CODE : BLUE

32151/QB/HYD-RND-C-CO / IITJEE / 25-5-2011 / IITJEE

NARAYANA IIT ACADEMY

INDIA

Time : 3:00 ID.NO :

SR - IIT - SPARK IITJEE MODEL (2009 PAPER-1 )

Exam Date : 4-6-2011 Max Marks : 240

INSTRUCTIONS : 1) This booklet is your Question Paper containing 60 questions. Maximum marks: 240. 2) The question paper consists of 3 parts (Chemistry, Mathematics and Physics). Each part has 4 sections. 3) Section-I contains 8 multiple choice questions. Q.No: 1 to 8, 21 to 28 and 41 to 48. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct. For each questions in Section I, you will be awarded 3 marks if you have darkened only the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer, minus one (-1) mark will be awarded. 4) Section-II contains 4 multiple correct answer(s) type questions. Q.No: 9 to 12, 29 to 32 and 49 to 52. Each question has 4 choices (A), (B), (C) and (D), out of which ONE OR MORE is/are correct. For each question in Section II, you will be awarded 4 marks if you have darkened all the bubble(s) corresponding to the correct choice(s) for the answer, and zero mark if no bubble is darkened. In all other cases, minus one (-1) mark will be awarded. 5) Section-III contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions bearing Q.No: 13 to 18, 33 to 38, 53 to 58 have to be answered. Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct. For each question in Section III, you will be awarded 4 marks if you darken the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus one (-1) mark will be awarded. 6) Section-IV contains 2 questions. Q.No: 19, 20, 39, 40 and 59, 60. Each question contains statements given in two columns, which have to be matched. The statements in Column I are labeled A, B, C and D, while the statements in Column II are labeled p, q, r, s and t. Any given statement in Column I can have correct matching with ONE OR MORE statement(s) in Column II. For each question in Section IV, you will be awarded 2 marks for each row in which you have darkened the bubble(s) corresponding to the correct answer. Thus, each question in this section carries a maximum of 8 marks. There is no negative marking for incorrect answer(s) for this section.

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CHEMISTRY
SECTION-1
Section-I contains 8 multiple choice questions. Each question has 4 choices (A) , (B) , (C) and (D) , out of which ONLY ONE is correct. For each questions in Section I , you will be awarded 3 marks if you have darkened only the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer, minus one (-1) mark will be awarded.

1) Which of the following statements is wrong regarding ozone ? A) Ozone is used for sterilization of water . B) Ozone is an unstable, blue diamagnetic gas with characteristic pungent odour. C) The deep blue colour of ozone in liquid state is due to its paramagnetic nature. D) Ozone can oxidize cyanide ion to cyanate ion. 2) Which of the following is a correct reaction / statement ? A) B) C) D) can act only as monodetate ligand .

3) Identify the incorrect statement from the following? A) SO2 acts both as oxidizing agent as well as reducing agent B) C) In has a regular tetrahedral shape. , there are six and six bonds

D) SO2 is more powerful reducing agent in alkaline medium than in acidic medium.
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4) Which of the following statements regarding sulphurous acid is false? A) Ozone cannot decolorize acidified KMnO4 B) In alkaline solution reducing action of sulphurous acid is due to sulphite ion C) Sulphite ion is tetrahedral in shape with all S - O bond lengths are equal D) Among chaleogens, catenation property is maximum for sulphur. 5) In which of the following reaction(s) O2 is not formed as one of the products ?

A) 1 and 3 6) When

B) 1 and 4

C) 3 and 4

D) 1, 3 and 4

gas is passed into aqueous sulphur dioxide, is formed.

A) A clear solution of B) C) D) Both

only is converted into a yellow precipitate of sulphur . only is converted into a yellow precipitate of sulphur. and are converted into a yellow precipitate of sulphur. act as an oxidizing agent? B) D)

7) In which of the following reactions does A) C)

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8) The structure of the A) Only B) C) D)

molecule in the gas phase contains

bonds between sulphur and oxygen. bond between sulphur and oxygen only. bond between sulphur and oxygen only. bond and bond between sulphur and oxygen . SECTION-2

bonds and bonds and bonds ,

Section-II contains 4 multiple correct answer(s) type questions. Each question has 4 choices (A) , (B) , (C) and (D) , out of which ONE OR MORE is/are correct. For each question in Section II, you will be awarded 4 marks if you have darkened all the bubble(s) corresponding to the correct choice(s) for the answer, and zero mark if no bubble is darkened. In all other cases, minus one (-1) mark will be awarded. 9) Oxyacids of sulphur having more than one kind of oxidation states for surphur are A) C) Thiosulphuric acid Pyrosulphurous acid B) D) Pyrosulphuric acid Trithionic acid

