Beruflich Dokumente
Kultur Dokumente
2012
Fe(SCN)2+
Red
Ksp = [Hg22+][IO3]2 = x(2x)2 = 1.3 1018 x = [Hg22+] =6.9 107M 0.050M KNO3 + saturated solution of mercurous iodate [Hg22+] =1.0 106M Ion dissociation is increased by increasing the ionic strength
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Ionic strength
Ionic strength, is a measure of the average electrostatic interactions among ions in an electrolyte ; it is equal to one-half the sum of the terms obtained by multiplying the molarity of each ion by its valence squared.
: Ba2+
: IO32-
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I-
Ai = [C]i
where [C] = molarity of species C,
i = activity
350 pm
300 pm
coefficient
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Ex: In 0.033 M Hg2(NO3)2 solution calculate the activity coefficient and activity
for Hg2
2+ .
Ex: In 0.042 M BaCl2 solution calculate the activity coefficient and activity for
Ba2+ .
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12
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Equilibrium Calculations Using Activity Coefficients Ex: Find the relative error introduced by neglecting activities in calculating the Ex: Find the solubility of Ba(IO3)2 in 0.033 M solution of MgCl.
solubility of Ba(IO3)2 in 0.033 M solution of Mg(IO3)2.
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14
Ex: Use activities to calculate the molar solubility of Zn(OH)2 in 0.010 M KCl. Ksp=3.0x10-16
Ex: Use activities to calculate the pH of the 0.100 M CH3COOH solution. Ka= 1.75x10-5
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16
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Ex: What is the pH of 0.0200 M Benzoic acid a) in water b) in 0.10 M CaCl2. Ka=6.28x10-5
H.W. : When mixing 20.0 mL 0.250 M KOH and 80.0 mL 0.0220 M ZnCl2 calculate the
solubility of Zn(OH)2 using activities. Ksp = 3.0x10-16
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