Advanced Cleaning Product Formulations Volume5

ADVANCED CLEANING RODUCT FORMULATIONS
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ADVANCED CLEANING PRODUCT FOR MULATlONS

Volume 5
Ernest W. Flick
NOYES PUBLICATIONS WILLIAM ANDREW PUBLISHING, LLC

Nomich, New York, U.S.A.
Copyright 0 1999 by Ernest W. Flick No part of this book may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying, recording or by any information storage and retrieval system, without permission in writing from the Publisher. Library of Congress Catalog Card Number: 89-30274 ISBN: 0-8155-1431-X Printed in the United States Published in the United States of America by Noyes Publications/William Andrew Publishing, LLC 13 Faton Avenue, Norwich, New York 13815
10 9 8 7 6 5 4 3 2
Library of Congress Cataloging-in-Publication Data (Revised for vol. 5) Flick, Ernest W. Advanced cleaning product formulations Includes bibliographical references and index. 1. Cleaning compounds. I. Title TP990.F56 1989 668'1 89-30274 ISBN 0-8155-1186-8 (v. 1) ISBN 0-8155-1346-1 (v. 2) ISBN 0-8155-1382-1 (v. 3) ISBN 0-8155-1396-8 (v. 4) ISBN 0-8155-1431-X (v. 5)
To
the late Ernie and Jeanne and Allyn and Barbara and Chris and Rachel
reface
ohme 5) presents more than 423 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volumes 1, 2, 3 and 4 published earlier. ~ ~ in the cleaning product industry has gradually been~undergoing ~ ~ ~ a ~ significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria. o
The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ( ):
H.
Household and Industrial Cleaners and Polishes 1. Bathroom Cleaners (9) 2. Dairy, Food and General Industrial Cleaners (27) 3. Degreasers (9) 4. Dishwashing Detergents (34) 5. General Purpose Cleaners (31) 6. Glass CleanersPoiishes (12) ard Surface Cleaners (21) 8. Laundry Products (55) 9. Metal Cleaners and Polishes (72) 10. Oven, Grill and Hot Plate Cleaners (9) 11. Polishes, Coatings and Finishes (6) 12. Rinse Aids (2) 13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (33) 14. Miscellaneous (33)
vii
viii
11.
Preface
Transportation Cleaners and Polishes 15. Auto Cleaners and Polishes (6) 16. Car and Truck Wash Compounds (49) 17. Whitewall Tire Cleaners (3) 18. Miscellaneous (12)
Each formula is located in the chapter which is most applicable. The reader, seeking a formula for a specific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader.
111. A chemical trademark section where each tradenamed raw material included in the book is listed with a chemical description rand the supplier's name. The specifications which each raw material meets are included, if applicable.
IV. Main office addresses of the suppliers of trademarked raw materials.

Each formulation in the book lists the following information, as available, in the manufacturer's own words: Description of end use and most outstanding properties. The percent by weight or volume of each raw material included i the n formula, rounded to a decimal figure. Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type. The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company andlor the primary source's publication title, or both. A formula number is included, if applicable. The table of contents is organized in such a way as to serve as a subject index. My fullest appreciation is expressed to the companies and organizations who supplied the original starting formulations included in this book. I also thank the suppliers of the raw materials included in these formulations, who furnished information describing their trademarked raw materials. Newburyport, Massachusetts July 1999 Ernest W. Flick
NOTICE
To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequences arising from, such information. This book is intended for informational purposes only. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. Final determination of the suitability of any information or product for use contemplated by any user. We recommend that anyone intending to rely on any recommendation of materials QB procedures mentioned in this publication should satisfy himself as to such suitability, and that he can meet all applicable safety and health standards.
X
ntents and Subject Index

SECTION I OUSEHOLD AND INDUSTRIAL CLEANERS AND POLISHES
OM CLEANERS:
Toilet Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . athroom Cleaner with Disinfectant . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Acid Bathroom Cleaner . . . . . . . . . . . . . . . . . . . . . . . Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ o w ~ ~ ~ Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . l d e w Tile Porcelain and Bathroom Cleaner. Acid . . . . . . . . . . . . . . . . . . Tub and Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hypochlorite Tub and Tile Cleaner and Mildew Stain Remover . . . Toilet Bowl Cleaner with Bleach .........................
...............................
2 3
4
4 5
5 6 6 6 7
2.
FOOD AND GENERAL INDUSTRIAL CLEANERS . . . . . 8 Acid Industrial and Household Cleaners Oxalic Acid Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 ust Removal Jelly . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 Cleaners for Industrial Application 10 Desinfecting Cleaner. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . Dipping Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Destainer sphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 uced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 11
Zero phosphate. powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . Baking Pan Cleaner phosphate. powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Cleaners BBll Purpose-Food Process Plant . . . . . . . . . . . . . . . . . . . . . . Hard Surface Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . .
12
12
13 13
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xii
Contents and Subject Index

High Foaming Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . 14 Heavy Duty Alkaline Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . 44 Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 Industrial and High Pressure Cleaners Cleaner, Strongly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Cleaner. Weakly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Cleaner. Strongly Alkaline (Phosphate-Free) . . . . . . . . . . . . . 15 Cleaner. Weakly Alkaline (Phosphate-Free) . . . . . . . . . . . . . . 45 Metal Cleaner (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Food Industry Cleaner (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Milk Can Cleaner (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 Powdered Enzyme Presoaks Economy Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 Premium Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 Enzyme Prespotter for Oily/Smutty Soils . . . . . . . . . . . . . . . . IS Sanitizing Cleaner (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 9 Sanitizing Agent (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
3 DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 Aqueous Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 Aqueous Degreaser d-Limonene Microemulsion . . . . . . . . . . . . . . . . . . . . . . . . . 21 Water Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 Degreaser Concentrate (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . 22 Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . . 22 Solvent Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 Solvent Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 Engine Cleaner and Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . 24
4. DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . .
25
Automatic Dishwash Detergent-Consumer (Zero Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 26 Automatic Dishwash Detergent-Consumer (Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 26 Automatic Dishwash Detergent-Industrial & Institutional (Phosphate. Solid Block . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 Automatic Dishwashing Detergent-Industrial & Institutional (Liquid~7
xiii
Automatic Dishwash Detergent-Industrial & Institutional (Zero.Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 28 Automatic Dishwash Detergent-Industrial & Institutional (Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 28 Automatic Dishwashing Gel with Chlorine Bleach . . . . . . . . . . . . 29 Clear. Colorless Manual Dish Wash . . . . . . . . . . . . . . . . . . . . . . 30 Powder Stainless Silverware Pre-Soak . . . . . . . . . . . . . . . . . . . . 30 Low Alkaline Warewashing Block . . . . . . . . . . . . . . . . . . . . . . . 30 Dish Washing Agents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 sh w/Amine Oxide/LABS/SLES . . . . . . . . . . . . . . . . . . . 33 Dish Wash w l h i n e Oxide/LABS/ALES . . . . . . . . . . . . . . . . . . 33 Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Foam Booster: E-14-5 in Hand Dishwashing Liquids 34 Economy Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Standard Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 90% Premium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Rernium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Hand Dish Detergent Formulations Clear Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 Pearlescent Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 Rand Dishwashing Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Light Duty Liquid. Premium Hand Dishwash . . . . . . . . . . . . . . . 38 Light Duty Liquid Low Cost Hand Dishwash . . . . . . . . . . . . . . . 38 Liquid Automatic Dishwasher Detergent . . . . . . . . . . . . . . . . . . . 39 Manual Dishwashing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 Manual Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Now-Chlorinated Machine Dishwashing Compound. Liquid . . . . . 42 Chlorinated Machine Dishwashing Compound. Powder . . . . . . . . 42 Non-Chlorinated Machine Dishwashing Compound. Powder . . . . 42 Premium Hand Dishwashing Detergent . . . . . . . . . . . . . . . . . . . . 43 Dish Washing Agents for Manual Use . . . . . . . . . . . . . . . . . . . . 43
5 GEN LEANERS . . . . . . . . . . . . . . . . . . . . . . . Abrasive Cleaner with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . rasive Cleaner Without Bleach . . . . . . . . . . . . . . . . . . . . . . . . Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . All Purpose Cleaner - No Rinse . . . . . . . . . . . . . . . . . . . . . . . . . AB1-Purpose Disinfectant Cleaner . . . . . . . . . . . . . . . . . . . . . . . . All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . &alp Purpose Cleaner w/Amide/hosphate Ester . . . . . . . . . . . . . . A Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
44
45 46 47 48 49 49 50 50
xiv

(Phosphate. Liquid. Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 All Purpose Concentrate (Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5% Calcium Carbonate Abrasive Cleaner Without Bleach . . . . . . . . . 52 Citric Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 General Purpose Cleaner (Consumer Low Alkaline. Non-Phosphate Powder) . . . . . . . . 54 General Purpose Cleaner (Consumer High Alkaline. Non-Phosphated Powder) . . . . . . . 54 General Purpose Spray & Wipe Cleaner . . . . . . . . . . . . . . . . . . . 55 General Purpose Spray & Wipe . . . . . . . . . . . . . . . . . . . . . . . . . 56 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 Hypochlorite Vertical Surface Cleaner . . . . . . . . . . . . . . . . . . . . 57 Pump Spray All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 57 Liquid Cleanser with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 Pine Oil Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Disinfecting Cleaner. Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Sodium Bicarbonate Abrasive Cleaner Without Bleach . . . . . . . . 60
All Purpose Cleaner Concentrate
6 GLASS CLEANERS/POLISHES . . . . . . . . . . . . . . . . . . . . . . . . . . 6 1 Anti.Fogging. Anti-Static Glass Cleaner . . . . . . . . . . . . . . . . . . 62 Glass Cleaner. Ready to Use . . . . . . . . . . . . . . . . . . . . . . . . . . . 62 Glass Cleaner Concentrate (Non-Ammoniated) . . . . . . . . . . . . . . 63 Glass Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 Glass and Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Premium Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . 65 Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Windows/Glass Glass Cleaner (Concentrate) . . . . . . . . . . . . . . . . . . . . . . . . . 66 Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . 66 Windshield Washer Concentrate (Low VOC) . . . . . . . . . . . . . . . . 66
7 HARD SURFACE CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . Hard Surface Cleaner Concentrate (All Purpose Type) . . . . . . . . . Concentrated Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . Hard Surface Cleaner-Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . Pine Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
67 58 68
69 69 69
70

Bard Surface Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . Hard Surface Cleaner Concentrate w/dLimonene . . . . . . . . . . . . . Bard Surface Cleaner Concentrate (Phosphate. Liquid) . . . . . . . . . Hard Surface Spray Cleaner (Phosphate. Liquid) . . . . . . . . . . . . . Hard Surface Cleaner Concentrate wmipentene . . . . . . . . . . . . . . Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Abrasive Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Tile and Sanitary Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . Hard Surface Cleaner-All Purpose . . . . . . . . . . . . . . . . . . . . . . . old and Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . .
xv
71 71 72 72 73 73 74 74 74 75 76
77 78 78 79 80 80 80 81 82 82 82 83
83
84
PRODUCTS
gent for Fine Fabrics-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent for Fine Fabrics-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Laundry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 h 1 Liquid Laundry Detergent with Enzyme & Optical . . . . . . . Surfactant Rich Detergent for Nursing Homes . . . . . . . . . . . . . . . Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . . dustrial Heavy Duty Laundry Liquid . . . . . . . . . . . . . . . . . . . . Industrial Laundry Detergents High Caustic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . Mixed Builder Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . Washing Paste with Bleaching Agent . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Consumer (Liquid) . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Consumer (Zeolite Built. Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . Laundry Detergent-Consumer (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Consumer phosphate. Powder) ............................... bundry Break-Industrial & Institutional (Liquid. Phosphate) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Break-Industrial & Institutional (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Industrial & Institutional (NTAJZeolite. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Break-Industrial & Institutional (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Industrial & Institutional (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Industrial & Institutional (Sodium Carbonate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . .
................................
84
85
85
86 86
87
87
m i

Laundry Break-Industrial & Institutional phosphate. Powder. High Alkalinity) . . . . . . . . . . . . . . . . . . 88 Laundry Break-Industrial & Institutional (Zero Phosphate Powder. High Alkalinity . . . . . . . . . . . . . . . . 88 Laundry Detergent-Industrial & Institutional (Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 89 Laundry Detergent-Industrial & Institutional (NTA, Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 Laundry Detergent-Industrial & Institutional (Sodium Carbonate with Flow Aid. Powder) . . . . . . . . . . . . . . 90 Laundry Detergant-Industrial & Institutional (Phosphate. Solid Block) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94 6 Laundry Detergent-Industrial and Institutional (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 91 Laundry Detergent-Industrial and Institutional (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 91 1 Laundry Detergent-Industrial & Institutional (Phosphate Built. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . 92 Laundry Detergent-Industrial & Institutional (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92 Laundry Builder-Industrial & Institutional 93 (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Industrial & Institutional (Zeolite Built. Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . 93 Laundry Prespotter Sprayable Gel . . . . . . . . . . . . . . . . . . . . . . . . 94 Laundry Prespotter Sprayable Liquid . . . . . . . . . . . . . . . . . . . . . 95 Light Duty Liquid Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 Calsoft LAS-99 Based . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 Dry Cleaner: Pre Spot-Water Soluble . . . . . . . . . . . . . . . . . . . . . 99 99 Wool Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Two Part Industrial Laundry Detergents Break Formulations Highly Alkaline Break . . . . . . . . . . . . . 5 0 10 Mixed Builder Break . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 Detergent Additive . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 Ultra Liquid Laundry Detergent . . . . . . . . . . . . . . . . . . . . . . . . 101 Fine Fabric Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 61
9 METAL CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . Acid Metal Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dipping Cleaner for Silver . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aluminum CleanerBrightener . . . . . . . . . . . . . . . . . . . . . . . . . Powdered Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
802
p03
103 104 104 1104

Aluminum Cleaner Concentrate F-498 . . . . . . . . . . . . . . . . . . . Aluminum Wash F-499 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ffing Compound Remover . . . . . . . . . . . . . . . . . . . . . . . . . . t Alkaline Paint Stripper Concentrate . . . . . . . . . . . . . . . . . . Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Semi-synthetic Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . General Purpose Machine Cleaner . . . . . . . . . . . . . . . . . . . . . . Aircraft Cleaner Type I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . V General Purpose Synthetic Fluid (A) . . . . . . . . . . . . . . . . . . . . . General Purpose Synthetic Fluid (3) . . . . . . . . . . . . . . . . . . . . . Copper Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . General Purpose Synthetic Fluid (C) . . . . . . . . . . . . . . . . . . . . . General Purpose Synthetic Fluid @) . . . . . . . . . . . . . . . . . . . . . Metal Cleaner (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aluminum Cleaner phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . eta1 Cleaner phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . Alkaline Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . Semi Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Silver and Metal Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Soluble Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Soluble Oil Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . Synthetic Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Synthetic DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . Oil Based DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . Spray Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . . . . Synthetic Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Synthetic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Universal Scouring Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Water Soluble Stamping Fluid . . . . . . . . . . . . . . . . . . . . . . . . . -40 Type Lubricant Concentrate . . . . . . . . . . . . . . . . . . . . Penetrating Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Burnishing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
xvii
105 105 106 106 106 107 109 109 110 110 111 111 111 112 112 113 113 114 115 116 116 117 119 120 122 122 123 124 124 124 125 130 133 133 134 134 134 134
xviii
10
OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . High Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aerosol Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . Oven Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . Oven Cleaner wphosphate . . . . . . . . . . . . . . . . . . . . . . . . . . . .
135 136 B6 3 137 138

138
139
139
10 4
140
1 POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . 1 Furniture Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . LeatherPlastic Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Marble Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rust Removing Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Scratched Wood Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . High Gloss. Detergent Resistant Polish . . . . . . . . . . . . . . . . . . .
11 4
142 143 144
144
145 145
12
. .
RINSE AIDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
14 .6
147 147
Rinse Aid. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rinse Aid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
13
RUG. FLOOR, CARPET. UPHOLSTERY SHAMPOOS AND CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Foam Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . Steam Rug Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Steam Rug Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Carpet Cleaners for the Spray-Extraction Process . . . . . . . . . . . Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rug Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Carpet Shampoo. High Foam . . . . . . . . . . . . . . . . . . . . . . . . . . Carpet Spot Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . Vinyl Dressing (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Steam Carpet Cleaner For Hard Water Systems . . . . . . . Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy-Duty Floor Scrubber . . . . . . . . . . . . . . . . . . . . . . . . . . . Household Carpet Freshenedhtistat . . . . . . . . . . . . . . . . . . . .
n48
19 4
149 149 149 150 150 15 11
151
152 15 12 153
153 154 154
155 155 155

156

Pump Spray Carpet Antistat . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Leather. Vinyl. and Plastic Cleaner and Restorer . . . . . . . Liquid Leather. Vinyl. and Plastic Cleaner . . . . . . . . . . . . . . . . Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . Premium. Medium Duty Steam Extraction Carpet Cleaner . . . . . uty Steam Extraction Carpet Cleaner . . . . . . . . . . . . . . aming Carpet Extractor Detergent . . . . . . . . . . . . . . . . . m Cleaner (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . No Rinse Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . No-Rinse Floor Cleaner Degreaser ...................... Wax Stripper (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ax Stripper (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concentrated Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . .
xix
156 157 157 158 158 158 159 159 160 160 160 161 161 161 162 163 163 163 164 164 164 164 165 165 166 167 168 169 170 171 171 172 173 174 174 174 175 175 176
CEELANEQUS
.................................
acteriostatic Concentrate w/Pine Oil . . . . . . . . . . . . . . . . . . . . General Disinfectant Solution . . . . . . . . . . . . . . . . . . . . . . . . . . Hospital Disinfectant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concrete Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . White Wall Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . d ' l h o n e n e Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . Paste Nand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dipentene Microemulsion Formulations -alkaline Formulations . . . . . . . . . . . . . . . . . . . . . . . . . line Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hydrocarbon Solvent Microemulsions Emsol D-110 Formulations . . . . . . . . . . . . . . . . . . . . . . . . Isopar M Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . h w Viscosity Silicone Emulsion Using Pemulen Resins . . . . . . Luminizing Pet conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . Pea Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iao-Emulsions with d-Limonene ..................... Micro-Emulsions with Pine Oil . . . . . . . . . . . . . . . . . . . . . . . . Plastic Bottle Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Bottle Wash Formulations w Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . oderate Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Terpene Microemulsions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concentrated Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wax Emulsion Using Pemulen Resins . . . . . . . . . . . . . . . . . . . .
xx

SECTION 11 TRANSPORATION CLEANERSl AND POLISHES
15 AUTO CLEANERS AND POLISHES
Chrome Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Car Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Spray Cleaner for Aluminum Trucks . . . . . . . . . . . . . . . Aluminum Cleanermrightener . . . . . . . . . . . . . . . . . . . . . . . . . Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . Mild Abrasive Automobile Polish . . . . . . . . . . . . . . . . . . . . . . .
....................
1 198 19 7 180 181
181 18 11
182 %83
184
16
CAR AND TRUCK WASH COMPOUN S . . . . . . . . . . . . . . . . Car Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . Automobile Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . Car Wash (Calsoft LAS-99-Based) . . . . . . . . . . . . . . . . . . . . . Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash (Calsoft T-60-Based) . . . . . . . . . . . . . . . . . . . . . . . CarWash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Paste Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . Windshield Washer Formulation . . . . . . . . . . . . . . . . . . . . . . . . Car Wash Concentrate w/Alcohol Ethoxylate . . . . . . . . . . . . . . Car and Truck Wash Formula . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash and Care Car Shampoo with Water-Repellent Effect . . . . . . . . . . . . . Rinse-off Agent (Water Repellent) . . . . . . . . . . . . . . . . . . . Rinse-off Agent (Water-Repellent) Without Hydrocarbons . Windshield-Cleaner (Summer) . . . . . . . . . . . . . . . . . . . . . . Windshield-Cleaner (Winter) . . . . . . . . . . . . . . . . . . . . . . . Insect Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wheel Cleaner, Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . Tar Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Car Wax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Auto Wipe & Shine Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concentrated Traffic Film Removers . . . . . . . . . . . . . . . . . . . . Foamy Brush Car Wash, Liquid . . . . . . . . . . . . . . . . . . . . . . . . Low Cost Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . General Purpose Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~
184 185
15 8 185 186
186 187 187
187
133
189
189
189
190
10 9 190 10 9 1B 9
191 191
191
192
192 193 194 194 195 195

Boat Wash & Car Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Truck Wash. Liquid . . . . . . . . . . . . . . . . . . . . . . . Heavy D t Truck Wash. Powder . . . . . . . . . . . . . . . . . . . . . . . uy Premium Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . . . Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Auto Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . Touchless Vehicle Wash Detergent (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . Vehicle Wash Detergent (Low pH) (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . Tmck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Economy Tnuck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . Car Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash and Wax Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . Vehicle Wash Detergent (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (Liquid. low foam) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Vehicle Wash Detergent (Low pH) (Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . Touchless Vehicle Wash Booster/Additive (Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . .
xxi
195 196 196 197 197 197 198 198 199 199 199 199 200 200 201 201 202
203 203 203
ITEWALL TIRE CLEANERS . . . . . . . . . . . . . . . . . . . . . . Mitewall Tire Cleaner (Zero Phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
SCEEUNEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aircraft Cleaner (Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Auto Care: Hnterior/Exterior Rubber & Vinyl Protectant . . . . . . . Boat Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concrete CIeanerDegreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . Garage Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Acid Rust Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ConcreteDriveway Cleaners For Other Stains . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Concrete Cleaner (Phosphate Free) Formula 1C . . . Vinyl Dressing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ressing (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
204 205 205 206 207 208 208 208 209 209 210 210
xxii
SECTION III: TRADEMARKED RAW MATE SECTION IV: SUPPLIERS' ADDRESSES
s . . . . . . . . . . 2nn .
a
~ ~
. ... . . . . . . . . . . . . .
229
ection I
Household and Industrial Cleaners and Polishes
1. Bathroom Cleaner
Bathroom Cleaners
A c i d i c Toilet Bowl C l e a n e r Carbopol r e s i n s a r e used t o t h i c k e n t h i s a c i d i c t o i l e t bowl c l e a n e r f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p r o v i d e s v e r t i c a l c l i n g t o increase t h e contact time o f t h e detergent on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e . I n s r e d ie n t :
5
43.00 2.00
DI Water
Carbopol 6 7 4 ( 1 ) C i t r i c A c i d (50%) A l k y l benzene s u l f o n i c a c i d 97%) ( 2 ) Sodi u d o d e c y l d i p h e n y l o x i de d i s u l f o n a t e (45%) ( 3 ) m B r o o k f ie l d v i s c o s i t y ( R V T 20 rpm): 4,000 P r o d u c t pH: 1 .O-2.0 Product C l a r i t y : C l e a r
(1)
50.00
2.00 3.00
cps
BFGoodrich Dowfax 2A1
i2j Stepan Co.: B i o s o f t 5-100

( 3 ) Dow Chemical Co.: Procedure: 1 . M i x t h e D I w a t e r and c i t r i c a c i d s o l u t i o n t o g e t h e r . 2 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e w a t e r / c i t r i c a c i d solu t i o n . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 30 m i n u t e s . The p r o d u c t w i l l become i n c r e a s i n g l y t h i c k e r w i t h t i m e - h e a t i n g t o 40-50C w i l l h a s t e n t h e p r o c e s s . 3 . Add t h e s u l f o n i c a c i d and t h e d i p h e n y l o x i d e d i s u l f o n a t e surfactant. 4 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Cool t h e p r o d u c t t o room t e m p e r a t u r e .
Total Actives:
C i t r i c a c i d : 25.00 A l k y l benzene s u l f o n i c a c i d : 1.94 Dodecyl d i p h e n y l o x i d e d i s u l f o n a t e : 1.35
SOURCE:
BFGoodrich S p e c i a l t y Chemicals:
DET-351
Advanced Cleaning Product Formulatioris
Bathroom Cleaner with Disinfectant Inqredi ents: A: Veegum T, Magnesium Aluminum Silicate Rhodopol 23, Xanthan Gum Deionized Water B: Diatomaceous Earth (Super Floss) Tetrasodium EDTA (Hampene 100) Sodium o-Phenylphenate (Dowicide A) Sodi um A1 kyl benzene Sul fonate (Cal soft L - 4 0 ) Butyl Cellosolve Wt .%*
1
.oo
0.35 86.65
5.00 2.75 0.25 3.00

1
.oo
Procedure: 1 . Dry blend the Veegum T and Rhodopol 23 and add them to the water while stirring with an homogenizer at 5000 rpm. Continue mixing for 30 minutes. 2. Slowly add the Part 8 ingredients in the order shown, mixing each for 5 minutes. * A s received basis SOURCE: R.T. Vanderbilt Co., Inc.: Formulation No. 363 Heavy Duty Acid Bathroom Cleaner Inqredi ents: Hydroxyacetic acid Sulfamic acid Ammonyx LO Water, D.I.
Wt%
5.0 5.0 10.0 80.0
Mixing Procedure: Add ingredients to water in the order given and mix until homogeneous. Properties: Appearance: Clear liquid pH, as is: 1.0 Solids, %: 1 4 . 0 Density, lbs/gal: 8.7 Use Instructions: Use as is o r dilute as needed. Do not use on natural marble or polished aluminum. Use gloves. Do not mix with bleach. Storage Stability: Formulation is freeze/thaw stable through 3 cycles. Formulation is stable for 3 weeks @ 50C. SOURCE: Stepan Co.: Formulation No. 200
Bathroom Cleaners
M i 1dew Remover
Ingredients: Van Gel 0 D e i o n i z e d Water Sodium H y d r o x i d e , 50% S o l u t i o n Sodium H y p o c h l o r i t e , 10% S o l u t i o n ( H y p u r e N ) Vanseal NALS-30
Wt%*
3.00 85.55 0.45 10.00 1.oo
Procedure: 4 . S l o w l y s p r i n k l e t h e Van Gel 0 i n t o w a t e r a t room t e m p e r a t u r e w h i l e m i x i n g w i t h a homogenizer o r d i s p e n s e r o p e r a t i n g a t 5000 rpm. C o n t i n u e m i x i n g f o r 40 m i n u t e s . 2 . Add sodium h y d r o x i d e and m i x u n t i l u n i f o r m l y d i s s o l v e d . Slow t h e m i x e r t o 1 0 0 0 rpm o r l e s s . 3 . Add t h e Vanseal NALS-30. A v o i d a i r e n t r a p m e n t . M i x u n t i l uniform. F o r m u l a t i o n No. 458 Bowl /Mi 1dew C 1 e a n e r
A:
Ingredients: Veegum T , Magnesium Aluminum S i l i c a t e T e t r a s o d i u m P y r o p h o s p h a t e (TSPP) Water
5.00
0.25 50.75
34.00 10.00
8 : Sodium H y p o c h l o r i t e , 5 . 2 5 % Sodium M e t a s i l i c a t e , Anhydrous
Procedure: 1 . D r y b l e n d t h e Veegum T and TSPP. S l o w l y add t h e w a t e r w h i l e a g i t a t i n g a t maximum a v a i l a b l e s h e a r . C o n t i n u e u n t i l smooth. 2 . Add P a r t B i n g r e d i e n t s s l o w l y i n t h e o r d e r shown, m i x i n g a f t e r each a d d i t i o n u n t i l smooth and u n i f o r m . F o r m u l a t i o n No. 424 *As r e c e i v e d b a s i s SOURCE: R.T. V a n d e r b i l t Co., I n c . : Suggested F o r m u l a t i o n s
Advanced Cleaning Product Formulations
Tile,
P o r c e l a i n a n d Bathroom C l e a n e r , A c i d
Ingredients: 75.5 Water, D . I . Xanthan Gum 0.5 P e t r o BAF Powder 2.0 P h o s p h o r i c A c i d , 75% 12.0 10.0 H y d r o x y a c e t i c A c i d , 70% q.s. Perfume, Dye B l e n d i n g Procedure: Add Xanthan Gum s l o w l y t o w a t e r w i t h h i g h speed m i x i n g . A l l o w t o m i x u n t i l m a t e r i a l t h i c k e n s . Add r e m a i n i n g i n g r e d i e n t s i n o r d e r l i s t e d . I f p r o b l e m s d e v e l o p a d d i n g Xanthan Gum t o w a t e r , p r e m i x t h e Xanthan Gum i n some i s o p r o p a n o l b e f o r e a d d i n g t o water. F o r m u l a 529 Tub and T i l e C l e a n e r Ingredient: Water, D . I . P h o s p h o r i c A c i d , 86% H y d r o c h l o r i c A c i d , 37% R e w o t e r i c AM TEG V a r o n i c T202 SR Blending Procedure: Add in g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y each a d d i t i o n . T y p i c a l P r o p e r t ie s : V i s c o s i t y , c p s : 293 S o l i d s : 16.3% pH: 1 . 7 F o r m u l a 530 H y p o c h l o r i t e Tub and T i l e C l e a n e r a n d M i l * S t a i n
67.4
17.6 13.5 0.5 1.o between
Remoz
Ingredients: Water, D . I . 44.9 Sodium H y d r o x i d e (30%) 1.o Varox 365 1.5 Sodi urn H y p o c h l o r i t e ( 5 . 7 % ) 52.6 Blending Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t io n . Typical Properties: V i s c o s i t y , cps: 4 S o l i d s : 3.8% pH: 13.5 F o r m u l a 531
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Bathroom Cleaners
T o i l e t Bowl C l e a n e r w i t h B l e a c h Carbopol r e s i n s a r e used t o t h i c k e n t h i s t o i l e t bowl w i t h c h l o r i n e b l e a c h f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n provides v e r t i c a l c l i n g t o increase the contact time of the d e t e r g e n t on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e .
I n qr e d D I Water Carbopol 676 ( 1 ) P o t a s s i um h y d r o x i d e ( 4 5 % ) 2 . l r P o t a s s i u m s i l i c a t e (39%) ( 2 ) Potassium carbonate Sodium h y p o c h l o r i t e ( 1 2 . 5 0 % ) Amine O x i d e (30%) ( 3 )

B r o o k f i e l d v i s c o s i t y (RVT-20rpm) : 2 , 5 0 0 c p s P r o d u c t pH: 12-13 P r o d u c t c l a r i t y : Opaque ( 1 ) BFGoodri c h ( 2 ) PQ C o r p . ( 3 ) Lonza, I n c . : B a r l o x 12
i-w
Wt% 60.75 1.25 5.00 5.00 5.00 8.00 10.00
Procedure: 1 . U s i n g m o d e r a t e a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . W i t h c o n s t a n t a g i t a t i o n , add t h e p o t a s s i u m h y d r o x i d e and t h e p o t a s s i u m s i l i c a t e . M i x u n t i l homogeneous. 3 . C o n t i n u e a g i t a t i o n and add t h e p o t a s s i u m c a r b o n a t e f o l l o w e d by t h e b l e a c h . 4 . Add t h e amine o x i d e s u r f a c t a n t and m i x u n t i l homogeneous. 5 . Add c o l o r a n d f r a g r a n c e , a s d e s i r e d .
Total Actives:
S i l i c a t e (as Si02): 1.32 C a r b o n a t e ( a s Na2C03): 3 . 8 4 Available Chlorine: 1.OO Amine O x i d e : 3 . 0 0
SOURCE:
DET-350
2. Dairy, Food and
General Industrial Cleaner
D a i q , Food and General Industrial Cleaners
A c i d I n d u s t r i a l and Household C l e a n e r s O x a l i c A c i d Gel
Inqredients: Water Van Gel B Rhodopol 2 3 O x a l i c A c i d D i h y d r a t e , 12.59n Aqueous S o l u t i o n P o l y s o r b a t e 40 (Tween 4 0 )
W t .%*
53.70 2.50 0.80 40.00 3.00
Procedure: 1 . Dry b l e n d t h e Van Gel 3 and Rhodopol 2 3 and add them t o t h e w a t e r w h i l e m i x i n g w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm. C o n t i n u e m i x i n g f o r 60 m i n u t e s . 2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t v o r t e x and s l o w l y add t h e o x a l i c a c i d s o l u t i o n . 3 . When a l l t h e a c i d has been added, add t h e P o l y s o r b a t e 40 and mix u n t i l u n i f o r m . F o r m u l a t i o n N o . 466 Rust Removal J e l IY Insredi ents: Water Van Gel B Rhodopol 2 3 P h o s p h o r i c A c i d, Octoxynol-9
WtD/ou
53.20 3.00 0.80 40 0 0 3 00
50% Aqueous Sol u t ion
Procedure: 1 . D r y b l e n d t h e Van Gel 0 and Rhodopol 2 3 and add them t o he w a t e r w h i l e m i x i n g w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm. C o n t i n u e m i x i n g f o r 60 m i n u t e s . 2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t v o r t e x and s l o w l y add t h e P h o s p h o r i c A c i d s o l u t i o n . 3 . A f t e r a l l t h e a c i d has been added, add t h e O c t o x y n o l - 9 and mix u n t i l u n i f o r m . F o r m u l a t i o n No. 467 *As r e c e i v e d b a s i s
SOURCE: R . T .
V a n d e r b i l t Co.,
I n c . : Suggested F o r m u l a t i o n s
10
Cleaners f o r I n d u s t r i a l A p p l i c a t i o n D e s i n f e c t i n q Cleaner, A c i d
I n s ed ien t s : water P h o s p h o r i c a c i d (85Oh) S u l p h u r i c a c i d (98%) P r o p e t a l 241 Dodigen 226 F o r m u l a CT 06-06-01

D i ppi n q C1 e a n e r I r ed i n e-n-t-sL itatger Tetrapotassium pyrophosphate C a u s t i c soda D i p r o p y l e n e g l y c o l monomethyl S u l f e t a l 4069 Zusol a t 1008/85 F o r m u l a CT 07-03-01
wts/, 48.0 24.0 5.0 3.0 20.0
Wt%
75.5 10.0 1.5 5.0 5.0 3.0
ether
Spray C 1 e a n e r Insredients: Water Cublen D50 T r i e t h a n o l ami ne S u l f e t a l 4105 P r o p e t a l 241 Z u s o l a t l005/85 P h o s f e t a l 201 Butyl glycol C i t r u s terpene I n h i b i t o r 4000 F o r m u l a CT 07-06-01 Ingredients water Sul f e t a l 4105 P r o p e t a l 99 Zusolat 1005/85 Butyl glycol Orange t e r p e n e Formula CT 07-06-03 Q 58.0 3.0 3.0 4.0 2.0 0.5 2.0 5.0 0.5 22.0
86.0
6.0 3.0 0.5 4.0 0.5

General Formulations
SOURCE:
Zschimmer & Schwarz GmbH 8, C o . :
Dairy, Food and General Industrial Cleaners
I1
D e s t a in e r (Phosphate, Powder) S o i l - O r g a n i c s t a i n s : f o o d , mold and g r a s s Surface-Cement, wood, p a i n t , p o l y m e r i c A p p l i c a t i o n Method-Brush Manufacture-Dry blend/Agglomeration Compos i t to^ *STPP M e t s o Beads 2048 Sodium S u l f a t e PQ Epsom S a l t **Octylphenoxy Polyethoxyethanol, Sodium P e r b o r a t e , Monohydrate
Wt%
25.0 25.0 8.0 2.0 2.0
9-
0 M o l e s EO ion)
38.0
Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 oz/ga
**
FMC Rhone P o u l e n c I g e p a l C A - 6 3 0 Destai ner (Reduced Phosphate,
Powder)
S o i l - O r g a n i c s t a i n s : f o o d , mold and g r a s s Surface-Cement, wood, p a i n t , p o l y m e r i c A p p l i c a t i o n Methods-Brush Manufacture-Dry blend/Agglomeration n : Composi t i o *STPP M e t s o Beads 2048 Sodi um S u l f a t e PQ Epsom S a l t **Octylphenoxy Polyethoxyethanol, V a l f o r 100 Z e o l i t e A Sodium P e r b o r a t e , Monohydrate Use L e v e l : 3-6 oz/gallon
9 - 1 0 Moles EO
% & 10.0 25.0 8.0 2.0 2.0 15.0 38.0
* **
FMC Rhone-Poulenc
I g e p a l CA-630 D e t e r g e n t F o r m u l a t i o n Guide
SOURCE:
PQ C o r p . :
12
Eaa C l e a n e r
L x o phosphatS?,.powder)
S o i 1- P r o t e i n S u r f a c e - E g g and egg h a n d l i n g e q u i p m e n t A p p l i c a t i o n M e t h o d - H i g h p r e s s u r e s p r a y (700-1400 Manufacture-Dry blend Composi t i o n : Sodium C a r b o n a t e M e t s o Beads 2048 Sodium S u l f a t e V a l f o r 100 Z e o l i t e A * S o d i urn D i c h l o r o i s o c y a n u r a t e 2H20 * * S o d i um A1 k y l a r y l S u l f o n a t e Powder ( 9 0 % ) Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 oz/gallon)
psi)
Wt%
30.0 20.0 12.0 30.0 3.0

5.0
**
O l i n Chemical Witco
B g k i - n g Pan C l e a n e r (Phosphate,- Powder) S o i l - A n i m a l f a t and g r e a s e , v e g e t a b l e o i l S u r f a c e - A 1 umi num and s t e e l A p p l i c a t i o n Method-Irnmersion/brush Manufacture-Dry blend/Agglomeration
O ~ ~t 1 o n : S l *Sodium C a r b o n a t e *STPP **Nonylphenoxy P o l y e t h o x y e t h a n o l , Metso Pentabead 2 0 C
9-10 M o l e s 0
Wt% 35.0 12.0 3.0 50.0
Use D i l u t i o n .
1 . 5 % bw ( 2 o z / g a l l o n )
I g e p a l CO-630 Detergent F o r m u l a t i o n Guide
* **
FMC Rhone-Poulenc
PQ C o r p . .
SOURCE:
13
Heavv D u t v C l e a n e r s A l l Purpose-Food P r o c e s s P l a n t Ingredients: Water EDTA ( E t h y l e n e d i a m i n e t e t r a c e t i c A c i d ) TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) P i l o t SXS-40 KOH, 45% Calamide C Weight% 74.00 2.00 4.00 5.00 10.00 5.00
Comments a b o u t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s i n o r d e r l i s t e d . 2 . Water and EDTA g i v e a m i l k y w h i t e s o l u t i o n . 3 . Upon a d d i n g t h e o t h e r i n g r e d i e n t s t h e s o l u t i o n i s c l e a r . 4. EDTA can b e s u b s t i t u t e d w i t h Na4EDTA t o make a c l e a r f i n a l solution. 5 . T h i s i s a heavy d u t y c l e a n e r f o r f o o d p r o c e s s i n g p l a n t s . 6 . Use l e v e l . 2-4 o z p e r g a l l o n . F o r m u l a t i o n HDC-004-01 Hard S u r f a c e Spray Cleaner
- qredients: In
Water TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) E t h y l e n e G l y c o l Monobutyl E t h e r C a l s u d s 81 NH40H, 28%
Weight% 89.00 1.oo 3.00 4.00 3.00
Comments a b o u t t h i s f o r m u l a : 1 . I n g r e d i e n t Water and TKPP when m i x e d a r e c l e a r . 2 . Hazy s o l u t i o n when E t h y l e n e G l y c o l M o n o b u t y l E t h e r i s added. 3 . W i t h t h e a d d i t i o n o f C a l s u d s 81 t h e s o l u t i o n t u r n s c l e a r and has a pH o f 9. 4 . When iUH40H i s added, t h e pH i n c r e a s e s t o 1 2 . F o r m u l a t i o n HDC-002-01 SOURCE: P i 1o t Chemical
Co. : Suggested Formul a t i ons
14
H i qh Foaming A1 k a l ine C l e a n e r
M o n a t e r i c EH c o n t r i b u t e s t o d e t e r g e n c y and e f f e c t i v e l y cont r o l s b o t h t h e k r a f f t and c l o u d p o i n t i n t h i s h i g h foaming formulation. I n n r e d ie n t s : Wt9/o Water 76.0 Sodium H y d r o x i d e (50%) 10.0 Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) 2.0 Dodecyl benzenesul f o n i c a c i d 2.0 M o n a t e r i c EH 8.0 Nonoxynol -1 0 2.0 Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package. Recommened Use D i l u t i o n : 1 : 2 0 w i t h w a t e r F o r m u l a t i o n F-768 Heavy D u t y A l k a l i n e Degreaser M o n a t e r i c EH a i d s i n t h e removal o f o i l y s o i l s w i t h o u t emuls i f i c a t i o n . I t e a s i l y displaces o i l y s o i l s from hard surfaces and keeps them f r o m r e d e p o s i t i n g . Ingredients: Wt% Water 65.0 20.0 Sodi u m H y d r o x i de ( 5 0 % ) Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) 3.0 M o n a t e r i c EH 10.0 Nonoxynol -1 0 2.0 Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package. Recommended Use D i l u t i o n : 1 : 2 0 w i t h w a t e r . F o r m u l a t i o n F-769 Steam C1eaner Mona NF-20 c o n t r i b u t e s t h e non-foaming and d e t e r g e n c y t i e s i n t h i s formulation. I n a r e d ients: Water Potassi u Hydroxide m Sodium M e t a s i l i c a t e (Anhydrous) T e t r a p o t a s s i u Pyrophosphate m Mona NF-20 Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Typical Properties: Cloud P o i n t : 75C K r a f f t Point: tOC Recommended Use D i l u t i o n : 4-6 o z . / g a l . F o r m u l a t i o n F-762 proper-
WtO/o
65.00 3.00 10.00 10.00 12.00
SOURCE: Mona I n d u s t r i e s ,
15
I n d u s t r i a l and Hiqh Pressure Cleaners - eaner. Strong1 y A1 Kal i ne C1

Inqredients: Water Cublen D 50 Tetrapotassi um pyrophosphate C a u s t i c soda Sodi u m m e t a s i 1 i c a t e S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 Butyl glycol F o r m u l a CT 06-13-01
y% w
76.5 1.o 4.0 0.6 4.9 4.0 2.0 2.0 5.0
C1 e a n e r , Weakly A1 k a l ine Ingredients: Water Cublen D 50 Tetrapotassium pyrophosphate T r i e t h a n o l ami ne S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 Butyl glycol F o r m u l a CT 0 6 - 1 3 - 0 2 Cleaner, S t r o n q l y A1 k a l i n e (Phosphate-Free) I n g r e d i e c Water Cublen D50 Sodi um m e t a s i 1 i c a t e C a u s t i c soda S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 Butyl glycol F o r m u l a CT 06-13-03 @1 eaner, Weak1 y A1 k a l ine ( Phosphate-Free1 Ingredients: Water C u b l e n D 50 T r i s o d i um c i t r a t e S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 Butyl glycol T r i e t h a n o l ami n e F o r m u l a CT 06-13-04
Wt%
80.4 1.o 2.0 3.6 4.0 2.0 2.0 5.0
Wt%
80.5 1. o 4.9 0.6 4.0 2.0 2.0 5.0
Wt%
80.4
1. o
2.0 4.0 2.0 2.0 5.0 3.6
SOURCE:
Zschimmer & Schwarz GmbH & C o . :
16
Metal Cleaner
(m
S o i l - P e t r o l e u m and a n i m a l o i l and g r e a s e Surface-Metal: Steel A p p l ic a t i on Method-Immersi on Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Water S t a r Sodi um S i 1 ic a t e Sodium H y d r o x i d e (50%) *Phosphate E s t e r * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; Use D i l u t i o n : 2%-5% b v
w.t%
65.6 15.6 6.3 5.0 7.5
6 Moles EO)
**
Rhone-Poulenc Rhodafac RE-610 Rhone-Poulenc R h o d a s u r f 91-6