10) Which of the following statements about sulphur is/are correct? A) Sulphur exists as octa atomic B) molecule with puckered ring structure - hybridization involving both

In molecule each sulphur atom undergoes bonding and non bonding pairs of electrons

C) There are two single covalent bonds and two lone pairs of electrons associated with each S atom in molecule molecule is

D) The S-S-S bond angle in

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11) Which of the following statements regarding the manufacture of process is/are true? A) Sulphur is burnt in air to form B) C) D) is catalytically oxidized to is dissolved in water to get 100% sulphuric acid

by contact

obtained by contact process is of higher purity than that obtained by lead chamber process

12)

The correct set of oxidation numbers of sulphur atoms in H2S2O3 can be A) + 6,-2 B) + 4, 0 C) +2, +4 D) +5, -1

SECTION-3 Section-III contains 2 paragraphs. Based upon each paragraph , 3 multiple choice questions have to be answered. Each question has 4 choices (A) , (B) , (C) and (D) out of which ONLY ONE is correct. For each question in Section III , you will be awarded 4 marks if you darken the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases , minus one (-1) mark will be awarded. P) The element sulphur is one of the important chalcogens. It exhibits allotropy . It is partly due to its tendency to get polymerized and partly due to its different crystal structures , adopted . It reacts with oxygen with great affinity & forms different oxides & oxyacids. Now answer the following . 13) Which of the following forms of sulphur occur naturally as yellow crystals in volcanic regions ? A) Sulphur B) Sulphur C) Sulphur D) Sulphur

14) Which of the following species, given below does not give a white precipitate with ? A) B) C) D)

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15) Which of the following statements is not true ? A) Both S 2 F2 and S 2Cl2 undergo disproportionation in water. B) C) is a reductive type bleach . is the most stable form and it has chains, cross-linked into sheets.

D) Thiosulphates are made by boiling alkaline sulphite solutions . P) sulphur forms hexahalides, tetrahalides, dihalides and monohalides. Sulphur forms only hexafluoride but not hexachlorides, hexabromides and hexa iodides. Sulphur halides tend to hydrolyse easily. Sulphur hexafluoride is an exception. Oxides of sulphur under suitable conditions reaction with halogen to form oxohalides. Of the oxohalides, the most important are those of sulphur especially sulphur dichloride oxide (Thionyl chloride) and sulphur dichloride dioxide (sulphuryl chloride) . These react with water to produce corresponding oxoacids (involving no change in oxidation number). 16)

does not hydrolyse in water due to which of the following ? i) strong bonds which cannot be broken easily molecules cannot

ii) steric hindarence of six fluorine atoms surrounding sulphur approach sulphur iii) double bond character of A) B)

bonds due to back bonding from fluorine to sulphur C) D)

17) Thionyl chloride is dissolved in water. Which of the following statements is wrong about the solution? A) The solution will give white precipitate with baryta water soluble in dil.HCl B) The solution turns orange dichromate to green C) The solution turns the lead acetate paper to black D) It fumes in moist air and gives dense white fumes with
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18) Sulphuryl chloride is dissolved in water. Which of the following statements is wrong about the solution ? A) It gives white ppt with barium chloride insoluble in any acid B) The solution contains two different types of acids a monobasic and a dibasic acid C) On warming the solution hydrated sulphuryl chloride crystallises out. D) The oxidation states of the elements in sulphuryl chloride do not change when dissolved in water SECTION-4 Section-IV contains 2 questions. Each question contains statements given in two columns , which have to be matched. The statements in Column I are labeled A , B , C and D , while the statements in Column II are labeled p , q , r , s and t. Any given statement in Column I can have correct matching with ONE OR MORE statement(s) in Column II. For each question in Section IV , you will be awarded 2 marks for each row in which you have darkened the bubble(s) corresponding to the correct answer. Thus , each question in this section carries a maximum of 8 marks. There is no negative marking for incorrect answer(s) for this section. 19) Match the following Column I Column II (a) Dithionic acid (p) (b) (c) (d) Thiosulphuric acid Caros acid Marshalls acid (q) (r) (s) (t) 20) Match the following Column I (a) (b) (c) (d) -O O - linkage

Column II (p) bonds (q) Both -2 & + 6 oxidation states (r) (s) Cyclic structure Reducing agent

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MATHEMATICS
SECTION-1 Section-I contains 8 multiple choice questions. Each question has 4 choices (A) , (B) , (C) and (D) , out of which ONLY ONE is correct. For each questions in Section I , you will be awarded 3 marks if you have darkened only the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer , minus one (-1) mark will be awarded. 21) If (1, 2) is focus of a parabola which touches both coordinate axes then length of its latus rectum is A)

8 5

B)

4 5

C)

2 5

D)

1 5
to the parabola

22) The number of distinct normals that can be drawn from is A) 23) B) C) D)

