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=
For these expressions, energies are expressed in electron volts per K
+
- Cl
-
pair, and r is
distance in nanometers. The net energy E
Net
is the sum of the two expressions above.
(a) Superimpose on a single plot E
N
, E
R
, and E
A
versus r up to 1.0 nm.
Curves of E
A
, E
R
, and E
N
are shown on the plot below.
1.0 0.8 0.6 0.4 0.2 0.0
-7
-6
-5
-4
-3
-2
-1
0
1
2
Interatomic Separation (nm)
B
o
n
d
i
n
g
E
n
e
r
g
y
(
e
V
)
E
A
E
R
E
N
r
o
= 0.28 nm
E
o
= -4.6 eV
MatS 2001 Fall 2011
Solutions to Problem Set #4
09/ 30/ 11 02: 05: 00 PM Page 3 of 4 FL11
(b) On the basis of this plot, determine (i) the equilibrium spacing r
0
between the K
+
and
Cl
-
ions, and (ii) the magnitude of the bonding energy E
0
between the two ions.
From this plot
r
o
= 0.28 nm
E
o
= -4.6 eV
(c) Mathematically determine the r
0
and E
0
values the equations derived in Problem (34)
and compare these with the graphical results from part b.
From the equation for E
N
A = 1.436 B = 5.86 x 10
-6
n = 9
Thus,
r
o
=
\
|
.
|
A
nB
1/(1 - n)
=
(
(
1.436
(9)(5.86 x 10
-6
)
and
1/(1 - 9)
= 0.279 nm
E
o
= -
1.436
(
(
1.436
(9)(5.86 x 10
-6
)
1/(1 - 9)
+
= - 4.57 eV
5.86 x 10
-6
(
(
1.436
(9)(5.86 x 10
-6
)
9/(1 - 9)
4-4 Make a plot of bonding energy versus melting temperature for the metals listed in Table
2.3. Using this plot, approximate the bonding energy for copper, which has a melting
temperature of 1084C.
Below is plotted the bonding energy versus melting temperature for these four metals. From this
plot, the bonding energy for copper (melting temperature of 1084C) should be approximately 3.6
eV. The experimental value is 3.5 eV.
MatS 2001 Fall 2011
Solutions to Problem Set #4
09/ 30/ 11 02: 05: 00 PM Page 4 of 4 FL11
4000 3000 2000 1000 0 -1000
0
2
4
6
8
10
B
o
n
d
i
n
g
E
n
e
r
g
y
(
e
V
W
F e
A l
H g
3 . 6 e V
M e l t i n g T e m p e r a t u r e ( C
4-5 An aluminum- alloy bar of length 2 meters at room temperature ( 300 K) is exposed to a
temperature of 100C ( =23x10
-6
K
-1
).
(a) What will be the length of this bar at 100C?
( ) ( ) ( )
6
0 0
23 10
1 1 2 1 373 300 2.0034 l l l T m K m
K
| |
= + = + = + =
|
\ .
a) What stress will be generated in the aluminum-alloy bar heated to 100C if the bar
was constrained between rigid supports and not allowed to expand? Will this stress be
compressive or tensile?
( )( )( )
6 1
70 23 10 373 300 117.53 E GPa K K MPa
= = =
This would be a compressive stress.