Food I n d u s t r y C l e a n e r
(W
S o i l - H e a v y f o o d g r e a s e , o i l and p r o t e i n Surface-Metal, ceramic, polymeric, glass A p p l i c a t i o n Method-Wipe, mop o r b r u s h Manufacture-Mix t a n k w i t h p r o o e l l e r s t i r r e r Composition: Water TKPP (60%) N C l e a r Sodium S i l i c a t e Sodi um H y d r o x i d e (50%) *Phosphate E s t e r **Ethylene Glycol n-Butyl Ether * * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; Use D i l u t i o n : 6-12% bw ( 8 - 1 6 o z / g a l l o n )
Wt%
74.0 3.0 7.0 3.5 2.5 5.0 5.0
6 . 5 Moles 0 )
**
***
Rhone-Poulenc Rhodafac RE-600 Dow C h e m i c a l , U n i o n C a r b i d e Rhone-Poulenc R h o d a s u r f LA-7 Detergent F o r m u l a t i o n Guide
SOURCE: PQ C o r p . :
17
M i l k Can C l e a n e r (Phosphat_e, Powder)

Sol 1 - F a t
and p r o t e i n Surface-Metal A p p l i c a t i o n Method-Wipe o r b r u s h Manufacture-Dry blend/Agglomeration WX/, 30.0 30.0
Compo_sition *STPP M e t s o Beads 2048 *Sod1 u m C a r b o n a t e +*Sod1 um D i c h l o r o i s o c y a n u r a t e , 2H20 * * * S o d i u m A1 k y l a r y l S u l f o n a t e Powder,

Use D i l u t i o n
(90%)
35.0 3.0 2.0
0.75-1
5% bw (1-2 o z / g a l l o n )
* ** ***
FMC O l i n Chemical w1 t c o M i l k Can CLea-ner (Zeco Phosphate, Powder) S o l 1 - F a t and p r o t e i n S u r f ace-Metal A p p l i c a t i o n Method-Wipe o r b r u s h Manufacture-Dry blend
Composi t i on : Val f o r 100 Z e o l i t e A Metso Pentabead 20 Sodium C a r b o n a t e *Sodium D i c h l o r o i s o c y a n u r a t e , 2H20 **Sod1 um A 1 k y l a r y l S u l f o n a t e Powder, Use L e v e l : 1 - 2 o z / g a l l o n
Wt%
20.0 40.0
35.0
3.0
(90%) 2.0
* **
O l i n Chemical Stepan, W i t c o
PQ C o r p . :
SOURCE:
D e t e r g e n t F o r m u l a t i o n Guide
18
Powdered Enzyme Presoaks Economy Presoak Component: Soda Ash Sodium Metasilicate Pentahydrate Sodium Dodecylbenzenesulfonate Powder Burcosperse AP Powder Burcotase EP-60 Premi um Presoak Component: Soda Ash STPP Neodol 25.7 Sodium Metasi 1 icate Pentahydrate Sodium Dodecylbenzenesulfonate Powder Burcosperse AP Powder Burcotase EP-60 The recommended use concentration o f these products i s g/1 in the presoak bath. F o r optimum results, the presoak temperature should be 130-15OF. Enzyme Prespotter f o r Oilv/Smuttv Soils Component: Water Propyl ene G1 ycol Dodecyl benzenesul foni c Acid TEA-85 Burco TME Nonionic Surfactant* Burcotase LL-100 *An HLB of 9 . 5 - 1 0 . 0 preferred.
wtD/,
49.0 10.0 10.0 20.0 5.0 5.0 1.o
Wt%
80.0 10.0 5.0 3.0 2.0
5
40.0 35. n 5.0 10.0 5.0 3.0 2.0
1-4
i s preferred. Alcohol ethoxylates are
Add components in the order listed. Blend until uniform between each addition. Cool before adding the enzyme.
SOURCE: Burlington Chemical G o . , Inc. : Suggested Formulations
Dairy,Food and General Industrial Cleaners
19
S a n i t i z i n s Cleaner (Phosphate, Powder) S o i l - H o s p i t a l s o i l : sebum, b l o o d , u r i n e , e t c . Surface-Metal, ceramic, polymeric A p p l i c a t i o n Method-Wipe o r b r u s h Manufacture-Dry Blend Composi t 1 1 0 ~ Metso Beads 2048 *Sodium C a r b o n a t e *STPP **Sodi urn D i c h l o r o i s o c y a n u r a t e , 2H20 ***Sod; um A1 k y l a r y l S u l f o n a t e Powder (99%) Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 oz/gallon)
Wt%
20.0 35.0 30.0 10.0 5.0
* ** ***
FMC 01 i n Chemical witco Sani t i z i na A a e n t (Phosphate, Powder)_
S o i l - H o s p i t a l s o i l : sebum, b l o o d , u r i n e , Surface-Metal, ceramic, polymeric A p p l i c a t i o n Method-Wipe, b r u s h Manufacture-Dry blend/Agglomeration Composi t i on : *STPP *Sodi um C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl6; M e t s o Pentabead 20 Quaternary Germicide Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2
etc.
Wt%
12 M o l e s EO) 30.0 25.0 10.0 30.0 5.0
oz/gallon)
**
FMC Rhone-Poulenc R h o d a s u r f LA-12 Detergent F o r m u l a r y Guide
3 Degreaser .
20
Degreasers
21
Aqueous D e s r e a s e r Ingredients: Water NaOH, 50% Cal s o f t LAS-99 P i l o t SXS-40 C a l o x y l a t e N-9 TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) Sodium M e t a s i 1 i c a t e E t h y l e n e G l y c o l Monobutyl Ether Comments a b o u t t h i s f o r m u l a : D i s s o l v e t h e s a l t s i n t h e water f i r s t . F o r m u l a t i o n DEG-001-01 Aqueous D e q r e a s e r d - L i monene M i c r o e m u l s i o n Ingredients: d - L i monene C a l s u d s CD-6 C a l imu1 se PRS Diethylene Glycol n-Butyl Water Weight% 9.90 9.80 2.44 4.93 73.00 Wei q h t % 60.80 2.00 9.40 8.70 4.60 4.70 6.60 3.20
Ether
Comments a b o u t t h i s f o r m u l a : 1 . A d d i t i o n a l C a l s u d s CD-6 may b e needed t o c l a r i f y t h e sample. 2 . Add t h e w a t e r s l o w l y . F o r m u l a t i o n DEG-002-01 Water Based D e a r e a s e r Ingredients: Water NaOH, 50% Cal s o f t LAS-99 P i lot SXS-40 Na4EDTA C a l o x y l a t e N-9 E t h y l e n e G l y c o l Monobutyl Ether Sodi urn M e t a s i 1 ic a t e Weight% 68.50 2.00 7.00 7.50 2.00 5.00 3.00 5.00
Comments a b o u t t h i s f o r m u l a : 1 . T h e r e i s a p h o s p h a t e v e r s i o n where 3 . 5 % sodium t r i p h o s p h a t e i s s u b s t i t u t e d f o r t h e sodium m e t a s i l i c a t e and Na4EDTA. 2 . Use w a t e r t o b a l a n c e i n g r e d i e n t s . F o r m u l a t i o n DEG-006-01
SOURCE:
P i l o t Chemical C o . :
Suggested F o r m u l a t i o n s
22
Advanced Cleaning Product Formulatiorrs
m r e a s e r Concentrate ( L i q u i d)
Soil-Grease, o i l Surface-Pai n t , polymeric, metal A p p l i c a t i o n Method-Spray o r w i p e Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Water M e t s o Beads 2048 *Sodi urn P o l y a c r y l a t e (40%) **Phosphate E s t e r * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 6 M o l e s EO) * * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO) Use D i l u t i o n : Normal Duty-1.5% bw ( 2 o z / g a l l o n ) Heavy D u t y - 3 . 0 % bw ( 4 o z / g a l l o n )
w"o t/
67.0 8.0 5.0 10.0 5.0
5.0
* ** ***
****
Rhone-Poulenc Rhone-Poulenc Rhone-Poulenc Rhone-Poulenc
C o l l o i d 226/35 P o l y a c r y l a t e (40%) Rhodafac R E - 6 1 0 R h o d a s u r f 91-6 R h o d a s u r f A-24
Metal De-Oiling L i q u i d Concentrate ( L i quid ) Soi 1 - P e t r o l e u m - b a s e d o i 1 S u r f a c e - M e t a l : S t e e l , c o p p e r , aluminum, e t c . Appl i c a t i o n Method-Spray a n d / o r immersi on Manufacture: Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Water S t a r s o Sodi urn S i 1 i c a t e EDTA, T e t r a s o d i u m (37%) Sodium X y l e n e S u l f o n a t e (40%) * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11 Use D i l u t i o n : 2%-4% b v
W B
6 M o l e s EO) 2 . 5 M o l e s EO)
42.0 12.0 16.0 20.0 3.0 7.0
**
Rhone-Poulenc R h o d a s u r f 91-6 Rhone-Poulenc R h o d a s u r f A-24
SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t on G u i d e
aegreasers
23
S o l v e n t Denreaser Carbopol r e s i n s a r e used t o e m u l s i f y and s t a b i l i z e t h i s d-limonene o i l based e m u l s i o n . I n a d d i t i o n , t h e use o f t h e r e s i n provides v e r t i c a l c l i n g t o increase the contact time o f t h e d e t e r g e n t on t h e s o i l e d s u r f a c e and enhance consumer convenience. I n q r e d ient : D I Water Carbopol ETD 2623 ( 1 ) d-Limonene ( 2 ) Propylene g l y c o l methyl e t h e r ( 3 ) Alkylbenzene s u l f o n i c a c i d ( 4 ) C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO ( 5 ) Isopropanol Sodium h y d r o x i d e (50%) B r o o k f ie l d v i s c o s i t y (RVT-20 P r o d u c t pH: 9 . 5 - 1 0 P r o d u c t C1 a r i t y : Opaque
(1)
9
81.18 0.32 10.00 2.00 2.00 1.50 2.50 0.50
rpm) : 750 cps
(2) (3) (4) (5)
BFGoodrich A r y l e s s e n c e , I n c . : H-7892 d-limonene Dow Chemical : Dowanol PM Stepan C o . : B i o s o f t S-100 S h e l l Chemical: Neodol 23-6.5
Procedure:
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Add t h e d-limonene w i t h good a g i t a t i o n and mix u n t i l homogeneous. 3 . Reduce a g i t a t i o n and add t h e g l y c o l e t h e r , s u l f o n i c a c i d , and alcohol ethoxyl ate. 4 . Add t h e i s o p r o p a n o l 5 . Add t h e sodium h y d r o x i d e u n t i l t h e t a r g e t pH r a n g e i s reached. 6 . Add c o l o r , as d e s i r e d .
T o t a l Actives: d-limonene: Propylene g l y c o l methyl e t h e r : Sodium a1 k y l b e n z e n e s u l f o n a t e : Psopropanol : C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO: SOURCE: BFGoodrich S p e c i a l t y Chemicals:
10.0 2.0 2.2 1.5 2.5
DET-330
24
S o l v e n t Based Deqreaser Insredients: Kerosene Aristonate M Pine O i l T a l l O i l F a t t y Acid C a l o x y l a t e N-9 Hexyl ene G1 y c o l Comments a b o u t t h i s f o r m u l a : 1 . Use a l o w o d o r g r a d e o f t a l l o i l f a t t y a c i d . 2 . Add i n g r e d i e n t s i n t h e o r d e r i n d i c a t e d . 3. A r i s t o n a t e L can be s u b s t i t u t e d f o r A r i s t o n a t e M~ F o r m u l a t i o n DEG-004-01 S o l v e n t Based Degreaser Ingredients: Aristonate M T r i t o n X-45 T r i t o n N-101 Kerosene Comments a b o u t t h i s f o r m u l a : 1 . Kerosene can be s u b s t i t u t e d w i t h A r o m a t i c Naphtha. 2 . A r i s t o n a t e M can be s u b s t i t u t e d w i t h A r i s t o n a t e L . F o r m u l a t i o n DEG-003-01 E n q i n e C l e a n e r and Deqreaser Ingredients: Water M I PA C a l imu1s e PRS Dowanol DPM Na4EDTA Comments a b o u t t h i s f o r m u l a : Clear, p a l e y e l l o w product F o r m u l a t i o n DEG-005-01 SOURCE: P i 1o t Chemi c a l Co. : Suggested Formul a t ions Weight% 58.94 20.33 5.08 45.24 0.41 W ig h t % e 5.10 5.00 2.99 86.93 Wei ghP% 72.85 3.00 10.00 10.06 3.02 1.06
lshwashing Detergents
25
26
A u t o m a t i c Dishwash Deteraent-Consumer ( Z e r o Phosohate. C h l o r i n e F r e e . Powder1 S o i l - F o o d g r e a s e , o i l and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manufacture-Dry Blend/Agglomeration Composi t i on : Sodi urn C i t r a t e D i h y d r a t e * B r i t e s i l H20 Hydrous P o l y s i l i c a t e Sodi urn C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) * * * A c u s o l 445ND S o d i um P o l y a c r y l a t e ( 9 2 % sol id s ) ****Sodium P e r b o r a t e Monohydrate V a l f o r 100 Z e o l i t e A Sodium S u l f a t e 10.0 20.0 23.0 3.0 4.0 10.0 15.0 15.0
* **
*** ****
2 . 0 w e i g h t r a t i o powder w i t h 1 7 . 5 % w a t e r Rhone-Poulenc A n t a r o x BL-330 Rohm & Haas; o r use a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l 479ND ( 2 w t . % each) O r use Sodium D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e ) a t 2 w t % . Balance w i t h s u l f a t e .
A u t o m a t i c Dishwash Detersent-Consumer (Phosphate, C h l o r i n e F r e e , Powder)
S o i 1-Food g r e a s e , o i 1 and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manufacture-Dry blend/Agglomeration Composi t i on : RU L i q u i d Sodium S i l i c a t e *Sodium C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) * * * A c u s o l 445ND Sodi um P o l y a c r y l a t e (92% s o l id s ) ****Sodium P e r b o r a t e M o n o h y d r a t e *STPP Sodi um S u l f a t e 15.0 23.0 3.0 4.0 10.0 30.0 15.0
* ** *** ****
FMC Rhone-Poulenc A n t a r o x BL-330 Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l 479ND ( 2 w t . % each) O r u s e Sodi u m D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e ) a t 2 w t %. B a l a n c e w i t h s u l f a t e . Detergent F o r m u l a t i o n Guide
SOURCE: PO C o r p . :
Dishwashing Detergents
27
A u t o m a t i c Dishwash D e t e r c i e n t - I n d u s t r i a l & I n s t i t u t i o n a l (Phosphate, S o l i d B l o c k ) S o i l - F o o d g r e a s e , o i l and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manufacture-Solid block Composi t i on : M e t s o Beads 2048 NaOH (50% S o l u t i o n ) *STPP *Sodi um C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9
Wt%
25.0 25.0 35.0 12.0 M o l e s EO; C12-15)
3.0
* **
FMC Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 A u t o m a t i c D i shwashi n g D e t e r g e n t - I n d u s t r i a1 & I n s t i t u t i o n a l (L iquid) S o i l - F o o d g r e a s e , o i l and p r o t e i n S u r f a c e - M e t a l , c e r a m i c and g l a s s A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition : Water * A c r y s o l ASE 108 ( A c r y l i c P o l y m e r ) * * T r i t o n DF-16 ( N o n i o n i c S u r f a c t a n t ) P o t a s s i um H y d r o x i d e (45%) TKPP (60%) N C l e a r Sodium S i l i c a t e
Wt%
50.9 6.9 3.0 1.2 25.0 13.0 oz/gallon)
Use D i l u t i o n : 0 . 1 5 - 0 . 3 0 % bw ( 0 . 2 - 0 . 4
* **
Rohm & Haas; Rohm & Haas;
o r Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e ( 4 0 % ) o r Rhone-Poulenc A n t a r o x EL-330 Detergent F o r m u l a t i o n Guide
28
Advarrced Clearring Product Formulatiorls
A u t o m a t i c D i s h w a s h D e t e r g e n t T I n d u s t r i a l - &- I n s t i ~ ! . ! t i g n ~ j (Zero-Phosphate, C h l o r i n e F r e e , Powde_rj S o i l - F o o d g r e a s e , oil and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manuf a c t u r e - D r y B1 e n d / A g g l o m e r a t i on Composi t io n : M e t s o P e n t a b e a d 20 Sod1 um C a r b o n a t e * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 M o l e s 0 ; C12-15) * * A c u s o l 445ND Sodium P o l y a c r y l a t e ( 9 2 % s o l i d s ) ***Sodium P e r b o r a t e M o n o h y d r a t e B l e a c h Val f o r 100 Z e o l i t e A Sodium S u l f a t e
Wt%
30.0 26.0
3.0
4.0 10.0 15.0
12.0
* ** ***
Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l C h e m i c a l Neodol 25-7 Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l 479ND ( 2 w t % e a c h ) . O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e ) a t 2 w t % . Balance w i t h s u l f a t e .
A u t o m . a t i c P ~ h w a ~ h _ D e t e ~ e _ n ~ . ~ I ~.d - u Stri-a 1 _&-Ins t_ii-tluti_ o?e_a_8 LP h o s p h a t e _ , C h l _ o r i n e _Free- Pow_s1ec)

S o i l - F o o d g r e a s e , o i l and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manufacture-Dry Blend/Agglomeration Composition: G t s o P e n t a b e a d 20 *STPP * S o d i um C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 M o l e s EO; C12-15) * * * A c u s o l 445ND S o d i um P o l y a c r y l a t e ( 9 2 % sol i d s ) ****Sodium P e r b o r a t e Monohydrate B l e a c h
Wt%
30.0 25.0 28.0 3.0 4.0 10.0
* **
*** ****
FMC Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l C h e m i c a l Neodol 2 5 - 7 Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l 479ND ( 2 w t % e a c h ) O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e ) a t 2 w t % . Balance w i t h s u l f a t e . Detergent F o r m u l a t i o n Guide
SOURCE: PP C o r p . :
29
A u t o m a t i c D i s h w a s h i ng Gel w i tJ1_..Chlori n e B1 e a c h Carbopol r e s i n s a r e used t o t h i c k e n t h e p r o d u c t t o reduce s p l a s h i n g , p r o v i d e c u p r e t e n t i o n i n t h e d i s h w a s h e r , and c r e a t e a s t a b l e suspension o f i n s o l u b l e s ( i . e . phosphate b u i l d e r s ) i n t h i s AOL f o r m u l a t i o n c o n t a i n i n g c h l o r i n e b l e a c h . Inqredient: 01 w a t e r C a r b o p o l 672 ( 1 ) P o t a s s i um h y d r o x i d e ( 4 5 % ) 2 . l r p o t a s s i u m s i l i c a t e (39%) ( 2 ) P o t a s s i urn c a r b o n a t e ( 3 ) Sodium t r i p o l y p h o s p h a t e ( 4 ) S o d i um h y p o c h l o r i t e ( 1 2 . 5 C 0 h ) Sodium n - d e c y l d i p h e n y l o x i d e d i s u l f o n a t e ( 4 5 % ) ( 5 ) B r o o k f i e l d v i s c o s i t y (RVT-20 P r o d u c t p H : 12-13 P r o d u c t c l a r i t y : Opaque (1 BFGoodri c h ( 2 The P C o r p . O ( 3 Armand (4 FMC C o r p . ( 5 ) O o w C h e m i c a l : Dowfax 382 Procedure: 1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l 1e r s u i t a b 1 e f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s . Screen t h e Carbopol r e s i n i n t . 0 t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r ( 8 0 0 r p m ) . A l l o w t o m i x u n t i l homogeneous and f r e e o f p o l y m e r l u m p s . 2 . Add i n t h e p o t a s s i u m h y d r o x i d e a n d p o t a s s i u m s i l i c a t e . M i x u n t i l homogeneous. The p r o d u c t w i l l become v e r y t h i c k a t t h i s poi n-t. 3 . Add t h e p o t a s s i u m c a r b o n a t e and p h o s p h a t e . M i x u n t i l t h e r e a r e no more p h o s p h a t e p a r t i c l e s . H e a t i n g t o 50-60C w i l l speed t h i s p r o c e s s . 4 . Add t h e b l e a c h and t h e n t h e s u r f a c t a n t . M i x u n t i l homogeneous. A d j u s t t h e pH t o 12-13 u s i n g KOH. 00 n o t u s e a c i d t o r e d u c e t h e pH, e s p e c i a l l y a f t e r t h e a d d i t i o n o f t h e b l e a c h . 5 . Add c o l o r and f r a g r a n c e , a s d e s i r e d . Cool t h e p r o d u c t t o b e l o w 30C t o a v o i d e x c e s s i v e b l e a c h d e c o m p o s i t i o n . rpm): 15,000 cps
Wt% 44.75 1.25 5.00 15.00 5.00 20.00 8.00 1.oo
Total Actives: Phosphorous c o n t e n t : S i l i c a t e (as Si02): C a r b o n a t e ( a s Na2CO3): Ava i 1a b 1e c ti 1o r ine :

SOURCE:
5.0 3.9 3.8 1.o
BFGoodrich S p e c i a l t y C h e m i c a l s : DET-100
30
Clear, Insredients: Water, D . I. W i t c o l a t e ES-3 R e w o t e r i c AM 8-14 Ethanol Sodium C h l o r i d e
C o l o r l e s s Manual - D i s h Wash
Wt%
57.5 34.2
5.0
3.0 3.3
B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . D i s s o l v e c o m p l e t e l y between each a d d i t i o n . Comment: R e w o t e r i c AM 8-14: Formula 1 3 2 Grease c u t t e r and foam b o o s t e r .
Powder S t a i n l e s s S i l v e r w a r e Pre-Soak I n q r e d ie n t s : Sodium Carbonate (Soda Ash) P e t r o BAF Powder DeSonic 1 1 N T r i sodi u m Phosphate, Anhydrous C a u s t i c Soda Beads 61 e n d i ng P r o c e d u r e : Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d Use D i 1u t u i on : 1 o z / g a l Formula 1 2 7 Low A1 k a l ine Warewashi nq Block I n q r e d ie n t s : Water, D . I . R.U. S i l i c a t e DeSoni c LFD-97 Sodium Carbonate (Soda Ash) Sodium T r i p o l y p h o s p h a t e Code 185 B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . When s l u r r y i s produced, p o u r i n t o molds and a l l o w t o harden. Formula 1 2 9
W B 16.0 29.0 2.0 23.0 30.0
Wt%
67.0 5.0 11 . o 2.0 25.0
31
Dish Washi nq Agents clear, liquid, 25% W A S alkanesulphonate:ethersulphate=4:l

Ingredi e m A : H o s t a p u r SAS 6 0 Genapol Z R O l i q u i d B: Water Preservative DY e Perfume Tests: v i s c o s i t y (rnPas) : 75 C l o u d p o i n t : <-5C
Wto/,
33.30 17.90
48.50 0.10 q.s. 0.20
Inqredients: A : H o s t a p u r SAS 60 Genapol ZRO l i q u i d B: Water P r e s e r v a t iv e DYe Perfume Genagen LAB Tests: V i s c o s i t y (mPas): Cloud p o i n t : <-5C Inqredients: A : H o s t a p u r SAS 60 Genapol ZRO l i q u i d
B: Water Preservative DY e Perfume Genagen LAB
33.30 17.90
47.50 0.10 q.s. 0.20 1 .oo
100
33.30 17.90
44.50
0.10
9,s. 0.20 4.00
Tests: V i s c o s i t y (mPas): 2 3 0 C l o u d p o i n t : <-5c Manufacturing: One a f t e r a n o t h e r , SOURCE: t h e components o f B a r e added t o A Suggested F o r m u l a t i o n s
Hoechst A k t i e n g e s e l l s c h a f t :
32
D i s h Washi nq A g e n t s
C l e a r , liquid, 30% WAS

a1 k a n e s u l p h o n a t e : e t h e r s u l p h a t e = 4 : 1 Insredients: A : H o s t a p u r SAS 60 Genapol Z R O l i q u i d
3:
40.00 21 . 4 0 37.30 0.10 q.s. 0.20

1.oo
Water Preservative DY e Perfume Genagen LAB
Tests: V i s c o s i t y (mPas) : 380 C l o u d p o i n t : <-5C Inqredients: A : H o s t a p u r SAS 60 Genapol Z R O l i q u i d
wtsl,
40.00
21.40
0 : Water Preservative DY e Perfume Hoe S 3924

Tests: V i s c o s i t y (mPas) : 420 C l o u d p o i n t : <-5C Ingredients: A : H o s t a p u r SAS 60 Genapol Z R O l i q u i d
El:
37.30 0.10
q.s.
0.20 1 .oo
wt./, 40.00 21.40

34.30 0.10 q.s. 0.20 4.00
Water P r e s e r v a t iv e DY e Perfume Hoe S 3924
Tests: V i s c o s i t y (mPas) : 61 0 C l o u d p o i n t : <-5C Manufacturing: One a f t e r a n o t h e r , t h e components o f 8 a r e added t o A . Suggested F o r m u l a t i o n s
SOURCE:
Hoechst A k t i e n g e s e l l s c h a f t :
33
D i s h Wash w/Am&e lngredients: Water, D . I . W i t c o n a t e 1240 Varox 1770 W i t c o l a t e SE-5
Oxide/LABS/SLES
Wtl
66.3 10.3 5.3 18.1
81 e n d i ng P r o c e d u r e : Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Add e t h a n o l as needed t o l o w e r v i s c o s i t y . Typical Properties: V i s c o s i t y , c p s : 620 S o l i d s : 16.8% pH: 9 . 1 2 F o r m u l a 117
D i s h Wash w / A m i n e Oxi de/LABS/ALES

I n g r e d i e n t s1 Water, D . I . W i t c o n a t e 1240 Varox 1770 W i t c o l a t e LES-6OA Ethanol 70.0 13.8 3.1 8.2 5.0
B1 end? ng P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . A c i d i f y w i t h C i t r i c A c i d t o pH=6.5. Typical Properties: V i s c o s i t y , cps: 4 S o l i d s : 10.1% pH: 6 . 6 8 F o r m u l a 118
__ Hand Di shwashi ng L i sui d

Ingredients: Water W i t c o n a t e AOS W i t c a m i de 128T W i t c o l a t e LES-6OC Blendjng Instructions: Add a l l i n g r e d i e n t s i n t h e o r d e r l i s t e d , a d d i t i ons . F o r m u l a 106
K %
60.0 26.0
4.0 10.0
m i x i n g w e l l between
SOURCE:
Witco Corp.:
34
Foam B o o s t e r :
Ez-4-5
in Hand D i shwashi na L i q u i d s
L i q u i d d i s h f o r m u l a t o r s a r e challenged t o produce low c o s t q u a l i t y p r o d u c t s . Hand d i s h d e t e r g e n t s a r e e x p e c t e d t o foam i n t h e p r e s e n c e o f f o o d s o i l s , c u t g r e a s e and c l e a n . I n a d d i t i o n , a e s t h e t i c s , s k i n m i l d n e s s , and e n v i r o n m e n t a l i m p a c t a r e a l s o m a j o r p r o d u c t c o n s i d e r a t i o n s . The f o l l o w i n g d a t a i l l u s t r a t e d how E-14-5 can b e used t o f o r m u l a t e c o s t e f f e c t i v e p r o d u c t s s u i t a b l e f o r t h e v a r i o u s l i q u i d d i s h soap m a r k e t segments. O p t i m i z e d l i q u i d d i s h d e t e r g e n t s c o n t a i n i n g E-14-5 p r o v i d e t h e optimum i n c o s t p e r f o r m a n c e when compared t o a l l o t h e r t y p e s o f foam b o o s t e r s . A l t h o u g h i t p e r f o r m s w e l l a l o n e , E-14-5 s y n e r g i s t i c a l l y enhances t h e p e r f o r m a n c e o f most t r a d i t i o n a l foam b o o s t e r s a s i l l u s t r a t e d b e l o w w i t h Coco d i e t h a n o l a m i d e . Economy Eormul a t i on
I gredi ent s : n Deionized water Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) Ethyl alcohol Tomah E-14-5 Coco d i e t h a n o l ami de
W. t%
59.7 2 5 . 9 ( 15) 8.4(5)
0
3 3
Standard Formulation
I gredi e n m Deionized water Dodecylbenzene s u l f o n a t e , sodium s a l t , ( 6 0 % s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (60% s o l i d s ) Ethyl alcohol Tomah E-14-5 Coco d i e t h a n o l ami de
90% Premi u m Formul a t ion Inqredi ents: Deionized water Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) L a u r y i a l c o h o e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) Ethyl alcohol Tomah E-14-5 Coco d i e t h a n o ami de
wt>
52.9 31 . 0 ( 1 8 ) 10. l ( 6 ) 1.5 3 3
Wt.%
38.6 38.8(22.5) 12.6(7.5) 4
_ Premi urn _ o r _ u l a t i o n _ F m ~ -
I n q r e d i en& Deionized water Dodecyl benzene s u l f o n a t e , s o d i um s a l t , (60% s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (6O0h s o l i d s ) Ethyl alcohol Tomah E-14-5 Coco d i e t h a n o l ami de SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
Wt.%
28.3 46.6( 27) 15.1 (9) 4 3 3
35
Hand D i s h D e t e r a e n t F o r m u l a t i o n s C l e a r D i shwash
IngredienPs 1
\N t %
12.30 8.00 52.50 18.20 6.00
Water SXS (4O%j C12 A i f a O i e f in s u i f o n a t e ( 2 8 . 7 5 % s o i i d s j Lauryl e t h e r s u l f a t e - 3E0 (27.5% s o l i d s ) Tomah AO-728 S p e c i a l NaCl*
3.00
M i x i ng I n s t r u c t i o n s : Add t h e i n g r e d i e n t s i n t h i s o r d e r . M i x u n t i l homogeneous a f t e r each a d d i t i o n

SpG 2 0 / 2 0 C : 1 . 0 5 pH: 6 V i s c o s i t y : 505 c p s ( B r o o k f i e i d LVT 3 0 rpm s p i n d l e number 2)
NOTES:
*Add more N a c l t o i n c r e a s e v i s c o s i t y .
__ P e a r i e s c e n t U i shwash
ingredients: Water Dodecyibenzene s u i f o n a t e ( 6 0 % s o l i d s ) C a u r y i e t h e r s u l f a t e - 4 E 0 (60% s o i i d s j O p a c i f i e r L a t e x (4OWja P e a r l i z i n g Agent ( 4 7 % j * * Tomah A0-728 S p e c i a i Tomah A m p h o t e r i c L Mixing Instructions: Add t h e i n g r e d i e n t s i n t h i s o r d e r . M i x u n t i i homogeneous a f t e r each a d d i t i o n . SpG 2 0 / 2 0 C : 1 . 0 3 6.5 V i s c o s i t y : 1363 c p s ( B r o o k f i e l d LVT,
PH:
WLL7O
54.40 25.00 8 . 30 0.04 2.30 4.00 6.00
12 rpm,
s p i n d l e number
NOTES:
* **
L y t r o n 295 Mortor! i n t e r n a t i o n a l E u p e r i a n PK-771, Henkei Suggested F o r m u l a t i o n s
SOURCE: Tomah P r o d u c t s , f n c . :
36
Hand D i s h w a s h i n g L i q u i d C a r b o p o l r e s i n s c a n be used t o b u i l d r h e o l o g y i n p l a c e o f u s i n g h i g h e r s u r f a c t a n t l e v e l s . T h i s w i l l improve t h e s k i n f e e l and m i l d n e s s . A d d i t i o n a l l y , because o f t h e i r h i g h y i e l d v a l u e , t h e use o f Carbopol r e s i n s w i l l i n c r e a s e foam s t a b i l i t y . Inqredient: D I Water Carbopol ETD 2623 ( 1 ) 5 8 0 0 MW p o l y a c r y l i c a c i d ( 2 ) A l p h a s u l f o m e t h y l e s t e r (37%) ( 3 ) TEA (99%) Sodium l a u r y l e t h e r s u l f a t e (28%) ( 4 ) Coconut d i e t h a n o l ami de ( 5 ) B r o o k f i e l d v i s c o s i t y (RVT-20 P r o d u c t pH: 6 . 0 - 7 . 0 Product c l a r i t y : Clear rpm): 400-600 cps Q 38.11 0.70 4.00 27.03 5.50 17.86 2.00
( 1 ) BFGoodrich ( 2 ) BFGoodrich: Good-Rite K-7058 ( 3 ) Stepan Co.: A l p h a s t e p ML-40 ( 4 ) Henkel C o r p . : S t a n d a p o l ES-3 ( 5 ) Stepan C o . : N i n o l 11-CM Procedure: 1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s P r e h e a t t h e w a t e r t o 40-5OC. Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 r p m ) . A l l o w t o m i x f o r a t l e a s t 15 m i n u t e s o r u n t i l homogeneous and f r e e o f p o l y m e r lumps. 2 . Add i n t h e l o w m o l e c u l a r w e i g h t p o l y a c r y l a t e w i t h c o n s t a n t mixing. 3 . Add i n t h e ASME s u r f a c t a n t w i t h a l o w l e v e l o f a g i t a t i o n t o a v o i d e x c e s s i v e foam g e n e r a t i o n . 4 . Add i n t h e TEA, l a u r y l e t h e r s u l f a t e , and c o c o n u t DEA. 5 . A d j u s t t h e pH u s i n g TEA t o r e a c h t h e t a r g e t r a n g e . Add c o l o r and p e r f u m e , a s d e s i r e d . Cool b a t c h t o room t e m p e r a t u r e . Total Actives: Alpha s u l f o methyl e s t e r : Sodium l a u r y l e t h e r s u l f a t e : Coconut d i e t h a n o l a m i d e : 5 8 0 0 MW p o l y a c r y l i c a c i d : 10.00 5.00 2.00 2.00
SOURCE:
BFGoodrich S p e c i a l t y C h e m i c a l s :
DET-I10
37
Hand Dishwashina P a s t e Carbopol r e s i n s a r e used t o t h i c k e n and suspend i n s o l u b l e s i n t h i s hand d i s h w a s h i n g p a s t e . A d d i t i o n a l l y , because o f t h e i r h i g h y i e l d v a l u e , t h e use o f Carbopol r e s i n s w i l l i n c r e a s e t h e foam s t a b i 1it y . I n a r e d ient :
D I water
Wt%
41.50 1 .oo 17.00 5.00 7.50 15.00 5.00 8.00
Carbopol 672 ( 1 ) A l k y l b e n z e n e s u l f o n i c a c i d (9796) ( 2 ) Sodi u h y d r o x i d e (50%) m 2 . 4 r sodium s i l i c a t e (52%) ( 3 ) Sodium t r i p o l y p h o s p h a t e ( 4 ) Sodium c a r b o n a t e Sodium o l e f i n s u l f o n a t e (40%) (5) B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 75,000 cps P r o d u c t pH: 10-11 P r o d u c t c l a r i t y : Opaque
( 1) (2) (3) (4)
BFGoodri ch Stepan Co.: B i o s o f t S-100 The PO Corp. F C Corp. M ( 5 ) Stepan Go.: E i o t e r g e AS-40
Procedure: 1 . Use a L i g h t n i n M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t o n s . Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 r p m ) . A l l o w t o m i x u n t i l homogeneou and f r e e o f polymer lumps. 2 . Add t h e s u l f o n i c a c i d w i t h c o n t i n u o u s a a i t a t i o n . 3 . Add t h e sodium h y d r o x i d e and sodium s i l i c a t e w i t h c o n t i n u o u s a g i t a t i on. M i x u n t i1 homogeneous. 4 . S l o w l y , add t h e phosphate. M i x u n t i l homogeneous and f r e e o f phosphate p a r t i c l e s . H e a t i n g t h e p r o d u c t t o 50-60C w i l l speed up t h i s p r o c e s s . 5 . Add t h e sodium c a r b o n a t e and o l e f i n s u l f o n a t e . M i x u n t i l homogeneous. 6 . A d d c o l o r and f r a g r a n c e , as d e s i r e d .
T o t a l A c t ives : Phosphorous c o n t e n t : S i l i c a t e (as Si02): Carbonate ( a s Na2C03): Sodium o l e f i n s u l f o n a t e : Sodium a l k y l b e n z e n e s u l f o n a t e :

