Beruflich Dokumente
Kultur Dokumente
Methacrylic acid
Index
SR. NO 1 2 3 4
PAGE NO. 4 6 8 9
5 6 7 8 9 10
10 11 12 13 14 21
1 MGM CET
A seminar report
Methacrylic acid
History
The first acrylic acid was created in 1843. Methacrylic acid, derived from acrylic acid, was formulated in 1865. The German chemists Fittig and Paul discovered in 1877 the polymerization process that turns methyl methacrylate into polymethyl methacrylate. Methacrylic acid can be readily polymerized, its presence in copolymers reduces the softening temperature and ardness. It also improves adhesion of surface coatings and adhesives. Because Methacrylic acid is a carboxylic acid, it can be converted by conventional methods into methacrylates, N-substituted methacryl amides, methacrylamide, N-substituted methacryl amides and acryloyl chloride.
Methacrylic acid, abbreviated MAA, is an organic compound. This colourless, viscous liquid is a carboxylic acid with an acrid unpleasant odor. It is soluble in warm water and miscible with most organic solvents. Methacrylic acid is produced industrially on a large scale as a precursor to its esters, especially methyl methacrylate (MMA). The methacrylates have numerous uses, most notably in the manufacture of polymers with trade names such as Lucite and Plexiglas.
2 MGM CET
A seminar report
Methacrylic acid
3D structure:
A seminar report
Methacrylic acid
Basic properties:
4 MGM CET
A seminar report
Methacrylic acid
Thermodynamic properties:
Chemical identifiers:
5 MGM CET
A seminar report
Methacrylic acid
Safety properties:
Toxicity properties:
The principal application, consuming approximately 80% of the MMA, is the manufacture of polymethyl methacrylate acrylic plastics (PMMA). Methacrylic acid is also used for the production of the co-polymer methyl methacrylate-butadiene-styrene (MBS), used as a modifier for PVC. Also used in fracture repair in small exotic animal species using internal fixation. Polymers containing methacrylic acid are used in applications such as ion exchange,surface coating,auxiliaries for leather and textile industry,flocculants
A seminar report
Methacrylic acid
Manufacturer and supplying all types of methacrylic acid copolymers. Address: Ahmedabad, India. 2. Polymers Enterprises
Bulk trader of methyl methacrylate monomer and methacrylic acid. Address: Mumbai , India. 3. Gujarat State Fertilizers & Chemicals Limited
Suppliers and manufactuers of methacrylate monomer, agricultural chemicals, fertilizer chemicals, laboratory chemicals and methacrylic acid. Address: Vadodara India. 4. Surplus Chemicals Experts
Trader of pivaloyl chloride, polypropylene glycol, tertiary butyl benzene, alkyl naphthalene sulphonate and methacrylic acid. Address: Ghaziabad, India. 5. Ankush Enterprise
Supplier and trader of chemicals, laboratory chemicals, acrylates, speciality monomers, amines and methacrylic acid. Address: Mumbai, India.
MANUFACTURING PROCESS :
7 MGM CET
A seminar report
Methacrylic acid
The compound is manufactured by several methods, the principal one being the
BY ACETONE CYNOHYDRIN
acetone cyanohydrin (ACH) route, using acetone and hydrogen cyanide as raw materials. The intermediate cyanohydrin is converted with sulfuric acid to a sulfate ester of the methacrylamide, methanolysis of which gives ammonium bisulfate and MMA. Although widely used, the ACH route coproduces substantial amounts of ammonium sulfate.
BY ISOBUTENE
Using isobutane which is sequentially oxidized first to methacrolein and then to methacrylic acid) use of non-toxic feedstock isobutane is inherently much safer with regards to workers' exposure and accident potential. Further, isobutane can be obtained from renewable sources in the future, as indicated by some recent research.
Process Selection
8 MGM CET
A seminar report
Methacrylic acid
From these two manufacturing process for methacrylic acid we select process of acetone cynohydrin due to following reasons.
Simplicity of the process. Very low envornmental impact and absence of co-product. Low cost of raw materials. Overall yield of the process.
