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ATOMIC STRUCTURE.
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The proton and neutron together called as Charge on proton is , electron is and neutron is . Electron was discovered by First model of atom was proposed by According to Thomson electrons are present in Thomson's model of atom failed to explain Rutherford proposed the model of atom based on his experiment. Rutherford's model of atom is also known as According to Rutherford, atoms are in shape. Most of the mass of the atom is present in its According to Rutherford, the two forces acting on the electron are and Quantum theory of radiation is proposed by
According to Quantum theory electromagnetic radiation is in the form of packets called

forces.
.

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Quantum principle is In the formula E = hv 'h' is Planck based on his theory explained the radiation of Value of Planck's constant is Bohr proposed a model of atom based on According to Bohr's model, electrons revolve in The energy of a stationary orbit which is near to the nucleus is Electron jumps from energy level to energy level. When electron jumps form higher energy level to lower energy level the difference in the energy levels is radiated as Angular momentum of electron is equal to In the formula mvr = nh /2n 'n' is known as Splitting of spectral lines in the presence of magnetic field is known as Bohr's model is applicable only for the atoms of Elliptical orbits are introduced by The angular momentum of an electron revolving in elliptical orbit is
According to Sommerfeld stationary orbits are further divided into .

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Dual nature of electron was explained by . De broglie explained based on the dual nature of electron. Wave equation of electron was proposed by Derivations of wave equation lead to Stationary orbits are denoted by Sub stationary orbits are also known as The number of sub stationary orbits present in a stationary orbit depends on value. Number of sub stationary orbits in M orbit are Principle quantum number was proposed by 'n' value of N shell is The quantum number which gives the size and energy of an orbit is No. of sub stationary orbit in a stationary orbit is Azimuthal quantum number was proposed by
Azimuthal quantum number is also known as

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For a given value of n, the maximum value of l is Shape of sub stationary shell can be determined by using When l = 0, the shape of the orbit is Magnetic quantum number was proposed by . 'm' value depends on For a given 'l' value, 'm' can have values. The boundaries of 'm' values for a given 'l' value are Orbitals having same energy are called The orientation of orbitals in the presence of magnetic field can be determined by Reenat Education

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The shell having least energy is . Sub shells present in L- shell are Maximum value of l when n=5 is f- orbital is present in shell. No. of sub shells present in L shell are Spin quantum number was proposed by Spin of electrons takes the values as No. of electrons present in a sub shell are The region in space where there is finite probability of finding electron is called Shape of s- orbital is Type of orbital present in K- shell is Type of orbital present in L- shell are Type of orbital present in M-shell are Type of orbital present in N- shell are ' The n+l value of 3 s orbital is .
The region in space where the probability of finding electron is zero is called

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P-orbitals will start in shell. Shape of P-orbital is 'd'-orbital will start from The number of d- orbitals present in n = 3 is . The orbital with least energy is Among 3 s, 3p the orbital having least energy is . has given a diagram to know the order of energy levels of orbitals. A systematic representation of the occupation of electrons in the orbitals is known as According to principle electron occupies the orbital having lowest energy. Aufbau principle in terms of quantum numbers, the incoming electron occupies an orbital whose n+l value is The 'l' value of s-orbital is The 'l' value of p-orbital is . The 'l' value of d-orbital is The 'l' value of f-orbital is rule states that electron pairing takes place only after al the available degenerate orbitals are occupied by one electron each.
principle states that no two electrons will have all four quantum numbers same.

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Electronic Electronic Electronic Electronic

configuration of Si (Z = 14 ) is configuration of Zn (Z=30) is configuration of K (Z=19) is configuration of Cr (Z=24) is

The distance between nucleus and valency orbital is known as

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Units of atomic radius A0. 1 A0 = cm. Atomic radius depends on The minimum energy required to remove an electron from the outer most orbital of an atom in gaseous state is known as Units of Ionization Energy are As nuclear charge increases the I.E. As the ion charge increases the I.E. . I.E. with increase in atomic size. The energy released when an electron is added to a neutral gaseous atom in its lowest nergy state is known as Electron affinity is measured in Among 3p, 4s, 3d and 4p the orbital having least energy is After filling the 3d orbital electron enters into orbital. Valence electronic configuration of Cu is Reenat Education

Reenat Education MATCHING GROUP:A 1. 2. 3. 4. 5. Neils Bohr. Sommerfeld Uhlenbeck & Goudsmith Lande Louis De - Broglie ( ( ( ( ( D A B E C ) ) ) ) ) A) B) C) D) E) F) G) GROUP:B Elliptical orbits. Spin Quantum number. Dual nature of electron. Stationary orbits Magnetic Quantum Number. Wave Equation. Planetary model.

GROUP:A 1. 2. 3. 4. 5. Principle Quantum number Wave equation Quantum theory of radiation Planetary model of atom Azimuthal quantum number ( ( ( ( ( D E C B A ) ) ) ) ) A) B) C) D) E) F) G)

GROUP:B Sommerfeld Rutherford. Max planck Neils Bohr. Erwin schrodinger Louis De-broglie J.J.Thomson GROUP:B ( A ( D ( B ( C ( E ) ) ) ) ) A) B) C) D) E) n=1 n = 3. f - orbital. n = 2. s,p,d,f,and g orbitals.