SOURCE:
3.7 2.7 5.0 3.2 17.6
DET-111
38
L i g h t Duty Liquid, Ingredients: Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y W i t c a m i de 128T P e t r o LBA L i q u i d Sodium S u l f a t e Ethanol Formal i n P e r f u m e , Dye
Premium Hand D i s h w a s h
Wt%
30.2 21.7 36.7 5.0 1.9 2.6 1.8 0.1 9,s.
81 e n d i n g P r o c e d u r e : B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t pH t o 6 . 5 - 7 . 0 using C i t r i c Acid. Typical Properties: V i s c o s i t y , c p s : 230 A p p e a r a n c e : C1 e a r L i q u i d F o r m u l a 113
L i g h t D u t y L i q u i d Low C o s t Hand D i s h w a s h Ingredients:. W a t e r , D . I. W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y W i t c a m i d e 128T P e t r o LBA L i q u i d Sodium C h l o r i d e Formal i n Perfume, Dye
81 . 5
5.5
9.2 1.2 0.5 2.0 0.1 q.s.
Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . A d j u s t pH=6.5-7.0 using C i t r i c Acid. Typical Properties: V i s c o s i t y , c p s : 170 Appearance: C l e a r L i q u i d Formula 116
SOURCE:
Witco Corp.:
39
Liquid Automatic Dishwasher Deterqent T h i s f o r m u l a t i o n f e a t u r e s Van Gel ES, magnesium aluminum s i l i c a t e , as a s u s p e n d i n g a g e n t and r h e o l o g y m o d i f i e r . The sodium h y p o c h l o r i t e f u n c t i o n s as a d i s i n f e c t a n t , c l e a n i n g a g e n t and b l e a c h . Sodium m e t a s i l i c a t e a d j u s t s t h e f o r m u l a p H . The p h o s p h a t e b l e n d p r o v i d e s d e t e r g e n c y and t h e s u r f a c t a n t s contribute excellent r i n s a b i l i t y . Inqredi ents: A : Van Gel ES D e i o n i z e d Water
B : T e t r a p o t a s s i u m P y r o p h o s p h a t e , t e c h n i c a l powder Sodi um T r i p o l y p h o s p h a t e , t e c h n i c a l powder
Wt%
4.00 53.00 10.00 20.00 2.00 8.00 2.25 0.75
C:
Sodium M e t a a s i l i c a t e . Anhydrous Sodium H y p o c h l o r i t e , 1 2 . 5 % s o l n . Sodium X y l e n e s u l f o n a t e Deceth-4-Phosphate
D:
Procedure: P r e h e a t t h e w a t e r t o 5 5 t o 60C. H y d r a t e t h e Van Gel ES s l o w l y b y a d d i n g i t t o t h e a v a i l a b l e w a t e r u s i n g a h i g h speed d i s p e r s e r . Preblend B i n g r e d i e n t s , Add B t o A s l o w l y w i t h m i x i n g . M i x u n t i l u n i f o r m . Add C i n g r e d i e n t s i n t h e o r d e r l i s t e d , mixing u n t i l dissolved. Continue mixing w h i l e c o o l i n g r a p i d l y t o 25C. F i n a l l y , combine D i n g r e d i e n t s and add w h i l e m i x i n g s l o w l y u n t i l smooth and u n i f o r m ( a v o i d i n c o r p o r a t i o n of air). C o n s i s t e n c y and pH: Pumpable l i q u i d , V i s c o s i t y 1300-1800 c p s , B r o o k f i e l d Model LVT, S p i n d l e 4 a t 60 rpm measured a t room t e m p e r a t u r e a f t e r 3 0 days a g i n g ; pH a p p r o x i m a t e l y 1 2 . 5 . Suggested P a c k a g i n g : Squeeze b o t t l e o r pump.
SOURCE:
R.T.
Inc.:
F o r m u l a t i o n No. 438
40
Manual D i shwashi n q G e l F u n c t i o n s & B e n e f i t s : C a r b o p o l EX-473: * v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, independent o f surfactant type *provides high c l a r i t y across s u r f a c t a n t l e v e l * i m p a r t s y i e l d v a l u e f o r s u s p e n s i o n o f , f o r i n s t a n c e , encapsulated actives * a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems *easy-to-use, odorless, l i q u i d form i n i r e d l ent :
Wt%
DI w a t e r
C a r b o p o l EX-473 ( 3 0 % ) * Sodium c i t r a t e Sodium h y d r o x i d e ( 1 8 % ) Ammonium l a u r y l s u l f a t e (30%)** Sodium l a u r y l e t h e r s u l f a t e (30%)*** * V i s c o s i t y modi f i e r : B F G o o d r i c h * * A n i o n i c s u r f a c t a n t : Standapol A : Stepan Chemical * * * A n i o n i c s u r f a c t a n t : S t a n d a p o l ES-3: S t e p a n C h e m i c a l P h y s i c a l P r o p e r t i es : B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 8 , 0 0 0 C P P r o d u c t pH: 6 . 5 - 7 . 0 Product c l a r i t y : c l e a r
37.50
10.00 0.50 2.00 25.00 25.00
Procedure: 1 . U s i n g s l o w a g i t a t i o n ( 2 0 0 rpm) p r o v i d e d b y a L i g h - t n i n ' m i x e r o r s i m i l a r v a r i a b l e speed u n - i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i ng o p e r a t i o n s , add t h e C a r b o p o l EX-473 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m a n d homogeneous. 2 . Add t h e sodium c i t r a t e . M i x u n t i l t h e sodium c i t r a t e i s completely dissolved. 3 . A d j u s t t h e pH w i t h sodium h y d r o x i d e t o d e s i r e d pH. 4. Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n . 5 . Check pH, r e a d j u s t w i t h a d d i t i o n a l s o d i u m h y d r o x i d e i f necessary. 6 . Add f r a g r a n c e and c o l o r , a s d e s i r e d .
SOURCE:
DET-130
41
_ _ D i shwashi nq L i q u i d Manual
F u n c t i o n s B B e n e f i t s : Carbopol EX-473: * v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, i n d e p e n d e n t o f surfactant type *provides h i g h c l a r i t y across s u r f a c t a n t l e v e l * i m p a r t s y i e l d v a l u e f o r s u s p e n s i o n o f , f o r i n s t a n c e , encapsulated actives * a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems *easy-to-use, odorless, l i q u i d form
I n g r e d i en t .
DI w a t e r
Carbopol EX-473 ( 3 0 % ) Ammonium l a u r y l s u l f a t e (30%)* Sodium l a u r y l e t h e r s u l f a t e ( 3 0 % ) * + Sodium c i t r a t e Sodium h y d r o x i d e (18%) * A n i o n i c s u r f a c t a n t : S t a r i d a p o l A : Stepari Chemical * * A n i o n i c s u r f a c t a n t : S t a n d a p o l ES-3: Stepan Chemical Physical Properties: B r o o k f i e l d R V T v i s c o s i t y - 2 0 rpm: 5 0 0 CP Product pH: 6.5-7.0 Product c l a r i t y : Clear
yt%
43.00 5.50 25.00 25.00 0.50 I .oo
Procedure: 1 . Using slow a g i t a t i o n (200 r p m ) provided by a L i g h t n i n ' Mixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , add t h e C a r b o p o l E X - 4 7 3 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m and homogeneous. 2 . Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n . 3 . Add t h e sodium c i t r a t e , M i x u n t i l t h e sodium c i t i - a t e i s completely dissolved. 4 . A d j u s t t h e p H w i t h sodium h y d r o x i d e . 5 . Add f r a g r a n c e and c o l o r , a s d e s i r e d .
SOURCE:
BFGoodrich S p e c i a l t y C h e m i c a l s :
DET-120
42
N o n - C h l o r i n a t e d M a c h i n e D i s h w a s h i n q Compound, I n Q r e d ie n t s : Water, D . I . Sodi um T r i p o l y p h o s p h a t e Versene 2 2 0 , Powder Sodi um G1 u c o n a t e Sodium M e t a s i l i c a t e , P e n t a h y d r a t e C a u s t i c Soda 50% P e t r o ULF L i q u i d 81 e n d i ng P r o c e d u r e : Add a l l components i n t h e o r d e r shown, a d d i t i ons F o r m u l a 109
Liquid
\Mt%
79.5 2.0
1.o 7.0
.o
8.5
1 .o
m i x i n g w e l l between
C h l o r i n a t e d M a c h i n e D i shwashi n q Compound, Ingredients: Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y Sodi um T r i p o l y p h o s p h a t e (STPP) , L i g h t D e n s i t y DeSoni c LFD-97 Sodium M e t a s i l i c a t e , Anhydrous C a u s t i c Soda Beads CDB C l e a r o n
Powder
30.0
25.0 1. o
30.0 10.0 4.0
Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d , mixing thoroughly w i t h each a d d i t i o n . F o r m u l a 111 N o n - C h l o r i n a t e d M a c h i n e D i shwashi n g Compound. Inqredi ents: Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y Sodium T r i p o l y p h o s p h a t e (STPP), L i g h t D e n s i t y DeSoni c LFD-97 Sodium M e t a s i l i c a t e , Anhydrous C a u s t i c Soda Beads Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d , w i t h each a d d i t i o n . F o r m u l a 112 Powder
Wt% 33.0
25.0 2.0 30.0 10.0
mixing thoroughly
43
P r e m i um Hand D i shwashi ng D e t e r q e n t
Inqredients: Water, D . I . A1 p h a - S t e p MC-48 S t e o l CS-330 N i n o l 30-LL o r N i n o l 40-CO Sodium C h l o r i d e P r o p e r t i es : Appearance: C l e a r y e l l o w l i q u i d pH, as i s : 6 . 5 - 7 . 5 V i s c o s i t y @ 25 deg. C , c p s : 220 S o l i d s , % : 39-40 Density, l b s / g a l : 8 . 8 Freeze/thaw, 3 c y c l e s : Pass C o l d s t o r a g e @ 4 deg. C . , 2 weeks: F l a s h p o i n t , deg. F: >200
Wt%
6.9 56.0 30.0 5.6 1.5
Pass
M i x i n g Procedure: CHarge w a t e r . Add MC-48 and CS-330 and m i x . Add 30-LL o r 40-CO and m i x u n t i l homogeneous. S l o w l y add sodium c h l o r i d e t o t h i c k e n . M i x u n t i l c l e a r . A d j u s t p H w i t h s u l f u r i c a c i d o r sodium h y d r o x i d e as n e c e s s a r y .
Comment :
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .
SOURCE:
Stepan C o . :
F o r m u l a t i o n No. 173
D i s h Washina A q e n t s f o r Manual Use
Inqredi ents: Water Lumorol 4154 Z e t e s o l NL Z u s o l a t 1008/85 Sodium c h l o r i d e F o r m u l a t i o n CT 02-01-04 m e d ien t s : Water Z e t e s o l 2056 Amphotensid B 4 Z u s o l a t 1008/85 P u r t o n CFD F o r m u l a t i o n CT-02-01-05
79.0 12.0 6.0 1.o approx. 2 . 0
Wt%
76.5 20.0 2.0 1.o 0.5 Suggested F o r m u l a t i o n s
SOURCE:
5 General Purpose .
44
General Purpose Cleaners
45
Abrasive Cleaner w i t h Bleach Carbopol r e s i n s a r e used t o a c h i e v e a s t a b l e s u s p e n s i o n o f t h e c a l c i u m carbonate a b r a s i v e o a r t i c l e s i n t h e presence o f c h l o r i n e bleach lnqredient : DI[ Water Carbopol 674 o r 691* Good-Rite K-7058 (50%)** Sodi u h y d r o x i d e (50%) m 2 . 4 ~ sodium s i l i c a t e (52%) Sodium h y p o c h l o r i t e (14%) C a l c i urn c a r b o n a t e * * * Sodium n - d e c y l d i p h e n y l o x i d e d i s u l f o n a t e (45% *Suspension a i d : BFGoodrich * * A n t i - r e d e p o s i t i o n : BFGoodrich + * + A b r a s i v e : W h i t e #8 ( G e o r g i a M a r b l e ) * * * * A n i o n i c s u r f a c t a n t : Dowfax 382 (Dow Chemi
Wt%
53.76 0.80 2.00 2.80 2.50 7.14 30.00
1 .oo
****
Physi ea9 P r o p e r t i e s :
B r o o k f i e l d RVT v i s c o s i t y Product pH: 12-13 P r o d u c t c l a r i t y : Opaque ~ ~ ~ ~
20 rpm: 3,960 c p
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n '

M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous Add t h e low m o l e c u l a r w e i g h t p o l y a c r y l a t e p o l y m e r f o l l o w e d by t h e sodium h y d r o x i d e and sodium s i l i c a t e . M i x u n t i l homogeneous. Reduce a g i t a t i o n speed and add t h e sodium h y p o c h l o r i t e b l e a c h . (The p r o d u c t w i l l d r o p i n v i s c o s i t y a t t h i s p o i n t . ) Add t h e c a l c i u m c a r b o n a t e and f i n a l l y t h e s u r f a c t a n t w i t h c o n s t a n t a g i t a t i o n . M i x u n t i l homogeneous. Add f r a g r a n c e , as d e s i r e d . FGoedrich S p e c i a l t y Chemicals:
2.
3.
4.
5.
DET-343
46
A b r a s i v e Cleaner W i t h o u t
B1 each
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a s t a b l e suspension o f t h e h i g h l o a d i n g o f c a l c i u m carbonate abrasives
Insredient: D I Water Ethanol Carbopol 674 ( 1 ) Sodium h y d r o x i d e (50%) Sodium b i c a r b o n a t e Calcium carbonate ( 2 ) C12-15 1in e a r a1 coho1 , 3 moles EO ( 3 ) Coconut d i e t h a n o l ami de ( 4 ) B r o o k f ie l d v i s c o s i t y (RVT-20 P r o d u c t pH: 8-10 P r o d u c t c l a r i t y : Opaque
( 1 ) BFGoodr ich
Wt%
62.10 2.00 0.60 1 .00 1.20 30.00 2.50 0.60 cps
rpm) : 4,500
( 2 ) G e o r g i a M a r b l e Co.: G e o r g i a M a r b l e W h i t e # 8 ( 3 ) S h e l l Chemical: Neodol 25-3 ( 4 ) Stepan Co.: N i n o l 11-CM
Procedure: 1 . Add t h e e t h a n o l t o t h e w a t e r - h o l d i n g back 10 p a r t s o f w a t e r f o r s t e p #3. 2 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r / e t h a n o l m i x t u r e . M i x t h e s l u r r y for a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 3 . P r e p a r e a n e u t r a l i z i n g s o l u t i o n o f t h e 10 p a r t s o f w a t e r w i t h t h e sodium h y d r o x i d e and sodium b i c a r b o n a t e . Add t h i s t o t h e m i x t u r e formed above and m i x u n t i l homogeneous. 4 . Add t h e c a l c i u m c a r b o n a t e , a l c o h o l e t h o x y l a t e and coconut QEA. M i x u n t i l homogeneous. 5 . Add f r a g r a n c e , as d e s i r e d . Total Actives: C a l c i u carbonate: m C12-15 l i n e a r a l c o h o l , Coconut DEA: 30.0 2.5 0.6
3 moles EO:
SOURCE:
DET-340
47
A l l Purpose C l e a n e r
Ingredients: Urea Na4EOTA Water 2990 Ammonia C a l s o f t L-40 C a l o x y l a t e N-9 Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-001-01
Wei q h t % 2.00 2.00 88.00 1 .oo 5.00 2.00
Ingredients: Na4EDTA Water, Perfume Dowanol DPnB C a l s o f t L-40
Wei q h t % 4.00 84.00 4.00 8.00
Comments a b o u t t h i s f o r m u l a : Compare t o M r . C l e a n , a t r a d e m a r k o f P r o c t o r & Gamble. F o r m u l a t i o n APC-002-01 A l l Purpose C l e a n e r
Inqredi ent s : d - L i monene Calamide C Calamide C T W Cal imu1 se PRS Water

Comments a b o u t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s f i r s t and m i x . 2 . Add w a t e r s l o w l y . 3 . M i x u n t i l homogeneous. F o r m u l a t i o n APC-005-01 A l l Purpose C l e a n e r Inqredi ents: Water Calamide C T W Comments a b o u t t h i s f o r m u l a : Formula t h i c k e n s e f f e c t i v e l y . F o r m u l a t i on APC-003-01 SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s
Wei q h t % 40.00 4.00 4.00 10.00 42.00
Weight% 85.00 15.00
48
Inqredients: Na4EDTA Water Calamide C Calamide C T W P i l o t SXS-40 Laurami ne O x i d e Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-006-01 Wei q h t % 5.00 77.50 2.50 2.50 2.50 10.00
Inqredients: Na4EDTA Water 50% NaOH Cal s o f t LAS-99 P i l o t SXS-40 Calamide C Calamide C T W Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-007-01
Wei q h t %
5.00 76.10 0.80 2.80 5.30 5.00 5.00
A l l Purpose C l e a n e r - No R i n s e
Inqredients: Water C a l f a x 1OL-45 Na4 EDTA E t h y l e n e G l y c o l Monobutyl E t h e r Calamide C T W Comments a b o u t t h i s f o r m u l a : Spray a s i s , t h e n w i p e w i t h a p a p e r t o w e l . F o r m u l a t i o n APC-008-01 SOURCE: P i l o t Chemical Co.: Suggested F o r m u l a t i o n s Weight% 89.00 3.00 3.00 3.00 2.00
49
A 1 1- P u r p o s e C 1 e a n e r
Composi t ion : K e l z a n x a n t h a n gum A1 ip a l CD-128 G a f a m i d e CDD 518 B u t y l C e l l o s o l ve S o d i urn M e t a s i 1 ic a t e T r i s o d i urn P h o s p h a t e Water, Perfume
0.3 1.7
0.5 3.5 1.7 1.o 91.3
Procedure: P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum b y a d d i n g t h e powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n . Add o t h e r i n g r e d i e n t s as i n d i c a t e d . F o r a e r o s o l u s e , c h a r g e w i t h a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n a n d 15 p e r c e n t G e n e t r o n 12.
-ll-Purpose A
D i s i n f e c t a n t Cleaner
Composi ti= K e l z a n x a n t h a n gum Makon 1 0 Sodium T r i p o l y p h o s p h a t e V e r s e n e 100 Hyarnine 1 O X Water
Q 0.5 10.0 3.0 3.0 1.o 82.5
Procedure: P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum b y a d d i n g t h e powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n . Add o t h e r i n g r e d i e n t s a s i n d i c a t e d . F o r a e r o s o l u s e , c h a r g e w i t h a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n and 15 p e r c e n t G e n e t r o n 12.
SOURCE: M o n s a n t o P e r f o r m a n c e M a t e r i a l s : K e l z a n S u g g e s t e d
Formulations A l l Purpose C l e a n e r l n q r e d i en& R h o d a t e r g e SMC STPP Water
Wt%
10 2 88
Surfactants & Specialties: Suggested
SOURCE:
Rhone-Poulenc Formulations
50
A l l Purpose C l e a n e r w/Amide/Phosphate Innredi ents: W a t e r , D.I. Tetrapotassium Pyrophosphate Varami de A-1 0 Emphos 5AP
Ester
Wt%
83.0 5.0 10.0 2.0
81 e n d i ng P r o c e d u r e : Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Typical Properties: V i s c o s i t y , c p s : 145 S o l i d s : 17.0% pH: 8 . 8 Formula 514
Ingredients: Water W i t c o n a t e 1 2 6 0 S1 u r r y Witcamide 6445 Blending Procedure: B1 end i n g r e d i e n t s i n t h e o r d e r 1 is t e d . Typical Properties: V i s c o s i t y , c p s : 670 Sol i d s : 33.0% pH, as i s : 9 . 2 Formula 520 A1 1 Purpose C l e a n e r Ingredients: Water Sodi um T r i p o l y p h o s p h a t e C a u s t i c Soda, 50% W i t c o 12988 W i t c a m i de 6 4 4 5 Perfume, Dye Blending Procedure: Blend i n g r e d i e n t s i n order l i s t e d . T y p i c a l P r o p e r t ie s : Speci f ic G r a v i t y : 1 . 0 2 0 6 Wt./Gal. l b s . : 8 . 5 pH, as i s : 9 . 1 2 V i s c o s i t y , c p s : 107 Color: Beige Use D i l u t i o n : 1 - 2 o z . / G a l . Formula 535 SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
wto/,
56.0
38.5 5.5
W S 90.0 2.0 0.5 2.0 5.0 q.s.
51
A l l Purpose C l e a n e r C o n c e n t r e
(Phosphate, - L i q u i d , Foam) S o i 1 - G r e a s e and o i 1 Surface-Paint, polymeric, metal A p p l i c a t i o n Method-Spray Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i n o : Water M e t s o Beads 2048 TKPP ( 6 0 % ) *Phosphate E s t e r * * D i p r o p y l e n e G l y c o l Monomethyl E t h e r * * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 9-10 M o l e s E O ****Octylphenoxy P o l y e t h o x y e t h a n o l , 5 M o l e s EO Use D i l u t i o n : Normal D u t y - 1 . 5 % bw ( 2 o z / g a l l o n ) Heavy D u t y - 2 . 5 % b w ( 3 . 3 o z / g a l 1on) Tough D u t y - a s s u p p l i e d
Wt%
78.1 2.4 3.0
3.0
6.0 5.0 2.5
* **( *** ****
Rhone-Poulenc R h o d a f a c RE-610 Dow, A r c 0 C h e m i c a l Rhone-Poulenc I g e p a l CA-630 Rhone-Poulenc I g e p a l CA-520
A l l Purpose C o n c e n t r a t e
(Phosphate, Liquid1 S o i 1 - G r e a s e and o i 1 Surface-Paint, polymeric, metal A p p l i c a t i o n Method-Wipe o r b r u s h Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Water M e t s o Beads 2048 TKPP Sodium X y l e n e S u l f o n a t e , 40% *Ethylene Glycol n-Butyl Ether Pine O i l * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3, 6 . 5 M o l e s EO) * * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5, 3 M o l e s EO) Use D i 1u t i o n : 1 . 5 - 3 . 0 % bw ( 2 - 4 o z / g a l l o n )
wto/,
78.75 1 .oo 3.00 3.50 6.00
0.25 5.00
2.50
*
*l
*S*
Dow C h e m i c a l , U n i o n C a r b i d e Rhone-Poul enc R h o d a s u r f LA-7 Rhone-Poulenc R h o d a s u r f A-24
SOURCE:
PQ C o r p . :
52
Calcium Carbonate A b r a s i v e Cleaner W i t h o u t Bleach Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a s t a b l e suspension o f t h e h i g h l o a d i n g o f c a l c i u m c a r b o n a t e abrasives
I n q r e d ie n t : D I Water Carbopol ETD 2623 ( 1 ) Sodium h y d r o x i d e (50%) C12-I5 l i n e a r a l c o h o l , 3 moles EO ( 2 ) Sodium a l k y l benzene s u l f o n a t e ( 3 ) Calcium carbonate ( 4 ) P h y s i c a l P r o p e r t ies : B r o o k f i e l d V i s c o s i t y (RVT-20 P r o d u c t pH: 8-10 P r o d u c t C l a r i t y : Opaque rpm):
62.10 0.25 0.20 1.50 0.50 30.00
7,500 c p
Raw M a t e r i a l S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) S h e l l Chemical Co.: Neodol 25-3 ( 3 ) Stepan Co. : Nacconol SQG ( 4 ) Georgia Marble C o . : Georgia Marble White #8 Procedure: 1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i ng and b l endi ng o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s or u n t i l t h e s l u r r y i s homogeneous. 2. Add t h e sodium h y d r o x i d e t o r e a c h t a r g e t pli. The p r o d u c t w i l l become v e r y t h i c k a t t h i s p o i n t . 3 . Add t h e a l c o h o l e t h o x y l a t e and a l k y l b e n z e n e s u l f o n a t e s u r f a c t a n t s . M i x u n t i l homogeneous. 4 . Add t h e c a l c i u m c a r b o n a t e . M i x u n t i l homogeneous. 5. Add f r a g r a n c e , as d e s i r e d . Total Actives: Calcium carbonate: 30.00 C12-15 l i n e a r a l c o h o l , 3 moles EO: 1.50 Sodium a1 k y l b e n z e n e s u l f o n a t e : 0.50
SOURCE:
BET-341
53
C i t r i c A c i d Cleaner
F u n c t i a n e 8 B e n e f i t s : Carbopol ETD 2623:

* P r o v i d e s l o w p H t h i c k e n i n g v i a hydrogen b o n d i n g w i t h s u r f actant * I m p a r t s y i e l d v a l u e f o r suspension o f a b r a s i v e p a r t i c l e s *Provides v e r t i c a l c l i n g f o r increased s u r f a c e c o n t a c t t i m e *Shear t h i n n i n g r h e o l o g y f o r easy d i s p e n s i n g t h r o u g h t r i g g e r sprayer o r nozzle * E a s y - t o - d i s p e r s e r e s i n f o r improved and e a s i e r f u l l - s c a l e processing Inqiredi e n t :
Wt%
78.40 0.10 5.00 2.50 2.00 12.00
DI Water
Carbopo? ETD 2623 R e s i n * C12-15 l i n e a r a l c o h o l , 3 moles EO** C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO*** Alkylbenzene s u l f o n i c acid**** C i t r i c A c i d (50%)
*V iscos ity modi f ie r : BFGoodr ic h s W o n i o n i c s u r f a c t a n t : Neodol 25-3: She1 1 Chemical S h e l l Chemical >N**Nonionic s u r f a c t a n t : Neodol 23-6.5: * * r * A n i o n i c s u r f a c t a n t : B i o s o f t 5-100: Stepan
P h y s i c a l P r o p e r t iee:
B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: Initial: Age-Up V i s c o s i t y : Week 2 : Week 4 : Week 6: P r o d u c t pH: 1 . 4 Product c l a r i t y : T r a n s l u c e n t
S t o r a g e Temperature
25C .
5oc
50cP 400cP 600cP 400cP
50cP 170cP 250cP 350cP
Procedurw:
4.
2.
3.
4.
5.
U s i n g J m a r i n e b l a d e p r o p e l l e r and r a p i d a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t , s p r i n k l e t h e Carbopol ETD 2623 r e s i n i n t o t h e v o r t e x . A l l o w t o h y d r a t e f o r 15-20 m i n u t e s o r u n t i l no lumps a r e p r e s e n t . Warming t h e d e i o n i z e d w a t e r t o 30C w i l l decrease t h e h y d r a t i o n t i m e and i m p r o v e t h e d i s p e r s i b i l i t y o f t h e Carbopol powder. M i x t h e Neodol 25-3 and Neodol 2 3 - 6 . 5 ( o r warm s l i g h t l y i f needed) t o e n s u r e homogeneity. A d d w i t h moderate m i x i n g (300 r p m ) . A l l o w t o mix u n t i l u n i f o r m and smooth. Add t h e B i o s o f t S-100 w i t h moderate (300 rpm) m i x i n g and a l l o w t o m i x u n t i l u n i f o r m and smooth. S ~ O W add t h e C i t r i c A c i d w i t h s l o w m i x i n g (200 r p m ) . M i x ~ Y u n t i l smooth and u n i f o r m . Add f r a g r a n c e and c o l o r , a s d e s i r e d .
S O U R C E : B F G o o d r i c k S p e c i a l t y ChemicaJs:
DET-352
54
G e n e r a l P u r p o s e C1 e a n e r (Consumer Low Alkaline, Non-Phasphate Powder) S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , c l a y and p a r t i c u l a t e s o i l Surface-Hard surface, i . e . , metal, p l a s t i c , ceramic, concrete, and a s p h a l t A p p l i c a t i on Method-Wi p e o r B r u s h Manufacture-Dry blend/Agglomeration Composi t i o n : Sodi um C a r b o n a t e ( 1 i g h t d e n s i t y ) * B r i t e s i 1 C20 Hydrous P o l y s i 1 i c a t e * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5; 9 M o l e s EO) V a l f o r 100 Z e o l i t e A * * * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) Sodi um S u l f a t e Use L e v e l : 1-4 o z / g a l l o n 82.5% s o l i d s
Wt%
30.0 10.0 15.0 30.0 0.5 14.5
**
* ***
2 . 0 w e i g h t r a t i o s i l i c a t e powder, Rhone-Poulenc R h o d a s u r f LA-9 Rohm & Haas
G e n e r a l Purpose C l e a n e r (Consumer H i g h A 1 k a l ine, Non-Phosphated Powder1 S o i -Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , c l a y and p a r t i c u l a t e s o i l Sur ace-Hard s u r f a c e , i . e . , m e t a l , p l a s t i c , c e r a m i c , c o n c r e t e , and a s p h a l t App i c a t i o n Method-Wipe o r b r u s h Manufacture-Dry blend/Agglomeration Composi t i o n 1 Sodium S u l f a t e Sodi um C a r b o n a t e ( 1 ig h t d e n s i t y ) * L i q u i d N o n i o n i c S u r f a c t a n t ( C 1 2 - C l 5 ; 9 M o l e s EO) V a l f o r 100 Z e o l i t e A M e t s o Beads 2048 * * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) Use L e v e l : 1-4 o z / g a l l o n R h o d a s u r f LA-9 14.5 30.0 15.0 30.0 10.0 0.5
Wt%
**
Rhone-Poulenc Rohm & Haas
SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t i o n Guide
55
G e n e r a l P u r p o s e S p r a y & Wipe C l e a n e r Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g i n v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l s u r f a c e . T h i s "no-drip" action w i l l increase the contact time o f t h e detergent on t h e s o i l e d s u r f a c e a s w e l l a s enhance consumer c o n v e n i e n c e . Ingredient: D I Water C a r b o p o l ETD 2 6 9 1 ( 1 ) EDTA ( t e t r a s o d i u m s a l t ) Sodium m e t a s i l i c a t e , a n h y d r o u s P r o p y l ene g l y c o l m e t h y l e t h e r ( 2 ) C12-15 l i n e a r a l c o h o l , 7 m o l e s EO ( 3 ) B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 120 c p s P r o d u c t p H : 12-13 P r o d u c t C l a r i t y : C l e a r t o hazy ( 1 ) BFGoodri c h ( 2 ) Dow C h e m i c a l : Dowanol DPM ( 3 ) S h e l l C h e m i c a l : Neodol 25-7 Procedure: 1 . U s i n g m o d e r a t e a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s or u n t i l t h e s l u r r y i s homogeneous. 2 . Under s l i g h t a g i t a t i o n , add t h e EDTA and M e t a s i l i c a t e . 3 . C o n t i n u e a g i t a t i o n and add t h e g l y c o l e t h e r and a l c o h o l e t h o x y 1a t e . 4 . Add c o l o r and f r a g r a n c e , a s d e s i r e d . T o t a l Actives: Propylene g l y c o l methyl e t h e r : C 1 2 - I 5 l i n e a r a l c o h o l , 7 m o l e s EO:
wto/, 90.70 0.20 2.00 2.30 3.00 1.50
3.0 1.5
SOURCE:
DET-310
56
G e n e r a l P u r p o s e Spray & Wipe Ingredients: Water, D.I. Sodi um C i t r a t e A1 p h a - S t e p MC-48 S t e p a n o l WA-Extra N i n o l 11-CM
Wt%
79.0 2.0 10.0 7.0 2.0
M i x i n g Procedure: Charge w a t e r and s u r f a c t a n t s and m i x . Add sodium c i t r a t e and m i x u n t i 1 homogeneous. T y p i c a l P r o p e r t i es : Appearance: C l e a r c o l o r l e s s l i q u i d pH, as i s : 9 . 4 V i s c o s i t y I 2 5 deg. C : V e r y t h i n 3 S o l i d s , %: 1 0 . 0 Density, l b s / g a l : 8.54 C o l d s t o r a g e @ 4 d e g . C, 1 d a y : p a s s F r e e z e / t h a w , 3 c y c l e s : pass Performance: Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t : Commercial P r o d u c t - 66% s o i l removed f r o m t i l e s Above f o r m u l a t i o n - 82%' s o i l removed f r o m t i l e s Above f o r m u l a t i o n p e r f o r m s b e t t e r t h a n c o m m e r c i a l product. Use I n s t r u c t i o n s : Use as i s
Comment : The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .
SOURCE:
Stepan Co.:
Suggested F o r m u l a t i o n A1 1 -Purpose C1 e a n e r
No. 575
Ingredients: Water Z e t e s o l 2056 Z u s o l a t 1008/85
82.0 14.0 4.0 F o r m u l a t i o n CT 02-04-02
SOURCE:
57
H y p o c h l o r it e V e r t i c a l S u r f a c e C l e a n e r M o n a t r o p e 1250 i s a h y p o c h l o r i t e s t a b l e s u r f a c t a n t t h a t c o n t r i b u t e s t o w e t t i n g and f o a m i n g c h a r a c t e r i s t i c s .
In q r e d ie n t s : M o n a t r o p e 1250 Sodium C14-17 A l k y l Sec S u l f o n a t e (60%) Laurami ne O x i d e (30%) P o t a s s i u m H y d r o x i d e (45%) Sodi um T r i p o l y p h o s p h t e Sodium H y p o c h l o r i t e 5 . 2 5 % )
Procedure: Add i n g r e d i e n t s w t h a g i t a t i o n .
Wt%
2.0 2.0 10.0 15.0 5.0 66.0
Typical Properties: Appearance: C l e a r y e l l o w l i q u i d p H : 13

Recommended Use D i l u t i o n : Formul a t i on F-783
1:lO w i t h w a t e r
Pump S p r a v A l l
Purpose C l e a n e r Surfaces w i l l dry
A f a s t a c t i o n s p r a y and w i p e f o r m u l a t i o n . streak-f ree.
Inqredients: Water M o n a t e r g e 779 (DEA-Laureth S u l f a t e ) Propylene Glycol B u t y l Ether Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r l i q u i d Recommended Use D i 1 u t i o n : As i s SOURCE: Mona I n d u s t r i e s ,
Wt%
94.0 3.0 3.0 Package.
58
L i q u i d C 1 eanser w i t R B1 each I n t h i s f o r m u l a Van Gel B i s used t o suspend t h e a b r a s i v e and t o a d j u s t t h e v i s c o s i t y . The sodium c a r b o n a t e b u f f e r h e l p s m a i n t a i n a pH o f a b o u t 1 1 , n e c e s s a r y f o r t h e s t a b i l i t y o f t h e h y p o c h l o r i t e . T h i s l i q u i d c l e a n s e r o f f e r s t h e advantage o f m i l d ness i n u s e and g r e a t e r ease and e f f e c t i v e n e s s on v e r t i c a l s u r f a c e s a s compared t o powders. Ingredients: A : Van Gel B Water
2.25 62.25 '10.00 4.50 20.00 1 .oo
6 : Diatomaceous E a r t h
Sodium c a r b o n a t e Sodium h y p o c h l o r i t e , 5 . 2 5 % s o l n . Sodium L a u r y l S u l f a t e , 29% s o l n .
Procedure: S l o w l y add Van Gel B t o t h e w a t e r w h i l e a g i t a t i n g a t maximum a v a i l a b l e s h e a r . C o n t i n u e m i x i n g u n t i l smooth. Add r e m a i n i n g i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each a d d i t i o n . Consistency: Medium v i s c o s i t y liquid.
Suggested Packaging:
P l a s t i c squeeze b o t t l e .
SOURCE: R . T . V a n d e r b i l t
Co.,
Inc.:
F o r m u l a t i o n N o . 391
Clear, Ingredients: A : H o s t a p u r SAS 6 0 Genapol ZRO 1 iq u i d Genapol UD-080
B : Water
liquid
Wt% 10.0-15.0 0.0- 4.0 1.0- 3 . 0
Perfume Preservative Dye Manufacturing: Add one a f t e r a n o t h e r , t h e components o f B t o A .
ad 1 0 0 . 0 0.2 0.1
q.s.
Modern s t a n d a r d f o r m u l a t i o n s a r e based on a l k a n s u l p h o n a t e s and noni oni c s E t h e r s u l p h a t e s a r e used i n r a r e cases. Phosphates, sodium c a r b o n a t e and ammonia a r e n o t common any 1onger The above g u i d e f o r m u l a t i o n c o v e r s t h e common european p r o d u c t s .
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n
59
Pine O i l Cleaner Concentrate Ingredients: Pine o i l N i n o l 11-CM Makon 12 Ammonyx LO B i o - S o f t S-1 0 0 Isopropanol Water, D . I .
g
20.0 9.0 5.0 0.5 2.0 10.0 53.5
M i x i ng Procedure: Combine p i n e o i l , s u r f a c t a n t s and I P A . M i x u n t i l c l e a r . Add water s l o w l y w h i l e under a g i t a t i o n . Mix u n t i l c l e a r . Properties: Appearance: C l e a r y e l l o w l i q u i d Odor: P i n e V i s c o s i t y @ 25C, c p s : 50 pH ( a s i s ) : 8 . 1 D e n s i t y 1b s / g a l : 8 . 0 6 Freeze/Thaw ( 3 c y c l e s ) : Pass 50 C oven ( 1 week): Pass Use I n s t r u c t i o n s : D i l u t e 1-2 o z s i n t o one g a l l o n Performance: Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t : Above f o r m u l a t i o n : 73.0% s o i l removed f r o m t i l e s Commercial f o r m u l a t i o n : 5 5 . 5 % s o i l removed f r o m t i l e s SOURCE: S t e p a n Co.: F o r m u l a t i o n No. 208
D i s i n f e c t i n g Cleaner, Ingredients: Water C i t r i c acid Z u s o l a t 1008/85 Lumorol 4192 Trilon A liquid Lonzabac-1230 Ingredients: Water Disodium t e t r a b o r a t e decahydrate Sodi um b i c a r b o n a t e Burdac-114 Z u s o l a t '1008/85 Ingredients: Water Trilon A liquid Citric acid S u l f e t a l 4069 Z u s o l a t 1008/85 Lonrabac-1230 Alkaline
Wt%
57.5 2.0 3.5 5.0 7.0 25.0
Wt%
69.0 0.5 1.0 20.0 9.5
g
57.5 7.0 2.0 5.0 3.5 25.0 F o r m u l a t i o n s CT 06-09-01,
SOURCE:
Zschimmer & Schwarz GmbH & Co.: CT 06-09-02, CT 06-09-03
60
Advanced Cleaning Product Formulatiorrs
Sodi urn B i c a r b o n a t e A b r a s i v e C l e a n e r W i t h o u t B l e a c h
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a s t a b l e s u s p e n s i o n o f t h e h i g h l o a d i n g o r sodium b i c a r b o n a t e abrasives.
-g r e d i e n t : In
D I Water C a r b o p o l ETD 2691 ( 1 ) A l k y l benzene s u l f o n i c a c i d ( 2 ) C12-13 l i n e a r a l c o h o l , 6 . 5 m o l e s 0 ( 3 ) Sodium h y d r o x i d e ( 5 0 % ) Sodium b i c a r b o n a t e ( 4 ) : Grade 1 : Grade 5 :
wtsl, 44.25
0.50 0.75
2.50 2.00
20.00 30.00
Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 rprn): Product pH: 8.50 P r o d u c t C l a r i t y : Opaque
6,000 c p
Raw M a t e r i a l S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) Stepan Co.: B i o s o f t 5-100 ( 3 ) S h e l l C h e m i c a l C o . : Neodol 2 3 - 6 . 5 ( 4 ) Church & Dwight Procedure: 1 . U s i n g moderate a g i t a t i o n ( 8 0 0 r p m ) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 1 5 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Add t h e a l k y l b e n z e n e s u l f o n i c a c i d f o l l o w e d b y t h e a l c o h o l e t h o x y l a t e . M i x u n t i l homogeneous. 3 . Add t h e s o d i u m h y d r o x i d e . M i x u n t i l homogeneous. A d j u s t pH t o 8.50 p r i o r t o t h e next step. 4 . W i t h m i n i m a l a g i t a t i o n , s l o w l y add t h e s o d i u m b i c a r b o n a t e . M i x u n t i l smooth, homogeneous, and f r e e o f b i c a r b o n a t e l u m p s . Re-check p H and a d j u s t , i f n e c e s s a r y . 5 . Add c o l o r a n d f r a g r a n c e , a s d e s i r e d . T o t a l A c t iv e s : S o d i um b i c a r b o n a t e : C12-13 l i n e a r a l c o h o l , 6 . 5 m o l e s EO: Sodium a1 k y l benzene s u l f o n a t e : SOURCE: B F G o o d r i c h S p e c i a l t y C h e m i c a l s : 50.00
2.50
0.90
DET-342
leaners/Polishes
61
62
A n t i -Foggi ng , A n t i -Stat ic G l a s s C l eaner

I gredients : n Water Isopropyl Alcohol Adogen 66 Varox 365 Emcol 4500
MIBo/o
90.0 9.0 0.I 0.5 0.4
Blending Instructions: Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y . I f p r o d u c t i s hazy, a d d i t i o n a l I s o p r o p y l Alcohol can be used t o c l a r i f y t h e s o l u t i o n . G e n t l y h e a t i n g can b e used t o f a c i l i t a t e m i x i n g o f t h e Emcol 4500. Use I n s t r u c t i o n s : A p p l y f i n i s h e d p r o d u c t t o a t o w e l l e t e (Kimwipe, wipe onto t h e glass. A l l o w t o d r y . e t c . ) and
Product I n f o r m a t i o n : Product: Benefit : Varox 365 W e t t i n g a g e n t , d e g r e a s e r and d e t e r g e n t Adogen 66 A n t i - s t a t i c agent Emcol 4500 W e t t i n g a g e n t , c o u p l e r and d e t e r g e n t T h i s f o r m u l a t i o n p r e s e n t s a t h i n b a r r i e r between t h e w a t e r v a p o r ( f o g , steam, e t c . ) and t h e g l a s s w h i c h w i l l p r e v e n t f o g g i n g . The a b i l i t y t o l o w e r t h e s u r f a c e t e n s i o n o f t h e w a t e r prevents t h e c l i n g i n g o f i n d i v i d u a l water d r o p l e t s t o the glass; t h e r e f o r e l i g h t i s n o t s c a t t e r e d as much a s i t i s when p a s s i n g through i n d i v i d u a l d r o p l e t s . F o r m u l a 708
Glass Cleaner, Ingredients: Water, D . I . P e t r o BAF L i q u i d Isopropanol E t h y l e n e G l y c o l Monobutyl E t h e r Dye
Ready t o Use
84.9 0.1 10.0 5.0 q.s.
B l e n d i ng P r o c e d u r e : B l e n d i n g r e d i e n t s i n t h e o r d e r 1is t e d . F o r m u l a 705 SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Glass CleanerslPolishes
63
G l a s s C l e a n e r C o n c e n t r a t e (Non-Ammoniated) Ingredients: W a t e r , D . I. I s o p r o p a n o l , 99% P e t r o LBA Powder Monoethanol ami ne Perfume, Dye B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .
K %
7.5
82.0 1.o 0.5

q.
T h i s c o n c e n t r a t e s h o u l d be m i x e d w i t h n i n e p a r t s o f w a t e r t o one p a r t c l e a n e r t o b e r e a d y t o u s e . T h i s p r o d u c t r e q u i r e s a red label. F o r m u l a 702 Glass Cleaner Concentrate Inqredi ents: Water, D . I . P e t r o BAF L i q u i d DeSonic 5 N Ammonia, 29% Dye B l e n d i n g Procedure: Use D i l u t i o n : F o r m u l a 703 Blend i n g r e d i e n t s i n t h e order l i s t e d .
Wt%
77.0 20.0 1.o 2.0 q.s.
1 p a r t c o n c e n t r a t e t o 50 p a r t s w a t e r .
Amrnoniated G l a s s C l e a n e r m r e d ients: Water W i t c o l a t e 231 0 B u t y l C e l l o s o l ve Aqua Ammonia, 26 B e ' B l e n d i n g Procedure: F o r m u l a 704 Blend i n g r e d i e n t s i n t h e order l i s t e d .
Wt%
94.0 3.0 2.0 2.0
64
G l a s s and Window C l e a n e r Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g i n v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l s u r f a c e . T h j s "no-drip" a c t i o n w i l l increase the contact time o f t h e detergent on t h e s o i l e d s u r f a c e as w e l l as enhance consumer c o n v e n i e n c e . Inaredient: D I Water Carbopol ETD 2623 Isopropanol Ammonium h y d r o x i d e A l k y l b e n z e n e s u l f o n i c a c i d (97%) ( 2 ) Propylene g l y c o l methyl e t h e r (3) Physical Properties: B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 200 c p P r o d u c t pH: 9 . 5 - 1 0 . 0 Product C l a r i t y : Clear Raw M a t e r i a1 Suppl ie r s : ( 1 ) BFGoodrich ( 2 ) Stepan Chemical: B i o s o f t 5-100 ( 3 ) Dow Chemical: Dowanol PM Procedure: 1 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Add t h e i s o p r o p a n o l . 3 . Add t h e ammonium h y d r o x i d e . M i x u n t i l homogeneous. 4 . Add t h e s u l f o n i c a c i d and g l y c o l e t h e r w i t h m i n i m a l a g i t a t i o n t o a v o i d e x c e s s i v e foaming. 5 . Add a d d i t i o n a l ammonium h y d r o x i d e , i f necessary, t o r e a c h the t a r g e t pH r a n g e . 6 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Total Actives: Ammonium a l k y l b e n z e n e s u l f o n a t e : 0 . 3 0 Propylene g l y c o l methyl e t h e r : 2.00 Isopropanol: 5.00 SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-300
wel
92 * 45 (4.10 5.00 0.20 0.25 2.00
Glass CleanerslPolishes
65
H o u s e h o l d Window C l e a n e r Inqredients: Water. D . I . Isopropanol Varox 365 Methylene Blue
Wt%
89.3 10.0 0.7 q.s.
Blending Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . T y p i c a l P r o p e r t ies: V i s c o s i t y , cps: 4 S o l i d s : 0.2% pH: 7 . 4 F o r m u l a 706 Bremi u m Household W i ndow C1 e a n e r Ingredi ents: Water, D . I . Isopropanol Varox 1770 Methylene Blue Q 89.4 10.0 0.6 q. s
81 e n d i ng P r o c e d u r e : Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Typical Properties : V i s c o s i t y , cps: 4 S o l i d s : 0.23% pH: 6 . 2 F o r m u l a 707
GI ass @1e a n e r
Ingredients: Water. D . I . Isopropanol Dowanol EB R e w o t e r i c AM V
Wt%
q.s. 6.0 4.0 0.85
81 endi ng P r o c e d u r e : B l e n d i n g r e d i e n t s i n t h e o r d e r shown, ween each a d d i t i o n . F o r m u l a 709 SQURCE: W i t c o G o r p . :
mixing thoroughly bet-
66
W i n d o w s / G l ass
Gl-ass Cl g a n g r C C o n c e n t r a t e )
Ingredients: Water Ethylene G l y c o l Monobutyl Ether Isopropyl Alcohol Ammonia, 2 9 . 4 % C a l foam SLS-30 Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d F o r m u l a t i o n WIN-001-01
We i s h t YO 10.04 21.34 53.30 2.35 5.00
W i n-dzhield Washer C c n c e n t r a t e
Ingredients: Water Isopropyl Alcohol C a l s u d s 81 Comments a b o u t t h i s f o r m u l a : Use 4 0 2 . o f t h e c o n c e n t r a t e p e r g a l l o n . F o r m u l a t i o n WIN-002-01
Weigh_% 47.66 47.30 5.10
W i ndshjeld-pWashec C o n c e n t y a t e (Low VOC)
I r e d i-en t s : ng Water P r o p y l ene G1 y c o l Calsuds 81

Comments a b o u t t h i s f o r m u l a Use l e v e l : 2-4 o z p e r g a l l o n . F o r m u l a t i o n WIN-003-01 SOURCE: P i l o t C h e m i c a l C o . : Suggested F o r m u l a t i o n s
W i gh ts/, e 62.20 33.80 4.02
ard Surface Cleaners
67
68
A l k a l i n e Hard Surface Cleaner

