CANID 2011 (ACHM01) Advanced Secondary Chemistry 1 NAME: _______________________________ DATE:__/__/2011

ACHM01
PAGE 1

___/20= _____%

This Paper has 18 Questions Worth. The total numbers of marks available are 20. All questions must be attempted and answers must be marked with an [X] on the question as well as on the answering sheet provided at the back. 1. Which ion would undergo the greatest deflection in a mass spectrometer? A. 16O+ B. 16O2+ C. 18O2+ D. (16O18O)+ 2. When the following species are arranged in order of increasing radius, what is the correct order? A. Cl- , Ar , K+ B. K+ , Ar , ClC. Cl- , K+ , Ar D. Ar , Cl- , K+ 3. How many isomers are there of C5H12 A. Two B. C. D. Three Four Five

4. What is the systematic name for this compound? A. B. C. D. Z-4-Methylhex-2-ene E-2-ethylpent-3-ene Z-4-enthylpent-2-ene E-4-methylhex-2-ene

5. Propene reacts with hydrogen chloride gas to give mainly A. B. C. D. 1-Chloropropane 2-chloropropane 3-chloroprop-1-ene 1,2-dichloropropane

2011 (ACHM01) Advanced Secondary Chemistry 1

ACHM01
PAGE 2

6. Theoretical lattice energies can be calculated from electrostatic theory. Which of the following affects the magnitude of the theoretical lattice energy of an alkali metal halide, M+X A. B. C. D. The first electron affinity of X The first ionization energy of M The enthalpy of atomization of M The radius of the X- ion

*7. The student uses the following apparatus to determine the molar heat of combustion of ethanol. Initial mass of burner 133.20g Final mass of burner Initial Temp of Water Final Temp of Water
-1 -1

132.05g 25.0 C 45.5 C

(The can contains 300g of water, Density of Water: 1 gcm-3, Specific Heat Capacity: 4.18 J g K ) What will his reading be? A. B. C. D. 22.4 kJmol-1 25.7 kJmol-1 1030 kJmol-1 1180 kJmol-1

8. What is the product formed when Butanoic Acid Reacts with Pentanol A.

B.

C.

D.

2011 (ACHM01) Advanced Secondary Chemistry 1

ACHM01
PAGE 3

9. The Following Diagram shows A. B. C. D. An Endothermic reacion An Exothermic reaction A reaction which is catalysed Neither endothermic/exothermic

10. The enthalpy of combustion of methanol (CH3OH) is -711 kJmol-1. What mass of methanol must be completely burned in oxygen in order to produce 71.1 kJ of energy? A. B. C. D. 32g 3.2g 71.5g 715g

11. What is the best name for this molecule? A. B. C. D. 5-methyl-2-hydroxyhexane 2-methylhexan-5-ol 2-methyl-5-hydroxyhexane 5-methylhexan-2-ol

*12. What change occurs when a barium atom loses two electrons? A. B. C. D. It becomes a negative ion and its radius decreases It becomes a negative ion and its radius increases It becomes a positive ion and its radius decreases It becomes a positive ion and its radius increases

13. Which element must be present in an organic compound? A. B. C. D. Hydrogen Oxygen Carbon Nitrogen

2011 (ACHM01) Advanced Secondary Chemistry 1

ACHM01
PAGE 4

14. Which compound is a saturated hydrocarbon? A. B. C. D. Hexane Hexene Hexanol Hexanale

15. As the Elements of Group 1 on the Periodic Table are considered in order of increasing atomic radius, the ionization energy of each successive element generally A. B. C. D. Decreases Increases Remains the Same Changes inconsistently

16. Consider the following reaction AX The enthalpy change for the reaction represented above is HT. This reaction can be broken down into a series of steps as shown in the diagram:

A. B. C. D.

HT-H1-H2-H3=0 HT+H1+H2+H3=0 H3-(H1+H2)=HT H2-(H3+H1)=HT

2011 (ACHM01) Advanced Secondary Chemistry 1 17. Given the balanced equation representing a reaction: Cl2Cl+Cl What occurs during this reaction? A. B. C. D. A bond is broken as energy is absorbed A bond is broken as energy is released A bond is formed as energy is absorbed A bond is formed as energy is released

ACHM01
PAGE 5

18. The formula of a functional group is: A. B. C. D. An Acid An Ester An Aldehyde A Ketone

ANSWERING SHEET Please mark your answers within this box. SHADE the box you feel represents the correct answer. An example has been provided at the bottom 1 ABCD 2 ABCD 3 ABCD 4 ABCD 5 ABCD 6 ABCD 7 ABCD 8 ABCD 9 ABCD 10 ABCD 11 ABCD 12 ABCD 13 ABCD 14 ABCD 15 ABCD 16 ABCD 17 ABCD 18 ABCD If you feel the answer to a question is A, Shade A as follows: ABCD ACHM01 --- 2011 Examination

2011 (ACHM01) Advanced Secondary Chemistry 1

ACHM01
PAGE 6

*Question 7 and Question 12 are worth 2 marks. ANSWER SCHEME A 100% correct answer should look like this: ANSWERING SHEET Please mark your answers within this box. SHADE the box you feel represents the correct answer. An example has been provided at the bottom 1 ABCD 2 ABCD 3 ABCD 4 ABCD 5 ABCD 6 ABCD 7 ABCD 8 ABCD 9 ABCD 10 ABCD 11 ABCD 12 ABCD 13 ABCD 14 ABCD 15 ABCD 16 ABCD 17 ABCD 18 ABCD If you feel the answer to a question is A, Shade A as follows: ABCD ACHM01 --- 2011 Examination