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Vapor pressure, a manifestation of the tendency of a liquid or solid to become gaseous, is an important property of pure substances and solutions, one which can give a variety of useful information about, for example, the forces of attraction between molecules, molecular weights, and physical state. The vaporization of a liquid is called evaporation; the vaporization of a solid is called sublimation. For any pure substance, there are certain conditions of temperature and pressure at which the tendenc y of the substance to change state in one direction (e.g., liquid to gas) is exactly balanced by its tendenc y to change state in the opposite direction (e.g., gas to liquid). Under these special conditions, there is a state of equilibrium between the two phases. For a pure substance, such as water, there is a set of pressure-temperature points at each of which there is equilibrium between the gaseous and liquid phases. Since the liquid and gaseous phases coexist as these points, they are called liquid-gas coexistence curves. Each of the points along a liquid-gas coexistence curve is a boiling point; that is, the liquid will boil if the prevailing pressure is less than the equilibrium vapor pressure at that temperature. The particular boiling point temperature that corresponds to an equilibrium vapor pressure of exactly one atmosphere is called the normal boiling point; for water, this o temperature is exactly 100 C (373.15K). At prevailing pressures less than one atmosphere, the substance will boil at temperatures less than the normal boiling point. Just as there are points at which equilibrium exists between the liquid state and the gaseous state, there are pressure-temperature coexistence point at which there is equilibrium between the solid and liquid phases: these are called freezing points or melting points. The normal freezing point of a substance occurs at a prevailing pressure of exactly one atmosphere. The unique point at which all three phases (solid, liquid, and gas) are at equilibrium is called the triple point. This point is fascinating to observe in that, under pressure and temperature conditions at or very close to the triple point, one should be able to see evidence of simultaneous boiling and freezing of the substance. For water, the triple point occurs at 273.16K and 0.00603atm. By comparison, the freezing point of water at a prevailing pressure of 1.000atm is 273.15K. In this experiment, you will not only find the freezing and melting points of a substance, but also you will have an opportunity to observe its triple point. The substance under observation is t-butyl alcohol, which has the following structure:
To get to the triple point, you must lower the pressure, which you will accomplish by attaching the test tube to a water aspirator. This device provides suction by taking advantage of Bernoullis Principle, which says that the pressure adjacent and perpendicular to a flowing fluid (liquid or gas) is less than the pressure in the direction of the flow. The same phenomenon provides the basis for aerodynamics (why planes fly, etc.). A water aspirator consists of a main tube which has a hole in it that leads into a side tube. The water flows through the main tube; the pressure in the side tube is reduced, creating the suction. If the side tube from the aspirator is connected with thick rubber tubing to the test tube, and the water is turned on, the pressure in the test tube will be lowered, and eventually the liquid will begin to boil, because the pressure acting on the liquid (the prevailing pressure) will be less than the vapor pressure at that temperature. Causing the liquid to boil in this way lowers the temperature of the liquid, because vaporization is an endothermic process. Gradually the
temperature will continue to drop until it reaches a point at which the liquid will boil and freeze simultaneously. You should ultimately observe a boiling slush of t-butyl alcohol.
PROCEDURE
TRIPLE POINT
1. Obtain a rubber stopper (#4 size, two holes, no split), thermometer, large test tube (25x200mm size), and rubber tubing (approx. 50cm long) that has a short length of glass tubing in each end. Lubricate the bulb of the thermometer and one hole in the stopper with a drop of glycerine, and, grasping the thermometer and stopper with a towel, use a twisting motion to carefully slide the thermometer through the hole in the stopper. Alternatively, you may use a stopper tubing tool to safely insert the thermometer into the stopper. The Thermometer should be inserted far enough to reach nearly (but not entirely) to the bottom of the test tube. Next, insert one end of the rubber tubing in the other hole of the stopper just far enough to go all the way through the stopper. W ash off any glycerine with water when you are finished and dry off the thermometer and glass insert. 2. Obtain another rubber stopper (#6 size, two holes, no split), 250mL filter flask, a pan or 1000mL beaker half filled with ice water, and a short length of rubber tubing with glass insert in one end. Set up the trap and connect it to both the water aspirator and the test tube as shown in the illustration:
There are several reasons for having such a trap, one being that it will prevent most of the t-butyl alcohol vapors from being drawn into the water going down the drain. Another important reason is that the trap will catch any water accidentally drawn back into the s ystem before it gets into the test tube containing the t-butyl alcohol. Pure t-butyl alcohol freezes at a temperature near room temperature, so your instructor may have to place the reagent bottle in warm water to keep it in a liquid state. 3. Place three boiling stones and enough t-butyl alcohol in the test tube to cover the bulb of the thermometer. 4. Clamp the test tube to the ring stand, and ensure a tight seal when replacing the stopper in the test tube. 5. To properly operate the apparatus constructed, you should turn on the water aspirator BEFORE you close off the tubing connected to the trap, or stopcock. Touch your finger to the end of the stopcock tubing to ensure there is good suction. 6. Close the stopcock with parafilm, a pinchcock clamp, or your finger. The temperature should begin to drop almost immediately. After a short period of time, the liquid should start to boil, and eventually you should observe simultaneous boiling and freezing. Note the temperature at that point, which is the triple point temperature. W atch carefully or you may miss this very interesting phenomenon! (If you dont see boiling after a couple of minutes, your apparatus may have air leaks which are lowering the vacuum quality. Consult your instructor for possible solutions.)
7. After you observe the triple point, first open the stopcock on the trap to relieve the vacuum, and then you may turn off the water aspirator. (If you do this in the reverse order, water may be sucked into the trap, so make sure you have the correct order down.) 8. Remove the thermometer and tubing from the rubber stopper in the test tube. Keep the test tube with tbutyl alcohol in it; you will need it for your other two tests. Break down and return the equipment used for the trap, as well as the stopper that was in the test tube. The point at which all three phases are present simultaneously, the triple point of t-butyl alcohol, occurs at a pressure of 42.4mmHg (0.0558atm). Record the triple point temperature and pressure on your worksheet.
DATA ANALYSIS
Using graphing paper, apply all the information youve gathered about t-butyl alcohol on your worksheet to construct a phase diagram for t-butyl alcohol. You should have the following details: 1. 2. 3. 4. 5. Title X and Y axes labeled with proper units Identify the solid, liquid, and gaseous regions Boiling, freezing points at laboratory pressure, labeled Triple point, labeled
TEMPERATURE TRIPLE POINT BOILING POINT FREEZING POINT __________ __________ __________