Novel ether solvent cyclopentyl methyl ether ( CPME ) for process reduction and green sustainable

chemistry. Watanabe, Kiyoshi. Chem. Div., Nippon Zeon Co., Ltd., Japan. Farumashia (2007), 43(6),
549-551. Publisher: Pharmaceutical Society of Japan, CODEN: FARUAW ISSN: 0014-8601. Journal;
General Review written in Japanese. CAN 147:257213 AN 2007:671323 CAPLUS

Abstract

A review on phys. and chem. properties of CPME, and its applications as a solvent to Grignard reaction,
Pinner reaction, and Horner-Wadsworth-Emmons reaction in a microreactor.

Indexing -- Section 21-0 (General Organic Chemistry)

Addition reaction
(Pinner; application of cyclopentyl Me ether as solvent to)

Grignard reaction
Horner Wadsworth Emmons reaction
(application of cyclopentyl Me ether as solvent to)

Physical and chemical properties

(of cyclopentyl Me ether)

5614-37-9, Cyclopentyl methyl ether

Role: NUU (Other use, unclassified); PRP (Properties); USES (Uses)
(phys. and chem. properties, and applications as reaction solvents of)

Supplementary Terms

review cyclopentyl methyl ether solvent

Some utility and application with CPME.

Fain Kemikaru (2006), 35, (10), 53-60. Publisher: (Shi Emu Shi Shuppan, ) CODEN:FNKMAU ISSN:0913-
6150.

Development of a new solvent cyclopentyl methyl ether (CPME).

Fain Kemikaru (2006), 35, (6), 14-20. Publisher: (Shi Emu Shi Shuppan, ) CODEN:FNKMAU ISSN:0913-
6150

Autoxidation and safety characteristics of new ethereal solvent CPME.

Institution of Chemical Engineers Symposium Series (2007), 153, poster11/1-poster11/4. Publisher:
(Institution of Chemical Engineers, ) CODEN:ICESDB ISSN:0307-0492.
Bibliographic Information

Autoxidation and safety characteristics of new ethereal solvent CPME. Miyake, Atsumi; Nagasawa,
Keita; Watanabe, Kiyoshi. Department of Safety Engineering, Yokohama Natinal University, Tokiwadai,
Hodogaya-ku, Yokohama, Japan. Institution of Chemical Engineers Symposium Series (2007), 153
poster11/1-poster11/4. Publisher: Institution of Chemical Engineers, CODEN: ICESDB ISSN: 0307-0492.
Journal; Computer Optical Disk written in English. AN 2007:668472 CAPLUS

Abstract

Cyclopentylmethylether (CPME) is a newly developed ethereal solvent which has relatively a low soly. to
water and a high tolerance of formation of peroxides, and is expected to be an alternative solvent to
conventional solvent such as THF (THF). In this paper, to obtain quant. information on autoxidn. behavior
and safety characteristic of CPME, accelerated stability test was performed at 40 C and thermal and IR
spectroscopic analyses were carried out and the exptl. data was compared with those of THF.

Indexing -- Section 59 (Air Pollution and Industrial Hygiene)

Autoxidation
Peroxides
Safety
Solvents
(study of autoxidn. behavior and safety characteristics of new ethereal solvent cyclophenylmethylether)

Supplementary Terms

developing autoxidn safety ethereal solvent cyclophenylmethylether

Citations

1) Shurvell, H; Vibrational Spectroscopy 1997, 15, 137

2) Robertson, A; Nature 1947, 152, 153
3) Matsudo, K; Thesis, Yokohama National University 2004

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Cyclopentylmethyleter
Miyake, Atsumi; Nagasawa, Keita; Watanabe, Kiyoshi.   Autoxidation and safety characteristics 
of  new  ethereal  solvent  CPME.    Institution of Chemical Engineers Symposium Series  (2007), 
153  poster11/1­poster11/4.  CODEN: ICESDB  ISSN:0307­0492.  AN 2007:668472    CAPLUS