I gredient s : n Water, D . I . Sodi um M e t a s i 1 ic a t e Varami de A-83 W i t c o n a t e 30DS W i t c o n a t e SXS L i q u i d
34.0 8.0 12.0 40.0 8.0
81 e n d i n g P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t io n . Typical Properties: V i s c o s i t y , c p s : 205 S o l ids : 3 4 . 4 % pH: 1 2 . 5 F o r m u l a 516 Hard Surface CleaEer Concentrate ( A l l Ingredients: Water, D . I . T e t r a s p o t a s s i u m P y r o p h o s p h a t e , Anhydrous W i t c a m i de 1 PET Emphos 5AP W i t c o 1298S A Blending Procedure: Blend i n g r e d i e n t s i n order l i s t e d , addition. Typical Properties: S p e c i f i c G r a v i t y : 1.085 Wt./Gal. l b s : 9.04 pH, a s i s : 7 . 5 7 V i s c o s i t y , c p s : 94 3 Freeze/Thaw c y c l e s : Passed 1 Week @ 52C: Passed 4 Weeks Room Temp: Passed S o l i d s : 17.8% Appearance: C 1 e a r L i q u i d Use D i l u t i o n : 1-3 o z . / g a l . F o r m u l a 540 P u r p o s e Type)
\Ne%
82.0 10.0 1.o 4.0 3.0
m i x i n g w e l l a f t e r each
SOURCE: W i t c o C o r p . :
Hand Surface Cleaners
69
Concentrated Hard Surface Cleaner Ingredients: D e o d o r i z e d Kerosene Calamide C T W C a l o x y l a t e N-9 E t h y l e n e G l y c o l Monobutyl E t h e r Water N a4 E DTA Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 1-2 o z p e r g a l l o n . F o r m u l a t i o n HSC-009-01 Hard Surface Cleaner-Spray Inqredi ents: Wei q h t % Water 86.50 Ammonia, 29% 3.00 0.50 Na4EDTA Ethylene G l y c o l Monobutyl E t h e r 5.00 C a l s u d s 81 5.00 Comments a b o u t t h i s f o r m u l a : 1 . A f t e r a d d i t i o n o f E t h y l e n e G l y c o l Monobutyl E t h e r , t h e mixture i s cloudy. 2 . It becomes c l e a r w i t h t h e a d d i t i o n o f C a l s u d s 8 1 . F o r m u l a t i o n HSC-008-01 Wei q h t % 25.00 16.30 9.00 9.00 41 .30 0.40
P i n e Cleaner
Inqredi ents : Pine O i l I PA Calamide C T W Cal o x y l a t e N-9 C a l s o f t LAS-99 Water Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . Use a t 1-2 o z p e r g a l l o n . F o r m u l a t i o n HSC-004-01
-i n e P
Weight% 20.00 10.00 9.00 5.00 2.00 54.00
Cleaner Weight% 15.00 10.00 8.00 10.00 57.00
Ingredients: Pine O i l C a l s u d s CD-6 C a l o x y l a t e N-9 IPA Water Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HSC-007-01

~~~~~~~
P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
70
Advanced Cleatiing Product Formulations
H a r d S u r f a c e Cleanerc Ingredients: Water Sodi um M e t a s i 1 i c a t e Na4EDTA Dowanol PnB P i l o t SXS-40 C a l o x y l a t e N-9 P i n e 01 1 Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d F o r m u l a t i o n HSC-001-01 Hard-Surface-C1 @anex weight% 75.25 2.00 2.00 6.00 9.00 5.50 0.25
Ingredi ents : Water Sodi um M e t a s i 1 i c a t e Na4EDTA P i l o t SXS-40 Cal imu1 se PRS Dowanol PnB Cal o x y l a t e N-9 Comments s b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HSC-002-01
H a r d S u r f a c e Cle&ne_r
Wi q h t 9 6
74.50 2.00 2.00 7.00 3.00 5.00 6.50
Ingredisnts : Water Sodi um M e t a s i 1 i c a t e Na4EDTA P i l o t SXS-40 Calamide C T W Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 1 - 4 o z p e r g a l l o n . F o r m u l a t i o n HSC-005-01
Weisht_"L.
79.30
5.20 2.50 5.00 8.00
Hardsu.!-33Cs~_ec1 eaner
Irns r e d i en t-s 1 Water Sodi um C i t r a t e Soda Ash Ammonia, 29% P i l o t SXS-40 Calamide CWT Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 2-4 o z p e r g a l l o n . F o r m u l a t i o n HSC-006-01 SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s W i_ph % e t 58.50 15.00 5.00 3.50 8.00 1O.DO
Hand Sqface Cleaners
71
Hard Surface Cleaner w/Amphoteric Inqredi ents: Water, D . I . Sodi um C a r b o n a t e R e w o t e r i c AM KSF-40 Dowanol DPM Versene 100 W i t c o n a t e SXS (40%)
Wt%
75.0 4.0 10.0 5.0 2.0 4.0
Blending Procedure: Add i n g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . T y p i c a l P r o p e r t i es : V i s c o s i t y , cps: 4 S o l i d s : 10.2% pH: 10.8 F o r m u l a 507 H a r d S u r f a c e C l e a n e r C o n c e n t r a t e w/d'Limonene Ingredients: Phase I: Isopropanol Oleic A c i d .Varoni c K205 d ' L i monene Phase 11: Water, D . I . P o t a s s i u m H y d r o x i d e (87%)
10.0 8.8 5.0 12.0 62.2 2.0 Combine Phase
B1 e n d i ng P r o c e d u r e :
Combine Phase Phase 11. T y p i c a l P r o p e r t i es : V i s c o s i t y , cps: 75 S o l i d s : 13.8% pH: 1 0 . 2 F o r m u l a 508
i n g r e d i e n t s and m i x t h o r o u g h l y .
I 1 i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o
72
Hard Surface Cleaner Concentrate IPhosphate. L i q u i d ) S o i l - F o o d g r e a s e , o i l and p r o t e i n , p e t r o l e u m g r e a s e and o i l Surface-Metal, ceramic, polymeric, g l a s s A p p l i c a t i o n Method-Wipe, mop o r s p r a y ( d i l u t e d ) M a n u f a c t u r e - M i x t a n k w i t h p r o p e l 1e r s t i r r e r ComDosition A: Water TSP S t a r s o Sodium S i l i c a t e Sodium H y d r o x i d e (50%) *Phosphate E s t e r * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 6 Moles EO) * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 2 . 5 Moles EO) Composition B: Water TSP S t a r s o Sodi um S i 1 ic a t e Sodium H y d r o x i d e (50%) *Phosphate E s t e r * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cl1; 6 M o l e s EO) * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO) Use D i l u t i o n : 3-6% bw ( 4 - 8 oz/gallon) 71.4 1.6 14.0 4.0 5.0 2.8 1 .2
Wt%
65.4 1.6 18.0 5.0 6.0 2.8 1.2
* ** ***
Rhone-Poulenc Rhodafac RE-600 Rhone-Poulenc R h o d a s u r f 91-6 Rhone-Poulenc R h o d a s u r f A-24 Hard S u r f a c e Spray Cleaner LPhosphate, L i q u i d ) S o i l - F o o d g r e a s e , o i l and p r o t e i n , p e t r o l e u m g r e a s e and o i l Surface-Metal, ceramic, polymeric, g l a s s A p p l i c a t i o n Method-Spray and w i p e Manufacture-Mix tank w i t h p r o p e l l e r s t i r r e r
Composi t i on : Water TKPP N C l e a r Sodium S i l i c a t e Sodium H y d r o x i d e (50%) * D i p r o p y l ene G1 y c o l Monomethyl E t h e r * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 12-13 M o l e s Use: As i s , spray I g e p a l CA-720 Detergent F o r m u l a t i o n Guide
Wt% ~-
EO
90.00 2.00 1.88 0.12 5.00 1 .00
**
Dow Chemical Rhone-Poulenc
Hand Surface Cleaners
73
Hard S u r f a c e C l e a n e r C o n c e n t r a t e w/Dipentene
I nnredi e n t s : Phase I : Isopropanol Oleic Acid V a r o n i c K205 D i pentene

Phase 11: Water, D . I . Potassium H y d r o x i d e (87%)
Wt%
10.0 8.8 5.0 12.0 62.2 2.0
B l e n d i n g Procedure: Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine Phase I 1 i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o Phase X I
~
Typical Properties: V i s c o s i t y , cps: 50 Solids: 13.8% pH: 10.1 Formula 509 A 1 k a l ine Hard S u r f a c e C l e a n e r I n q r e d ients: Water, D . I . Sodi u M e t a s i 1i c a t e m Varami de A-83 \Mi t c o n a t e 3 0 D S W i t c o n a t e SXS L i q u i d
Wt%
62.7 3.0 5.0 6.8 2.5
B l e n d i n g Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Typical Properties: V i s c o s i t y , c p s : 32 S o l i d s : 1 1 .O% pH: 12.0 Formula 515
74
L i q u i d A b r a s i v e C 1e a n s e r Inqredients: Water, t a p C a l c i u m c a r b o n a t e , 100 mesh Sodium t a l l o w soap, f l a k e s A l p h a - S t e p MC-48 N i n o l 11-CM Sodi um C h l o r i d e
Wt%
48.5 42.5 2.0 2.5 2.0 2.5
M i x i ng P r o c e d u r e : Charge warm w a t e r and add c a l c i u m c a r b o n a t e w h i l e m i x i n g . Add soap and m i x u n t i l d i s p e r s e d . Add MC-48 and 11-CM and m i x u n t i l homogeneous. Add sodium c h l o r i d e t o t h i c k e n .
P r o p e r t i es : Appearance: Opaque, o f f - w h i t e creamy l i q u i d pH, a s i s : 9 . 3 V i s c o s i t y @ 25 deg C . : t h i x o t r o p i c s p i n d l e #3, 6 rpm, B r o o k f i e l d : 4520 c p s s p i n d l e #3, 12 rpm, B r o o k f i e l d : 3840 c p s s p i n d l e # 3 , 30 rpm, B r o o k f i e l d : 3060 c p s S o l i d s , % : 50 D e n s i t y , l b s / g a l : 11.69 S t o r a g e a t a m b i e n t temp, 1 week: N o s e p a r a t i o n Use I n s t r u c t i o n s : Use as i s
Performance: C l e a n s g r e a s e p e n c i l , s c u f f marks and l i p s t i c k f r o m v i n y l t i l e s s i m i 1 a r t o commerci a1 p r o d u c t s .
SOURCE: S t e p a n C o . :
F o r m u l a t i o n No. 3 1 4 T i l e and Sani t a r v C l e a n e r s
Inqredi ents: Z u s o l a t 1008/85 Water Xanthan Gum C i t r i c acid Inqredients: Amphotensid B 4 Water Citric acid
Wt%
5.0 79.6 0.4
15.0
Wt%
30.0 60.0 10.0 Suggested F o r m u l a t i o n s
SOURCE: Zschimmer & Schwarz GmbH & Co.: CT 02-10-03 and CT 02-10-04
Hand Sutface Cleaners
75
L i q u i d Hard Surface Cleaner Ingredients: A : Van Gel ES, Magnesium Aluminum S i l i c a t e Rhodopol 23, Xanthan Gum D e i o n i z e d Water
Wt%*
4.00 0.50 68.50 0.50 2.50 1.25 0.75 21 .oo
0 : Cocamide DEA (Monamid 150-ADD) A1 k o x y l a t e d F a t t y A l c o h o l (P1 u r a f a c C-17) T e t r a p o t a s s i um P y r o p h o s p h a t e P o t a s s i u m Phosphate T r i b a s i c D e i o n i z e d Water
C: Ammonium H y d r o x i d e , 28%
1 .oo
Procedure: 1 . D r y b l e n d t h e Van Gel ES and Rhodopol 23 and s l o w l y add them t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 r p m . C o n t i n u e m i x i n g f o r 40 m i n u t e s . 2. Combine t h e P a r t B i n g r e d i e n t s w i t h s l o w s t i r r i n g . 3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o produce a s l i g h t v o r t e x . 4 . Add P a r t I3 t o P a r t A, m i x f o r 5 m i n u t e s and t h e n add P a r t C and m i x f o r 5 m i n u t e s . F o r m u l a t i o n No. 303 Hard Surface C l e a n e r - A l l Ingredients: A : Veegum, Magnesi um A1 umi num S i 1 i c a t e Rhodopol 23, Xanthan Gum D e i o n i z e d Water Purpose
W t .%* 1.20 0.40 48.40
B : Calcium Carbonate
C:
40.00
C12-CI3 L i n e a r P r i m a r y A l c o h o l E t h o x y l a t e (Neodol 23-6.5)

Cocamide DEA ( N i n o l 40-CO) P r e s e r v a t i v e , Dye, F r a g r a n c e
9.00 1 .oo q.s.
Procedure: 1 . D r y b l e n d t h e Veegum and Rhodopol 23 and s l o w l y add t h e b l e n d t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 rpm. C o n t i n u e m i x i n g f o r 20 m i n u t e s . 2 . Add P a r t B and m i x f o r 10 m i n u t e s . 3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o produce a s l i g h t v o r t e x . 4 . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5 m i n u t e s a f t e r each a d d i t i o n . F o r m u l a t i o n f r o m S h e l l Chemical Co. AS r e c e i v e d b a s i s
SOURCE:
R . T . V a n d e r b i l t Co., I n c . : Van Gel and Veegum i n H a r d S u r f a c e C l e a n e r s and P o l i s h e s : Suggested F o r m u l a t i o n s
76
M o l d and M i l d e w Remover Carbopol r e s i n s a r e used t o v e r t i c a l c l i n g when s p r a y e d on "no-drip" a c t i o n w i l l increase g e n t on t h e s o i l e d s u r f a c e and reduce s p l a s h i n g and t o p r o v i d e a v e r t i c a l surface. This the contact time o f the deterenhance consumer c o n v e n i e n c e .
I n p r e d ie n t : D I water Carbopol 672 ( 1 ) Sodium h y d r o x i d e (50%) Sodium m e t a s i l i c a t e , p e n t a h y d r a t e P r i m a r y a l k a n e s u l f o n a t e (40%) ( 2 ) Sodium h y p o c h l o r i t e (15.00%) B r o o k f ie l d v i s c o s i t y (RVT-PO P r o d u c t p H : 12-13 P r o d u c t c l a r i t y : Opaque rpm) : 120 cps
\Rlt%
84.50 1 .00 2.00 0.50 5.00
7.00
( 1 ) BFGoodrich ( 2 ) Stepan C o . :
B i o - T e r g e PAS-8S
Procedure : 1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i ng and b l e n d i ng o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Under moderate a g i t a t i o n , add t h e sodium h y d r o x i d e and t h e metasilicate. 3. Add t h e a l k a n e s u l f o n a t e . 4 . Under l o w a g i t a t i o n , add t h e sodium h y p o c h l o r i t e b l e a c h . 5 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Total Actives: Primary alkane sulfonate: Available chlorine: 2.0 1.0
SOURCE:
DET-320
Laundry Products
77
78
Detergent f o r Fine Fabrics-1 Powder Inpredi ents: Genapol OA-080 DDBS-Na* Thermphos NW T a l l o w soap, Powder Sodi um d i s i 1 i c a t e S o k a l a n CP 5 S o k a l a n HP 22 A q u a m o l l i n BC Powder Perfume Sodi um s u l p h a t e
Q
3.0 15.0 25.0 1 .O-3.0 3.0
1 .o 1 .o 0.5 q.s.
ad 1 0 0 . 0
Manufacturing: To b e p r e p a r e d by s p r a y m i x p r o c e s s . T h e r e f o r e DDBS-Na must b e employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s not suitable. *DDBS=Dodecyl Benzene S u l p h o n a t e Detergent f o r Fine Fabrics-2 Powder Inqredients: Genapol OA-080 DDBS-Na* Z e o l i t h A (Wessalith T a l l o w soap, Powder Sodi um d i s i 1 ic a t e S o k a l a n CP 5 S o k a l a n HP 22 Aquamoll i n BC Powder Perfume Sodium s u l p h a t e
Wt% 3.0 15.0 20.0-25.0 1.0- 3.0 3.0 2.0- 3.0

1 .o 0.5
q.s. ad 100.0
Manufacturing: To b e p r e p a r e d b y s p r a y m i x p r o c e s s . T h e r e f o r e DDBS-Na must b e employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s not suitable. *DDBS=Dodecyl Benzene S u l f o n a t e
SOURCE: H o e c h s t A k t i e n g e s e l l s c h a f t :
Laundry Products
79
Heavy D u t y L a u n d r y Ingredients: Wei q h t % Water 28.90 Sodi um H y d r o x i d e , 50% 6.60 Calamide C 7.00 P i l o t SXS-40 12.50 40.00 Cal s o f t LAS-99 Cal o x y l a t e N - 9 5.00 Comments a b o u t t h i s f o r m u l a : Add C a l o x y l a t e N - 9 a f t e r 50% o f LAS-99 has been n e u t r a l i z e d . F o r m u l a t i o n HDL-001-01 Heavy D u t y L a u n d r y Inqredients: Water P i l o t SXS-40 Calamide C T W Sodium S i l i c a t e ( S o l i d ) C a l s o f t L-60 EDTA (Ethylenediaminetetraacetic A c i d ) Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HDL-006-01 Heavv D u t y L a u n d r y Wei o h t % 42.50 22.50 4.00 3.01 18.00 2.50
I n q r e d ie n t s : Water C a l f a x DB-45 C a l o x y l a t e N-9 P r o p y l ene G1 y c o l TKPP ( T e t r a P o t a s s i um Pyrophosphate) Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HDL-007-01

Heavv D u t y L a u n d r y Inqredients: Water TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) Sodium S i l i c a t e ( S o l i d ) C a l s o f t L-60 P i l o t SXS-40 Calamide C T W Comments a b o u t t h i s f o r m u l a : May need t o be h e a t e d t o s o l u b i l i z e t h e s u r f a c t a n t . F o r m u l a t i o n HDL-008-01
Weight% 78.50 7.00 7.00 2.50 5.00
Wei q h t % 42.00 15.00 10.00 18.00 10.00 5.00
SOURCE:
P i 1o t Chemical
Co. : Suggested Formul a t i ons
80
I
Components: Water T r i e t h a n o l ami ne 85% D i e t h y l ene G1 y c o l B u r c o l 117 B u r c o l LAF-6 Burcowi t e BBH-PO B u r c o t a s e SL-160
& I L i q u i d Laundrv Detergent w i t h Enzyme & O p t i c a l

% by Weisht
50.00 3.25 20.00 10.00 10.00 1.25 0.50
B u r c o LAF-6 i s used t o c o n t r o l foam as w e l l a s t o p r o v i d e w e t t i n g and d e t e r g e n c y . Procedure: Charge 1 / 2 o f w a t e r I3 120F. Add 1 , 2 , 3 , & 4 and b l e n d . Add r e m a i n i n g w a t e r . Cool t o 1OOF. Add 5 and 6 . B l e n d u n t i l u n i f o r m . 1% pH: 9 . 5 % s o l i d s : 26 Lbs/gal : 8.66 S u r f a c t a n t R i c h D e t e r g e n t f o r N u r s i n o Homes Ingredients: Water TKPP Sodium M e t a s i l i c a t e P e n t a h y d r a t e B u r c o t e r g e DG-40 B u r c o NPS-876 SXS-40%
% bv W e i q h t 30 5 5
40 10 10
6-8 ounces p e r 100 pounds o f l a u n d r y . Heavy s o i l s may r e q u i r e s l i g h t l y higher levels. SOURCE: B u r l i n g t o n Chemical Co.: Suggested F o r m u l a t i o n s
Powder f o r A u t o m a t i c D i s h w a s h i n n M a c h i n e s Ingredients: A Genapol 2908 B Sodium m e t a s i 1 i c a t e x 5H20 C Sodium c a r b o n a t e Sodi um d i c h l o r o i s o c y a n u r a t e Thermphos N W
YO
by W e i q h t
1 .oo
52.00 10.00 2.00 35.00
Manufacturing: I Spray A on B . I 1 One a f t e r a n o t h e r , t h e components o f C a r e added t o 1 A p p l i c a t i o n : 1-29 d e t e r g e n t / L d i s h w a s h i n g l i q u o r SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n
Laundry Products
81
IndustriaT Heavy Duty Laundry L i q u i d

Carbopol ETD 2691 is t o p r o v i d e p r o d u c t phase s t a b i l i z a t i o n i n t h i s high a l k a l i n i t y i n d u s t r i a l strength cleaner.
I nsredient :
D I water
Wt%
49.00 0.50 18.00 5.50 2.00 5.00 20.00
Carbopol ETD 2691 ( 1 ) 612-15 l i n e a r a l c o h o l , 7 moles EO ( 2 ) Sodium a l k y l b e n z e n e s u l f o n a t e (60%) ( 3 ) Potassium h y d r o x i d e (45%) Sodium m e t a s i l i c a t e , anhydrous T e t r a p o t a s s i u m pyrophosphate P h y s i c a l Pi-opert ie s : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 900 P r o d u c t pH: 14 P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich ( 2 ) S h e l l Chemical C o . : Neodol 25-7 ( 3 ) Stepan Co.: B i o s o f t D-62
PP.0cedure: I . Use a b i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an

i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s . Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 rpm). A l l o w t o mix u n t i l homogeneous and f r e e o f polymer lumps. W i t h s l o w m i x i n g , add i n t h e a l c o h o l e t h o x y l a t e and a l k y l benzene s u l f o n a t e s u r f a c t a n t s . C o n t i n u e a g i t a t i n g and add t h e p o t a s s i u m h y d r o x i d e and metas i li c a t e . Add i n t h e pyrophosphate w i t h minimal a g i t a t i o n t o a v o i d a i r entrapment. Add dyes and f r a g r a n c e , as d e s i r e d . Sodi u a1 k y l benzene sul f o n a t e : m C12-15 l i n e a r a l c o h o l , 7 moles EO: T e t r a p o t a s s i u m pyrophosphate:
2.
3.
4.
5.
Total Wcti ves :

3.30 18.00 20.00
SOURCE:
DET-201
82
I n d u s t r i a l Laundry D e t e r a e n t s H i g h C a u s t i c FormulaComponents: Burco NPS-816 Burcosperse LP B u r c o l i t e BSGH-255 Dequest 2000 50% NaOH
% bv Weiaht 15.0 10.0 5.0 5.0 65.0
Procedure: B l e n d a l l components e x c e p t 50% NaOH. S l o w l y add NaOH w i t h a g i t a t i o n . Keep t e m p e r a t u r e below 1 6 0 F d u r i n g t h e e n t i r e agitation. Mixed B u i l d e r F o r m u l a t i o n Components: Water 45% KOH B u r c o s p e r s e LP TKPP Burco NPS-816 S t a r Grade Sodium S i l i c a t e
% by Weight
31.5 23.5
10.0 10.0 15.0 10.0
Procedure: D i s s o l v e KOH i n w a t e r . S l o w l y add Burcosperse LP w h i l e a g i t a t i n g . Keep t e m p e r a t u r e below 160F. Add TKPP and s t i r u n t i l d i s s o l v e d . Add Burco NPS-816, t h e n S t a r Grade Sodium S i l i c a t e and b l e n d u n t i l u n i f o r m . Use l e v e l s a r e 6-12 ounces p e r 100 pounds, l o a d i n g , temperature, e t c . depending on s o i l
SOURCE: B u r l i n g t o n Chemical Co.,
Washi np P a s t e w i t h 81 e a c h i n g A g e n t Ingredients: Water Sodium t r i p o l y p h o s p h a t e Sodium d i t h i o n i t Xanthan Gum Whi t e - s p i r i t Lumorol 4154 Zusol a t 1005/85
% b y Weiaht 39.0 3.0 12.0 2.0 10.0 30.0 5.0

F o r m u l a t i o n CT 07-06-01
SOURCE:
Zschimmer & Schwarz GmbH & Co.:
Laundry Products
83
L a u n d r y Deteraent-Consumer (Liquid) S o i l - B o d y o i l and p e r s p i r a t i o n , body w a s t e . make-up, S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n Method-Household w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition: Water Fluorescent Brightener C a r b o x y m e t h y l c e l l u l o s e (CMC) * A c r y s o l A S E - I 08 **Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 M o l e s 0 Potassium H y d r o x i d e (45%) ***Sodium C i t r a t e ( a n d / o r C i t r i c A c i d ) K a s i l #6 Potassium S i l i c a t e
EDTA
food s o i l
Wt%
37.6 0.2 0.5 6.0 10.0 2.2 25.0 12.5 5.0 1.o
Enzymes ( P r o t e a s e )
x(
** ***
Rohm & Haas; o r Rhone-Poulenc C o l l o i d 225/35 P o l y a c r y l a t e (40%) Rhone-Poul enc I g e p a l CO-630 A d j u s t p H w i t h c i t r i c a c i d t o m a i n t a i n pH f o r e f f e c t i v e enzyme p e r f o r m a n c e ( i . e . 8 . 5 - 9 . 5 p H ) . L a u n d r y Detergent-Consumer I Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d ) S o i l - B o d y o i l and p e r s p i r a t i o n , body w a s t e , f o o d s o i l , S u r f a c e - C o t t o n and c o t t o n - p o l y e s t e r A p p l i c a t i o n Method-Household w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r make-up
Composition : Water C a r b o p o l 674 D L i q u i d Sodium S i l i c a t e * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) Sodium C a r b o n a t e V a l f o r 100 Z e o l i t e A * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-.13, EO 6 . 5 M o l e s )
t:
Wt%
52.6 0.5 8.1 0.9 9.1 24.5 4.3
**
Rohm & Haas S h e l l Chemical Neodol 23-6.5
SOURCE:
PQ C o r p . :
Detergent Formulary Guide
84
Laundry Detergent-Consumer ( Z e r o Phosphate, Powder) S o i l - A c i d i c f o o d f a t , o i l grease, b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n - p o l y e s t e r A p p l i c a t i o n Method-Household Washing Machine Manufacture-Dry Blend/Agglomeration Composition: Sodi u Carbonate m B r i t e s i l H20 Hydrous P o l y s i l i c a t e *Acusol 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) * * L i n e a r A 1 k y l benzene S u l f o n a t e (LAS) * * * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) V a l f o r 100 Z e o l i t e A Sodi u S u l f a t e m O p t i c a l B r i g h t e n e r , Perfume Use L e v e l :
Wt9/o
30.0 10.0 2.0 10.0 5.0 30.0 12.5 0.5
1000 ppm d e t e r g e n t d e l i v e r e d t o wash ( 1 gram d e t e r g e n t / l i t e r o f water)
* **
***
Rohm & Haas Stepan Nacconol 9OG (90% a c t i v e ; powder) Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7
Laundry Detergent-Consumer (Phosphate, Powder) S o i l - A c i d i c f o o d f a t and p r o t e i n , body p e r s p i r a t i o n , dirt Surface-Polyester, cotton/polyester, cotton A p p l i c a t i o n Method-Household washing machine Manufacture-Dry blend/agglomeration Composi t i on : B r i t e s i l H20 Hydrous P o l y s i l i c a t e *STPP *Sodium Carbonate Sodi u S u l f a t e m * * L i n e a r A1 k y l benzene Sul f o n a t e (LAS) * * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; O p t i c a l B r i g h t e n e r , Perfume Use L e v e l : g r a s s and
C12-15)
Q 10.0 30.0 30.0 14.5 10.0 5.0 0.5 of
1000 ppm d e t e r g e n t d e l i v e r e d t o wash ( 1 g r a m / l i t e r water)
* ** ***
FMC Stepan Nacconol 90G (90% a c t i v e ; powder) Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Co. Neodol 25-7
Laundry Products
85
Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l ( L i q u i d , Phosphate1 S o i l - A c i d i c f o o d f a t , o i l a n d g r e a s e ; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition A : Water TKPP P o t a s s i urn H y d r o x i d e (45%) S t a r Sodium S i l i c a t e Sodium H y d r o x i d e (50%) C o m p o s i t i o n B: Water TKPP P o t a s s i u m H y d r o x i d e (45%) S t a r Sodi um S i 1 i c a t e Sodium H y d r o x i d e (50%) Use D i l u t i o n : Light Soil: 34.1 10.0 30.4 18.0 7.5
wts/, 25.6 10.0 30.4 24.0 10.0
0.25% by w e i g h t o r 1 l b p e r 100 l b s 1a u n d r y Medium t o Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2 l b s p e r 100 l b s l a u n d r y N o t e : Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s o f b u i l d e r t o 1 p a r t d e t e r g e n t . Laundry B r e a k - I n d u s t r i a l (Liquid)
& Institutional
S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition: Water N C l e a r Sodium S i l i c a t e Sodium H y d r o x i d e (50%) Use D i l u t i o n : Light Soil:
%
0-20 70-90 10-20
0.25% b y w e i g h t o r 1 l b p e r 100 l b s 1a u n d r y Medium/Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2 l b s p e r 100 l b s l a u n d r y Notes: Blend t h i s b u i l d e r s o l u t i o n t o 1.7-2.0 r a t i o Si02/Na20 b w f o r b e s t s t a b i l i t y and i n d u s t r i a l d e t e r g e n c y . D o r BJ-120 sodium s i l i c a t e s c a n a l s o b e used as b u i l d e r solutions without blending. Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t . SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
86
Advanced Cleaning Product Formulatiom
Laundry D e t e r s e n t - I n d u s t r i a l & I n s t i t u t i o n a l (NTA/Zeol it e , P o w d e d S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Dry blend/Agglomeration Composi t i on : M e t s o Beads 2048 Sodi um C a r b o n a t e NTA * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles V a l f o r 100 Z e o l i t e A 25.0 38.0 15.0 12.0 10.0
EO; C 1 2 - 1 5 )
Use L e v e l : L i g h t S o i l - O . 2 5 % b y w e i g h t o r 1 l b p e r 1 0 0 l b s 1a u n d r y Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s 1a u n d r y Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y or f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 L a u n d r y B r e a k - I n d u s t r i a1 & I n s t i t u t i o n a l ( Z e r o Phosphate, Powder) S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine M a n u f a c t u r e - U s e as r e c e i v e d
Composi t i on : M e t s o Beads 2048 Use D i l u t i o n :
Wt46
100.0
L i g h t S o i l - O . 2 5 % by w e i g h t o r 1 l b p e r 1 0 0 l b s 1a u n d r y Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - O . 7 5 % by w e i g h t o r 3 l b s p e r 100 I b s 1a u n d r y at
N o t e : Use i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) 2-4 p a r t s b w o f b u i l d e r w i t h 1 p a r t d e t e r g e n t .
Laundqi Products
87
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Phosphate, Powder) S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry blend/Agglomeration WtO/o Composition: Metso Beads 2048 25.0 35.0 *Sodium C a r b o n a t e *STPP 30.0 10.0 * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 m o l e s EO; C12-15) Use L e v e l : L i g h t Soi 1-0.25% b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y Medium S o i l - O . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspendi n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n c r e a s e t h e s u r f a c t a n t adosrbency o f d e t e r g e n t b l e n d . x< FMC Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7
**
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Sodium Carbonate, Powder) S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry blend/Agglomeration Q Composi t i on : Metso Beads 2048 25.0 55.0 Sodium C a r b o n a t e Sodi um S u l f a t e 10.0 * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 10.0 Use L e v e l : L i g h t Soi 1-0.25% b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d . ' k Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 SQURCE:
PQ G o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
88
Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l (Phosphate. Powder, H i g h A l k a l i n i t y ) S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry b l end/Agglomeration Wt% Composition A : 60.0 Metso Beads 2048 Sodium H y d r o x i d e Beads 40.0 Composition 8: Wt% Metso Beads 2048 30.0 *STPP 20.0 *Sodium Carbonate 28.0 Carboxymethylcellulose 2.0 20.0 Sodium H y d r o x i d e Beads Use D i l u t i o n : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s 1aundry Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 1 0 0 I b s 1aundry Heavy S o i l - 0 . 7 5 % by w e i g h t o r 3 l b s p e r 1 0 0 lbs 1aundry Note: Use t h e s e a l k a l i b u i l d e r s i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r w i t h 1 p a r t detergent FMC
Laundrv B r e a k - I n d u s t r i a1 8, I n s t i t u t i o n a l ( Z e r o Phosphate Powder, H i ah A1 k a l in i t v ) S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry blend/Agglomeration Wt% Composi t i on A : Metso Beads 2048 60.0 Sodium H y d r o x i d e Beads 40.0 Composition 8: W S Metso Beads 2048 30.0 Sodi u Carbonate m 28.0 Carboxymethylcel l u l o s e 2.0 20.0 Sodium H y d r o x i d e Beads V a l f o r 100 Z e o l i t e A 20.0 Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 I b s 1aundry Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 0 0 l b s 1aundry N o t e : Use t h e s e a l k a l i b u i l d e r s i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2 - 4 p a r t s bw o f b u i l d e r w t h 1 p a r t detergent SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundry Products
89
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Reduced Phosphate, Powder) S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Dry blend/Agglomeration Composition: Wt% 25.0 M e t s o Beads 2048 35.0 *Sodium C a r b o n a t e 20.0 *STPP 10.0 % * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 m o l e s EO; C12-15) 10.0 V a l f o r 100 Z e o l i t e A Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 1 0 0 l b s l a u n d r y Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s 1a u n d r y Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspendi n g / e m u l s i f y i ng power i s needed. B r i t e s i 1 H20 w i 11 a1 so i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d . 9 6 FMC dc* Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l (NTA, Powder) S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a1 washi ng machine Manufacture-Dry blend/Agglomeration Composi t i on : Wt% M e t s o Beads 2048 25.0 Sodium C a r b o n a t e 40.0 NTA 25.0 10.0 * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) Use L e v e l : L i g h t S o i l - 0 . 2 5 % b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s 1a u n d r y N o t e : U s e B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l also i n crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d . *Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7
SOURCE:
PQ C s r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
90
Laundry D e t e r q e n t - I n d u s t r i a l B I n s t i t u t i o n a l (Sodium Carbonate w i t h F l o w A i d . Powder) S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r Appl ic a t ion Method-I n d u s t r ia1 wash ing mach i ne Manufacture-Dry blend/agglomeration Composi t ion : Metso Beads 2048 Sodium Carbonate Sodi um S u l f a t e * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C 1 2 - 1 5 ) V a l f o r 100 Z e o l i t e A Use L e v e l : 20.0 55.0 10.0 10.0 5.0
Wt%
L i g h t S o i l : 0.25% by w e i g h t o r 1 l b p e r 1 0 0 l b s 1aundry Medium S o i l : 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s 1 aundry Heavy S o i l : 0.75% b y w e i g h t o r 3 l b s p e r 100 l b s 1 aundry
Note: Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more susp e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 Laundry D e t e r g a n t - I n d u s t r i a l & I n s t i t u t i o n a l IPhosphate, S o l i d Block) S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a1 washing machine Manufacture-Sol i d b l o c k
Composi t i on : Metso Beads 2048 NaOH ( 5 0 % S o l u t i o n )
Wt%
25.0 25.0 35.0 12.0
*STPP
*Sodium Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; C12-15)
3.0
* **
F C M Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7
SOURCE:
PQ C o r p . :
Laundry Products
91
Laundry D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l (Zero Phosphate, Powder) S o i l - A c i d i c f o o d f a t , o i l g r e a s e , b l o o d , sebum and body w a s t e S u r f a c e - C o t t o n and c o t t o n p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Dry Blend/Agglomeration
Wt% Composition : Sodi um C a r b o n a t e 35.0 15.0 * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles 0 ; C12-15) V a l f o r 100 Z e o l i t e A 25.0 M e t s o Beads 2048 25.0 Use L e v e l : L i g h t S o i l - 0 . 2 5 % b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y Medium S o i l - O . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a1 k a l in i t y is d e s i r e d and more s u s p e n d i n g / e m u l s i f y i n g powder i s needed. B r i t e s i l H20 w i l l a l s o i n crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t blend. *Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7
L a u n d r y D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l ( Z e r o Phosphate, Powder) S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine M a n u f a c t u r e - D r y B1 end/Aggl o m e r a t i on Composi t ion : Wt% Sodium C a r b o n a t e 44.5 * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 18.0 30.0 V a l f o r 100 Z e o l i t e A * * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) 2.5 5.0 M e t s o Beads 2048 Use L e v e l : L i g h t S o i 1-0.25% b y w e i g h t o r 1 l b p e r 1 0 0 l b s l a u n d r y Medium S o i l - O . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d . Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 Rohm & Haas
**
SOURCE:
PQ Corp. : D e t e r g e n t F o r m u l a t i o n G u i d e
92
Laundry D e t e r q e n t - I n d u s t r i a l & I n s t i t u t i o n a l [ P h o s p h a t e B u i 1t , L i q u i d ) S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, make-up, S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition A: Water TKPP P o t a s s i u m H y d r o x i d e (45%) S t a r s o Sodium S i l i c a t e Sodi um H v d r o x i d e ( 5 0 %.) , *PhosphaGe E s t e r **Liquid Nonionic Surfactant food s o i l
Wt%
54.5 4.6 13.7 15.0 4.2 5.0 3.0
(C12-C15,
7-9 M o l e s 0 )
C o m p o s i t i o n B: Wt% Water 59.1 P o t a s s i u m H y d r o x i d e (45%) 13.7 S t a r s o Sodi um S i 1 i c a t e 15.0 Sodium H y d r o x i d e ( 5 0 % ) 4.2 *Phosphate E s t e r 5.0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-C15, 9 Moles EO) 3.0 Use D i l u t i o n : 0 . 2 5 % - 0 . 5 0 % b y w e i g h t or 1-2 l b s p e r 1 0 0 l b s 1a u n d r y Rhone-Poulenc Rhodafac RE-610 Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9
* **
Laundry D e t e r g e n t - I n d u s t r i a l ( L i quid)
& Institutional
food soi 1
Soi 1-Body o i 1 and p e r s p i r a t i o n , body w a s t e , make-up, S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
wts/, Composition: 28.7 Water 0.1 F1 u o r e s c e n t B r i g h t e n e r C a r b o x y m e t h y l c e l l u l o s e (CMC) 0.5 * A c r y s o l ASE-108 ( A c r y l i c P o l y m e r ) 6.0 **Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-1 0 M o l e s EO 10.0 2.2 P o t a s s i um H y d r o x i d e (45%) TKPP (60%) 40.0 K a s i 1 #6 P o t a s s i um S i 1 i c a t e 12.5 Use D i l u t i i o n : 0.25%-0.50% by w e i g h t or 1-2 l b s p e r 1 0 0 I b s 1a u n d r y Rohm & Haas; or Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e (40%) **Rhone-Poulenc I g e p a l CO-630
Detergent Formulary Guide
Laundry Products
93
Laundry B u i l d e r - I n d u s t r i a l (L iquid)
& Institutional
S o i l - A c i d i c f o o d , f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition A : P o t a s s i u m H y d r o x i d e (45%) i C l e a r o r E Sodium S i l i c a t e U C o m p o s i t i o n B: Water Potassium Hydroxide ( S o l i d ) N C l e a r or E Sodium S i l i c a t e Composition C: Water Potassium Hydroxide ( S o l i d ) N C l e a r o r E Sodium S i l i c a t e Sodium H y d r o x i d e ( S o l i d ) Use D i l u t i o n : Light Soil:
Wt%
35-45 55-65
Wt%
11.0 37.0 52.0
Wt%
6.0 28.0 52.0 14.0
0.25% by w e i g h t o r 1 l b p e r 100 l b s 1a u n d r y Medium t o Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2 l b s p e r 100 l b s l a u n d r y