9 MGM CET
A seminar report
Methacrylic acid
In this process dry acetone and hydrogen cynide react with in presence of catalyst to give cynohydrin. The cynohydrin react with excess concentration of sulfuric acid (1.4 to 1.8 mole ratio of cynohydrin). The next stage at 80-100 oC mixture is subjected to thermal cracking at 125-160 oC. This mixture is now sent to cooler and then series of reactors at 80-100 oC with 2-4 hr residence time. The reactor effluents then passes to astripping column where crude methal methacrylate,water and exess of methanol is removed overhead. Crude methyl methacrylate is extracted with water to recover methanol which is concentrated and recycled to the esterification reactor. For the next process wasted ester is then purified further in distillation,overall yield is 80-90% based on reaction. In last distillation column upper organic layeris provided us methacrylic acid and lower is for residue recovery. In this way we get methacrylic acid by acetone cynohydrinprocess.
10 MGM CET
A seminar report
Methacrylic acid
11 MGM CET
A seminar report
Methacrylic acid
Composition: Toxicological Data on Ingredients: Methacrylic Acid: ORAL (LD50): Acute: 1250 mg/kg [Mouse]. 1200 mg/kg [Rabbit]. 1060 mg/kg [Rat]. DERMAL (LD50): Acute: 500 mg/kg [Rabbit].
Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation (lung irritant). Corrosive to skin and eyes on contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Classified None. by OSHA, None. by NIOSH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, liver, eyes, eye, lens or cornea. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated
12 MGM CET
A seminar report
Methacrylic acid
or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
A seminar report
Methacrylic acid
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. Ingestion: Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Serious Ingestion: Not available.
Flammability of the Product: Combustible. Auto-Ignition Temperature: 365C (689F) Flash Points: CLOSED CUP: 77C (170.6F). Flammable Limits: LOWER: 1.6% UPPER: 8.1% Products of Combustion: These products are carbon oxides (CO, CO2). Fire Hazards in Presence of Various Substances: Highly flammable in presence of heat. Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Special Remarks on Fire Hazards: Not available. Special Remarks on Explosion Hazards: Not available.
A seminar report
Methacrylic acid
Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal. Large Spill: Combustible material. Corrosive liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. If the product is in its solid form: Use a shovel to put the material into a convenient waste disposal container. If the product is in its liquid form: Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Absorb with an inert material and put the spilled material in an appropriate waste disposal. Do not touch spilled material. Use water p. 3 spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Precautions: Keep container dry. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapour/spray. Never add water to this product Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes Keep away from incompatibles such as oxidizing agents, acids. Storage:
15 MGM CET
A seminar report
Methacrylic acid
May corrode metallic surfaces. Store in a metallic or coated fiberboard drum using a strong polyethylene inner package. Flammable materials should be stored in a separate safety storage cabinet or room. Keep away from heat. Keep away from sources of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containing material. Keep container dry. Keep in a cool place.
16 MGM CET
A seminar report
Methacrylic acid
Physical state and appearance: Liquid. (Above room temperature) Odor: Repulsive. (Strong.) Taste: Not available. Molecular Weight: 86.09 g/mole Color: Colorless. pH (1% soln/water): Not available. Boiling Point: 163C (325.4F) Melting Point: 16C (60.8F) Critical Temperature: Not available. Specific Gravity: 1.015 (Water = 1) Vapor Pressure: 0.975 mm of Hg (@ 20C) Vapor Density: 2.97 (Air = 1) p. 4 Volatility: Not available. Odor Threshold: Not available. Water/Oil Dist. Coeff.: Not available. Ionicity (in Water): Not available. Dispersion Properties: See solubility in water, diethyl ether, acetone. Solubility: Partially soluble in diethyl ether, acetone. Very slightly soluble in methanol, n-octanol.
Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Not available. Incompatibility with various substances: Reactive with oxidizing agents, acids. Corrosivity: Corrosive in presence of steel. Special Remarks on Reactivity: Not available. Special Remarks on Corrosivity: Not available. Polymerization: Yes.
17 MGM CET
A seminar report
Methacrylic acid
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion. Toxicity to Animals: Acute oral toxicity (LD50): 1060 mg/kg [Rat]. Acute dermal toxicity (LD50): 500 mg/kg [Rabbit]. Chronic Effects on Humans: CARCINOGENIC EFFECTS: Classified None. by OSHA, None. by NIOSH. The substance is toxic to lungs, liver, eyes, eye, lens or cornea. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant). Special Remarks on Toxicity to Animals: Not available.
Protective Equipment:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles.
REFERENCES
1. BIBLIOGRAPHY: Handbook Of Polymer Data, Thomas.O.Brien Kirk, Othmer: Encyclopedia of Chemical Technology- Vol. 17,18.
18 MGM CET
A seminar report
Methacrylic acid
Perrys Chemical Engineers Handbook, Robert H. Perry, Don W. Green 7th Edition.
19 MGM CET