A circle drawn on any focal chord of the parabola as diameter cuts the parabola at two points and (other than the extremity of focal chord) then A) B) C) D) have the property that their

24)

Suppose that three points on the parabola normal lines intersect at a common point The sum of their x-coordinates is A) 0 B) C)

D)

25)

An equilateral triangle SAB is inscribed in the parabola having its focus at S. If the chord AB lies towards the left of S, then length of the side of the triangle is A) B) C) D)

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26) Equation of the line passing through cutting the parabola at two distinct points A and B such that AB subtends right angle at the origin is A) C) 27) The locus of a point the parabola from such that the slopes of three normals drawn to be connected by the relation is A) B) D)

B)

C)

D)

28)

The mirror image of the parabola at the point A) C) is

in the tangent to the parabola

B) D)

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SECTION-2 Section-II contains 4 multiple correct answer(s) type questions. Each question has 4 choices (A), (B) , (C) and (D) , out of which ONE OR MORE is/are correct. For each question in Section II, you will be awarded 4 marks if you have darkened all the bubble(s) corresponding to the correct choice(s) for the answer , and zero mark if no bubble is darkened. In all other cases, minus one (-1) mark will be awarded. 29) If a normal chord of slope is equal to A) 30) B) C) 1 D) subtends an angle at the vertex of the parabola then its

Consider a circle whose centre is the focus of the parabola and which touches the directrix of the parabola. Then a point of intersection of the circle and the parabola is A) B) C) D)

31)

Whatever be the value of parabola of A) B)

, the line C)

is a normal to the D)

32) A) B) C) D)

be the equation of a parabola, then The length of the latus rectum is The axis of the parabola is vertical The y-coordinate of the vertex is The x-coordinate of the vertex is

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SECTION-3 Section-III contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions have to be answered. Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct. For each question in Section III, you will be awarded 4 marks if you darken the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus one (-1) mark will be awarded.

P) The normal at any point In case of parabola

of curve is line perpendicular to tangent at the equation of normal at is

. and

the shortest distance between any two curves always exist along the common normal 33) If normal at , then A) 10 34) of hyperbola is B) 20 C) 30 and is C) 5 D) None of these D) 40 is then the intersects the curve again at

If the shortest distance between number of solution(s) of A) 3 B) 4

35) Number of normals drawn from A) 0 B) 1

to C) 2

is D) 3

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P) From a point

a pair of tangents PQ and PR are drawn to circle

such that QR is chord of contact. Considering PQ and PR as adjacent sides a parallelogram PQSR is formed. Equation of chord of contact QR is and be the circles circumscribing the triangle PQR and QRS. Now answer the following questions on the basis of above information 36) Point A) 37) Equation of circle A) C) 38) Equation of diagonal PS is A) B) C) D) is B) is B) D) Cannot be found C) D)

SECTION-4 Section-IV contains 2 questions. Each question contains statements given in two columns, which have to be matched. The statements in Column I are labeled A, B, C and D, while the statements in Column II are labeled p , q , r , s and t. Any given statement in Column I can have correct matching with ONE OR MORE statement(s) in Column II. For each question in Section IV, you will be awarded 2 marks for each row in which you have darkened the bubble(s) corresponding to the correct answer. Thus, each question in this section carries a maximum of 8 marks. There is no negative marking for incorrect answer(s) for this section.

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39) Match the following pair of planes with their lines of intersections Column -I Column -II (A) (p) 13 Parabola and the circle having its centre at intersects at right angle, at the point then one value of is equal to (B) The angle between the tangents drawn to (q) 8 at the points where it is intersected by the line to (C) If the line (D) is then has the value equal

is the directrix of the parabola (r) , then one of the value of k is /are (s) (t) 4

Length of the normal of the parabola where abscissa & ordinate are equal is

at the point

40) Match the following Column I (A) Equation of chord AB of the parabola if tangents at perpendicular to each other then is (B) From is A and B are (q) 3 Column II (p) 2

tangents PA and PB are drawn to the

parabola then length of AB is (C) Number of integral values of b for which origin and (r) lies on same side of line for

(D) The product of length of perpendiculars drawn from the (s) two foci to the tangent at any point on the ellipse is
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PHYSICS
SECTION-1 Section-I contains 8 multiple choice questions. Each question has 4 choices (A) , (B) , (C) and (D) , out of which ONLY ONE is correct. For each questions in Section I , you will be awarded 3 marks if you have darkened only the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer, minus one (-1) mark will be awarded. 41) Moment of inertia of a uniform rod of length L and mass M about an axis passing through from one end and perpendicular to its length is A) B) C) D)

42) A flywheel rotates with a uniform angular acceleration. Its angular velocity increases from 20 rad/s to 40 rad/s in 10 seconds. How many rotations did it make in this period ? A) 80 B) 100 C) 120 D) 150