N o t e : Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l ( Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d ) S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, f o o d s o i l , S u r f a c e - C o t t o n and. c o t t o n - p o l y e s t e r a c h i ne A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing Manufacture-Mix t a n k w i t h p r o p e l l e r s t r r e r Composition: Water C a r b o p o l 674 Metso Beads 2048 *Acusol 445N Sodi um P o l y a c r y a t e (45% s o l d s ) Sodium C a r b o n a t e V a l f o r 100 Z e o l i t e A * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-13; EO 6 . 5 M o l e s )
8
make-up
WtO/o
57.06 0.5 2.7 1.04 9.1 24.5 4.3
**
Rohm 8: Haas S h e l l Chemical Neodol 2 3 - 6 . 5

PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
SOURCE:
94
Laundry P r e s o o t t e r S p r a y a b l e Gel Carbopol ETD 2623 i s used i n t h i s f o r m u l a t i o n t o c o s t e f f e c t i v e l y t h i c k e n t h e s u r f a c t a n t system i n t o a g e l f o r m - which can be a p p l i e d t o t h e f a b r i c by b r u s h o r sprayed on due to C a r b o p a l ' s shear t h i n n i n g n a t u r e . Inaredi ent: D I water Carbopol ETD 2623 ( 1 ) C12-15 l i n e a r a l c o h o l , 3 moles 0 ( 2 ) C12-13 l i n e a r a l c o h o l , 6 . 5 males 0 ( 3 ) EDTA ( t e t r a sodium s a l t ) Sodium h y d r o x i d e (18%) B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 8,300 cps P r o d u c t pH: 7.0-8.0 P r o d u c t c l a r i t y : Opaque ( 1 ) BFGoodrich ( 2 ) S h e l l Chemical Co.: ( 3 ) S h e l l Chemical C o . : Neodol 25-3 Neodol 23-6.5 83.75 0.20 10.00 5.00 0.50 0.55
Procedure: 1 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Add i n b o t h o f t h e a l c o h o l e t h o x y l a t e s u r f a c t a n t s . M i x u n t i l homogeneous. 3. Add i n t h e EDTA. 4 . Add i n t h e sodium h y d r o x i d e u n t i l t h e pH i s a t t a i n e d . 5 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Total Actives: C12-15 l i n e a r a l c o h o l , 3 moles EO ( 2 ) : C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO ( 3 ) :
10.0 5.0
SOURCE:
BFGoodrich S p e c i a l t y Chemicals: DET-224
Laundry Products
95
Laundry Presootter Sorayable L i q u i d
Carbopol ETD 2 6 2 3 i s used i n t h i s f o r m u l a t i o n t o s l i g h t l y t h i c k e n t h e s u r f a c t a n t system and e n a b l e t h e p r o d u c t t o s t a y i n c o n t a c t w i t h t h e s o i l l o n g e r b y r e d u c i n g seepage t h r o u g h t h e fabric. I n s r e d ie n t :

D I water
Wt%
84.30 0.05 10.00 5.00 0.50 0.15
Carbopol ETO 2623 ( 1 ) C12-15 l i n e a r a l c o h o l , 3 moles 0 ( 2 ) C12-13 l i n e a r a l c o h o l , 6 . 5 moles 0 ( 3 ) EOTA ( t e t r a sodium s a l t ) Sodi u h y d r o x i d e (18%) m B r o o k f i e l d v i s c o s i t y (RVT-20 P r o d u c t pH: 7 . 0 - 8 . 0 P r o d u c t c l a r i t y : Opaque rpm) : 2 5 0 cps
( 1 ) BFGoodri ch ( 2 ) S h e l l Chemical Co.: Neodol 2 5 - 3 ( 3 ) S h e l l Chemical Co.: Neodol 2 3 - 6 . 5
Procedure: I . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 1 5 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
Add i n b o t h o f t h e a l c o h o l e t h o x y l a t e s u r f a c t a n t s . Mix u n t i l homogeneous. 3 . Add i n t h e EDTA. 4 . Add i n t h e sodium h y d r o x i d e u n t i l t h e pH i s a t t a i n e d . 5 . Add c o l o r s o l u t i o n and f r a g r a n c e , as d e s i r e d .
2.
Total Actives: C12-15 l i n e a r a l c o h o l , C12-13 l i n e a r a l c o h o l ,
3 moles EO: 6 . 5 moles EO:
10.0 5.0
SOURCE:
DET-220
96
L i g h t Duty L i q u i d Detergent wej-ghs Ingredients: 48.45 Water 7.50 P i l o t SXS-40 30.00 C a l s o f t L-60 5.00 Calamide C 8.30 C a l foam EA-603 0.60 C a l s o f t LAS-99 0.10 C i t r i c Acid 0.05 Sodium C i t r a t e Comments a b o u t t h i s f o r m u l a : 1 . pH=7.1 2 . Add C i t r i c A c i d i f pH i s h i g h o r Sodium C i t r a t e i f pH i s l o w . 3 . V i s c o s i t y s h o u l d b e 300 c P s . F o r m u l a t i o n LDL-001-01
L i s h t Duty Liquid Detergent Ingredients: Water C a l s o f t L-60 P1 l o t s x s - 4 0 Calamide C C a l f o a m EA-603 C a l s o f t LAS-99 Opaci f i e r Sod1 um C i t r a t e Comments a b o u t t h i s f o r m u l a : 1 . Add e i t h e r C i t r i c A c i d o r C a l s o f t LAS-99 Weight% 22.31 39.70 22.10 7.06 7.35 0.56 0.88 0.04 t o a d j u s t pH t o
7.0-7.2.
2 . S o l i d s 45%. 3 . S u b s t i t u t i n g C a l s o f t L-40 p r o d u c t s o l i d s t o 42%. F o r m u l a t i o n LDL-002-01 for C a l s o f t L-60 w i l l lower
L i g h t Duty L i q u i d Detergent Weight% Ingredients: 18.80 Water 70.00 Calsuds A 10.00 C a l foam ES-303 0.10 Perfume 0.10 K a t h o n CG 1.oo Opaci f ie r Comments a b o u t t h i s f o r m u l a : 1 . I f o p a c i f i e r i s t o be added, w i t h h o l d 5% o f t h e w a t e r 2 . Add t h e o p a c i f i e r t o t h e w a t e r p r i o r t o a d d i n g t o t h e detergent. F o r m u l a t i o n LDL-004-01
SOURCE:
P i l o t Chemical C o . : Suggested F o r m u l a t i o n s
Laundry Products
97
L i g h t -Duty L i q u i d Detergent Ingredi ents : Water C a l s u d s CD-6 P i l o t SXS-40 C a l foam EA-603 Cal s o f t LAS-99 Weight% 50.20 25.00 6.80 10.00
6.00
Comments a b o u t t h i s f o r m u l a : 1 . I n g r e d i e n t s s h o u l d be added i n t h e o r d e r l i s t e d t o a i d i n blending. 2. Sodium C i t r a t e / C i t r i c A c i d s h o u l d be added f o r pH a d j u s t m e n t t o 7+. 3 . S a l t ( S o d i u m o r Ammonium C h l o r i d e ) w i l l r a i s e t h e v i s c o s i t y . F o r m u l a t i o n LDL-006-01
L i g h t Duty L i q u i d Detergent
In g r e d i e n t s : Water P i l o t SXS-40 C a l s o f t T-60 C a l foam ES-303 Calamide C P r e s e r v a t iv e S o d i um C h l o r i d e

Comments a b o u t t h i s f o r m u l a : V i s c o s i t y 275 cPs. Sol i d ~ = 3 2 - 3 3 % pH=6.2 F o r m u l a t i o n LOI-007-01 L i g h t Duty L i q u i d Detergent Ingredients: Water P i l o t sxs-40 L i n e a r A1 coho1 E t h o x y l a t e NaOH, 5 0 % D i e t h a n o l am1 ne C a l s o f t LAS-99 Comments a b o u t t h i s f o r m u l a : S o l 1 ds=30% Good f o r g r e a s y a p p l i c a t i o n s . F o r m u l a t i o n IDL-006-01
Weight% 36.90 5.00 40.00 15.00 2.00 0.10 1 .00
Weight% 65.16 6.29
2.52
2.81 0.43 19.77
SOURCE:
P i l o t C h e m i c a l Co : S u g g e s t e d F o r m u l a t i o n s
98
L i g h t Duty L i q u i d Detergent I n g r e d i ent-sl Water Ammonium C h l o r i d e P i l o t sxs-40 C a l s o f t L-60 Cal foam ES-303 Calamide C C i t r i c Acid P r e s e r v a t iv e Weight% 13.90 2.40 19.60 44.10 15.80 4.00 0.10 0.10
Comments a b o u t t h i s f o r m u l a : 1 . A s i s pH=8.0. 2 . Add C i t r i c A c i d i n p l a c e o f Sodium C i t r a t e t o l o w e r pH. F o r m u l a t i o n LDL-009-01 Ligh-t- D u t y L i q u i d D e t e r q e n t C a l s o f t LAS-99 Based Ingredients: Water NaOH, 50% C a l s o f t LAS-99 P i l o t SXS-40 Cal foam ES-303 C a l o x y l a t e N-9 C i t r i c Acid Opaci f ie r Preservative Comments a b o u t t h i s f o r m u l a : A d d in g r e d i e n t s i n o r d e r 1 is t e d . F o r m u l a t i o n LDL-011-01 L i g h t D u t y L i q u i d Detergent C a l s o f t LAS-99 Based Ingredients: Water NaOH, 50% Cal s o f t LAS-99 Calamide C P i l o t SXS-40 Cal foam ES-303 C a l o x y l a t e N-9 C i t r i c Acid Opaci f ie r Comments a b o u t t h i s f o r m u l a : Add ingredients i n order l i s t e d . F o r m u l a t i o n LDL-012-01 SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s Weight% 52.40 4.40 16.30 5.00 12.50 2.20 6.00 0.10 1.oo Weight% 43.60 5.80 21.70 16.70 3.00 8.00 0.10 1 .oo 0.10
Laundry Products
99
a h t Duty L i q u i d Detergent __ o f t LAS-99 Based Cals

Inaredients; Water C a l s o f t LAS-99 NaOH, 50% Alcohol Ethoxyl a t e Calamide C P i l o t SXS-40 Perfume P r e s e r v a t iv e Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . Formul a t i on LDL-014-01
Dry Cleaner:
Weight% 54.60 16.30 4.35 10.00 2.05 12.50 0.10 0.10
Light DutLLCquid D e t e r E n t Pre-Spot-Water S o l u b l e
Ingredients: Weight% Water 75.70 2.00 Calamide C C a l o x y l a t e N-9 11.00 C a l i mu1 s e PRS 11 .oo C i t r i c Acid 0.20 Perfume & C o l o r 0.10 Comments a b o u t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s i n o r d e r 1 i s t e d . V i s c o s i t y i n c r e a s e s as C a l o x y l a t e N-9 i s added. 2 . A c l e a r p r o d u c t i s o b t a i n e d when a l l i n g r e d i e n t s a r e m i x e d together. 3 . D e t e r g e n t f r a g r a n c e R-1264 can be used i n t h i s f o r m u l a . 4 . Use l e v e l : d i l u t e 8 : l w i t h w a t e r . F o r m u l a t i o n LDY-001-01 Li-ght D u t y Li.qu2d D e t e r g e n t Wool _Wash I c g r e d i ents-: C a l s o f t T-60 C a l ami d e CW-100 C a l f o a m ES-303 C i t r i c Acid Comments a b o u t t h i s f o r m u l a : The room t e m p e r a t u r e v i s c o s i t y i s a b o u t 520 c P s . F o r m u l a t i o n LDY-002-01
--
Wei g h t % 14.15 5.48 39.64 0.13
L i g h t D u t E L i q u j d Detergent Wool Wash We1 g h t % 50.06 49.93
I r e d i g nt s : ng Calsuds A Water Comments a b o u t t h i s f o r m u l a : The room t e m p e r a t u r e v i s c o s i t y i s a b o u t 25 c P s . F o r m u l a t i o n LDY-004-01
SOURCE:
P i l o t Chemical Co. : Stiggested F o r m u l a t i o n s
100
Two Part Industria1 Laundry Deteraents
Break Formulations Hi q h l v A 1 kal ine Break Components: Water Burcosperse LP Burcolite BSGH-255 Dequest 2000 50% NaOH Mixed Builder Break Components: Water 45% KOH Burcosperse LP TKPP Sodi um Si 1 i cate (Star Grade)
%
% by
Weight 5 10 5
5
75
by Weight
40.0
27.5
10.0
10.0 12.5
Procedure: Add components in the order listed. Blend until homogeneous between each addition. Keep temperature below 160F during bl endi ng. Detergent Additive Components: Water Burco NPS-816 Neodol 25-7 Dodecylbenzenesulfonic Acid TEA-85
% by
Weight 60.00 10.00 12.50 11.65 5.85
Procedure: Add components in the order listed. Blend until homogeneous between each addition. Use Level: Break: 4-12 ounces/100 pounds Detergent: 2-4 ounces/100 pounds SOURCE: Burlington Chemical Co., Inc.: Suggested Formulations
Laundry Products
101
U l t r a L i q u i d Laundrv Deterqent Ingredients: Wt% A l p h a - S t e p MC-48 29.0 5.0 Sodi urn 01e a t e Alcohol, Ethoxylate, 7 19.0 Borax 1.3 0.5 3A A l c o h o l P r o p y l ene G1 y c o l 5.0 PVP K-15 0.8 Q . S . t o 100.0 W a t e r , f r a g r a n c e & dye M i x i n g Procedure: Combine A l p h a - S t e p MC-48, p r o p y l e n e g l y c o l , a l c o h o l e t h o x y l a t e and w a t e r w h i l e m i x i n g u n t i l s o l u t i o n i s homogeneous. H e a t t o a p p r o x i m a t e l y 50 deg. C, add sodium o l e a t e and m i x u n t i l s o l u t i o n and i s a g a i n homogeneous. A l l o w m i x t u r e t o c o o l t o room t e m p e r a t u r e and add t h e r e m a i n i n g i n g r e d i e n t s w i t h m i x i n g . A d j u s t p H w i t h c a u s t i c soda o r c i t r i c a c i d i f n e c e s s a r y . Typical Formulation Properties: F o r m u l a t i o n D e s c r i p t i o n : SME/Soap Based HDL pfl: 8-10 V i s c o s i t y : 200-350 c p s Density: 8.6 Appearance: C l e a r , l i g h t y e l l o w 1 q u i d Use I n s t r u c t i o n s : Use 1 / 3 c u p p e r n o r m a l s i z e w a s h l o a d Comment: A l p h a - S t e p MC-48 i s an e x c e l l e n t oap s o l u b i l i z e r t h a t c a n make h i g h soap l e v e l s p o s s i b l e i n f i n i s h e d p r o d u c t s . F o r m u l a t i o n N o . 658 F i n e F a b r i c Wash Ingredients: Wt% Water, D . I . 43.4 A l p h a - S t e p MC-48 46.0 N i n o l 30-LL 4.6 Sodi um c h l o r i d e 6.0 M i x i n g Procedure: Charge w a t e r and MC-48 and m i x . Add 30-LL and m i x u n t i l homogeneous. Add sodium c h l o r i d e t o t h i c k e n . A d j u s t pH w i t h s u l f u r i c a c i d o r sodium h y d r o x i d e as n e c e s s a r y . Properties: Appearance: C l e a r y e l l o w l i q u i d pH, as i s : 7 . 5 V i s c o s i t y @ 25 deg. C, c p s : 220 S o l i d s , %: 2 9 . 0 F r e e z e / t h a w , 3 c y c l e s : pass C o l d s t o r a g e @ 4 deg. C, 1 week: p a s s H i g h temp. s t o r a g e @ 50 deg. C, 1 week: p a s s Density, l b s / g a l : 0.6 Use I n s t r u c t i o n s : Use s m a l l amount f o r hand w a s h i n g o r 1 / 4 cup f o r machine washing. Comment : The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e . F o r m u l a t i o n No. 358 SOURCE: Stepan C o . : Suggested F o r m u l a t i o n s
9. Metal Cleaners and Polish
Metal Cleaners and Polishes
103
Acid Metal Cleaner* The c o m b i n a t i o n o f Veegum and Rhodopol 2 3 suspends t h a a b r a s i v e and p r o v i d e s a s t a b l e , f r e e f l o w i n g c l e a n e r w i t h good v e r t i c a l s u r f a c e c l i n g . Veegum i s p r o t e c t e d a g a i n s t f l o c c u l a t i o n i n t h i s pH 1 c o m p o s i t i o n t h r o u g h base exchange w i t h t h e i m i d a z o l i n e . T e t r a s o d i u m EDTA f a c i l i t a t e s t h i s exchange. Veegum and Rhodopol p r o v i d e s y n e r g i s t i c t h i c k e n i ng w i t h b e t t e r v i s c o s i t y s t a b i l i t y and i n h i b i t i o n o f s y n e r e s i s t h a n i s p o s s i b l e w i t h e i t h e r t h i c k e n e r a l o n e . Diatomaceous E a r t h p r o v i d e s good c l e a n s i n g and p o l i s h i n g . Inqredients: Veegum Rhodopol 23 Water
y &
0.8 0.4 72.1 0.9 0.8 15.0 10.0
A:
6: T e t r a s o d i u m EDTA 1 - H y d r o x y e t h y l - 2 - c a p r y l i m i d a z o l i ine Phosphoric a c i d Diatomaceous E a r t h
Procedure: S l o w l y add them t o t h e w a t e r w h i l e B l e n d Veegum and Rhodopol a g i t a t i ng a t maximum a v a i 1ab e s h e a r . C o n t i n u e m i x i n g u n t i l smooth. Add B i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each a d d i t i o n u n t i l smooth and un f o r m ( a v o i d i n c o r p o r a t i o n o f a i r )
Consistency:
White,
pourable l i q u i d .
Suggested P a c k a g i n g : P l a s t i c squeeze b o t t l e w i t h p r e c a u t i o n a r y labeling f o r acid. *U.S. P a t e n t No. 4,302,253
SOURCE:
R.T.
I n c . : F o r m u l a t i o n No. 392
D i ppi ns C1 e a n e r f o r S i 1v e r
Ingredients: Z u s o l a t 1008/85 Thiourea Hydrochloric acid Water
2.5 8.0 3.0 86.5 F o r m u l a t i o n CT 0 2 - 1 5 - 0 2
SOURCE: Zschimmer & Schwarz GmbH & C o . :
104
A1 umi num C1 e a n e r / B r i g h t e n e r T r a d i t i o n a l l y , a n i o n i c s u r f a c t a n t s have o f f e r e d b e t t e r d e t ergency t h e n n o n i o n i c s , b u t were n o t c o m p a t i b l e i n a c i d systems. T h i s f o r m u l a t i o n uses Avanel S - 7 0 , an a n i o n i c m o l e c u l e w h i c h p e r f o r m s even a t v e r y low p H ' s and a i d s i n t h e removal o f s u r f a c e o i l s and d e p o s i t s . U n l i k e n o n i o n i c s , Avanel 5-70 w i l l d i s s o l v e r e a d i l y i n t o the formulation without forming gel p a r t i c l e s thus e l i m i n a t i n g t h e need f o r e x c e s s i v e a g i t a t i o n . T h i s f o r m u l a t i o n can be used f o r o v e r - t h e - r o a d aluminum t r a i l e r s , w i r e wheels on a u t o m o b i l e s o r i n t h e p r e p a r a t i o n o f aluminum f o r a n o d i z i n g and c l eani ng. Inqredients: Dei o n i zed Water Phosphoric A c i d ( 8 5 % ) C i t r i c Acid (50%) N i t r i c Acid (70%) Avanel S-70
Wt%
83.0 6.0
8.0
1.o
2.0
Procedure: Charge t h e w a t e r t o a m i x i n g v e s s e l . Under slow a g i t a t i o n and w i t h due c a r e , add t h e a c i d s t o t h e w a t e r . Add t h e Avanel S - 7 0 and m i x 10 m i n u t e s . NOTE: I f a d d i t i o n a l b r i g h t e n i n g i s r e q u i r e d , t h e n i t r i c a c i d c o n c e n t r a t i o n may be i n c r e a s e d t o 1 . 5 % . F o r m u l a t i o n CM-101 Powdered M e t a l C l e a n i n g C o n c e n t r a t e I n a r e d ients: Sodi u H y d r o x i d e m Sodium Carbonate STPP Avanel 5-70 Procedure: Add i n g r e d i e n t s as l i s t e d . A1 u m i num C1 eaner Ingredients: D e i o n i z e d Water Avanel S - 7 0 T e t r a p o t a s s i u m Pyrophosphate Sodium M e t a s i l i c a t e P e n t a h y d r a t e C a r b i t o l Solvent
85.0 6.0
Wt%
58.5
13.5
20.0 8.0
5.0 1.o
3.0
Procedure: Charge v e s s e l w i t h i n g r e d i e n t s i n t h e o r d e r l i s t e d u s i n g mode r a t e a g i t a t i o n . NOTE: Other Avanel p r o d u c t s c o u l d be used i n t h i s f o r m u l a t i o n t o achieve d i f f e r e n t s u r f a c t a n t c h a r a c t e r i s t i c s .
SOURCE:
P G Industries, P
105
A1 umi num C l e a n e r C o n c e n t r a t e F-498
UhWeight
Water Sodium M e t a s i l i c a t e (Anhydrous) T e t r a Potassium Pyrophosphate (Powder) Mona NF-10
75 10 5 10
Procedure: D i s s o l v e sodium m e t a s i l i c a t e and t e t r a p o t a s s i u m p y r o p h o s p h a t e i n w a t e r w i t h m i x i n g , t h e n add Mona N F - 1 0 . Typical Properties: Appearance : C l e a r 1 iq u i d Cloud P o i n t : 8 8 C Recommended Use D i l u t i o n : 1 t o 4 o z / g a l Aluminum Wash F-499
% By Weiaht
Water Sodium M e t a s i l i c a t e (Anhydrous) T e t r a Sodium Pyrophosphate (Powder) B u t y l Carbi t o 1 Mona N F - I 0
88
2
3 2 5
Procedure: D i s s o l v e sodium m e t a s i l i c a t e and t e t r a sodium p y r o p h o s p h a t e i n w a t e r , t h e n add B u t y l C a r b i t o l and Mona NF-10. Typical Properties: Appearance: C l e a r 1 iq u i d pH: 1 2 . 8 Recommended Use D i l u t i o n : 1 : l O w i t h water
SOURCE: Mona I n d u s t r i e s , I n c . :
106
B u f f i nq Compound Remover Component: Water TEA B u r c o t r o p e 1250 B u r c o s p e r s e LP Borax B u r c o TME B u r c o LAF-6 Add components i n o r d e r l i s t e d . each a d d i t i o n .
%
42.5 20.0 12.5 12.5 5.0 5.0 5.0 B l e n d u n t i l homogeneous between
H o t A1 k a l in e P a i n t S t r i p p e r C o n c e n t r a t e
Compo n e n t s : 45% KOH K a s i l #1 B u r c o HCS-50 NF Add components i n t h e o r d e r l i s t e d . between each a d d i t i o n . SOURCE: B u r l i n g t o n Chemical
a
67 32 1
B l e n d u n t i l homogeneous
Co.,
M e t a l De-Oi 1 in g L i q u i d C o n c e n t r a t e (Liquid) S o i l - Petroleum-based o i l S u r f a c e - M e t a l : S t e e l , c o p p e r , aluminum, e t c . A p p l i c a t i o n Method - Spray a n d / o r i m m e r s i o n Manufacture - Mix tank w i t h p r o p e l l e r s t i r r e r Composi t i on : Water Starso EDTA, T e t r a s o d i u m ( 3 7 % ) Sodi um X y l ene S u l f o n a t e ( 4 0 % ) C9-C11 L i n e a r A l c o h o l , 6 Moles EO C9-C11 L i n e a r A l c o h o l , 2.5 M o l e s EO Use D i l u t i o n : 2%-4% b v SOURCE: The
wtu/,
42.0 12.0 16.0 20.0 3.0
7.0
PQ C o r p . : Suggested F o r m u l a t i o n
107
Cutting O i l
Monalube 215 p r o v i d e s e x c e l l e n t l u b r i c i t y , and e x t r e m e p r e s s u r e p r o p e r t i e s . T h i s f o r m u l a t i o n i s used i n machining, stamping and d r a w i n g f e r r o u s and n o n f e r r o u s m e t a l s . Wt% Innredients: 100 P a l e O i l 95.0 Monalube 215 5.0 Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C1 e a r Amber L i q u i d V i s c o s i ty/4OC: 24 CS Performance Data: Fa1 ex ( D i r e c t S c a l e ) : 2000 Lbs. /56 I n . -Lbs Draw Bead E f f i c i e n c y : 95 Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115 Formul a t ion F-791
Cutting O i 1
Inqredients: 100 P a l e O i l 90.0 Monalube 205 5.0 Monalube 215 5.0 Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C l e a r Amber L i q u i d V i s c o s i t y ( 4 0 C ) : 25 CS Fa1 e x : 2250 Lbs / 6 0 I n . -Lbs Appl i c a t i ons: F o r machi n i ng s t a m p i n g and d r a w i n g . F o r m u l a t i o n F-792
Cutting O i l
Wt% Inqredients: 85.0 100 P a l e O i l Monalube 205 5.0 Monalube 215 5.0 5.0 Monalube 225 Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C1 e a r Amber L i q u i d V i s c o s i t y / 4 0 C : 30 CS Performance Data: F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 7 0 I n . . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115 Appl i c a t i ons: Heavy d r a w i n g and s t a m p i n g F o r m u l a t i o n F-793 SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
108
Cutting O i l
Ingredients: 100 P a l e O i l Monalube 215 Monalube 225
% &
90.0 5.0 5.0
Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. T y p i c a l P r o p e r t ie s : Appearance: C l e a r Amber L i q u i d V i s c o s i t y 40C: 27 CS Performance D a t a : F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./6O I n . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115 Formul a t ion F-794 Cuttina O i l Insredients: 100 Pale O i l Monalube 225
WtO/o
95.0 5.0
Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C1 e a r Amber L i q u i d V i s c o s i t y 40C: 24 C S Performance D a t a : F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./6O I n . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115 Formul a t ion F-795 Cutting Oi1 Inqredients: 100 P a l e O i l Monalube 215 Monalube 325
Wt%
90.0 5.0 5.0
Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C l e a r Dark Brown L i q u i d V i s c o s i t y 40C: 22 CS P e r f o r m a n c e Data: F a l e x ( D i r e c t S c a l e ) : 2250 L b s . / 5 5 I n . - L b s . F o r m u l a t i o n F-796 SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s
109
Cutting O i l s Semi-Synthetic-Cutting Ingredients: A r i s t o n a t e M-LF Oleic Acid TEA P r o p y l ene G l y c o l Water
Oi1
Wei q h t % 17.77 2.98 2.75 15.04 61.48
Comments a b o u t t h i s f o r m u l a : 1 . M i x a l l of t h e i n g r e d i e n t s , e x c e p t t h e P r o p y l e n e G l y c o l . 2 . Add t h e w a t e r SLOWLY. 3 . Add t h e P r o p y l e n e G l y c o l l a s t . F o r m u l a t i o n SOF-001-01 C u t t i n g O i 1 Concentrate Ingredi ents: Aristonate M D r e s i n a t e 91 I g e p a l CO-430 KOH, 45% O l e i c A c i d , Emersol 2 1 3 O l e i c A c i d Diethylene Glycol Water Wei g h t % 60.60 20.20 0.10 1.25 8.25 7.10 2.50
Comments a b o u t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l . 2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r . F o r m u l a t i o n SOL-001-01 Cutting O i 1 C o n c e n t m e
I ny,,edie n t s : Aristonate M Neodol 2 5 - 3 TEA, 85% Oleic Acid D i e t h y l ene G1 y c o l Water
Weight% 51.80 21.60 4.50 8.50 8.60 5.00
Comments a b o u t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 1 0 0 SUS n a p h t h e n i c o i l . 2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 1 6 0 ppm h a r d w a t e r . F o r m u l a t i o n SOL-002-01
SOURCE:
P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
I 10
G e n e r a l Purpose Machine C l e a n e r T h i s i s an e x c e l l e n t a l l - p u r p o s e c l e a n e r f o r c l e a n i n g a l l t y p e s o f f e r r o u s p a r t s and machine s u r f a c e s . Monacor 4000 i s i n c o r p o r a t e d f o r added c o r r o s i o n p r o t e c t i o n .
I gredients : n Water T r i e t h a n o l a m i ne Monacor 4000 Monami ne CF-1 OOM M o n a t e r i c CyNa-50 T e t r a s o d i u m EDTA (40%) T r i a d i n e 10 ( P r e s e r v a t i v e ) Procedure: Mix t h e i n g r e d i e n t s i n o r d e r a t ambient temperature. between each a d d i t i o n a t moderate speed. Typical Properties: Appearance: C l e a r amber l i q u i d S p e c i f i c G r a v i t y : 1 .06 pH C o n c e n t r a t e : 1 0 . 2 p H o f a 1:10 s o l u t i o n : 9 . 8 Recommended Use D i l u t i o n : 1 : 1 0 w i t h w a t e r Cast I r o n B l o c k : Pass Corrosion Test: 1:10 D i l u t i o n F o r m u l a t i o n F-770
A i r c r a f t C l e a n e r Type I V
69.00 4.00 3.50 6.00 6.00 10.00 I .50

M i x we1 1
The f o l l o w i n g f o r m u l a t i o n uses Monamulse 653-838 as an emuls i f i e r i n a m i l i t a r y s p e c i f i c a t i o n (MIL-C-855706) f o r m u l a t i o n . Inaredient: P a r t A: Monamulse 653-0313 Monami ne 1-76 A r o m a t i c 150 Isopar M (Odorless Mineral S p i r i t s ) Diethylene Glycol Butyl Ether Decanol
vvts/,
7.0 2.7 7.5 7.5 3.5 1.6
P a r t B: T r i s o d i u m Phosphate (Dodecahydrate) 2.7 Water 55.1 P l u r o n i c F98 1.8 Hycar 1422 10.6 Procedure: Add i n g r e d i e n t s o f P a r t A & P a r t 8 s e p a r a t e l y w i t h a g i t a t i o n . Add P a r t B t o P a r t A . A g i t a t e u n t i l u n i f o r m . Typical Properties: Appearance: C1 e a r L i q u i d F o r m u l a t i o n F-784
Inc.:
111
General Purpose S y n t h e t i c F l u i d ( A ) Ingredients: M a s l i p 501 Bas= Maphos 8135 Mazon R I 4 A T r i e t h a n o l a m i n e , 85% B i o c i de Water
Wt96
5.0
8.0 8.0
12.0
0.5 Balance
Procedure: 4 . Add i n g r e d i e n t s as l i s t e d . 2. T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d be f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1:40 ( l i g h t d u t y ) w i t h water t o form a ready-to-use f l u i d . For increased and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 4 A . For i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f l u b r i c a n t o r extreme p r e s s u r e a d d i t i v e . General Purpose S y n t h e t i c F l u i d (BZ Ingredients: M a s l i p 500 Mazon R I 8 B P r o p y l ene G y c o l 1 T o l y t r i a z o l e (Climax) T r i e t h a n o l a m i ne, 85% 8 i o c i de Water
Wt%
38.0
12.0 2.5 2.5 10.0 0.5

Balance
Procedure: 1 . Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d be f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1:40 ( l i g h t d u t y ) w i t h water t o form a ready-to-use f l u i d . For increased r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 8 B . For i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f l u b r i c a n t o r extreme p r e s s u r e a d d i t i v e . Copper M a c h i n i n a F l u i d Ingredients: Macol 5100 Mazon R I 6 Maphos 8135 Potassi u Hydroxide m B i o c i de Water Procedure: Add i n g r e d i e n t s as l i s t e d .
Wt%
15.0
8.0
7.0 6.0 0.5

Balance
SOURCE:
PPG I n d u s t r i e s ,
112
G e n e r a l Purpose S y n t h e t i c F l u i d ( C ) Ingredients: M a s l i p 501 A Mazon R I 8 B Maphos 58 T r i e t h a n o l ami ne, B i o c i de Water
Mle9/0
30.0 12.0 6.0
85%
7.0
0.5
5al ance
Procedure: 1. Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d b e f u r t h e r d i l u t e d f r o m 1:lO ( h e a v y d u t y ) t o 1 : 4 0 ( l i g h t d u t y ) w i t h water t o form a ready-to-use f l u i d . For increased r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 8 8. F o r i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount of l u b r i c a n t o r extreme pressure a d d i t i v e . G e n e r a l Purpose S y n t h e t i c F l u i d ( D ) I n s r e d ients: M a s l i p 501 Base Mazon R I 8 A Maphos 8135 T r i e t h a n o l ami n e , B i o c i de Water
Wt%
12.0 25.0 5.0 12.0 0.5 5 a l ance
85%
Procedure: 1 . Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d b e f u r t h e r d i l u t e d f r o m 1 : l O (heavy d u t y ) t o 1 : 4 0 ( l i g h t d u t y ) w i t h water t o form a ready-to-use f l u i d . For increased r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 8 A . F o r i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f l u b r i c a n t o r extreme pressure a d d i t i v e .
SOURCE:
Inc.:
113
Metal Cleaner (Phosphate, Powder) Soi 1 -Drawing l u b r i c a n t , a n i m a l f a t and g r e a s e Surface-Steel A p p l i c a t i o n Method-Spray M a n u f a c t u r e - D r y b l e n d / A g g l o m e r a t on Composi t i on :
*STPP
*Sodi um C a r b o n a t e **Alkoxylated l i n e a r alcohol nonion c s u r f a c t a n t ( 1ow foam) Metso Beads 2048 Sodi um H y d r o x i d e Beads
10.0 25.0 5.0 30.0 30.0
Use: Heavy d u t y l o w - f o a m i n g m e t a l c l e a n e r w h i c h i s good f o r a spray c l e a n i n g process. Use D i l u t i o n : 0.8-1.5% bw ( 1 - 2 o z / g a l l o n )
**
FMC O l i n P o l y t e r g e n t S-305LF o r Rhone-Poulenc I g e p a l CO-530

A1 umi num C1 e a n e r (Phosphate, Powder)
Soi 1- L i g h t d r a w i n g o i 1 Surface-Aluminum A p p l i c a t i o n Method-Spray washer M a n u f a c t u r e - D r y b l end/Aggl o m e r a t i on Composi t i on : Metso Beads 2048 *STPP *Sodi um B i c a r b o n a t e **Sodium P o l y a c r y l a t e * * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 9-10 Moles EO Use D i l u t i o n : 1.5-3.036 bw ( 2 - 4 o z / g a l )
Wt%
45.0 30.0 20.0 3.0 2.0
* ** ***
FMC Rohm 8 Haas A c u s o l 445ND (92% s o l i d s ) , Rhone-Poul enc I g e p a l CA-630 PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
SOURCE:
114
M e t a l C1 e a n e r (Phosphate. Powder2 S o i l - O i l , d r a w i n g l u b r i c a n t , a n i m a l f a t and g r e a s e Surface-Steel A p p l i c a t i o n Method-Immersion ManufacturekDry blend/Agglomeration Composi t i o m *Sodium C a r b o n a t e *STPP **Octylphenoxy Polyethoxyethanol ( 6 Moles 0 ) Metso Beads 2048 Sodi um H y d r o x i d e Beads Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 o z / g a l l o n )
20.0 8.0 2.0 30.0 40.0
* **
FMC Rhone-Poulenc I g e p a l CA-630 M e t a l C1 eaner (Phosphate, Powder) S o i l - O i l , d r a w i n g l u b r i c a n t , animal f a t and g r e a s e Surface-Steel A p p l i c a t i o n Method-Immersion/electrolytic c l e a n i n g Manufacture-Dry blend/Agglorneration
Com o s i t i o n : TSPF TSP Metso Beads 2048 Sodium C a r b o n a t e * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l (12-13 Moles EO) Sodium H y d r o x i d e Beads Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 o z / g a l )
Wt%
15.0 5.0 35.0 28.0 2.0 15.0
Rhone-Poulenc I g e p a l CA-720
SOURCE: P C o r p . : D e t e r g e n t F o r m u l a t i o n Guide O
115
I Phosphate,
Metal Cleaner Powder 1
S o i 1 - 0 i 1, f a t , p r o t e i n Surface-Stai nless s t e e l A p p l i c a t i o n Method-Cleaning i n p l a c e Manufacture-Dry blend/Agglomeration Composi t i o n A : *STPP *Sodium C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; M e t s o Beads 2048 Sodi um H y d r o x i d e Beads
- mposition Co
3 M o l e s EO)
40.0 12.0 3.0 25.0 20.0
0: *STPP *Sodium C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; Metso Pentabead 20

Use D i l u t i o n :
WtO/o
3 Moles EO)
40.0 12.0 3.0 45.0
1 . 5 - 3 . 0 % bw ( 2 - 4 o z / g a l l o n )
**
FMC Rhone-Poluenc R h o d a s u r f A-24 M e t a l C1 e a n e r ( Z e r o Phosphate, Powder) S o i 1-Oi 1 , d r a w i n g l u b r i c a n t , animal f a t and g r e a s e Surface-Steel A p p l i c a t i o n Method-Immersion M a n u f a c t u r e - D r y b l e n d / A g g l o r n e r a t i on
n : Composi t i o V a l f o r 100 Z e o l i t e A Sodium C a r b o n a t e * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l (9-10 Moles E O ) Metso Pentabead 20 A c u s o l 445ND Sodi um P o l y a c r y l a t e Use L e v e l : 3-6 o z / g a l l o n
g
WtO/o
15.0 38.0 2.0 43.0 2.0
Rhone-Poulenc
I g e p a l CA-630 Detergent F o r m u l a t i o n Guide
SOURCE:
PB C o r p . :
116
Non-Phosphorous Aluminum C l e a n e r T h i s i s a t o t a l l y o r g a n i c , p h o s p h a t e - f r e e aluminum c l e a n e r t h a t p r o v i d e s e x c e l 1e n t c l e a n i ng and b r i g h t e n i ng o f a1 umi num. The Avanel S - 7 0 p r o v i d e s f o r removal o f o r g a n i c s u r f a c e d e p o s i t s and, by s u r f a c e t e n s i o n r e d u c t i o n , b e t t e r c o n t a c t between t h e aluminum s u r f a c e and t h e o r g a n i c a c i d s . I n a d d i t i o n t o i n d u s t r i a l a p p l i c a t i o n s l i k e c l e a n i n g o v e r - t h e - r o a d aluminum t r a i l e r s and aluminum p r i o r t o a n o d i z i n g , t h i s c l e a n e r may also be used i n household a p p l i c a t i o n s such as c l e a n i n g aluminum f l a s h i n g , windows and door f i x t u r e s . Depending on t h e a p p l i c a t i o n , t h i s p r o d u c t may be used i n a D r e s s u r e wash, pump s p r a y o r d i p tank. Inqredients: C i t r i c A c i d , 50% G l u c o n i c A c i d , 50% Avanel S-70 D e i o n i z e d Water, Dye
w.e-l
12.0 8.0 3.0 Balance
Procedure: Charge t h e w a t e r , c i t r i c a c i d , g l u c o n c a c i d and Avanel S - 7 0 M i x w e l l . Ifdye i s t o be added, p a r t o f t h e w a t e r s h o u l d be he d good a g i t a t i o n . The o u t ; and t h e dye added t o t h i s w a t e r w i t d i s s o l v e d dye can t h e n be added t o t h e b a t c h . NOTE: C e r t a i n dyes may n o t be s t a b l e under t h e s e c o n d i t i o n s . Consequently, s h e l f s t a b i l i t y t e s t s s h o u l d be p e r f o r m e d . F o r m u l a t i o n CM-102
A 1 k a l ine A1 u m i num C1 eaner

I n a r e d ie n t s : Dei o n i zed Water Avanel S - 7 0 T e t r a p o t a s s i u m Pyrophosphate Sodium M e t a s i l i c a t e P e n t a h y d r a t e Macol 48 pH ( a s i s ) : 1 1 . 5 - 1 2 . 5 Appearance: C l e a r , w a t e r - w h i t e l i q u i d S p e c i f i c G r a v i t y : 1.05 Procedure: Charge t h e w a t e r and d i s s o l v e t h e b u i l d e r s a l t s under a g i t a t i o n . When d i s s o l v e d , c h a r g e t h e r e m a i n i n g i n g r e d i e n t s . C o n t i n u e m i x i n g f o r a t l e a s t 15 m i n u t e s . NOTE: T h i s a l k a l i n e aluminum c l e a n e r has shown e x c e l l e n t c l eani ng p r o p e r t i e s w i t h o u t c h e m i c a l a t t a c k o f t h e m e t a l . T h i s f o r m u l a t i o n may b e c u t -!:I w i t h water t o prepare a m i l d hard-surface c l e a n e r . F o r m u l a t i o n CM-1034
87.0 4.0 5.0
1.o
3.0
SOURCE:
117
Semi S y n t h e t i c T h i s f o r m u l a t i o n i s p a r t i c u l a r l y u s e f u l f o r heavy m a c h i n i n g and l i g h t d r a w i n g f o r f e r r o u s and s t a i n l e s s s t e e l . Ingredients: 100 P a l e O i l Monalube 320 Monalube 610 Monalube 205 Monalube 215 T r i e t h a n o l ami ne (99%) Monacor BE Water Procedure: Combi ne i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Fa1 ex ( D i r e c t S c a l e ) : 2500 L b s . /50 I n . - L b s . Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Appearance: C l e a r pH: 9 . 6 F o r m u l a t i o n F-797 Semi S y n t h e t i c InQredients: 100 P a l e O i 1 Monalube 320 Monalube 610 Monalube 220 T r i e t h a n o l a m i n e (99%) Monacor BE Water
wt9j0 9.0
wt9j0 9.0
9.0
13.6 0.8 0.8 3.2 5.0 58.6
9.0
13.6 1.6 3.2 5.0 58.6
Procedure: M i x i t e m s 1,2, and 3 u n t i l c l e a r . Add i t e m s 4,5, and 6 . 5% o f c o n c e n t r a t e t o 95% w a t e r f o r m s m i c r o e m u l s i o n . F o r m u l a t i o n c a n be u s e d f o r g r i n d i n g and l i g h t m a c h i n i n g . T y p i ca9 P r o p e r t i es : Appearance : C1 e a r Amber L i q u i d Performance Data ( 5 % i n Water): Appearance: C l e a r L i q u i d
pH:
9.5
S u r f a c e T e n s i o n (dynes/cm): 32 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./45 I n . - L b s . Formul a t ion F-800
Inc.:
I18
Advanced Cleaning Product Forniulations
Semi S y n t h e t i c Inaredients: 100 P a l e O i l Monalube 225 TEA Monalube 610 Water Typical Properties: Appearance: C 1 e a r Amber L i q u i d Performance Data ( 5 % i n w a t e r ) : Appearance: C1 e a r L i q u i d pH: 9 . 0 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2750 Lbs. / 5 5 I n . -Lbs F o r m a c h i n i n g l i g h t s t a m p i n g and d r a w i n g . F o r m u l a t i o n F-799 Semi S y n t h e t i c Inqredients: 100 P a l e O i l Monalube 320 Monalube 610 Monalube 205 T r i e t h a n o l a m i n e (99%) Monacor BE Water
y&
10.0 5.5 7.5 25.0 47.5
Wt%
9.0 9.0 13.6 1.6 3.2 5.0 58.6
