be taken while processing.) 1. Tristar 3000;3 point by BET per ASTM D 3663 2. New substances under regulation (EG) 1907 / 2006 (REACH), Art. 3, Nr. 22 3. reported new substance under chemicals law Various other stoichiometries are available on request. Other oxides and metal powders for fuel cells are under development. The values in above tables are typical values only and do not constitute a specification.
Su rfa ce
at er
pu
rit
Ar ea 1 )
Europe
H.C. Starck GmbH Im Schleeke 7891 38642 Goslar Germany Sales T +49 5321 751 -3145 F +49 5321 751- 4145 bettina.essmann @hcstarck.com Application Engineering T +49 5321 751 -3962 F +49 5321 751 -4962 thomas.schmidt @hcstarck.com H.C. Starck International Sales GmbH Branch Office UK Aizlewoods Mill, Nursery Str. Sheffield S3 8GG United Kingdom T +44 114 282 3156 F +44 114 282 3244 helen.cousins@hcstarck.com H.C. Starck International Sales GmbH Branch Office France, Italy and Spain 36 Rue des tats Gnraux 78 000 Versailles France T +33 1 3951 4815 F +33 1 3951 4993 herve.rousseau@hcstarck.com
For minor advanced ceramic material requirements please contact
H.C. Starck International Sales GmbH Branch Office Scandinavia Kungsporten 4A 42750 Billdal, Sweden T +46 31939590 F +46 31832575 kennet.almkvist@hcstarck.com
ABCR GmbH & Co. KG Im Schlehert 10 76187 Karlsruhe Germany T +49 721 95061-0 F +49 721 95061-80 hcstarck@abcr.de
North America
H.C. Starck Inc. 8050 Beckett Center Dr., Suite 304 West Chester, OH 45069 USA T +1.513.942.2815 F +1.513.942.0354 karsten.beck@hcstarck.com
Asia
H.C. Starck Ltd. 1-30-5 Hamamatsucho Minato-ku, Tokyo 105-0013 Japan T +81 3 5776 5023 F +81 3 5402 0071 kunihiko.tozaki @hcstarck.com H.C. Starck International Sales GmbH Branch Office Taiwan 5F, No. 188, Sec 5, Nanjing E. Rd. Taipei 10571 Taiwan, Republic of China T +886 2 2528 8936 F +886 2 2528 8829 jim.huang@hcstarck.com H.C. Starck International Sales GmbH Branch Office Korea 5th Fl. Ilwon Bldg., 1001-1 Daechi-Dong, Kangnam-Gu, Seoul, Korea T +82 2538 0740 F +82 2538 2031 gihong.park@hcstarck.com H.C. Starck Trading (Shanghai) Co. Ltd. Room 302 City Gateway No. 398 North Caoxi Road Xu Hui District, Shanghai 200030 Peoples Republic of China T +86 21 60905255 F +86 21 60905256 david.dai@hcstarck.com
HDW 09/08
The conditions of your use and application of our products, technical assistance and information (whether verbal, written or by way of production evaluations), including any suggested formulations and recommendations, are beyond our control. Therefore, it is imperative that you test our products, technical assistance and information to determine to your own satisfaction whether they are suitable for your intended uses and applications. This application-specific analysis at least must include testing to determine suitability from a technical as well as health, safety and environmental standpoint. Such testing has not necessarily been done by H.C. Starck. All information is given without warranty or guarantee. It is expressly understood and agreed that the customer assumes and hereby expressly releases H.C. Starck from all liability, in tort, contract or otherwise, incurred in connection with the use of our products, technical assistance and information. Any statement or recommendation not contained herein is unauthorized and shall not bind H.C. Starck. Nothing herein shall be construed as a recommendation to use any product in conflict with patents covering any material or its use. No license is implied or in fact granted under the claims of any patent. Properties of the products referred to herein shall, as a general rule, not be classed as information on the properties of the item for sale. In case of order please refer to issue number of the respective product data sheet. All deliveries are based on the latest issue of the product data sheet and the latest version of our General Conditions of Sale and Delivery.
H.C. Starck GmbH Im Schleeke 78 91 38642 Goslar Germany T +49 5321 751-0 F +49 5321 751-6192 info@hcstarck.com www.hcstarck.com