Thermochemistrypart3

TypeofEntalphy Type of Entalphy

1. StandardEntalphyFormation(Hf0) N2 +3H2 2NH3 Hf0= 46kJ/mol 2. StandardEntalphyofDissociaton(Hd0) N2 +3H2 2NH3 Hd0=+46kJ/mol 3. StandardEntalphyofCombustion(Hc0) CH4 +2O2 CO2 +2H2OHd0=393.5kJ/mol

ExerciseofThermochemistry

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Titaniummetalisusedasastructuralmaterial y g pp j inmany hightechapplicationssuchasinjet engines.Whatis thespecificheatoftitanium inifittakes 89.7Jtoraisethetemperatureof in if it takes 89 7 J to raise the temperature of a33.0gblockby5.20C?Whatisthemolar heatcapacityoftitanium? heat capacity of titanium?

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CalculatethespecificheatofaliquidFirst,300 g gofitareputinthecalorimeterin placeof p p thewater,thenacurrentof0,742ampis passedfor3min 22sec withresistance8,5 passed for 3 min 22 sec with resistance 8 5 ohm, raisingitstemperaturefrom21,647Cto 22,406C 22 406C

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ThespecificheatofMnO2is0,117 cal/gC Howmuchheatisneededtoraisethe temperatureof120 gofMnO2 from20,0Cto 30,0 C? Whatisthemolarheat capacityof 30 0C? What is the molar heat capacity of MnO2?

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A50.0mLsampleof0.400Mcopper(II)sulfatesolutionat 23.35Cismixedwith50.0mL of 0.600Msodiumhydroxide solution,alsoat23.35C,inthecalorimeter.Afterthe l i l 23 35C i h l i Af h reactionoccurs,thetemperatureoftheresultingmixtureis measuredtobe 25.23 C.Thedensityofthefinalsolutionis measured to be 25 23C The density of the final solution is 1.02g/mL. CalculatetheenergyproducedinkJ/mol(Cu(OH)2 formed). Assumethatthespecificheatofthesolutionisthesameas thatofpurewater,4.184J/gC. CuSO4(aq) + 2NaOH(aq) Cu(OH)2(s) +Na2SO4(aq)

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Weburn14.4gofmagnesiuminexcess g p p nitrogenatconstant atmosphericpressureto formMg3N2.Thenwe bringthereaction mixturebackto25 C.Inthisprocess 136.7kJ mixture back to 25C In this process 136 7 kJ ofheatisgivenoff.Whatisthestandard molar enthalpy of formation of Mg3N2? enthalpyofformationofMg3N2?

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