GROUP:A 1. 2. 3. 4. 5. K - Shell L - Shell M - Shell N - Shell O - Shell

GROUP:A 1. 2. 3. 4. 5. Ar Al Mg Ca Ne ( C ( E ( B ( F ( A ) ) ) ) ) A) B) C) D) E) F) G)

GROUP:B 1s2 1s2 1s2 1s2 1s2 1s2 1s2 2s2 2s2 2s2 2s2 2s2 2s2 2s2 2p6 2p63s2 2p63s2 2p63s2 2p63s2 2p63s2 2p63s2

3p6 3p2 3p1 3p64s2 3p4

ELECTRONIC CONFIGURATION OF SOME ELEMENTS Element Name of the element Hydrogen symbol H Atomic number 1 1s1 Electronic configuration Long form Valence configuration 1s1

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Reenat Education Helium Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorin Neon Sodium Magnesium Aluminium Silicon Phosphorous Sulphur Chlorine Argon Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc He Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 1s2 1s22s' 1s22s2 1s2 2s 2 2p' 1s2 2s2 2p2 1s2 2s2 2p3 1s2 2s2 2p4 1s22s22p5 1s22s22p6 1s22s22p63s' 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s 2s 2p 3s 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2 1s22s22p63s2
1 c21,2 -. 6 0

1s2 (He) (He) (He) (He) (He) (He) (He)

2s1 2s2 2s2 2p1 2s 2 2p 2 2s 2 2p 3 2s 2 2p 4 2s 2 2p 5

3P1 3p2 3p3 3p4 3p5 3p6 3p64s1 3p64s2


2

3p 4s 3d 3p64s23d2 3p64s23d3 3p64s13d5 3p64s23d5 3p64s23d6 3p64s23d7 3p64s23d 3p64s13d10 3p64s23d10

o-r.6 j

2 oj1

(He) 2s 2 2p 6 (Ne)3s1 (Ne)3s2 (Ne)3s23p1 (Ne)3s23p2 (Ne)3s23p3 (Ne)3s23p4 (Ne)3s23p5 (Ne)3s23p6 (Ar) 4s1 (Ar) 4s2 l A A/I J (Ar)4s 3d (Ar)4s23d2 (Ar)4s23d3 (Ar)4s13d5 (Ar)4s23d5 (Ar)4s23d6 (Ar)4s23d7 (Ar)4s23d8 (Ar)4s13d10 (Ar)4s23d10
1

ANSWERS
1) Nucleons 2) Positive, Negative, No charge 3) J.J.Thomson 4) J.J. Thomson 5) Nucleus 6) Atomic spectra 7) a - ray scattering experiment 8) Planetary model or Nuclear model 9) Spherical 10) Nucleus 11) Centripetal, Centrifugal 12) Max planck 13) Quanta 14) E = hv 15) Planck's Constant 16) Black body 17) 6.625 x 10-27 erg sec or 6.625 x 10-34 joule.sec 18) Planck's Quantum theory 19) Stationary orbit 20) Less 21) Higher, Lower 22) E 2 - E 1 = hv 23) mvr = nh /2n. 24) Principle q u a n t u m n u m b e r 25) Zeeman effect 26) Single electron 27) Sommerfield 28) mvr = kh/ 2n 29) Sub stationary orbits 30) Louis De Broglie 31) Quantizationof angular momentum 32) Erwin Schordinger 33) Atomic orbitals 34) Principle quantum number 35) Atomic orbitals 36) n 37) 3 38) Neils bohr 39) 4 40) Principle quantum number 41) n2 42) Somerfield 43) Angular momentum quantum number 44) n - 1 45) l 46) Circular 47) Lande 48) l 49) (2l + 1) 50) -l to +l 51) Degenerate orbitals 52) Magnetic quantum number 53) K 54) s and p 55) 4 56) N 57) 2 58) Uhlenbeck and Goudsmith 59) +1/2 or -1/2 60) 2 61) Orbital 62) Spherical 63) s 64) s and p 65) s, p, and d 66) s,p,d, and f 67) 3 68) Nodal region 69) L 70) Dumbell 71) M 72) 5 73) 1s 74) 3S 75) Moeller 76) Electronic configuration 77) Aufbau 78) n + l 79) 0 80) 1 81) 2 82) 3 83) Hund's 84) Pauli's exclusion 85) 1s22s2 2p6 3s2 3p2 (or) (Ne) 3s2 3p2. Reenat Education

Reenat Education 86) 1s22s2 2p6 3s2 3p6 4s2 3d10 (or) (Ar) 4s2 3d10. 87) 1s22s2 2p6 3s2 3p6 4s1 (or) (Ar) 4s1. 88) 1s22s2 2p6 3s2 3p6 4s1 3d5(or) (Ar) 4s1 3d5 89) Atomic radius 90) A0 91) 10-8 Cm 92) Principle quantum number 93) Ionization energy 94) e.v or K. Cal/mole or K. Joule/mole 95) increases 96) increases 97) Decreases 98) Electron Affinity 99) ev 100) 3p 101) 4p 102) 4s13d10.

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