43) The moment of inertia of a uniform semicircular disc of mass M and radius r about a line perpendicular to the plane of the disc through the centre is A) B) C) D)

44) When a torque acting upon a system is zero, which of the following will be constant A) C) 45) If Force angular momentum B) D) linear momentum linear impulse and be the torque of

be a force acting on a particle having the position vector this force about the origin, then B) D)
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A) C)

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46) A thin spherical shell of radius R lying on a rough horizontal surface is hit sharply and horizontally by a cue. Where should it be hit so that the shell does not slip on the surface? A) C) above the centre B) D) above the centre at the centre of the shell

47) A disc of mass m and radius R has a concentric hole of radius r. Its moment of inertia about an axis through its centre and perpendicular to its plane is A) B) C) D)

48) Average torque on a projectile of mass , initial speed and angle of projection between initial and final positions P and Q as shown in figure about the point of projectile is

A)

B)

C)

D)

SECTION-2 Section-II contains 4 multiple correct answer(s) type questions. Each question has 4 choices (A), (B), (C) and (D), out of which ONE OR MORE is/are correct. For each question in Section II, you will be awarded 4 marks if you have darkened all the bubble(s) corresponding to the correct choice(s) for the answer, and zero mark if no bubble is darkened. In all other cases, minus one (-1) mark will be awarded. 49) Two bodies (low M.I. and high M.I.) are rotating with equal rotational kinetic energy and applying same Retarding torque, their stopping angular displacement are and stopping time and Respectively ,then : A) B) C)
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and

D)
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50)

A particle moves in a circle of radius r with angular velocity linear velocity is

. At some instant its . At this

and radius vector with respect to centre of the circle is of the particle would be C) D)

particular instant centripetal acceleration A) B)

51) A man spinning in free space changes the shape of his body, e.g., by Spreading his arms or curling up. By doing this, he can change his A) C) moment of inertia angular velocity B) D) angular momentum Rotational kinetic energy

52) The torque vector and that A)

on a body about a given point is found to be where is a constant is angular momentum of the body about that point. From this it follows

is perpendicular to

at all times. does not change with time.

B) the component of C) the magnitude of D)

in the direction of

does not change with time.

does not change with time.

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SECTION-3 Section-III contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions have to be answered. Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct. For each question in Section III, you will be awarded 4 marks if you darken the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus one (-1) mark will be awarded.

P) Four solid spheres each of mass m and radius r are located with their centres on four corners of a square of side as shown in Fig.

53) The moment of inertia of sphere A about diagonal AB is A) B) C) D)

54) The moment of inertia of sphere B about side AD is A) B) C) D)

55) The moment of inertia of the system of four spheres about diagonal AB is A) B) C) D)

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P) A man of mass 100 kg stands at the rim of a turn table of radius 2m, moment of inertia . The table is mounted on a vertical smooth axis, through its center. The whole system is initially at rest. The man now walks on table with constant speed 1m/s relative to earth along the rim. 56) With what angular velocity will the turn table rotate A) 0.5 rad/sec B) 0.1 rad/sec C) 0.05 rad/sec D) 0.2 rad/sec

57) Through what angle will the turn table have rotated when the man reaches his initial position on it A) B) C) D)

58) Through what angle will it have rotated when the man reaches his initial position relative to earth A) B) C) D)

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SECTION-4 Section-IV contains 2 questions. Each question contains statements given in two columns, which have to be matched. The statements in Column I are labeled A, B, C and D, while the statements in Column II are labeled p , q , r , s and t. Any given statement in Column I can have correct matching with ONE OR MORE statement(s) in Column II. For each question in Section IV, you will be awarded 2 marks for each row in which you have darkened the bubble(s) corresponding to the correct answer. Thus, each question in this section carries a maximum of 8 marks. There is no negative marking for incorrect answer(s) for this section. 59) The mass is uniformly distributed in the given rigid bodies. Match the moment of inertia for various rigid bodies given below Column I (a) (b) Circular disc of mass M and radius R. Then M.I. (p) about tangent perpendicular to plane of disc Cylinder of mass M and radius R and length L, then (q) M.I. about the axes through its end face (diameter of the face) and perpendicular to length Rectangular Lamina of mass M, length L and breadth (r) R then M.I. through centre of Lamina and perpendicular to its plane Sphere of mass M and radius R then M.I. about any tangent of the sphere (s) Column II

(c)

(d)

(t)

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60) A uniform semi-circular disc of mass M and radius R lies in the X-Y plane with its centre at the origin as shown in figure. Also, axis PQ is in the X-Y plane. Then match for the moment of inertia of semi-circular disc about different axis

Column I (a) (b) (c) (d) (p) (q) (r) (s)

Column II

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