Procedure: M i x i t e m s 1 , 2, and 3 u n t i l c l e a r . Add i t e m s 4 and 5 t h e n 6 . 5% o f c o n c e n t r a t e added t o w a t e r f o r m s m i c r o e m u l s i o n . S u g g e s t e d f o r g r i n d i n g and m a c h i n i n g f o r b o t h f e r r o u s and n o n f e r r o u s metals. Typical Properties: Appearance: C l e a r Amber L i q u i d Performance Data ( 5 % i n Water): Appearance: C l e a r L i q u i d pH: 9.5 Surface Tension: 27.0 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 e x ( D i r e c t S c a l e ) : 2500 L b s . /57 I n . -Lbs F o r m u l a t i o n F-801
Inc.:
119
Silver and M e t a l Polish

I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become permanently suspended The r e s i n a1 so p r e v e n t s "creami ng" o r phase separa t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .
~
Insredient: SF96 S i l i c o n e F l u i d (350) ( 1 ) Dow C o r n i n p 20 Release C o a t i n g ( 2 ) S t o d d a r d S o l v e n t (3) P r i f a c 2922 L a u r i c A c i d D I Water Morphol ine Carbopol EZ-2 ( 4 ) Ammoni u h y d r o x i d e m b g o p g l i e K a o l i C l a y (5) ysp c a f Proper+es. B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): P r o d u c t pH: 8.50 Product C l a r i t y : P a s t e
1 .oo 2.00 20.00 2.00
Wt%
43.48
0.86
0.35 0.31 14.00

1 0 , 0 0 0 cps
Raw M a t e r i a l S u p p l i e r s :
( 1 ) General E l e c t r i c ( 2 ) Dow C o r n i n g Corp. ( 3 ) Exxon Corp. ( 4 ) BFGoodrich (5) Kaopolite, Inc. Procedure: 4 . Add t h e s i l i c o n e f l u i d , r e l e a s e c o a t i n g , s o l v e n t , and l a u r i c a c i d P o a v e s s e l . Mix u s i n g a h i g h shear m i x e r . 2 . C o n t i n u e t o m i x , and add t h e water (43.48 p a r t s ) and t h e morphol ine. 3 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r (16.00 p a r t s ) by s i m p l y "dumping" i t i n . The polymer w i l l wet o u t i n a few m i n u t e s . Add t h e d i s p e r s i o n t o t h e above m i x t u r e w i t h good a g i t a t i o n . 4 . Add t h e ammonium h y d r o x i d e t o r e a c h t h e t a r g e t pH. 5 . Add t h e c l a y and mix u n t i l u n i f o r m .
T o t a l A c t ives : Silicone f l u i d : Stoddard s o l v e n t : Re1ease c o a t i ng : Abras i vet
1 .oo 20.00
2.00
14.00
FGoodrich S p e c i a l t y Chemicals: DET-563
120
Soluble O i 1 Ingredients: 100 P a l e O i l Monalube 605 P a r o i l 160
WtO/o
80.0 20.0 20.0
Procedure: Combine a l l i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typi c a l P r o p e r t i es : Appearance: C l e a r Dark Brown Performance Data (5% i n w a t e r ) : Appearance: M i 1 ky L i q u i d pH: 8 . 5 F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 6 0
In.-Lbs.
Above f o r m u l a t i o n f o r heavy d u t y m a c h i n i n g and d r a w i n g f o r use on s t a i n l e s s s t e e l and f e r r o u s m e t a l s . F o r m u l a t i o n F-803
Soluble O i 1
Ingredients: 100 P a l e O i l Monalube 605
Wt%
85.0 15.0
Procedure: Combine above i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 5 0 C . Typical Properties: Appearance: C l e a r L i g h t Brown L i q u i d Performance Data (5% i n w a t e r ) : Appearance: M i 1 ky Emulsion pH: 8 . 8 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 1750 L b s . / 4 7 I n . - L b s . Appl i c a t i o n : For g r i n d i n g and v e r y l i g h t m a c h i n i n g . Formul a t ion F-804
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
121
S o l u b l e Qi 1 Inaredients: 100 P a l e O i l Monalube 6 0 5 Wonalube 2 1 5 T EA
Wt%
78.0 15.0 5.0 2.0
Procedure: M i x above i n g r e d i e n t s w i t h a g i t a t i o n . Warm t o 12OF. I f s o l u t i o n i s s l i g h t l y hazy, a d j u s t w i t h t a l l o i l f a t t y a c i d . Typical Properties: Appearance: M i l k y E m u l s i o n P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: M i 1 ky Emu1 s i o n pH: 8 . 0 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2500 L b s . / 5 5 I n . - L b s . The above f o r m u l a t i o n i s s u g g e s t e d f o r g r i n d i n g and l i g h t machining. F o r m u l a t i o n F-805 Soluble O i 1 Ingredients: 100 P a l e O i l Monalube 6 0 5 Monalube 215
Wt%
85.0 10.0 5.0
Procedure: Combine i n g r e d i e n t s w i t h a g i a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C l e a r Amber L i q u d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Aooearance: M i 1 k v E m u l s i o n pH: 8 . 0 Falex ( D i r e c t S c a l e ) : 1250 Lbs./45
..
In.-Lbs.
The above f o r m u l a t i o n i s s u g g e s t e d f o r g r i n d i n g and l i g h t machining. F o r m u l a t i o n F-806
SOURCE:
Mona I n d u s t r i e s ,
122
Soluble O i l Machining F l u i d Monalube 225 p r o v i d e s l u b r i c i t y , and EP p r o p e r t i e s i n t h i s m a c h i n i n g f l u i d . T h i s f o r m u l a t i o n was d e s i g n e d f o r m a c h i n i n g c a r b o n s t e e l , b r a s s , b r o n z e c o p p e r and s t a i n l e s s s t e e l . Ingredients: N a p h t h e n i c O i l (lOOSUS/lOO) Monalube 225 Monalube 605 T r i e t h a n o l a r n i n e (99%) Procedure: Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . F a l e x EP T e s t : D i r e c t Load S c a l e : 2 7 5 0 l b s Torque: 47 i n c h pounds Use D i l u t i o n s : G r i n d i n g : I-2% i n water L i g h t M a c h i n i n g : 3-5% i n w a t e r M o d e r a t e M a c h i n i n g : 5-7% i n w a t e r Heavy M a c h i n i n g : 8-10% i n w a t e r F o r m u l a F-764 S y n t h e t i c Machininq F l u i d T h i s f o r m u l a t i o n i s i d e a l f o r machining carbon s t e e l , b r o n z e , c o p p e r , aluminum and s t a i n l e s s s t e e l . Ingredients: Monalube 225 T r i e t h a n o l a m i n e (99%) Water Procedure: Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . F a l e x EP T e s t P r o c e d u r e : C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n D i r e c t Load S c a l e 3000 l b s . T o r q u e 60 i n c h pounds Formul a t i on F-766 SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s brass,
Wt%
72.0 5.0 20.0 3.0
wto/, 15.0 30.0 55.0
123
Svnthetic Ingredients: Monalube 210 T r i e t h a n o l a m i n e (99%) Water A n t i foam Procedure: Combine in g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d Performance Data (5% i n Water): Appearance: C l e a r L i q u i d pH: 8 . 5 S u r f a c e T e n s i o n : 42 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 5 6 I n . - L b s . The f o r m u l a t i o n i s d e s i g n e d f o r f e r r o u s and n o n f e r r o u s m e t a l s primarily f o r grinding. Formul a t i on F-819 Synthetic Inqredi ents: Monalube 210 Monalube 315 T r i e t h a n o l a m i n e (99%) Water Procedure.: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 5 6 I n . - L b s . F o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s systems p r i m a r i l y f o r g r i n d i n g . F o r m u l a t i o n F-820
Wt%
16.6 33.3 50.0 0.1
K %
12.5 12.5 25.0 50.0
124
S y n t h e t i c Drawing/Stampinp F l u i d T h i s f o r m u l a t i o n i s i d e a l f o r stamping hot o r c o l d r o l l e d s t e e l . Ingredients: Monalube 225 T r i e t h a n o l a m i n e (99%) Monalube 315 Water Procedure: Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . F a l e x EP T e s t P r o c e d u r e : C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n D i r e c t Load S c a l e 3 0 0 0 l b s . T o r q u e 55 i n c h pounds F o r m u l a t i o n F-765
O i 1 Based Drawi ng/Stampi ng F1ui d
15.0 30.0 20.0 35.0
Monalube 225 p r o v i d e s l u b r i c i t y , EP and c o n t r i b u t e s t o t h e c o r r o s i o n p r o t e c t i o n p r o p e r t i e s i n t h i s heavy-duty stamping/ d r a w i n g f 1u i d . Ingredients: Paraffinic O i l Monalube 225
Wt%
(300SUS/lOO) 90.0 10.0
Procedure: B l e n d Monalube 225 i n t o t h e o i l F a l e x EP T e s t : D i r e c t Load S c a l e : 3000 l b s T o r q u e 57 i n c h pounds F o r m u l a t i o n F-763 S p r a y M e t a l C1 e a n i n g C o n c e n t r a t e Ingredients: Water Sodi um M e t a s i 1 i c a t e Sodium C a r b o n a t e Sodi um H y d r o x i d e M o n a t r o p e 1250 Alkyl Polyal kylene Ether Procedure: Add i n o r d e r l i s t e d w i t h a g i t a t i o n , making s u r e each ingredient i s dissolved before next addition. F o r m u l a t i o n F-751 75.00 3.00 4.00 5.00 11.00 2.00
SOURCE:
Inc.:
125
S y n t h e t i c Formula Inqredients: Monalube 205 Monalube 210 T r i e t h a n o l a m i n e (99%) Water Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C1 e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d
pH:
Wyt
5.0 10.0 30.0 55.0
8.7
S u r f a c e T e n s i o n : 27 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 7 I n . - L b s . T h i s f o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s systems f o r a r e a s o f m a c h i n i n g and g r i n d i n g a t 10% f o r m i l d s t a m p i ng. F o r m u l a t i o n F-813 S y n t h e t i c Formula Inqredients: Monalube 205 Monalube 210 Monalube 315 T r i e t h a n o l ami ne (99%) Water Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C1 e a r Amber L i q u i d Performance Data ( 5 % i n Water): Appearance: C1 e a r L i q u i d pH: 8 . 0 S u r f a c e T e n s i o n : 32 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 5 7 I n . - L b s . T h i s f o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s systems f o r a r e a s o f m a c h i n i n g and g r i n d i n g a t 10% f o r m i l d s t a m p i ng. F o r m u l a t i o n F-814
wt%
5.0 10.0 10.0 30.0 45.0
Inc,:
126
S y n t h e t i c Formula Inqredients: Monalube 2 0 5 Monalube 2 2 0 T r i e t h a n o l a m i n e (99%) Monalube 315 Water Procedure: M i x i t e m s 1, 2 , 3,
w%%
4.5 9.0 27.0 20.0 39.5
and 4 . Add w a t e r and mix u n t i l homogeneous.
Typical Properties: Appearance: C l e a r Amber L i q u i d Performance Data (5% i n W a t e r ) : Appearance: T r a n s l u c e n t S o l u t i o n pH: 9 . 0 Surface Tension: 32 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Falex ( D i r e c t S c a l e ) : 2500 Lbs./47 I n . - L b s . F o r m u l a t i o n F-815 S y n t h e t i c Formula C l e a r product designed f o r f e r r o u s g r i n d i n g . Ingredients: Monalube 210 Mona1ube 1 1 0 Water Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C1 e a r Sol u t i on Performance Data (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d pH: 7 . 5 F a l e x ( D i r e c t S c a l e ) : 2 5 0 0 Lbs./45 N o t e : No TEA needed. F o r m u l a t i o n F-816 15.0
40.0
45.0
In.-Lbs.
Excess DEA i n Monalube 110 n e u t r a l i z e s PE.
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
127
S y n t h e t i c Formula P r o d u c t d e s i gned f o r g r i n d i ng and 1 ig h t m a c h i n i n g Ingredients: Monalube 2 1 0 T r i e t h a n o l a m i n e (99%) Monalube 315 Water Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties : Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d pH: 8 . 0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 5 I n . - L b s . F o r m u l a t i o n F-817 S y n t h e t i c Formula Inaredients: Monalube 215 T r i e t h a n o l ami ne (99%) A n t i foam Water Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 5 S u r f a c e T e n s i o n : 42 bs./44 F a l e x ( D i r e c t S c a l e ) : 2500
Wt%
15.0 30.0 10.0 45.0
Wt%
16.6
33.3
0.1
50.0
In.-Lbs.
P r o d u c t d e s i g n e d f o r machi n ng f e r r o u s and n o n f e r r o u s m e t a l . A l s o some v e r y l i g h t s t a m p i n g . F o r m u l a t i o n F-818
Inc.:
128
S y n t h e t i c Formula Ingredients: Monalube 210 Monoethanol ami ne Water Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d Performance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 1 1 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1ex ( D i r e c t Scal e ) : 2250 Lbs. /58 I n . - L b s . Formulated f o r g r i n d i n g a p p l i c a t i o n s . F o r m u l a t i o n F-821 Ferrous metals o n l y . Q 16.6
33.3
50.4
S y n t h e t i c Formula Ingredients: Monalube 205 T r i e t h a n o l a m i n e (99%) A n t i foam Water Procedure: Combi ne in g r e d i e n t s w i t h a g i t a t i o n . T y p i c a l P r o p e r t i es : Appearance: C l e a r Amber L i q u i d Performance Data (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d pH: 8 . 3 S u r f a c e T e n s i o n (dynes/cm): 24 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1ex ( D i r e c t S c a l e ) : 2500 Lbs / 5 5 In. -Lbs 16.6
33.3
0.1 50.0
T h i s i s t h e most u n i v e r s a l f o r m u l a s i n c e i t can be used on all m e t a l l u r g y a t 1% t o 2%. I t a l s o can be used f o r g r i n d i n g a t 5% t o 8% f o r m a c h i n i n g and a t 8% t o 15% f o r r e a l heavy m a c h i n i n g . F o r m u l a t i o n F-822
SOURCE:
Inc.:
129
S v n t h e t i c Formul a
Inaredi ents: Monalube 205 Monalube 1 1 0 Water Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r S o l u t i o n P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d ptl: 8 . 0 S u r f a c e T e n s i o n : 28 C a s t I r o n B l o c k C o r r o s i o n e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2250 Lbs./5O I n . - L b s . F o r use i n m a c h i n i n g and 1 g h t s t a m p i n g f o r f e r r o u s and nonferrous metals. 10 i s enough t o n e u t r a l i z e t h e NOTE: Excess DEA i n Monalube phosphate e s t e r . F o r m u l a t i o n F-823 *thetic Ingredients: Monalube 2 0 5 Monoethanol ami ne Water Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d
pH:
Wt%
10.0
30.0
60.0
Formula 25.0 25.0 50.0
10
C a s t I r o n B l o c k : Pass Fa1 ex ( D i r e c t S c a l e ) : 2000 Lbs. /50
I n . -Lbs.
F o r f e r r o u s systems f o r m a c h i n i n g and g r i n d i n g . Formul a t ion F-824
Inc.:
130
Synthetic Formulation Inqredients: Monalube 210 Monalube 225 TEA Water Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . T y p i c a l P r o p e r t i es : Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d pH: 8 . 5 S u r f a c e T e n s i o n ( d y n e s / c m ) : 42 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 6 I n - L b s .
For machining,
10.0 10.0 40 0
~
40.0
forming, Forrnul a t i on F-807
and s t a m p i n g a l l m e t a l s
S y n t h e t i c Formulat Inqredients: Monalube 225 Monalube 3 1 0 T r i e t h a n o l ami ne (99%) Water
15.0
25.0
30.0 30.0
Procedure: M i x Monalube 225 w i t h t r i e t h a n o l a m i n e and add Monalube 315. M i x u n t i l c l e a r , t h e n add w a t e r . T y p i c a l P r o p e r t i es : Appearance: C l e a r C o n c e n t r a t e P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 6 S u r f a c e T e n s i o n : 41 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./55 I n . -Lbs F o r heavy d u t y s t a m p i n g o f f e r r o u s m e t a l s a t 1 0 t o 20% i n w a t e r . F o r m u l a t i o n F-808
131
Svnthetic Formulation
I n g r e d i en t s : Monalube 2 0 5 Monalube 210 Monalube 220 T r i e t h a n o l a m i n e (99%) Water

Procedure: M i x i t e m s 1, 2,
5.0 10.0 10.0 50.0 25.0
3 , and 4 . Then add w a t e r .
Typical Properties: Appearance: C l e a r L i q u i d Performance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 9 . 0 S u r f a c e T e n s i o n : 32 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 5 7 I n . - L b s F o r s t a m p i n g , d r a w i n g and b r o a c i n g 10 t o 20% i n w a t e r . Formul a t ion F-809 Synthetic Formulation Inqredients: Monalube 205 Monalube 225 T r i e t h a n o l a m i n e (99%) Water Procedure: Mix items 1, 2,
wtsl,
5.0 10.0 30.0
55.0
3,
and 4 ,
t h e n add w a t e r and m i x .
Typical Properties: Appearance: C1 e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 7 Surface Tension: 35 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2250 L b s . / 5 1 I n . - L b s . Application: F o r f e r r o u s and n o n f e r r o u s systems f o r and s t a m p i n g . F o r m u l a t i o n F-810 mach n i ng, forming,
Inc.:
Suggested Formu a t i ons
132
Synthetic Formulation Inqredients: Monalube 215 Monalube 220 T r i e t h a n o l a m i n e (99%) Water Procedure: Combine in g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d Performance Data (5% i n Water): Appearance: C l e a r L i q u i d pH: 9 . 0 S u r f a c e T e n s i o n : 42 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2500 Lbs. / 4 7 I n . -Lbs Use i n m a c h i n i n g and s t a m p i n g f o r b o t h f e r r o u s and n o n f e r r o u s metallurgy. F o r m u l a t i o n F-811 Synthetic Formulation Inqredients: Monalube 205 Monalube 220 T r i e t h a n o l a m i n e (99%) Water Procedure: Combine in g r e d i e n t s w i t h a g i t a t i o n . T y p i c a l P r o p e r t i es : Appearance: C1 e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 0.7 S u r f a c e T e n s i o n : 35 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 3 5 I n . - L b s . For machining, forming, F o r m u l a t i o n F-812 and s t a m p i n g f o r a1 1 m e t a l 1u r g y Inc.: Suggested F o r m u l a t i o n s
Wt%
9.0 9.0 36.0 46.0
5.0 10.0 30.0 55.0
133
U n i v e r s a 1 S c o u r i na P a s t e Inqredients: A : T y l o s e CBR 10000
WtO/o
5.00 51 . 8 0 21.80 10.70 2.00 0.70 0.00
5: Water (50C)
C: H o s t a p u r SAS 60 Genapol ZRO 1 iq u i d Genapol U D - 0 3 0 K o m p e r l a n KD NaCl Preservative, Perfume
0:
q.s.
M a n u f a c k u r i ng: I. A, w h i c h i s added b y c o n t i n u i n g s t i r r i n g , s h o u l d s w e l l , u n t i l a homogeneous g e l f r e e o f lumps h a s been o b t a i n e d I I . Add one a f t e r a n o t h e r , t h e components o f C t o I . 1 1 1 . F i n a l l y D i s added.
Tests :
V i s c o s i t y ( B r o o k i e l d RVT, sp.
6,
1 0 m i n -1,
25C):
49b00 mPas
SOURCE:
Hoeckst A k t e n g e s e l l s c h a f t :
Suggested F o r m u l a t i o n
A1 u m i n u m C 1 e a n e r Comoosi t i o n : K e l z a n x a n t h a n gum Butyl Cellosolve T e r g i t o l NP Phosphoric A c i d (85%) Citric Acid S o d i um D i c h r o m a t e Water
Wt%
1 .o 4.0
3.0
3.0
4.0 trace 85.0
Procedure: D i s s o l v e K e l z a n x a n t h a n gum i n w a t e r . Add t h e c i t r i c and p h o s p h o r i c a c i d s f o l l o w e d b y 5 u t y l C e l l o s o l v e a n d T e r g i t o l NP. To u s e , s p r e a d e v e n l y on t h e s u r f a c e t o b e c l e a n e d and a l l o w s u f f i c i e n t t i m e f o r t h e c l e a n i n g a c t i o n t o be accomplished.
SOURCE:
Monsanto P e r f o r m a n c e M a t e r i a l s : Formulation
K e l z a n Suggested
134
Water Sol u b l e Stampi ng F1u i d Ingredients: \nit% M a s l i p 501 Base 30.0 Mazon R I 8 B 12.0 D i e t h a n o l ami ne 8.8 1.2 P r o p y l ene G1 y c o l T r i e t h a n o l a m i n e , 85% 10.0 Water Balance Procedure: Add i n g r e d i e n t s as l i s t e d . I f more l u b r i c i t y i s r e q u i r e d , add Macol 5 1 0 0 . I f more c o r r o s i o n i n h i b i t o r i s r e q u i r e d , add more Mazon R I 8 8. Use 1O:l d i l u t i o n r a t e f o r heavy d u t y a p p l i c a t i o n . WD-40 Type L u b r i c a n t C o n c e n t r a t e
I r e d ien t s : nq S-Maz 8 0 Mazawet 7 7 H i t e c E-515 ( E t h y l ) Palmetic Acid S h e l l f l e x 213 S h e l l Sol 135 Procedure: Add i n g r e d i e n t s as l i s t e d .
W
3.7 1.Q 5.2
0.7 10.5 70.9
Penetrating O i l I n a r e d ie n t s : Wt% S-Maz 80 2- 6 Mazon R I 6 7-1 2 M a s i l SF-10 0- 1 0- 1 Nekal WT-27 Gafac RE-40 0- 1 0- 6 I n d o p o l H-100 Odor1 ess M i n e r a S p i r i t s 11 ance Procedure: Add i n g r e d i e n t s as l i s t e d . NOTE: A p o r t i o n o f t h e m i n e r a l s p i r i t s may be d e l e t e d and s u b s t i t u t e d w i t h a n a p h t h e n i c o i l ( 5 - 1 5%). B u r n i s h i n s Compound Ingredients: Mazamide 65 Mafo 1 3 MOD 1 Mazon R I 4 A T r i s o d i u Phosphate m EDTA Water Procedure: Add i n g r e d i e n t s as l i s t e d .
Wt%
10.0 7.0 5.0 7.0 1 .o 70.0
SOURCE:
PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
10. Oven, Grill and Hot Plate Cleaners
136
C a u s t i c Oven C l e a n e r Inaredients: A : Van Gel C, 4 . 8 % Aqueous D i s p e r s i o n Dei o n i zed Water B: Sodium H y d r o x i d e , 50% S o l u t i o n
Wt%*
62.50 45.75 5.00
C:
Butyl Carbitol Aminomethyl P r o p a n o l (AMP-95) Sodium Cocoamphoacetate ( M o n a t e r i c CM-36s) 50% S o l u t i o n
'10.00 1.50 0.25

5.00
D . Sodium H y d r o x i d e ,
Procedure: 1 . Make t h e 4.8% Van Gel C d i s p e r s i o n b y s l o w l y a d d i n g 4 . 8 p a r t s b y w e i g h t o f Van Gel C i n t o 9 5 . 2 p a r t s b y w e i g h t o f w a t e r o f a t room t e m p e r a t u r e , w h i l e m i x i n g w i t h a homogenizer a t 5000 rpm. C o n t i n u e m i x i n g f o r 60 m i n u t e s . Add t h e r e m a i n i n g P a r t A w a t e r t o t h e i n d i c a t e d amount o f d i s p e r s i o n and m i x u n t i l uniform. 2 . S l o w l y add P a r t B and a d j u s t homogenizer speed as r e q u i r e d t o a c h i e v e good m i x i n g o f e n t i r e b a t c h . 3 . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g each u n t i l u n i f o r m . A v o i d e n t r a p m e n t o f a i r and g e n e r a t i o n o f foam. 4. S l o w l y add P a r t D and m i x u n t i l u n i f o r m . F o r m u l a t i o n N o . 461 N o n - C a u s t i c Oven C l e a n e r Inqredi ents: A : Water Van Gel C, Magnesium Aluminum S i l i c a t e Rhodopol 50MD, Xanthan Gum 6 : D i e t h a n o l ami n e Triethanolamine T r i p r o p y l e n e g l y c o l M e t h y l E t h e r (Dowanol TPM) P o t a s s i u m C a r b o n a t e , 25% Aqueous S o l u t i o n Vanseal NACS-30, Sodium L a u r o y l S a r c o s i n a t e
Wt%*
55.00 0.75 0.25 5.00 5.00 5.00 28.00 1.oo
Procedure: 1 . D r y b l e n d t h e Van Gel C and Rhodopol 50MD and add t h e m i x t u r e t o t h e w a t e r w h i l e s t i r r i n g w i t h a homogenizer o p e r a t i n g a t 5000 r p m . C o n t i n u e m i x i n g f o r 30 m i n u t e s . 2 . S l o w l y add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r shown. M i x each f o r 5 m i n u t e s . Package. F o r m u l a t i o n No. 468 *As r e c e i v e d b a s i s SOURCE: R.T. V a n d e r b i l t Co., I n c . : Suggested F o r m u l a t i o n s
Oven, Grill and Hot Plate Cleaners
137
H i g h C a u s t i c Oven C l e a n e r
Carbopol r e s i n s a r e used t o t h i c k e n t h i s h i g h c a u s t i c f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p r o v i d e s v e r t i c a l c l i n g t o i n c r e a s e t h e c o n t a c t t i m e o f t h e d e t e r g e n t on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e . Inaredient: D I Water Carbopol 674 ( 1 ) Potassium h y d r o x i d e (45%) Propylene g l y c o l methyl e t h e r ( 2 ) C8-16 a l k y l p o l y g l y c o s i d e (50%) ( 3 ) B r o o k f i e l d v i s c o s i t y (RVT-20 Product pH: Product c l a r i t y : 8FGoodrich ( 2 ) Dow Chemical : Dowanol PM ( 3 ) Henkel C o r p . : Glucopon 425CS
(1)
Wei Qht P e r c e n t 71.03 69.78 2.00 0.75 22.22 22.22 3.00 3.00 3.00 3.00
rpm) :
250 CPS 13-14 Clear
5,000 CPS 13-14 Clear
Procedure: 1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e DI w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Add t h e p o t a s s i u m h y d r o x i d e w i t h c o n t i n u o u s m i x i n g . 3 . Add t h e g l y c o l e t h e r . 4 . Add t h e APG s u r f a c t a n t . M i x u n t i l homogeneous. 5. Add f r a g r a n c e , as d e s i r e d . Total Actives: Potassium h y d r o x i d e : 10.00 P r o p y l e n e g l y c o l m e t h y l e t h e r : 3.00 C8-16 a l k y l p o l y g l y c o s i d e : 1.50 FGoodrich S p e c i a l t y Chemicals: OET-360
138
Oven C l e a n e r Ingredients: A : Veegum T, Magnesium Aluminum S i l i c a t e Rhodopol 23, Xanthan Gum D e i o n i z e d Water
B:
VVt%*
0.40 1.20 80.40
Sodium H y d r o x i d e , 50% Deceth-4 Phosphate (Rhodafac RA-600)
8.00 10.00
Procedure: 1 . Weigh t h e w a t e r , h e a t i t t o 85-9OC and m i x w i t h an homogenizer a t 5000 rpm. 2 . D r y b l e n d t h e Veegum T and Rhodopol 23 and s l o w l y add them t o t h e w a t e r . C o n t i n u e m i x i n g f o r 20 m i n u t e s . 3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o p r o d u c e a s m a l l v o r t e x . Cool t o 55C. 4 . Add t h e P a r t B i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5 m i n u t e s a f t e r each a d d i t i o n . NOTE: I t i s p a r t i c u l a r l y i m p o r t a n t t h a t t h e Sodium H y d r o x i d e s o l u t i o n be added v e r y s l o w l y w i t h good m i x i n g o f t h e e n t i r e batch. F o r m u l a t i o n f r o m Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s A e r o s o l Oven C1 e a n e r Ingredients: A : Veegum T, Magnesium Aluminum S i l i c a t e Dei o n i zed Water
8 : n-Methyl
W t %* 1 .50 74.25
P y r r o l i d o n e (M-Pyrol) 20.00 D i s o d i u m C o c o a m p h o d i p r o p i o n a t e ( M i r a n o l C2M-SF C o n c . ) 3.25 Nonoxynol ( I g e p a l CO-630) 1 .oo
Procedure: 1 . Weigh w a t e r and p l a c e on h o m o g e n i z e r . 2 . D i s p e r s e t h e Veegum T i n t h e w a t e r u s i n g a homogenizer a t 5000 r p m . C o n t i n u e m i x i n g for 20 m i n u t e s , w h i l e h e a t i n g t o 70C. 3 . Combine t h e i n g r e d i e n t s o f P a r t 8 , h e a t t o 70C. 4 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o provide a s l i g h t vortex. 5 . Add P a r t B t o P a r t A and c o o l w h i l e m i x i n g t o 30C. 6 . Package i n a e r o s o l can u s i n g Propane/Butane p r o p e l l a n t . Formulation from I n t e r n a t i o n a l S p e c i a l t y Products. *As r e c e i v e d b a s i s
SOURCE:
R.T. V a n d e r b i l t Co.,
Inc.:
Oven, Grill and Hot Plate Cleaners
139
Oven C l e a n e r Composition: K e l z a n x a n t h a n gum T r i s o d i um Phosphate Sodi urn m e t a s i 1 ic a t e S u l f o n a t e OA5 B r i j 96 S i 1 icone 2 0 0 F l u i d 3 5 0 c s Hexane Water
0.1 3.2 1.l 2.1 3.2 4.0 4.2 82.1
Procedure: P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum as b e f o r e and add n e x t t h r e e i n g r e d i e n t s . M i x t h e B r i j 96, S i l i c o n e and hexane s e p a r a t e l y . Then add w a t e r s o l u t i o n t o t h e s i l i c o n e / h e x a n e m i x w i t h c o n s t a n t a g i t a t i o n . F o r a e r o s o l u s e c h a r g e w i t h 90% conce n t r a t e and 10% G e n e t r o n 1 2 . Heavy D u t y Oven C l e a n e r Compos i t i on : Kelzan xanthan gum A n t a r o n FC-34 Sodi um h y d r o x i d e Water
Wt%
0.3
2.0
10.0 87.0
Procedure: P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum t h e n add A n t a r o n . S e p a r a t e l y , p r e p a r e t h e 40% sodium h y d o x i d e s o l u t i o n and s l o w l y add t o m i x . F o r a e r o s o l use c h a r g e w i t h 80% m i x t u r e and 20% o f 1 : l m i x o f G e n e t r o n 1 2 and 1 1 4 .
SOURCE:
Monsanto P e r f o r m a n c e M a t e r i a l s : T e c h n i c a l B u l l e t i n 1 - 2 0 : K e l zan Formul a t i ons
140
Oven C 1 e a n e r w / A m p h o t e r i c Ingredients: Water, D . I . Sodi urn C i t r a t e Sodi um M e t a s i 1 ic a t e Sodium H y d r o x i d e , 40% Monoethanol ami ne Dowanol PM R e w o t e r i c AM HC W i t c o 1298SA DeSonic 9 N
\Mt96
71 . 6 2.1 4.2 6.5 4.2 3.1 3.1
3.1
2.1
Blending Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i on. Typical Properties: V i s c o s i t y , c p s : 96 pH: 1 3 . 9 F o r m u l a 1114
Oven
C l e a n e r w/Phosphate
Ingredient s : Phase I : Water, D . I . C a r b o p o l 940 Phase 11: Water, D . I . P o t a s s i u m H y d r o x i d e , 87% Tetrapotassium Pyrophosphate Phase 111: R e w o t e r i c AM HC
71 . 4 1.3
15.4 2.4 3.6
5.9
Blending Procedure: Combine Phase I i n g r e d i e n t s and m i x u n t i l homogeneous. Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e v e s s e l and m i x t h o r o u g h l y . W h i l e m i x i n g , p o u r Phase I1 i n t o Phase I . M i x t h o r o u g h l y t h e n add Phase 1 1 . Formula 1115
dishes, Coatings and Finishes
141
142
F u r n i t u r e P o l i sh I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a1 so p r e v e n t s "creaming" o r phase separa t i o n b y suspending and s e p a r a t i n g t h e o i l d r o p l e t s . Inqredient: P a r t A: D I Water Carbopol EZ-2 TEA
wp9b
(1)
91.10 0.20 0.20 0.25 0.25 0.08 0.10 1.82

4.00
P a r t B: C a r d i s 36 Wax ( 2 ) Hoechst Wax S ( 3 ) Oleic Acid Morphol i ne D I Water Part C: SM2133 S i l i c o n e Emulsion ( 4 ) SM2135 S i l i c o n e Emulsion ( 4 ) Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): Product pH: 7.00 Product C l a r i t y : P o l i s h Raw M a t e r i a l S u p p l i e r s : ( 1 ) BF G o o d r i c h ( 2 ) P e t r o l i t e S p e c i a l t y Polymers ( 3 ) Hoechst Celanese ( 4 ) General E l e c t r i c
2.00
9,500 cps
Procedure: 1 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r b y s i m p l y "dumping" i t i n . The p o l y m e r w i l l wet o u t i n a few m i n u t e s . 2. Add t h e TEA. M i x u n t i l homogeneous. 3. P r e p a r e P a r t B. Add t h e C a r d i s Wax, Hoechst Wax S, and o l e i c a c i d t o a vessel. With m i l d s t i r r i n g , b r i n g t h e temperature up t o 96-IOOC. When m e l t e d , add t h e m o r p h o l i n e u n t i l t h e m i x t u r e i s homogeneous. Add t h e w a t e r a t 95C. C o n t i n u e s t i r r i n g u n t i l t h e t e m p e r a t u r e reaches 45C. Cool t o room temperature. 4. Add P a r t B. 5. Add i n t h e s i l i c o n e e m u l s i o n s w i t h m i l d m i x i n g . Total Actives: 0.50 T o t a l Wax : T o t a l S i l i c o n e : 6.00
SOURCE:
DET-530
Polishes, Coatings and Finishes
143
Leather/Plastic
Polish
I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a1 so p r e v e n t s "creami ng" o r phase s e p a r a t i o n b y suspending and s e p a r a t i n g t h e o i l d r o p l e t s . I n q r e d ie n t :
Wt%
50.00 2.00 (2)
1.oo
DI Water
Renex 20 ( 1 ) Morphol ine SF96 S i l i c o n e F l u i d ( 3 5 0 ) Oleic Acid Mineral S p i r i t s 01 Water Carbopol EZ-2 ( 3 )
5.00 2.00 20.00 19.60

0.40
Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): P r o d u c t pH: 8 . 5 P r o d u c t C l a r i t y : Opaque Raw M a t e r i a l S u p p l i e r s : (1) I C I Surfactants ( 2 ) General E l e c t r i c ( 3 ) BFGoodrich
3,200 c p s
Procedure: 1 . D i s s o l v e t h e Renex 2 0 and m o r p h o l i n e i n t h e w a t e r w i t h m i l d agitation. 2 . D i s s o l v e t h e s i l i c o n e f l u i d and t h e o l e i c a c i d i n t h e m i n e r a l s p i r i t s . Add t o t h e above m i x t u r e w i t h good a g i t a t i o n . 3 . I n a s e p a r a t e v e s s e l , d i s p e r s e 0 . 4 0 p a r t s o f Carbopol i n t o 49.60 p a r t s o f w a t e r b y s i m p l y "dumping" t h e p o l y m e r i n t o t h e w a t e r . I n j u s t a few m i n u t e s , t h e polymer w i l l c o m p l e t e l y wet o u t . Add t h i s d i s p e r s i o n t o t h e above m i x t u r e . 4 . M i x u n t i l homogeneous.
Total A c t i wes:
Silicone Fluid: Mineral S p i r i t s : 5.00 20.00
SOURCE: BFGoodrich S p e c i a l t y Chemicals:
DET-540
144
M a r b l e P o l ish I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a1 so p r e v e n t s "creami ng" o r phase s e p a r a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s . Ingredient: we% D I Water 74.80 0.20 Carbopol EZ-2 ( 1 ) Mineral S p i r i t s 15.00 I g e p a l 630 ( 2 ) 3.70 Diatomaceous e a r t h ( 3 ) 8.00 T r i e t h a n o l ami ne 0.30 Physical Properties: B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 1 I , 700 cp P r o d u c t pH: 7 . 5 0 P r o d u c t C l a r i t y : Opaque Raw M a t e r i a l S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) Rhone-Poul enc (3) Kaopolite Procedure: 1 . D i s p e r s e t h e Carbopol i n t h e w a t e r b y s i m p l y "dumping" i t i n . The polymer w i l l wet o u t i n a few m i n u t e s . Add t h e s u r f a c t a n t w h i l e m i x i n g under moderate a g i t a t i o n . 2 . Add t h e m i n e r a l s p i r i t s . M i x u n t i l t h e e m u l s i o n becomes homogeneous. 3 . Add t h e TEA. M i x u n t i l smooth. 4 . Add t h e diatomaceous e a r t h . Mix u n t i l homogeneous. DET-552 Rust Removing P o l i s h Carbopol r e s i n s a r e used i n t h i s f o r m u l a t o t h i c k e n t h e g l u c o n i c a c i d t o e n a b l e improved a p p l i c a t i o n e f f i c a c y . The p o l y m e r w i l l a l s o i m p a r t v e r t i c a l c l i n g t o e n a b l e a p p l i c a t i o n s on v e r t i c a l o r angled surfaces. I n q r e d ie n t : Wt% D I Water 44.64 1-79 Carbopol 2-2 ( 1 ) Sodium h y d r o x i d e (50%) 35.71 G l u c o n i c a c i d s o l u t i o n (50%) ( 2 ) 17.86 Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 r p m ) : 3,000 c p P r o d u c t p H : 13.90 Product C l a r i t y : T r a n s l u c e n t Procedure: 1 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r . 2. A d d t h e sodium h y d r o x i d e w i t h a g i t a t i o n . T h i c k e n i n g will o c c u r immedi a t e l y 3 . Add t h e g l u c o n i c a c i d s o l u t i o n . M i x u n t i l homogeneous. DET-560
Suggested Formulations
Polishes, Coatings and Finishes
145
S c r a t c h e d Wood P o l i s h Ingredients: Veegum T, Magnesium Aluminum S i l i c a t e Dei o n i zed Water
Wt%
1.50 31.25 4.50 16.50 16.50
A:
B: S t e a r i c A c i d Carnauba Wax Beeswax, Ye1 1ow

C:
T r i e t h a n o l ami ne, M i n e r a l Spi r it s
99%
2.75 27.00
q.s
D:
P r e s e r v a t i v e , Dye,
Fragrance
Procedure: 1 . Weigh t h e w a t e r and m i x w i t h a p r o p e l l e r m i x e r a t 1800 rpm. 2 . S l o w l y add t h e Veegum T and m i x f o r 20 m i n u t e s w h i l e h e a t i n g t o 9OC. 3 . Combine t h e P a r t B i n g r e d i e n t s and h e a t t o 9OC. 4 . Add t h e P a r t C i n g r e d i e n t s t o t h e P a r t B m i x t u r e i n t h e o r d e r shown, m i x i n g each f o r 10 m i n u t e s . 5 . Add P a r t B+C t o P a r t A and m i x f o r 10 m i n u t e s . 6 . Cool t h e b a t c h t o 35C, add P a r t D, and m i x u n t i l u n i f o r m . *As r e c e i v e d b a s i s
SOURCE:
R.T.
H i qh
Inc.:
F o r m u l a t i o n No. 2 1 0
Gloss, D e t e r q e n t R e s i s t a n t P o l ish
A wax-free p o l i s h , which provides a high-gloss, detergent r e s i s t a n t f i n i s h on non-porous s u b s t r a t e s . S i m p l e a p p l i c a t i o n , w i t h o u t hard r u b b i n g o r b u f f i n g , r e s u l t s i n b o t h d e p t h o f g l o s s and d e t e r g e n t r e s i s t a n c e f o r e x t e n d e d p r o t e c t i o n .
Ingredients: ( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e ( 2 ) GP-RA-159 S i l i c o n e P o l i s h A d d i t i v e ( 3 ) Stoddard Solvent ( 4 ) Mineral S p i r i t s (Odorless) ( 5 ) GP-227 S i l i c o n e S u r f a c t a n t S o l u t i o n ( 6 ) K a o p o l i t e SF ( 7 ) S o f t Water ( 8 ) Bactericide
Wt%
9.0 1.5 3.5 3.5 9.0
3.4 70.0 0.1
Combine i n o r d e r shown w i t h h i g h s h e a r m i x i n g u n t i l t h i c k e n i n g o c c u r s . M i x u n t i l homogeneous and package. Formulation Properties: C o n t a i n s no wax High g l o s s Detergent r e s i s t a n t E a s i 1 y a p p l ied SQURCE: Genesee P o l y m e r s C o r p . : Non-smeari ng Cost e f f i c i e n t Cold b l e n d (Only m i x i n g r e q u i r e d ) Resistant t o wash-off Formula 20-12
12. Rinse Aids
146
Rinse Aids
147
R i nse A i d ,
Acid
Inqredients: Water, D . I . P e t r o 22 Powder DeSoni c LFD-97 Hydroxyacetic Acid,
Wt9/o
50.0
70%
5.0 35.0 10.0
Blending Procedure: 51 end i n g r e d i e n t s in t h e o r d e r 1 is t e d . Typical Properties: S p e c i f i c G r a v i t y : 1.105 Wt/Gal, l b s : 9 . 2 1 V i s c o s i t y , c p s : 85 C l o u d P o i n t , C : 59 S o l i d s , %: 4 0 Formula 131
R i nse A i d
Ingredients: Water, D . I . P e t r o 22 Powder DeSoni c LFD-97 Typical Properties: S p e c i f i c G r a v i t y : 1.029 Wt/Gal. l b s : 8 . 5 8 pH, as i s : 6 . 4 V i s c o s i t y , c p s : 80 C l o u d P o i n t , C : 68 S o l i d s : 40% Formula 130 SOURCE; W i t c o C o r p . : Suggested Formul a t ions
Wt%
60.0 5.0 35.0
13. Rug, Floor, Carpet,
Upholstery Shampoos an
148
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners
149
C a r p e t C1 e a n e r
I n qr e d i e n t s : Water T r i s o d i urn Phosphate Tetrapotassium Pyrophosphate P l u r a f a c D-25 A1 ip a l CO-436 Mazawet 7 7 EDTA ( T e t r a s o d i u m S a l t ) M Tinopal 5 B
Procedure: Add i n g r e d i e n t s as l i s t e d .
56.0 15.0 10.0 7.0 10.0 1.25 0.5 0.25
wt%
Low Foam C a r p e t Shampoo

Ingredients: Macol 2LF Ethylene Glycol Methyl Ether Sodi urn T r i p o l y p h o s p h a t e Sodi urn X y l ene S u l f o n a t e Mazu DF 210 SX Water ( s o f t ) Procedure: Add i n g r e d i e n t s as l i s t e d . Steam Rua C l e a n e r - A Ingredients: Macol OP 1 0 SP Sodium S i l i c a t e Sodi urn X y l ene S u l f o n a t e Water Procedure: Add i n g r e d i e n t s as l i s t e d .
S t e a m Rug C l e a n e r - 8
Wt%
6.0 10.0 1. o 1 .o 0.5 81 . 5
w a
5.0
10.0 5.0 80.0
Inqredients: Macol OP 1 0 SP Sodi um S i 1 ic a t e Sodium X y l e n e S u l f o n a t e Water Procedure: Add i n g r e d i e n t s as l i s t e d SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
Wt%
3.0 10.0 3.0 84.0
150
Carpet Cleaners f o r t h e Spray-Extraction Process Inqredients: C u b l e n 0 50 Tetrapotassium pyrophosphate P r o p e t a l 241 P r o p e t a l 281 S u l f e t a l 4105 Isopropanol Water F o r m u l a CT 02-08-01 Ingredients: Water Soap S u l f e t a l 4105 P r o p e t a l 99 Cont raspum 3 0 0 U b a t o l TR 1138 Isopropanol F o r m u l a C T 02-08-02
W S 1.o
5.0 2.0 3.0 4.0 4.0 81 . o
Wt%
75.0
1 .o
5.0 5.0 1. o 3.0 10.0
SOURCE: Zschimmer & Schwarz GmbH & C o . : G e n e r a l F o r m u l a t i o n s

C a r p e t Shampoo Liquid, transparent Ingredients: A : Hostapur 0s l i q u i d M e d i a l a n KA c o n c .
B: W a t e r ,
wtu/, 25.00 3.00 72.00 t h e components o f A a r e added t o 8 . Suggested F o r m u l a t i o n
Preservative
Manu f a c t u r i ng : One a f t e r a n o t h e r ,
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t :
151
I Phosphate,
C a r p e t Shampoo L i quid) clay
S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , and p a r t i c u l a t e S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method-Rug s c r u b b e r Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Water *TSP *STPP K a s i 1 # 6 P o t a s s i um S i 1 ic a t e **Phosphate E s t e r ***Sodi um A1 k y l naphtha1 ene S u l f o n a t e ****Octylphenoxy P o l y e t h o x y e t h a n o l , 7 - 8 M o l e s EO Use D i l u t i o n : 0 . 8 - 1 . 5 % bw ( 1 - 2 o z / g a l l o n )
Wt%
62.5 2.0 5.0 20.0 3.0 3.5 4.0
** *** ****
FMC Rhone-Poulenc Rhodafac RE-610 DeSoto Rhone-Poulenc I g e p a l CA-620

RUQ Steam C l e a n e r
S o i 1 -Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , and p a r t i c u l a t e S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method-Rug s c r u b b e r Manufacture-Mix t a n k w i t h p r o p e l l e r s t r r e r Composi t i on : Water Wetso Beads 2048 Sodi um X y l ene S u l f o n a t e , 40% * M i r a n o l JEM C o n c e n t r a t e (34%) Use D i l u t i o n : 4 . 7 - 9 . 4 % b w ( 6 - 1 2 o z / g a l l o n ) *Rhone-Poul enc; o r She1 1 Chemical Neodol 25-1 2 Detergent F o r m u l a t i o n Guide
clay
84.0 5.0 6.0 5.0
152
C a r p e t Shampoo,
I Q r e d ie n t s : n Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA
H i s h Foam
WtS/o
78.3 5.0 16.7
B1 e n d i n g P r o c e d u r e : B1 end in g r e d i e n t s i n t h e o r d e r 1 is t e d . P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , r e d u c e s t h e low temperature cloud p o i n t , g i v i n g e x c e l l e n t freeze/thaw p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n sodium l a u r y l s u l f a t e a l o n e . F o r m u l a 908 C a r p e t Shampoo, H i g h Foam Inqredients: Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA B l e n d i n g P r o c e d u r e : B 2nd i n g r e d i e n t s i n t h e o r d e r Use L e v e l :
1 t o 2 ounces p e r g a l l o n . is
I
Wt%
71.1 6.7
22.2
Comments : P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , r e d u c e s t h e low t e m p e r a t u r e c l o u d p o i n t , g i v i n g e x c e l l e n t f r e e z e / t h a w p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n sodium l a u r y l s u l f a t e a l o n e . F o r m u l a 910 C a r p e t S p o t Remover Inqredients: Water, 13.1. W i t c o l a t e WAC-LA P e t r o BA L i q u i d G l y c o l E t h e r DPM Glycol Ether P M FC-129 ( 1 % S o l i d s ) Blending Procedure: Blend ingredients i n t h e order l i s t e d .
Wt%
90.3 3.3 0.5 3.5 2.3 0.1
Typical Properties: S p e c i f i c G r a v i t y : 0.999 Wt./Gal. l b s . : 8.33 pH: 1 0 . 3 5 Use D i l u t i o n : Use as i s F o r m u l a 945 SOURCE: W i t c o C o r p . : S u g g e s t e d F o r m u l a t i o n s
153
Carpet 8 U p h o l s t e r y Cleaner T h i s o e n e r a l Duroose s t a i n remover f o r m u l a t i o n is o a r t i c u l a r l v e f f e c t i v e i n removing o i l s t a i n s . Ingredient : Wt% D e i o n i z e d Water ( h o t ) 37.0 SMA-2625 R e s i n 2.4 Aqua Ammonia 0.7 W i t c o l a t e WACLA 18.0 W i t c o n a t e 60T L i q u i d 4.0 Avanel 5-70 4.0 Dei o n i zed Water 34.0 Dye, Fragrance, e t c . (2.5. pH ( a s i s ) : 8.0-9.0 Appearance: C l e a r l i q u i d S p e c i f i c G r a v i t y : 1.016 Procedure: 1 . Charge t h e h o t w a t e r t o a m i x i n g v e s s e l and s t a r t a g i t a t i o n . S l o w l y s i f t i n t h e SMA-2625 R e s i n t o a v o i d c l u m p i n g . Add t h e Aqua Ammonia, a p p l y c o o l i n g , and mix w e l l u n t i l t h e r e s i n i s dissolved. 2 . Reduce a g i t a t i o n and add t h e r e m a i n i n g i n g r e d i e n t s . S t o p a g i t a t i o n t o permit deaeration o f t h e product p r i o r t o filling off. 3 . I f t h i s p r o d u c t i s t o be c o l o r e d , a p o r t i o n o f t h e f i n a l w a t e r s h o u l d be r e s e r v e d f o r d i s s o l v i n g t h e dye. A f t e r t h e dye is t h o r o u g h l y mixed, t h e dye s o l u t i o n may be added NOTE: Use " a s i s " on c a r p e t i n g . D i l u t e 1 O : l and 5 : l w i t h water f o r u pholstery.
V i n y l Dressing ( 8 ) Ingredient: Wt% Part A: M a s i l EM 250 C 18.0 M a s i l EM 10,000 C 10.0 Dei o n i zed Water 30.0 P a r t B: Macol OP-10 SP 2.0 G1 y c e r i ne 1.o D e i o n i r e d Water 38.0 Sodium Benzoate 1.o Procedure: 1 . To a m i x i n g v e s s e l , c h a r g e t h e M a s i l EM 250 C and M a s i l EM 10,000 C . S t a r t g e n t l e a g i t a t i o n . S l o w l y add t h e w a t e r so as n o t t o b r e a k t h e e m u l s i o n . 2. I n a s e p a r a t e m i x i n g v e s s e l , c h a r g e t h e Macol OP-10 SP and g l y c e r i n e t o t h e water. Mix w i t h g e n t l e a g i t a t i o n u n t i l a l l components a r e d i s s o l v e d , and t h e s o l u t i o n i s f r e e o f " f i s h e y e s " . Charge t h e sodium b e n z o a t e and m i x u n t i l d i s s o l v e d . 3 . Under g e n t l e a g i t a t i o n , add P a r t 0 t o P a r t A. C o n t i n u e m i x i n g g e n t l y t o a v o i d a i r e n t r a p m e n t . NOTE: T h i s f o r m u l a i s d e s i g n e d to b e used "as i s " . I f d e s i r e d , UV a b s o r b e r s and o t h e r compone n t s may be added t o t h e f o r m u l a t i o n . SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
154
Carpet & Upholstery Cleaner Ingredients: Dei o n i zed Water ( H o t ) SMA-2625 R e s i n Aqua Ammonia Sodi u m L a u r y l S u l f a t e R i chami de 5725 Avanel 5-70 Dei o n i zed Water Dye, F r a g r a n c e , E t c .
pH (as i s ) : 8.0-9.0 Appearance: C l e a r l i q u i d S p e c i f i c G r a v i t y : 1 .016
Wt%
37.0 2.37 0.67 18.0 4.0 4.0 33.96 As d e s i r e d
Procedure: Charge t h e h o t w a t e r t o t h e m i x i n g v e s s e l and s t a r t a g i t a t i o n . S l o w l y s i f t i n t h e SMA-2625 r e s i n t o a v o i d c l u m p i n g . Add t h e Aqua Ammonia, a p p l y c o o l i n g and m i x w e l l u n t i l t h e r e s i n i s d i s s o l v e d . Reduce a g i t a t i o n and add t h e r e m a i n i n g i n g r e d i e n t s . I f t h e p r o d u c t i s t o be c o l o r e d , a p o r t i o n o f t h e f i n a l water s h o u l d b e r e s e r v e d f o r d i s s o l v i n g t h e d y e . A f t e r t h e dye i s t h o r o u g h l y m i x e d , t h e d y e s o l u t i o n may b e added t o t h e p r o d u c t . Stop a g i t a t i o n t o p e r m i t deaeration o f t h e product p r i o r t o filling off. Notes : T h i s i s a g e n e r a l p u r p o s e o i l y s t a i n remover. T h i s f o r m u l a t i o n i s p a r t i c u l a r l y e f f e c t i v e a t r e m o v i n g o i l s t a i n s . Use a s - i s on c a r p e t i n g . D i l u t e 1 O : l and 5 : l w i t h w a t e r f o r u p h o l s t e r y . N o t e : The dye s h o u l d b e t h o r o u g l y s c r e e n e d t o a v o i d f a b r i c staining. F o r m u l a t i o n CP-101 L i q u i d Steam C a r p e t C 1 e a n e r F o r H a r d Water Systems Ingredients: Sodium M e t a s i 1 i c a t e A Tetrapotassium Pyrophosphate Emphos PS-331 Macol NP 11 D e i o n i z e d Water Procedure: Add i n g r e d i e n t s as l i s t e d .
Wt%
7.5 12.5 4.0 1.o 76.0
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
155
F1oor C l e a n e r Ingredients:
M a z a m i de 1281
wtsl, 8.0
2.0 2.0 88.0
Sodi urn T r i p o l y p h o s p h a t e T e t r a p o t a s s i u m Pyrophosphate Water Procedure: Add i n g r e d i e n t s as l i s t e d . L i q u i d F l o o r Cleaner Ingredients: Macol NP 9 . 5 Sodi urn T r i p o l yphosphate T r i s o d i urn Phosphate Sodi urn M e t a s i 1i c a t e P e n t a h y d r a t e Maphos 60A Water Procedure: A d d i n g r e d i e n t s as l i s t e d . NOTE: T h i s f o r m u l a t i o n i s s t a b l e t o 120F. F l o o r Scrubber Ingredients: Sodi urn M e t a s i 1 ic a t e Tetrasodium Pyrophosphate Emphos PS-331 D e i o n i z e d Water Mazami de 1281 Sodium H y d r o x i d e , 50% Procedure : Add i n g r e d i e n t s as l i s t e d .
Q 7.0 8.0 2.0 2.0 3.0 78.0
2.0 18.0 15.0 53.95 6.0 5.05
SOURCE:
Inc.:
156
Household Carpet F r e s h e n e r / A n t i s t a t InQredients: P a r t A: P u f f e d Borax ( 1 0 l b s / c u f t ) Fragrance Sodi um B i c a r b o n a t e L a r o s t a t 519 P a r t 6: Sodi um B i c a r b o n a t e
Wt%
1.8 0.2 15.0 3.0 80.0
Procedure: I n a r i b b o n m i x e r o r V - b l e n d e r , c h a r g e t h e p u f f e d b o r a x and f i r s t p o r t i o n o f sodium b i c a r b o n a t e . S t a r t m i x i n g and s l o w l y add t h e f r a g r a n c e . A f t e r a l l o f t h e f r a g r a n c e has been added, c o n t i n u e m i x i n g f o r 5 m i n u t e s t o c o m p l e t e a b s o r p t i o n . Add t h e L a r o s t a t 519 and t h e r e m a i n i n g sodium b i c a r b o n a t e . M i x f o r 15 m i n u t e s more. Notes : T h i s i s a powdered c o m b i n a t i o n consumer f r e s h e n e r / a n t i s t a t . The p r o d u c t i s d e s i g n e d t o b e shaken o n t o t h e c a r p e t , l i g h t l y r u b b e d i n t o t h e c a r p e t and t h e n t h e e x c e s s removed b y vacuuming. F o r m u l a t i o n SP-I01 Pump S p r a y C a r p e t A n t i s t a t Ingredients: P a r t A: Water Isopropyl Alcohol L a r o s t a t 264 A Appearance: C l e a r , w a t e r - w h i t e S p e c i f i c G r a v i t y : 0.98 t o pale-yellow l i q u i d
94.3 5.0 0.7
Procedure: To a m i x i n g vessel, charge t h e water, f o l l o w e d by t h e i s o p r o p y l a l c o h o l and L a r o s t a t 88. M i x u n t i l c l e a r . Notes : T h i s i s a n o n - a e r o s o l , pump s p r a y c a r p e t a n t i s t a t f o r t h e removal o f n u i s a n c e s t a t i c . T o remove s t a t i c f r o m c a r p e t i n g and other surfaces, spray l i g h t l y w i t h t h i s formulation. It i s not necessary t o s a t u r a t e t h e surface. I f a d d i t i o n a l p r o t e c t i o n i s needed, i t i s p r e f e r a b l e t o have r e p e a t a p p l i c a t i o n s r a t h e r t h a n one, t o i n s u r e even t r e a t m e n t . F o r m u l a t i o n SP-102
SOURCE: PPG I n d u s t r i e s ,
Inc.:
157
h i qlai d L e a t h e r . V i n v l , a n d P l a s t i c C l e a n e r and R e s t o r e r Inqredients: DeSonic 9N Dowanol PM G l y c o l E t h e r Isopropyl Alcohol Amy1 A c e t a t e Water
Wt%
10.0
5.0 2.5 1.o 81 . 5
Blending Instructions: Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y .
Use I n s t r u c t i o n s :
A p p l y f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . ) and w i p e o n t o t h e s u r f a c e t o b e c l e a n e d , t h e n r i n s e . A l t e r n a t i v e l y , s p r a y o n t o t h e s u r f a c e t o b e c l e a n e d , a l l o w t o s e t a few m i n u t e s , t h e n r i n s e o r hose o f f . Product I n f o r m a t i o n : Product: DeSonic 9N Dowanol PM G l y c o l E t h e r Amyl A c e t a t e Isopropyl Alcohol Formula 1000 L i q u i d Leather, InQredients: W i t c o n o l NP-100 Dowanol PM G l y c o l E t h e r Isopropyl Alcohol Amy1 A c e t a t e Water Benefit : Detergent and degreaser S o l v e n t and c o u p l i n g a g e n t Solvent Sol vent
Vinyl,
and P l a s t i c C l e a n e r
Wt%
10.0 5.0 2.5 1 .o 81.5
Blending Instructions: Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y .
Use I n s t r u c t i o n s :
A p p l y f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . ) and w i p e o n t o t h e s u r f a c e t o b e c l e a n e d , t h e n r i n s e . A l t e r n a t i v e l y , s p r a y o n t o t h e s u r f a c e t o b e c l e a n e d , a l l o w t o s e t a few m i n u t e s , t h e n r i n s e o r hose o f f . Product I n f o r m a t i o n : W i t c o n o l NP-100 Dowanol PM G l y c o l E t h e r Amyl A c e t a t e I s o p r o p y l A1 coho1 Formula 1001 Benefit : D e t e r g e n t and d e g r e a s e r S o l v e n t and c o u p l i n g a g e n t Sol vent Sol vent
158
Low Cost E x t r a c t i o n C a r p e t C l e a n e r
Ingredients: Water, D . I . P e t r o 22 Powder EDTA Powder Perfume 81 e n d i n g P r o c e d u r e : B1 end i n g r e d i e n t s in t h e o r d e r 1 isteci. Use D i l u t i o n : 1-2 o z / g a l F o r m u l a 901 91 . o 5.0 4.0 q. s .
of w a t e r
Premium, Medium D u t y Steam E x t r a c t i o n C a r p e t C l e a n e r Inqredients: Sodi um T r i p o l y p h o s p h a t e , L i g h t D e n s i t y Sodi urn M e t a s i 1 i c a t e , P e n t a h y d r a t e P e t r o 2 2 Powder Optical Brightener Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . Use D i l u t i o n : 1-2 o z / g a l Formula 904 Heavy D u t y Steam E x t r a c t i o n C a r p e t C l e a n e r Inqredi ents: Sodium C a r b o n a t e (Soda Ash) T r i s o d i u m Phosphate, C r y s t a l Sodium M e t a s i l i c a t e , P e n t a h y d r a t e Sodium S u l f a t e ( S a l t Cake) P e t r o 2 2 Powder B l e n d i n g Procedure: F o r m u l a 905 Blend i n g r e d i e n t s i n t h e order l i s t e d
Wt% 10.0 10.0 20.0 56.0 4.0
65.0 29.5 5.0 0.5
Use D i l u t i o n : 1-2 o z / g a l
SOURCE:
Witco Corp.: Suggested F o r m u l a t i o n s
159
Low Foaming C a r p e t E x t r a c t o r D e t e r g e n t
Component: Sodi um B i c a r b o n a t e STPP B u r c o LAF-6 Burco SZS B u r c o s p e r s e AP Powder B u r c o t a s e SP-60 ( i f d e s i r e d ) Fragrance
Wt%
t o 100% t o t a l 47.0 2.5 0.25 2.5 1.o as d e s i r e d
Procedure: S p r a y LAF-6 ( a n d i f d e s i r e d ) f r a g r a n c e o n t o STPP and b l e n d u n t i l a b s o r b e d . Add B u r c o S Z S , t h e n Sodium B i c a r b o n a t e and b l e n d u n t i l u n i f o r m . Add B u r c o s p e r s e A P Powder ( a n d i f d e s i r e d ) B u r c o t a s e SP-60. B l e n d u n t i 1 u n i f o r m . Use C o n c e n t r a t i o n : 2-3 ounces p e r g a l l o n i n e x t r a c t o r . SOURCE: B u r l i n g t o n Chemical C o . , Inc.: Suggested F o r m u l a t i o n s
RUQ Steam C l e a n e r (Liquid)
S o i l - Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , and p a r t i c u l a t e S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method - Rug s c r u b b e r Manufacture - Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition: Water M e t s o Beads 2048 Sodium X y l e n e S u l f o n a t e , 40% C12-Cl5 L i n e a r A l c o h o l , 12 M o l e s EO Use D i 1u t i on : 4 . 7 - 9 . 4 % bw ( 6 - 1 2 o z / g a l 1o n ) SOURCE: The PQ C o r p . : Suggested F o r m u l a t i o n
clay
Wt%
79.6 7.0 6.7 3.9
160
No Rinse F l o o r Cleaner
I npredie n t s : Water, D.I. Sodi u Carbonate m Rewoteric AM 8-14 Versene 100 Butyl Cellosolve
\Mt%
79.0
4.0 10.0 2.0

5.0
Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each addi t ion. Formula 932 Heavy D u t y F l o o r Cleaner Ingredients: Water, D.I. Varami de A-1 2 T r i sodi u Phosphate m Sodium Tripolyphosphate
Wt%
78.0
7.0
10.0 5.0
81 end$ng Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . T y p i c a l Propert ies : S o l i d s : 22.0% Formula 933
No-Rinse F l o o r Cleaner Deareaser

Ingredients: Deionized water Sodium carbonate Rewoteric AM V Versene 100 Butyl Cellosolve
WtO/o
79.0
4.0
10.0 2.0 5.0
Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: S o l i d s : 8.1% pH: 10.9 V i s c o s i t y : 4 cps Formula 951
SOURCE: Witco Corp. : Suggested Formulations
161
Wax S t r i p p e r ( A ) Inqredients: Oleic Acid Monoethanol ami ne Avanel S - 7 4 Potassium H y d r o x i d e , 45% Sodi u H y d r o x i d e , 50% m Versene 100 Dowanol TBA Water Procedure: Add i n g r e d i e n t s as l i s t e d . Wax S t r i p p e r ( B ) Inaredients: Oleic Acid Monoethanolamine Avanel S - 7 4 Potassium H y d r o x i d e , 45% Sodi u H y d r o x i d e , 50% m Versene 1 0 0 E t h y l e n e G1 y c o l Monobutyl E t h e r Water Procedure: Add i n g r e d i e n t s as l i s t e d . C o n c e n t r a t e d Wax S t r i p p e r Inaredients: Sodium H y d r o x i d e , Macol NP 9 . 5 EDTA, 40% Mazox LDA B a r q u a t MB-50 Monoethanolami ne Water
Wt%
7.0
2.0 2.0 1 .o 1 .o
1
.o
8 .o 1
5.0
7.0
81 . o 5.0
2.0 2.0 1 .o 1 .o 1 .o
WtO/o
50%
1 .o 0.5 1 .o 1 .o 8.5 8 .5 1
6.5
Procedure: Add i n g r e d i e n t s as l i s t e d . To use, d i l u t e 1 : l O t o 1:30. P Mac01 NP 1 0 . 5 can be s u b s t i t u t e d f o r t h e Macol N 9 . 5 . Mafo CB-40 can be s u b s t i t u t e d f o r t h e Mazox LDA.
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
14. Miscellaneous
1 fi7
Miscellaneous
163
B a c t e r i o s t a t i c C o n c e n t r a t e w/Pine 021 I n q r e d ie n t s : Wt% Phase I : Isopropanol 10.0 Oleic Acid 8.8 5.0 Varox 1 7 7 0 Pine O i 1 12.0 Phase 11: Water, D . I . 62.2 P o t a s s i um H y d r o x i d e (87%) 2.0 81 e n d i ng P r o c e d u r e : Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine Phase I T i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o Phase 1 1 . T y p i c a l P r o p e r t i es : V i s c o s i t y , cps: 5 S o l i d s : 10.6% pH: 9 . 3 Formula 302
_ e n e r a l D i s_n f _ c t_ n _ S_ l u t i o n ~ G ~ ~ _ i e a t o _ _
~
wtsl, 68.0 10.0 5.0 17.0 between
Ingredi e n t s :
Water. D . I . V a r q u a t 5 0 MC G1 y o x a l ( 4 0 % ) R e w o t e r i c AM DML-35 Blending Procedure: Add i n g r e d i e n t s 1 n o r d e r shown and d i s s o l v e c o m p l e t e l y each add1 t ion, Typical Properties: V l s c o s l t y , cps: 4 Sol 1 d s : 1 3 . 0 % pH: 7 . 1 Formula 3 0 3
-~r e d i Ing
Hospital D is infectant ents: Wt% Water, D . I . 84.2 9.6 V a r i q u a t 50 MC Varox 365 4.0 Versene 100 1.5 Sod1 urn H y d r o x i d e ( 3 0 % ) 0.7 Blending Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Typical Properties: Viscosity, cps: 4 S o l i d s : 6.7% pH: 1 2 . 2 Formula 304 SOURCE: Witco Corp,: Suggestecl F o r m u l a t i o n s
I64
C u t t i n g O i l Concentrate Ingredients: Wei s h t % Aristonate M 36.00 I g e p a l CO-430 20.00 8.00 TEA, 85% Oleic A c i d 8.00 100 SUS N a p h t h e n i c O i l 28.00 Comments a b o u t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l . 2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r . F o r m u l a t i o n SOL-003-01 Cutting Oi 1 Ingredients: Aristonate M TEA, 85% T a l l O i l A c i d , A c t i n o l FA-1 C a l a m i d e SM 100 SUS N a p h t h e n i c O i l Water Comments a b o u t t h i s f o r m u l a : E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r . F o r m u l a t i o n SOL-004-01 Wei q h t % 10.50 0.90 1.20 1.65 85.00 0.75
C o n c r e t e C 1e a n e r Ingredients: Weight% 5.00 C a l s o f t F-90 Sodi um S i 1 ic a t e 30.00 30.00 Sodium C a r b o n a t e Sodi um H y d r o x i d e 25.00 Sodi um T r i p h o s p h a t e 10.00 Comments a b o u t t h i s f o r m u l a : G r i n d m i x t u r e t o g e t h e r t o y i e l d a s l i g h t l y t a c k y w h i t e powder. F o r m u l a t i o n CON-001-01 White Wall Cleaner Wei s h t % Insredients : Water 60.20 C a l s o f t L-40 29.30 P i l o t SXS-40 2.20 Na4 EDTA 1.30 C a l o x y l a t e N-9 7.00 Comments a b o u t t h i s f o r m u l a : V i s c o s i t y o f t h e p r o d u c t i s a b o u t 160 cPs a t room t e m p e r a t u r e . F o r m u l a t i o n TIR-001-01
SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
Miscellaneous
165
d L i monene Water1 e s s Hand C1 e a n e r

Ingredients: Phase I : Water, D . I . T r i s o d i u m Phosphate Sodium C i t r a t e Glycerin Phase 11: d - L i monene DeSonic 9N V a r o n i c T202
Wt%
81 . O 1 .o 2.0 2.0
7.0
5.0 2.0
B l e n d i n g Procedure: I n v e s s e l fit1 combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . H e a t t o 140F. Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e v e s s e l and m i x t h o r o u g h l y . Heat t o 140F. W h i l e m i x i n g r a p i d l y , add Phase 11 Po Phase I.Cool q u i c k l y t o s t a b i l i z e e m u l s i o n . Typical Properties : Appearance, Room Temp.: S o l i d s : 12.0% pH: 1 0 . 4 Formula 1120 Heavy Cream
P a s t e Hand C l e a n e r Ingredients: Water, D . I . Varami de MA-1 R e w o t e r i c AM 8-15 W i t c o l a t e SE-5
WtS/o
70.0
10.0 10.0 10.0
81 e n d i n g P r o c e d u r e : Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i on. Typical Properties: V i s c o s i t y , c p s : 6360 S o l i d s : 19.5% pH: 8 . 7 Formula 1121
166
Dipentene Microemulsion Formulations D i p e n t e n e i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i n e o i l s c o n t a i n i n g r e l a t e d monocyclic t e r p e n e hydrocarbons, predomin a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same as l i m onene. D-limonene i s one o f t h e 2 o p t i c a l i s o m e r s o f d i p e n t e n e . ) O t h e r components o f commercial d i p e n t e n e i n c l u d e c a r e n e and a l p h a - and b e t a - p i n e n e . Non-alkaline Formulations Ingredients: D i p e n t e n e 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a l i S u r f a c t a n t Water
CPL, c : 1 1 CPH, C : 30 Emulsifier/Dipentene Ratio:
& %
5.00 6.40 0.80 0.80 87 00
~
1.60
Ingredients: D i p e n t e n e 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a i S u r f a c t a n t Water

C P L , c : 11 CPH, C : 50 Emu1 s i f e r / D i p e n t e n e R a t i o :
VVt.%
10.00 8.80
1.10
1.10 79.00
1.10
Inaredients: D i p e n t e n e 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a l i S u r f a c t a n t Water

CPL, c : 19 CPH, C : 41 Emulsifier/Dipentene Ratio:
Wt.%
20.00 14.40 1.80 1 .80 62.00
0.90
Add and m i x t h e f i r s t f o u r i n g r e d i e n t s ( d i p e n t e n e and emulsi f i e r s ) . D i s s o l v e t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r and add i t t o t h e e m u l s i f i e r s and d i p e n t e n e w i t h m i x i n g . C P L i s " l o w t e m p e r a t u r e c l o u d p o i n t " w h i l e CPH i s " h i g h temperature cloud p o i n t " .
SOURCE: Tomah P r o d u c t s ,
Inc.:
B u l l e t i n : Terpene M i c r o e m u l s i o n s
Miscellaneous
167
D i p e n t e n e M i c r o e m u l s i o n Formul a t i o n s ( C o n t i nued)
D i p e n t e n e i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i ne o i l s c o n t a i n i n g r e l a t e d m o n o c y c l i c t e r p e n e h y d r o c a r b o n s , predomi n a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same a s l i m o n ene. D-limonene i s one o f t h e 2 o p t i c a l i s o m e r s o f d i p e n t e n e . ) O t h e r components o f commercial d i p e n t e n e i n c l u d e c a r e n e and a l p h a - and b e t a - p i n e n e .
A l k a l i n e Formulations Ingredients: D i p e n t e n e 122
Wt.96
5.00
8.00 0.50 1 .50 83.30 1.70
E-14-5
E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e
CPL, C : 15 CPH, C : 4 4 Emulsifier/Dipentene Ratio:
2.00
Ingredients: D i p e n t e n e 122 E-14-5 E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e CPL, c : 20 CPH, C : 46 Emulsifier/Dipentene Ratio:
Wt.%
10.00 12.00 0.75 2.25 73.50 1.50
1 .50
Ingredients: D i p e n t e n e 122 E- 1 4 - 5 E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e
Wt.%
20.00 17.60 1.10 3.30 56.80 1.20
CPL, C : 18 CPH, C : 43 E m u l s i f i e r / D i p e n t e n e R a t i o : 1 .I0 Add and m i x t h e f i r s t f o u r i n g r e d i e n t s ( d i p e n t e n e and e m u l s i f i e r s ) . D i s s o l v e t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r and add i t t o t h e e m u l s i f i e r s and d i p e n t e n e w i t h m i x i n g . CPL i s " l o w t e m p e r a t u r e c l o u d p o i n t " w h i l e CPH i s " h i g h temperature cloud p o i n t " .
SOURCE: Tomah P r o d u c t s , I n c . : B u l l e t i n : Terpene M i c r o e m u l s i o n s
168
H y d r o c a r b o n S o l v e n t M i c r o e m u l s i ons Developed i n o r d e r t o o f f e r replacements f o r expensive d - l i m o n e n e and p i n e o i l i n m i c r o e m u l s i o n c l e a n e r s . They a l l have f l a s h p o i n t s above I O O C and l o w VOC c o n t e n t . Exxsol D-I10 Formula A: Ingredients: E x x s o l D-110 Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S u r f a c t a n t S o f t Water Formula 8 : Inaredients: E x x s o l D-110 Tomah E-14-2 Tomah E - 1 4 - 5 Tomah A l k a l i S u r f a c t a n t S o f t Water Formula C : Inqredients: E x x s o l D-110 Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S u r f a c t a n t S o f t Water Formulations
\Nt.%
20.0 11.9
5.4 4.3 58.4
Wt.%
30.0 17.9 8.1 6.5 37.5
Wt.%
40.0 23.9 10.8 8.7 16.6
Add each component i n t h e o r d e r g i v e n and m i x u n t i l homogeneous b e f o r e a d d i n g t h e n e x t component. Add t h e w a t e r i n p o r t i o n s with mixing. These m i c r o e m u l s i o n s s h o u l d be c l e a r and s t a b l e i n t h e tempe r a t u r e r a n g e f r o m 20-37C. O u t s i d e t h a t r a n g e t h e y may c l o u d o r s e p a r a t e , b u t w i l l r e g a i n c l a r i t y upon r e t u r n i n g t o room tempe r a t u r e . I f i t i s necessary t o r a i s e t h e c l o u d p o i n t temperature, a s m a l l amount o f a d d i t i o n a l Tomah A l k a l i S u r f a c t a n t s h o u l d b e added.
SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
Miscellaneous
169
Hydrocarbon S o l v e n t Microemulsions ( C o n t i n u e d l Developed i n o r d e r t o o f f e r r e p l a c e m e n t s f o r e x p e n s i v e d - l i m o n e n e and p i n e o i l i n m i c r o e m u l s i o n c l e a n e r s . They a l l have f l a s h p o i n t s above 1OOC and l o w VOC c o n t e n t .
Isopar M F o r m u l a t i o n s
I s o p a r M can b e s u b s t i t u t e d d i r e c t l y f o r t h e E x x s o l D-110 i n t h e above f o r m u l a t i o n s . I n a d d i t i o n , t w o f o r m u l a t i o n s w i t h l o w e r s o l v e n t c o n t e n t have been d e v e l o p e d . Unbui 1 t : Component: S o f t Water Sodium Metas l i c a t e P e n t a h y d r a t e Tomah E-14-2 Tomah E-14-5 Tomah A1 k a l i S u r f a c t a n t I s o p a r Wi
Wt.%
83.0 0.0
4.7 4.7 1.6
6.0
L i g h t l y b u i 1t : Component: S o f t Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S u r f a c t a n t Isopar M
Wt.%
79.0 1.o 5.6 5.6 1.a 7.0
S t a r t b y d i s s o l v i n g t h e sodium m e t a s i l i c a t e ( i f u s e d ) i n t h e w a t e r . Then add t h e E-14-2, E-14-5, a n d A l k a l i S u r f a c t a n t . M i x u n t i l homogeneous. F i n a l l y add t h e I s o p a r M i n p o r t i o n s w i t h m i x i n g . The m i x t u r e w i l l c l o u d , t h e n s h o u l d c l e a r a s t h e l a s t o f t h e I s o p a r M i s added. These m i c r o e m u l s i o n s w i l l b e c l e a r and s t a b l e i n t h e t e m p e r a t u r e r a n g e f r o m 20-5OC. The c l o u d p o i n t c a n be r a i s e d f u r t h e r b y a d d i n g a s m a l l amount o f a d d i t i o n a l A l k a l i Surfactant. SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
I70
. !o L
V i_s_cosi_tv_s_jlicon 1- si-o~n-UsinxPemulen ..Emu s
resins
S i l i c o n e o i l c a n b e e m u l s i f i e d and s t a b i l i z e d v i a t h e u s e o f Pemulen r e s i n s . The r e s i n s s t a b i l i z e e m u l s i o n s v i a e l e c t r o s t a t i c s t a b i l i z a t i o n . T h i s r e l i e v e s t h e c o n s t r a i n t o f s e e k i n g an appropr i a t e surfactant emulsifier. Inycedi e n t l D I Water Pemulen 1622 ( 1 ) Makon 10 ( 2 ) Dow 200 S i l i c o n e F l u i d ( 3 ) Triethanolamine Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 Product pH: 7.3 P r o d u c t C l a r i t y : Opaque Raw M a t e r i a1 S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) Stepan C o . ( 3 ) Dow C o r n i n g Procedure: 1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s S c r e e n t h e Pemuleri r e s i n i n t . o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r ( 8 0 0 r p m ) . A l l o w t o m i x u n t i l homogeneous and f r e e o f p o l y m e r l u m p s . 2 . Add t h e Makon 10 and m i x u n t i l homogeneous. 3 . Add t h e s i l i c o n e o i l w i t h v i g o r o u s a g i t a t i o n . M i x u n t i l uniform. 4 . Add t h e T E A . M i x u n t i l smoot.h. Total Actives: Silicone O i l : SOURCE:
W t"/. 83.80 0.20 0.70 15.00 0.30
rpm):
1,000 c p
15.00%
DET-510
Miscellaneous
171
Lumi n i z i n g P e t C o n d i t i o n e r P h o s p h o l i p i d EFA adds s h i n e and a s i l k y t e x t u r e t o t h e a n i m a l ' s c o a t o r mane. The Monaquat TG p r o v i d e s body b u i l d i n g c o n d i t i o n i n g and d e t a n g l i n g w h i l e l e a v i n g a s o f t smooth f e e l . Monaquat I S I E S i s an e f f e c t i v e l o n g l a s t i n g a n t i s t a t t h a t controls d i r t attraction. Inaredients: Water Hydroxyethyl C e l l u l o s e Stearic acid Stearyl alcohol Monaquat TG Monaquat I S I E S ( I s o s t e a r y l E t h y l m i d o n i u m E t h o s u l f a t e ) P h o s p h o l i p i d EFA ( L i n o l e a m i d o p r o p y l PG-Dimonium C h l o r i d e Phosphate) Sodium C h l o r i d e
Wt%
85.2 0.8 2.0 2.0 7.0 0.5 2.0 0.5
Procedure: Change w a t e r w i t h a g i t a t i o n , s p r i n k l e i n h y d r o x y e t h y l c e l l u l o s e and t u r n h e a t o n . A t 50-60C add s t e a r i c a c i d , s t e a r y l a l c o h o l , Monaquat TG, Monaquat I S I E S , P h o s p h o l i p i d EFA, and sodium c h l o r i d e . Heat and m i x t o 70-75C ( a smooth c r e m e ) . Cool t o 40C. A d j u s t pH t o 4 . 5 - 5 . 0 . A d d c o l o r , f r a g r a n c e and p r e s e r v a t iv e . Package. Typical Properties: Appearance: Opaque v i s c o u s l o t i o n Recommended Use D i l u t i o n : As i s F o r m u l a t i o n F-777 P e t Shampoo
A h i g h foaming, f r e s h and c l e a n .
m i l d detergent which w i l l
leave your p e t
Ingredients: Water M o n a t e r g e 779 d - L i monene
Wt%
70.0 25.0 5.0
Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t pH t o 7 . 0 . Add c o l o r and p r e s e r v a t i v e . Package. Typical Properties: Appearance: C l e a r y e l l o w l i q u i d Recommended Use D i l u t i o n : F o r m u l a t i o n F-774 1:50 w i t h water
Inc.:
172
M i cro-Emu1 s i ons with d-Li monene
The f o l l o w i n g c o n c e n t r a t e s a r e c l e a r , m i c r o - e m u l s i o n s o f imonene and w a t e r . These f o r m u l a s a r e g e n e r a l l y used b y u t i n g i n w a t e r a r e v e r y e f f e c t i v e f o r r e m o v i n g many o i l y . . I r e s i n o u s s o i l s . The f o r m u l a t h e m s e l v e s a r e c l e a r and e x h i b i t a bloom e f f e c t upon d i l u t i o n . Formula Inqredients: d - L i monene Monamul s e dL-1273 Water F o r m u l a I1 Inqredients: d - L i monene Monamulse dL-1273 Isopropanol Water Formula I11 Ingredients: d - L i monene Monamul se dL-1273 Water
I
Wt%
10.0 18.0 62.0
Wt%
35.0 28.0 5.0 32.0
Wt%
65.0 23.0 12.0
Procedure: I n a l l c a s e s , mix s u r f a c t a n t w i t h d-Limonene u n t i l d i s s o l v e d . Add o t h e r i n g r e d i e n t s e x c e p t w a t e r . M i x u n t i l homogeneous. Add water s l o w l y w i t h s t i r r i n g . Recommended Use D i l u t i o n : 1 : 1 0 w i t h w a t e r
I n c . : F o r m u l a t i o n F-786
Miscellaneous
173
M i cro-Emu1 s i ons w i t h P i ne O i 1
The fol 1owi ng f o r m u l a s a r e c l e a r m i c r o e m u l s i ons o f p i ne o i 1 and w a t e r . They r e p r e s e n t t h e r a n g e o f p i n e o i l and w a t e r concent r a t i o n s commonly used. The f o r m u l a s t h e m s e l v e s a r e c l e a r and e x h i b i t a bloom e f f e c t upon d i l u t i o n . Formula 1 Inaredients: Pine O i l Monamulse TRP Water Appearance: C l e a r D i l u t i o n (1% i n t a p w a t e r ) :
&& y 35.0
20.0 45.0
Blooms Formula 2
I ngredients : Pine O i l Monamul s e TRP Isopropanol Water Appearance: C1 e a r D i l u t i o n (1% i n t a p w a t e r ) :
WtO/o
20.0 20.0
5.0
55.0
Blooms
Formula 3 Ingredients: Pine O i l Monamul se TRP Isopropanol Water Appearance: C1 e a r D i l u t i o n (1% i n t a p w a t e r ) :
Wt%
9.0 10.0 10.0 71 .O
Blooms Formula 4
Inqredients: Pine O i l Monamul se TRP Water Appearance: C l e a r D i l u t i o n (1% i n t a p w a t e r ) :
WtO/o
2.0 5.0
93.0
Clear
Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package Recommended Use D i l u t i o n : 1 : l O w i t h w a t e r F o r m u l a F-785
Inc.:
174
P l a s t i c B o t t l e Wash Stable i n hard water Inqredients: Water KOH-45% K a s i l #I STPP B u r c o HCS-5ONF

% S o l i d s : 31.0
Wt%
26.5 19.5 39.0 8.0 7.0
Add components i n o r d e r l i s t e d .
B l e n d between a d d i t i o n s .
To f o r m u l a t e a l o w e r a c t i v i t y p r o d u c t , keep t h e r a t i o o f t h e components t h e same, so t h a t t h e b a l a n c e o f t h e f o r m u l a t i o n i s n o t d e s t r o y e d . End use c o n c e n t r a t i o n s w i l l depend o n d e g r e e o f s o i l t o b e removed. N o r m a l l y , a 2% end use c o n c e n t r a t i o n i s s u f f i c i e n t f o r b o t t l e cleaning.
A s l i g h t s i l i c a t e p r e c i p i t a t e may o c c u r upon l o n g s t a n d i n g .
B o t t l e Wash F o r m u l a t i o n s Low Foam
Inqredie n t s : 50% NaOH B u r c o BSGH-270 B u r c o HCS-50NF

Add BSGH-270 and HCS-50 NF t o 50% NaOH. M o d e r a t e Foam Inqredients: 50% NaOH B u r c o BSGH-270 B u r c o NPS-225 Water
y &
To 100% T o t a l 2.5-5.0% 0.5-2.5%
To 100% T o t a l 2.5-5.0% 0.5-2.5% 3.0-7.5%
I t i s recommended t h a t t h e BSGH-270 and NPS-225 b e d i s s o l v e d i n an e q u a l amount o f w a t e r and t h e c a u s t i c added t o t h a t p r e m i x . T o defoam t h i s f o r m u l a t i o n use a 3/1 r a t i o o f NPS-225/Burco LAF-I 25.
SOURCE: B u r l i n g t o n Chemical Co.,
Inc.:
Miscellaneous
175
Teroene M icroemul s i ons The f o r m u l a t i o n s g i v e n h e r e w i l l p r o d u c e c l e a r s t a b l e m i c r o e m u l s i o n s c o n t a i n i n g f r o m 15% t o 40% d - l i m o n e n e . G l i d s o l 180 ( f r o m SCM G l i d c o O r g a n i c s C o r p . ) , a p i n e o i l d e r i v a t i v e can b e s u b s t i t u t e d f o r d - l i m o n e n e i n t h e f o r m u l a t i o n s t o g i v e a f l a s h p o i n t above 1 4 0 F . N o t e t h a t o t h e r p i n e o i l s may n o t work i n t h e s e f o r m u l a t i o n s . Formula A: D-Limonene 40.0 Tomah E-14-5 22.4 Tomah E-14-2 2.8 Tomah A l k a l i S u r f a c t a n t 2.8 Water 32.0 % t o t a l s u r f a c t a n t : 28.0% Emul s i f i e r / T e r p e n e r a t i 0 : 0 . 7 0 0 F o r m u l a 5: Wt.9/o D-Li monene 30.0 Tomah E-14-5 19.2 Tomah E-14-2 2.4 Tomah A l k a l i S u r f a c t a n t 2.4 Water 46.0 % t o t a l s u r f a c t a n t : 24.0% Emul s i f ie r / T e r p e n e r a t i 0 : 0 . 8 0 0 Formula C : Wt.% D-Li monene 20.0 12.8 Tomah E - 1 4 - 5 1.6 Tomah E-14-2 Tomah A l k a l i S u r f a c t a n t 1.6 64.0 Water % t o t a l s u r f a c t a n t : 16.0% E m u l s i f i e r / T e r p e n e r a t i o : 0.800 Formula D: Wt.o/a D-Li monene 15.0 12.0 Tomah E-14-5 Tomah E-14-2 1.5 Tomah A l k a l i S u r f a c t a n t 1.5 Water 70.0 % t o t a l s u r f a c t a n t : 15.0% Emulsifier/Terpene r a t i o : 1.000 Add each component i n t h e o r d e r g i v e n and m i x u n t i l homogeneous b e f o r e a d d i n g t h e n e x t component. Add t h e w a t e r i n p o r t i o n s w i t h mixing. A t y p i c a l use l e v e l w o u l d b e a t 1 0 / 1 t o 4 0 / 1 w i t h w a t e r . About 1-2% d - l i m o n e n e a t use l e v e l i s u s u a l l y s u f f i c i e n t . Heavy g r e a s e would r e q u i r e a h i g h e r c o n c e n t r a t i o n o f d-limonene. Concentrated Formula Formula: 70.0 D-Limonene Tomah E-14-5 14.0 Monamid 7 0 5 4.0 T a l l O i l Fatty Acid 1.6 Monoethanolamine 0.4 Water 10.0 SOURCE: Tomah P r o d u c t s , I n c . : B u l l e t i n : T e r p e n e M i c r o e m u l s i o n s
176
Wax Emulsion U s i n g Pemulen R e s i n s T h i s wax e m u l s i o n can be c r e a t e d and s t a b i l i z e d v i a t h e use o f Pemulen r e s i n s . The r e s i n s s t a b i i z e e m u l s i o n s v i a e l e c t r o s t a t i c s t a b i l i z a t i o n . T h i s r e l i e v e s t h e c o n s t r a i n t o f s e l e c t i n g an appropriate surfactant emulsifier. Ingredient: Bareco C-36 Wax ( 1 ) Hoechst Wax E ( 2 ) Pemulen 1622 ( 3 ) 01 Water Morphol ine Physical Properties : P r o d u c t C l a r i t y : Opaque Raw M a t e r i a l S u p p l i e r s : ( 1 ) P e t r o l i t e Corp. ( 2 ) American Hoechst Corp. ( 3 ) BFGoodrich Procedure: 1. M e l t t h e waxes t o g e t h e r i n a v e s s e l , a p p r o x i m a t e l y a t 9 0 C . 2 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s Screen t h e Pemulen r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 rpm). A l l o w t o mix u n t i l homogeneous and f r e e o f p o l y m e r lumps. 3 . Heat t h e Pemulen d i s p e r s i o n t o 9OC. Add t h e Pemulen d i s p e r s i o n t o t h e m e l t e d wax w i t h v i g o r o u s a g i t a t i o n . 4 . Add t h e m o r p h o l i n e and cool q u i c k l y . Total Actives: T o t a l Wax: 20.00% SOURCE: BFGoodrich S p e c i a l t y Chemicals:
vytsb 12.00
8.00 0.30 79 5 0 0.20

~
DET-501
Section II sportation Cleaners and Polishes
177
15. Auto Cleaners and Polis
178
Auto Cleaners and Polishes
179
Chrome P o l i s h I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase s e p a r a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s . Ingredient: D I Water Morphol ine Pumice Snow F l o s s SFSB S i l i c o n e F l u i d ( 3 5 0 ) ( 1 ) Yarmor 302 P i n e O i l ( 2 ) Oleic Acid Mineral S p i r i t s TEA l a u r y l s u l f a t e ( 3 ) Cocamide DEA ( 4 ) D I Water Carbopol EZ-2 ( 5 ) Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 P r o d u c t pH: 9 . 0 P r o d u c t C l a r i t y : Opaque Raw M a t e r i a l S u p p l i e r s : ( 1 ) General E l e c t r i c ( 2 ) Hercules ( 3 ) Rhone-Poul enc ( 4 ) H e n k e l : Standamid ( 5 ) BFGoodri c h r p m ) : 10,800 c p 39.25 1.39 14.00 9.25 1.85 0.46 1.85 24.50 2.30 0.50 4.46 0.19
PO
Procedure: 1 . D i s s o l v e t h e morpholine i n t h e water. 2 . W i t h r a p i d a g i t a t i o n , add t h e pumice and Snow F l o s s . 3 . D i s s o l v e t h e s i l i c o n e o i l , p i n e o i l , and o l e i c a c i d i n t h e m i n e r a l s p i r i t s . S l o w l y add i n t o t h e above m i x t u r e w i t h rapid agitation. 4 . Add i n t h e TEA l a u r y l s u l f a t e and Standamid PD. B l e n d t h o r oughl y 5. I n a s e p a r a t e v e s s e l , d i s p e r s e 0 . 1 9 p a r t s o f Carbopol i n t o 4.48 p a r t s o f w a t e r by s i m p l y "dumping" t h e polymer i n t o t h e w a t e r . I n j u s t a few m i n u t e s , t h e polymer w i l l c o m p l e t e l y wet o u t . Add t h i s d i s p e r s i o n t o t h e above m i x t u r e . B l e n d thorough1y
T o t a l Asti ves :
Silicone Fluid: Total Surfactant: Mineral S p i r i t s : T o t a l Abrasives: 1.85 4.65 24.50 23.25 DET-551
FGoodrich S p e c i a l t y Chemicals:
I80
L i q u i d Car Polish I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase s e p a r a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s . Insredient: D I Water T r i e t h a n o l ami ne Wax Emulsion ( 1 ) Morphol ine SF90 S i l i c o n e F l u i d (350) ( 2 ) Oleic Acid Kerosene Mineral S p i r i t s D I Water Carbopol EZ-2 ( 3 ) Isopropanol Mineral S p i r i t s SF1706 R e a c t i v e Amine Polymer ( 4 ) SF1705 R e a c t i v e Amine Polymer ( 4 ) Kaopolite kaolin clay (5)
Wt96
37.80 8.20 2.50 2.00 1 * 50 2.50 10.00
8.00 49.70
0.30 0.40 5.00 1.50 2.10 8.50
Physical P r o p erties: B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 3,200 cps P r o d u c t pH: 8-9 P r o d u c t C l a r i t y : Opaque Raw M a t e r i a l S u p p l i e r s : ( 1 ) see EiFGoodrich L i t e r a t u r e DET-501 ( 2 ) General E l e c t r i c ( 3 ) BFGoodrich ( 4 ) General E l e c t r i c (5) Kaopolite, I n c . Procedure: 1 . M i x t o g e t h e r t h e w a t e r , TEA, wax emulsion, and t h e m o r p h o l i n e 2 . I n a s e p a r a t e v e s s e l , mix t h e s i l i c o n e f l u i d , o l e i c a c i d , kerosene and t h e m i n e r a l s p i r i t s t o g e t h e r . Add t h i s t o t h e above m i x t u r e w i t h v i g o r o u s a g i t a t i o n . 3. I n a s e p a r a t e v e s s e l , d i s p e r s e 0.30 p a r t s o f Carbopol i n t o 19.70 p a r t s o f water by s i m p l y "dumping" i t i n . The polymer w i l l wet o u t i n a few minutes. Add t h i s d i s p e r s i o n t o t h e above m i x t u r e . M i x u n t i l homogeneous. 4 . I n a s e p a r a t e v e s s e l , mix t h e i s o p r o p a n o l , m i n e r a l s p i r i t s , and t h e t w o r e a c t i v e amine polymers t o g e t h e r . Add t o t h e above m i x t u r e . M i x u n t i l homogeneous. 5 . S l o w l y add i n t h e c l a y . M i x u n t i l homogeneous. Total Actives: T o t a l Wax : 0.50 Silicone Fluid: 1.50 Mineral S p i r i t s : 11 .oo 3.60 React ive A m i ne Polymer : Abrasive: 8.50 SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-BOO
Auto Cleaners and Polishes
181
L i q u i d Spray C l e a n e r f o r A l u m i n u m T r u c k s
Bngredi e n t s : Water Phosphoric A c i d , 75% C i t r i c Acid Macol 48 Ammoni u B i f 1u o r i de m Avanel S-30
Wt% 50.0
20.0
10.0 4.0
3.0 3.0
~ r ~ c ~ d U r ~ ~ Add i n g r e d i e n t s i n o r d e r as l i s t e d . D i l u t e one p a r t c l e a n e r w i t h f i v e p a r t s w a t e r t o use.

A 1 umi n u m C l e a n e r / B r i n h t e n e r
Pnaredi e n t : Phosphoric A c i d , 85% C i t r i c A c i d , 50% N i t r i c A c i d , 70% Avanel S-70 Water
Wt% 6.0 8.0

1.o
2.0
83.0
Procedure: Charge t h e w a t e r t o t h e m i x i n g v e s s e l . Under s l o w a g i t a t i o n and w i t h due c a r e , add t h e a c i d s t o t h e w a t e r . Add t h e Avanel S - 7 0 and mix f o r 10 m i n u t e s . Note: I f a d d i t i o n a l b r i g h t e n i n g i s r e q u i r e d , t h e n i t r i c a c i d may be i n c r e a s e d t o 1.5%. F o r m u l a t i o n CM-101 Non-Phosphorous A l u m i n u m C l e a n e r Inaredi ent : C i t r i c A c i d , 50% G l u c o n i c A c i d , 50% Avanel 5-70 Water, Dye
Wt%
12.0
8.0
3.0 77.0
PPOC@dUr&?: Charae t h e w a t e r , c i t r i c a c i d , g l u c o n i c a c i d and Avanel S-70 t o t h e G i x i n g v e s s e i . M i x w e l l . I f - d y e i s t o be added, p a r t of t h e water s h o u l d be h e l d o u t . Add t h e dye t o t h e w a t e r w i t h good a g i t a t i o n and t h e n add t h e w a t e r t o t h e b a t c h . Formu 1a t ion CM- 102
UWCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
182
M i l d A b r a s i v e A u t o m o b i l e Polish I n q r e d ie n t : Part A: Masi 1 SF 1 , 0 0 0 Oleic Acid Carnauba Wax #1 Y e l l o w Isopar M Mazami de SS-1 0 P a r t B: Isopar M M a s i l 123 Part C : I sopar M Morphol ine P a r t D: Water K a o p o l i t e SF pH ( a s i s ) : 7 . 5 - 8 . 5 Appearance: Cream-Colored Paste Procedure: 1 . Charge t h e components i n P a r t A t o a steam-heated m i x i n g v e s s e l equipped w i t h a g i t a t i o n . S t a r t a g i t a t i o n and h e a t t o
Wt%
4.0 2.0 6.0 14.5 0.75
12.0
2.0
2.5 1.1
45.15 10.0
9QC.
I n s e p a r a t e v e s s e l s , charge P a r t B and P a r t C components. When P a r t A reaches 9OC and a l l t h e wax has m e l t e d , add P a r t B t o t h e v e s s e l f o l l o w e d by P a r t C . Apply c o o l i n g . 3 . I n a s e p a r a t e v e s s e l , p r e p a r e P a r t D by a d d i n g t h e K a o p o l d t e SF t o t h e w a t e r under a g i t a t i o n . Add P a r t D t o P a r t A and c o n t i n u e c o o l i n g . NOTE: The f i n i s h e d p r o d u c t i s a p a s t e . A s t i f f e r p a s t e can be p r e p a r e d by i n c r e a s i n g t h e o l e i c a c i d charge.
2.
SOURCE:
PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n S A - 1 0 1
r and Truck Wash Compounds
183
184
Car Shampoo C o n c e n t r a t e T h i s f o r m u l a t i o n produces c o p i o u s amounts o f foam w h i l e c l e a n i n g a u t o m o t i v e f i n i s h e s . I t i s m i l d t o b o t h t h e u s e r and t h e automotive f i n i s h . Ingredient: Part A: Dei o n i zed Water Sodi u C i t r a t e m
Wt%
30.0 0.5
P a r t 8: Mafo CSB-50 5.0 7.5 W i t c o n a t e 60 T L i q u i d Macol TD-12 4.0 T r i e t h a n o l ami ne, 85% 1.o D e i o n i z e d Water 52.0 pH ( a s i s ) : 8 . 0 - 9 . 0 Appearance: C l e a r , l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1.00 Procedure: 1 . Charge t h e f i r s t p o r t i o n o f w a t e r t o a m i x i n g v e s s e l and d i s s o l v e t h e sodium c i t r a t e i n i t . 2 . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d . S t o p a g i t a t i o n and p e r m i t t h e p r o d u c t t o d e a e r a t e p r i o r t o f i l l i n g o f f . NOTE: Use c o n c e n t r a t i o n i s 1-2 ounces p e r g a l l o n o f warm w a t e r . A u t o m a t i c Car Wash C o n c e n t r a t e
w.t% I n a r e d ie n t s : 50.0 Dei o n i zed Water 6.0 Maphos 60-A 3.0 Potassi u Hydroxide m 2.0 T e t r a p o t a s s i u m Pyrophosphate 2.0 Sodium M e t a s i l i c a t e , Anhydrous 2.0 Macol LF 120 Mazamide 00 2.0 Sodium X y l e n e S u l f o n a t e , 40% 3.0 Macol 48 3.0 D e i o n i z e d Water 27.0 pH ( a s i s ) : 12.5-13.5 Appearance: C l e a r , l i g h t - y e l l o w l i q u i d S p e c i f i c Gravity: 1 .06 Procedure: Charge t h e f i r s t p o r t i o n o f w a t e r t o t h e m i x i n g v e s s e l and s t a r t a g i t a t i o n . Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d and mix u n t i l c l e a r . NOTE: T h i s i s a h i g h l y a l k a l i n e c l e a n e r d e s i g n e d t o be used i n commercial a u t o m a t i c c a r washes a t a d i l u t i o n r a t e o f 1-2 ounces p e r g a l l o n . Do n o t use d i r e c t l y on a u t o m o t i v e f i n i s h e s F o r m u l a t i o n CA-102
SOURCE:
Inc.: Suggested F o r m u l a t i o n s
Car and Truck Wash Compounds
185
Car Wash ( C a l s o f t LAS-gg-Basedl Ingredients: Water NaOH, 50% D i e t h a n o l ami ne C a l s o f t LAS-99 Calamide C P i l o t SXS-40 Cal foam EA-603 Ammonium C h l o r i d e Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-008-01 Car Wash ( C a l s o f t LAS-99-Based) Ingredients: Water NaOH, 50% Cal s o f t LAS-99 Calamide C P i l o t SXS-40 C a l foam EA-603 C a l o x y l a t e N-9 Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s in o r d e r 1 is t e d F o r m u l a t i o n CWC-007-01 Car Wash ( C a l s u d s A-Based) Ingredients: Water Calsuds A C a l foam EA-603 C a l s u d s CD-6 Ammonium C h l o r i d e Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-006-01 Car Wash ( C a l s o f t T-60-Based) Ingredients : Water C a l s o f t T-60 Pi l o t sxs-40 C a l o x y l a t e N-9 Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-005-01 SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s
Weight% 72.50 2.40 0.50 10.10 3.70 7.00 2.80 1.oo
Wei q h t % 59.80 4.35 16.30 2.05 12.50 3.00

2.00
Wei a h t % 64.20 28.00 2.80 4.00 1 .oo
Weight% 70.00 20.00 5.00 5.00
186
Car Wash Readi l y removes a w i d e v a r i e t y o f r o a d s o i 1 s . Ingredients: Water Monaterge ALX-100s (Cocamide DEA ( a n d ) DEA D o d e c y l benzenesulfonate (and) Diethanolamine) 70.0 30.0
Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t pH t o 7 . 0 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e . Package. Typi c a l P r o p e r t i e s : Appearance: C l e a r y e l l o w l i q u i d Recommnded Use D i l u t i o n : 1 : 2 0 w i t h w a t e r F o r m u l a t i o n F-772 P a s t e Car Wax T h i s e a s i l y a p p l i e d a u t o m o b i l e p a s t e wax f o r m u l a w i l l p r o v i d e i m p r o v e d c l e a n i n g , d e p t h o f g l o s s , l a s t i n g b e a u t y and s h i n e t o new and o l d e r a u t o m o b i l e f i n i s h e s . M o n a s i l PCA w i l l p r o v i d e s h i n e and d e t e r g e n t r e s i s t a n c e t o any p a s t e wax f o r m u l a . Ingredients: P a r t I: M o n a s i l PCA Dimethicone (12,500 c s t ) Carnauba Wax #1 Y e l l o w T a l l O i l Fatty Acid Isopar K Kaopol it e 11 5 2 P a r t 11: Water TEA (99%)
We96
4.5 2.0 6.0 3.0 24.0 10.0
50.0 0.5
Procedure: P r e p a r e each phase s e p a r a t e l y , h e a t t o 70C. Add P a r t I I s l o w l y t o P a r t I w i t h good a g i t a t i o n . S t i r coo t o 40-50C and package. F o r m u l a t i o n F-826
Inc.:
Suggested Formu a t i o n s
187
Car Wash w / A m p h o t e r i c Ingredients: Water, D . I . Sodi um T r i p o l y p h o s p h a t e R e w o t e r i c AM 8-14 V a r o n i c DM-55 Sodi um H y d r o x i d e , 30% W i t c o 1298SA
wt%
55.0 4.0 10.0 2.0 9.0 20.0
Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e compl e t e l y between each a d d i t i o n . Typical Properties: V i s c o s i t y , c p s : 290 S o l i d s : 29.5% pH: 8 . 9 F o r m u l a 630 W i n d s h i e l d Washer C o n c e n t r a t e Ingredients: Water, D . I . Isopropanol P e t r o BAF Powder DeSophos 5AP EDTA, 38% B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . d i l u t e up t o 2 9 : l f o r summer u s e .
B1 e n d i ng
Wt%
56.0
30.0
1.o 0.5 2.5
Use " a s i s " i n w i n t e r ; F o r m u l a 666
W i n d s h i e l d Washer F o r m u l a t i o n Inqredi ents: W i t c o n a t e 1240 Isopropanol Water 1.o 39.0 60.0 t h e n add i s o p r o p a n o l
Wt%
51 e n d i ng P r o c e d u r e : D i s s o l v e W i t c o n a t e 1240 in w a t e r , F o r m u l a 867
188
Car Wash C o n c e n t r a t e w / A l c o h o l I n q r e d ie n t s : Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t c a m i d e 128T B l e n d i n g Procedure:
Ethoxylate 64.9 8.3 16.7 1.3 5.0 3.8
Blend ingredients i n t h e order l i s t e d
Typical Properties: V i s c o s i t y , c p s : 210 A c t i v e s , %: 2 3 . 7 F o r m u l a 61 1 Car Wash C o n c e n t r a t e w / A l c o h o l Ingredients: Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t c a m i d e 128T Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . T y p i c a l P r o p e r t ie s : V i s c o s i t y , c p s : 335 A c t i v e s , %: 37.5 F o r m u l a 611 Car Wash C o n c e n t r a t e w / A l c o h o l I n a r e d ie n t s : Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t c a m i d e 128T B l e n d i n g P r o c e d u r e : B1 end i n g r e d i e n t s i n t h e o r d e r 1 is t e d . Typical Properties: V i s c o s i t y , c p s : 315 A c t i v e s , %: 4 3 . 0 F o r m u l a 611 SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s Ethoxylate 36.0 15.0 30.0 6.0 8.0 5.0 Ethoxylate
W S 43.3
13.9 27.8 5.0 7.0 3.0
189
C a r and T r u c k Wash F o r m u l a
Ingredients: C a l f a x DB-45 C a l s o f t L-40 T r i s o d i um Phosphate Water Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-001-01 Car a n d T r u c k Wash F o r m u l a Ingredients: C a l f a x DB-45 C a l s o f t L-40 D i s o d i um Phosphate Water Comments a b o u t t h i s f o r m u l a : 1 . T h i s i s l o w e r p H f o r m u l a t h e n CWC-001-01. 2 . H e a t i n g i s n e c e s s a r y t o homogenize. F o r m u l a t i o n CWC-002-01 Car Wash [Powder) Ingredients: Sodi um T r i p o l y p h o s p h a t e C a l s o f t F-90 Cal o x y l a t e N-9 Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-003-01 Wei q h t % 85.00 5.00 10.00 Wei q h t % 20.00 25.17 10.04 44.76 Wei q h t % 19.83 24.95 10.02 45.18
C a r Wash ( C a l s u d s A-Based)
Inqredients: Calsuds A C a l foam EA-603 C a l o x y l a t e N-9 Water Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-004-01 SOURCE: B1 io t Chemi c a l Co. : Suggested F o r m u l a t i o n s Wei g h t % 50.00 3.00 2.00 45.00
190
Car Wash and Care Car Shampoo with Water-Repellent Effect Ingredients: Autopur WK 4332 Amphotensid 0 4 Water Formula CT 0 4 - 0 3 - 0 2 Rinse-off ARent (Water-Repellent) Ingredients: Autopoon GK 4004 Mulsifan RT 1 Produkt 2058 Pine oil Butyl di glycol Water Formula CT 0 4 - 0 5 - 0 7
wtu/, 17.0 6.0 6.0 3.0 8.0 60.0
Wt%
45.0 5.0 50.0
Rinse-off Aqent (Water-Repellent) Without Hydrocarbons Ingredients: Autopoon GK 4008 Mulsifan RT 1 Produkt 2058 Butyl di glycol Water Formula CT 04-05-03 Windshield-Cleaner (Summer) Inqredi ents: Water Ethanol Zusol at 1 0 0 5 / 8 5 Zusolat 1 0 0 8 / 8 5 Formula CT 0 4 - 0 6 - 0 1 Innredi ents: Water Zetesol NL Zusol at 1 0 0 8 / 8 5 Isopropanol Formula CT 0 4 - 0 6 - 0 4
SOURCE: Zschimmer & Schwarz GmbH &
Wt%
17.0 6.0 6.0 8.0 63.0
Wt%
67.9 20.0 5.2 6.9
Wt%
23.7 64.0 1.3 11 . o
Co.: Suggested Formulations
191
Car Wash and C a r e Windshield-Cleaner Ingredients: Water Isopropanol Z e t e s o l 2056 F o r m u l a CT 04-06-07 I n s e c t Remover Inqredi ents: S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 Trilon A liquid Monoethanol ami ne Butyl d i g l ycol Water F o r m u l a CT 04-07-01 Wheel C 1 e a n e r Ingredients: Water Tetrapotassium pyrophosphate Lumorol 4192 Z u s o l a t 1005/85 Butyl diglycol Orange t e r p e n e F o r m u l a CT 0 4 - 1 1 - 0 4 T a r Remover Inqredients: M u l s i f a n K 326 S p e z i a l Whi t e - s p i r i t n-butanol Oleic acid Water F o r m u l a CT 04-13-02 (Winter)
Wtl
29.5 70.0 0.5
Wt%
4.0 2.0 2.0 4.0 4.0 5.0 79.0
. A 1 k a l in e
Wt%
77.5 3.0 10.0 4.0 5.0 0.5
Wt%
15.0 60.0 7.0 3.0 15.0
SOURCE:
192
Car Wax
Ingredient: Part A: Morphol ine Water P a r t B: Wax S Oleic Acid M i n e r a l Spi r i t s Kerosene Part C: M a s i l EM 250 C M a s i l EM 1 0 , 0 0 0 C Snow F l o s s Kaopol it e SF Carbopol 941 ( 1 % i n w a t e r )
Wt%
0.8 44.2
1.o 18.0
8.0 9.0
10.0 3.0
3.0
3.0
As needed
Procedure: 1 . Add t h e m o r p h o l i n e t o t h e w a t e r w i t h h i g h speed m i x i n g . 2 . I n P a r t B , add t h e o l e i c a c i d , m i n e r a l s p i r i t s , kerosene, and Wax S w i t h h i g h speed m i x i n g . Add P a r t B t o P a r t A w i t h h i g h shear m i x i n g . 3 . Add t h e M a s i l EM 250 C and M a s i l EM 10,000 C f r o m P a r t C t o t h e c o n c e n t r a t e w i t h s l o w m i x i n g . Add t h e Snow F l o s s and K a o p o l i t e S F . T h i c k e n w i t h t h e Carbopol 941 s o l u t i o n . A u t o Wipe B S h i n e P o l i s h Ingredient; Part A: M a s i l SF 100 A-C 617A Oleic Acid M i n e r a l O i 1 , 70 SUS Part 0 : Morphol ine Carbopol 934 Triethanolamine Water
3.5
2.0
1.5
5.6
1.4 0.2 0.2 85.6
Procedure: 1 . Add t h e i n g r e d i e n t s i n P a r t A as l i s t e d and h e a t t o 9OC. 2 . F o r P a r t B, h e a t t h e w a t e r t o 85C. D i s p e r s e t h e Carbopol 934 i n t h e w a t e r . When c o m p l e t e l y d i s s o l v e d , add t h e t r i e t h a n o l amine. Then, add t h e m o r p h o l i n e . 3. Add P a r t A t o P a r t 0 and b l e n d .
SOURCE: PPG I n d u s t r i e s ,
193
Concentrated T r a f f i c F i l m Removers
Two f o r m u l a t i o n s were d e v e l o p e d w h i c h c o n t a i n 50% t o t a l w a t e r , i n c l u d i n g t h e w a t e r i n t h e sodium m e t a s i l i c a t e p e n t a h y d r a t e . One c o n t a i n s n o n i o n i c , t h e o t h e r h a s no n o n i o n i c b u t has more AO-14-2 and A l k a l i S u r f a c t a n t , t h e c o m b i n a t i o n o f w h i c h s h o u l d do as w e l l as t h e n o n i o n i c f o r h a r d s u r f a c e c l e a n i n g . Mix i n t h e order given: Formula 1: Component: Water Versene 1 0 0 Sodium M e t a s i l i c a t e P e n t a h y d r a t e Tomah A l k a l i S u r f a c t a n t Tomah AO-14-2 Tomah Q-17-2
% anhydrous b u i l d e r :
Wt%
22.00
38.00
8.00 16.00 8.00 8.00
19.00 S u r f a c t a n t / b u i l d e r r a t i o : 1.68
Mix i n t h e order given: Formula 2 : Component: Water Versene 100 Sodium M e t a s i l i c a t e P e n t a h y d r a t e Tomah A l k a l i S u r f a c t a n t Tomah AO-14-2 Tomah Q-17-5 Noni o n i c NP-9.5
% anhydrous b u i l d e r : 9.82% S u r f a c t a n t / b u i l d e r r a t i o : 4.07
Wt.%
36.20 19.70 4.10 10.00 10.00 10.00 10.00
N o t e t h a t sodium m e t a s i l i c a t e p e n t a h y d r a t e i s a c t u a l l y a b o u t 57% sodium m e t a s i l i c a t e on an anhydrous b a s i s . Versene 100 i s a b o u t 38% t e t r a s o d i u m EDTA on an a n h y d r o u s b a s i s . Thus t h e s e f o r m u l a t i o n s a r e a b o u t 50% t o t a l w a t e r when c a l c u l a t e d on an a n h y d r o u s b u i l d e r b a s i s . The s u r f a c t a n t s were c o n s i d e r e d on an a s - i s b a s i s , and n o t c o r r e c t e d f o r t h e w a t e r c o n t e n t . Anhydrous sodium m e t a s i l i c a t e and a n h y d r o u s t e t r a s o d i u m EDTA a r e r e a d i l y a v a i l a b l e ; a n h y d r o u s a m p h o t e r i c s and amine o x i d e s are not. These f o r m u l a t i o n s were made up and f o u n d t o b e f r e e z e - t h a w s t a b 1 e. F o r m u l a 1 was d i l u t e d 1/20 w i t h w a t e r t o 2.5% a c t i v e s , and t e s t e d b y s p r a y i n g on a d i r t y c a r . It was compared w i t h F o r m u l a t i o n T-107 T r a f f i c F i l m Remover a l s o a t 2.5% a c t i v e s . No s i g n i f i c a n t d i f f e r e n c e s were seen, so t h e absence o f n o n i o n i c d i d n o t adversely a f f e c t t h e performance o f t h e concentrated f o r m u l a t i on. SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
194
Foamy B r u s h Car Wash, Inqredients: Water, D . I . * C a u s t i c Soda, 50% W i t c o 1298SA W i t c o l a t e SE-5 P e t r o BAF L i q u i d W i t c a m i d e 128T Formal i n Sodi um C h l o r i d e Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . used t o a d j u s t v i s c o s i t y o f t h e p r o d u c t . T y p i c a l P r o p e r t i es : S p e c i f i c G r a v i t y : 1.015 Wt./Gal. l b s . : 8.46 pH, a s i s : 9 . 8 V i s c o s i t y , cps: 410 D i l u t i o n R a t i o a t Wand=l : 4 0 * I f u n s o f t e n e d t a p w a t e r i s used, t o counteract hardness. F o r m u l a 621
Liquid
Wtg
79.75 1.40 5.00 7.00 3.00 3.00 0.10
0.75
Sodium C h l o r i d e i s
add 0 . 2 5 % l i q u i d EDTA,
40%
Low C o s t Car= Ingredients: Water. D . I . P e t r o LBA Powder W i t c o l a t e SE-5 W i t c a m i d e 128T Formal in Sodi um C h l o r i d e Perfume, Dye
Wt%
89.9 1 .o 6.0 3.0 0.1 4.s. 4.s.
Blending Procedure: Blend t h e i n g r e d i e n t s i n t h e order l i s t e d . A d j u s t t h e p H = 7 . 5 - 8 . 0 . The Sodium C h l o r i d e i s used t o a d j u s t t h e v i s c o s i t y o f the f i n a l product. F o r m u l a 609
195
G e n e r a l Purpose C a r Wash T h i s i s a c o p i o u s - f o a m i n g , a l l - p u r p o s e c a r wash f o r m u l a t e d t o b e s a f e on c a r f i n i s h e s , y e t e f f e c t i v e i n t h e removal o f r o a d g r i m e and o t h e r s o i l s . Insredient : D e i o n i z e d Water Mazon 98 Macol TD-3 W i t c o l a t e WACLA Mazamide 80 Macol 48 Triethanolamine, D e i o n i z e d Water
w b
50.0 9.5 1.5 2.5 3.0 1.o 1.5 31 . O liquid
85%
pH ( a s i s ) : 8 . 5 - 9 . 5 Appearance: C l e a r , l i g h t - y e l l o w S p e c i f i c G r a v i t y : 1.02
Procedure: Charge t h e f i r s t p o r t i o n o f w a t e r t o a m i x i n g v e s s e l and s t a r t slow a g i t a t i o n (excessive a g i t a t i o n w i l l produce a f o a m i n g p r o b l e m ) . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d and m i x u n t i l c l e a r . NOTE: Use c o n c e n t r a t i o n i s 1-2 ounces p e r g a l l o n o f warm w a t e r . F o r m u l a t i o n CA-103
L i q u i d Car Wash Ingredient: Water W i t c o n a t e 60 T L i q u i d Macol OP-10 SP Mazamide 80 Hexyl Carbi t o 1 Methanol Procedure: Add i n g r e d i e n t s i n o r d e r a s l i s t e d . B o a t Wash & CarPCleaner
~~ ~~~~
34.0 30.0 10.0 6.0 10.0 10.0
NtS
Ingredient: Water Mazamide 80 Macol NP 9 . 5 W i t c o n a t e 60 T L i q u i d Procedure: Add i n g r e d i e n t s i n o r d e r as l i s t e d . SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
39.0 11 . o 5.0 45.0
vvt%
196
Advanced Cleaning Product Formulatiom
Heavy D u t y T r u c k Wash, L i q u i d
Inqredients: Water, D . I . T r i s o d i um Phosphate, C r y s t a l C a u s t i c Soda Beads W i t c o 1298 S o f t A c i d P e t r o BAF L i q u i d Sodium S i l i c a t e 40 Be' ( S t a r ) W i t c o l a t e SE-5 E t h y l e n e G l y c o l M o n o b u t y l E t h e r (EB) Emcol 6744 Blending Procedure: B l e n d i n g r e d i e n t s in o r d e r 1 i s t e d . Typical Properties: S p e c i f i c G r a v i t y : 1.042 Wt./Gal. l b s . : 8.69 pH, a s i s : 1 2 . 7 D i l u t i o n R a t e : D i l u t e 1 : 4 0 a t Wand F o r m u l a 603 70.0 2.0 2.0 10.0 3.0 3.0 3.0 3.0 4.0
Heavy D u t y T r u c k Wash,
Powder
Inqredients: Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y Sodium T r i p o l y p h o s p h a t e , L i g h t D e n s i t y DeSophos 5AP DeSonic 9N Sodium M e t a s i l i c a t e , Anhydrous Sodium S u l f a t e ( S a l t Cake) C a u s t i c Soda Beads Dye*
wtd/,
47.25 55.00 2.90 7.50 5.00 10.00 2.30 0.05
B1 e n d i ng P r o c e d u r e : P r e m i x Soda Ash and T r i p o l y t o g e t h e r and s l o w l y add DeSophos 5AP w h i l e m i x i n g . M i x u n t i l p r o d u c t i s u n i f o r m i n a p p e a r a n c e . Add DeSonic 9 N w h i l e m i x i n g . M i x u n t i l t h e p r o d u c t l o o k s d r y ( 4 - 5 m i n u t e s ) . Add M e t a s i l i c a t e , S a l t Cake and t h e n C a u s t i c Soda beads. * I f d y e i s used, m i x w i t h t h e DeSonic 9N. F o r m u l a 604 SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
197
Premium Car Wash C o n c e n t r a t e Ingredients: Water, D . I . Ethanol Varox 1 7 7 0 W i t c o n a t e AOS L i q u i d W i t c o l a t e SE-5
Wt%
11.7
5.9 17.6 46.8 17.6
B l e n d i ng P r o c e d u r e : Add a l l i n g r e d i e n t s e x c e p t W i t c o l a t e SE-5, i n o r d e r shown and d i s s o l v e completely between each a d d i t i o n . Add W i t c o l a t e SE-5 l a s t i n s m a l l a l i q u o t s a l l o w i n g c o m p l e t e d i s s o l u t i o n between additions.
T y p i c a l P r o p e r t i es : V i s c o s i t y , c p s : 160 S o l i d s : 35.4% pH: 8.4 Formula 629 Car Wash Ingredients: Water T e t r a p o t a s s i um Pyrophosphate, W i t c a m i de 6445
Wt%
60% 91.67 3.33 5.00
51ending Procedure: Blend i n g r e d i e n t s i n o r d e r l i s t e d . T y p i c a l P r o p e r t i es : V i s c o s i t y , cps: 2100 S o l i d s : 6.8% pH, as i s : 9 . 3 Formula 615 A u t o Shampoo C o n c e n t r a t e
P n g r e d ie n t s : Water, D . I . R e w o t e r i c A KSF-40 M W i t c o l a t e SE-5
Wt%
80.0 15.0 5.0
Blending Procedure: Add in g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 4.0 S o l i d s : 9.0% ptl: 9 . 5 Formula 628 SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
198
T o u c h l e s s V e h i c l e Wash D e t e r a e n t l Z e r o Phosphate, Powder) Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s , road f i l m Surface-Painted metal surface, Polymeric A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) M a n u f a c t u r e - D r y B1 end/Aggl o m e r a t i on Composition: \nrt36 Sodium C a r b o n a t e 25-30 M e t s o Beads 2048 20-25 *Sodium P o l y a c r y l a t e (92% s o l i d s ) 1.0- 3.0 5-1 0 Surfactant T u r b o b r i t e A1 umi n o s i 1 ic a t e 25-35 F i 1l e r s Balance D i l u t i o n : 1.0-2.0% by weight ( 0 . 1 - 0 . 2 pounds/gallon) Add 0 . 1 - 0 . 2 pounds o f d e t e r g e n t p e r g a l l o n o f w a t e r o u t p u t t o t h e s p r a y n o z z l e . M i x powder d e t e r g e n t i n t a n k and m e t e r i n t o c a r wash s y s t e m . M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e i s e x t r e m e l y e f f e c t i v e i n h i g h p r e s s u r e s p r a y wash systems f o r r e m o v i n g o i l and w a t e r d e p o s i t s , p a r t i c u l a t e s o i l s , and haze f r o m body p a r t s and w i n d s h i e l d s . C o n s t a n t a g i t a t i o n i n t a n k i s n e c e s s a r y t o keep T u r b o b r i t e suspended. V e h i c l e Wash D e t e r g e n t (Low pH) ( Z e r o Phosphate. Powder) Soil-Grease, o i l , s a l t , water deposits, c l a y , p a r t i c u l a t e s , road f i l m . Surface-Painted metal surface, Polymeric A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manufacture-Dry blend/Agglomeration Composi t i on : Wt% Sodium C a r b o n a t e 27.9 B r i t e s i 1 H20 Hydrous Sodi um P o l y s i 1 i c a t e 21 . o * A c u s o l 445ND Sodi um Pol y a c r y l a t e (92% s o l id s ) 3.0 **Liquid Nonionic Surfactant 12.0 36.1 V a l f o r 100 Z e o l i t e A * D i l u t i o n : 1 . 5 % by w e i g h t ( 0 . 1 2 5 p o u n d s / g a l l o n ) Add 0 . 1 2 5 pounds o f d e t e r g e n t p e r g a l l o n o f w a t e r o u t p u t t o t h e s p r a y n o z z l e . D i s s o l v e powder d e t e r g e n t i n t a n k and m e t e r i n t o c a r wash s y s t e m . M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f V a l f o r 100 i s e x t r e m e l y e f f e c t i v e i n h i g h p r e s s u r e s p r a y wash s y s t e m s f o r r e m o v i n g o i l and w a t e r d e p o s i t s , p a r t i c u l a t e s o i l s , and haze f r o m body p a r t s and w i n d s h i e l d s . C o n s t a n t a g i t a t i o n i n t a n k i s n e c e s s a r y t o keep V a l f o r 100 suspended i n s o l u t i o n . Rohm & Haas Low Foam: Rhone-Poulenc A n t a r o x BL-330 ( 3 moles E O ) H i g h Foam: S h e l l Chemical Neodol 23-6.5 o r Neodol 25-7
**
Detergent F o r m u l a t i o n Guide
199
Truck/Bus Wash Components: Burco TME B u r c o s o l v TM Neodol 91-6

TEA 85% % by Weight 7
Burcene 1 0 0 Water
5 20 5 2
8 a l ance
D i l u t e 50:l t o 1OO:l depending on degree o f s o i l t o be removed Economy Truck/Bus Wash Components: Water Burco TME Meodol 1.5 C i t r i c A c i d L i q u i d 50% KOH. 45% Ammonyx LO
TEA 85% % by Weight
76
D i l u t e 20:l t o 50:l depending on degree o f s o i l t o be removed.
SOURCE:
B u r l i n g t o n Chemical Co.,
Car Shampoo
I g r e d ien t s : n Z e t e s o l 2056 Lumo WW 75 Z u s o l a t 1008/85 P u r t o n CFD Water Formula D 1 1 / 1 0
% by Wei a h t
15.0
10.0
1. o 75.0
3.0
Car Wash and Wax Shampoo Ingredients: Zusol a t 1008/85 Wachsemul s i on 1864 Isopropanol Water, p r e s e r v a t i v e Formula D 12/2 % by Weiqht 10.0 10.0 2.0 q . s . t o make 1 0 0 . 0
SOURCE:
Zschimmer & Schwarz GmbH & Co.:
200
Advanced Cleaniris Product Formulations
V e h i c l e Wash D e t e r g e n t e h o s p h a t e . Powder1 Soil-Grease, o i l , s a l t , water deposits, c l a y , p a r t i c u l a t e s , road f i l m Surface-Painted metal surface, Polymeric A p p l i c a t i o n Method-High p r e s s u r e s p r a y Manufacture-Dry blend/Agglomeration Composition A : We9/0 Metso Beads 2048 20.0 *STPP 40.0 *TSP 5.0 *Sodi um C a r b o n a t e 20.0 **Sodium A 1 k y l a r y l Sul f o n a t e Powder (90%) 5.0 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-10; 6 Moles EO) 10.0 Composition 8: Wt% Metso Pentabead 20 30.0 *STPP 44. 0 *Sodi um C a r b o n a t e 10. 0 CMC 1 0 **Sodium A l k y l a r y l S u l f o n a t e Powder (90%) 5 0 5 0 * * * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 7-8 Moles EO *****Octylphenoxy P o l y e t h o x y e t h a n o l , 5 Moles EO 5 0 Use D i l u t i o n : 1 . 5 % b y w e i g h t ( 0 . 1 2 5 p o u n d s / g a l l o n ) D i s s o l v e i n s t o c k t a n k and meter i n t o wash system. Compos P i on 6 can be u t i l i z e d i n h i g h p r e s s u r e s p r a y carwash systems and s u p p l i e s adequate s o i l r e m o v a l . FMC Witco Rhone-Poulenc Rhodasurf 91-6 Rhone-Poulenc I g e p a l CA-620 Rhone-Poulenc I g e p a l CA-520
* ** *** ****
*****
V e h i c l e Wash D e t e r g e n t ( L i q u i d , low foam) Soil-Grease, o i l , s a l t , water deposits, c l a y , p a r t i c u l a t e s , road f i l m Surface-Painted metal surface, Polymeric A p p l i c a t i o n Method: H i g h p r e s s u r e s p r a y (700-1400 p s i ) Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Wt% Water 79.0 2.0 Metso Beads 2048 *Sodium P o l y a c r y l a t e (40%) 5.0 **Sodium X y l e n e S u l f o n a t e (40%) 8.0 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 Moles EO) 3.0 3.0 * * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles 0 ) Use D i l u t i o n : 10% bw ( 1 3 o z / g a l l o n ) Rhone-Poulenc C o l l o i d 226/35 (40%) Stepan, W i t c o Rhone-Poulenc R h o d a s u r f 91-6 Rhone-Poulenc Rhodasurf A-24 SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
* ** ***
****
201
V e h i c l e Wash D e t e r g e n t (Low PH) ( Z e r o Phosphate, L i q u i d ) Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s , road f i l m Surface-Painted metal s u r f a c e , Polymeric Appl ic a t i on Method-Hi gh p r e s s u r e s p r a y (700-1400 p s i ) Manufacture-Mix t a n k w i t h p r o p e l l e r spray Composi t i on : Wt% Water 51.66 Carbopol 674 0.5 D L i q u i d Sodium S i l i c a t e 8.1 *Acusol 445N Sodi u P o l y a c r y l a t e (45% s o l i d s ) m 1.84 9.1 Sodium Carbonate T u r b o b r i t e A 1 umi n o s i 1 ic a t e 24.5 * * L i q u i d Nonionic Surfactant 4.3 D i l u t e l i q u i d d e t e r g e n t w i t h w a t e r ( 1 g a l l o n d e t e r g e n t : 64 g a l l o n s w a t e r ) and d e l i v e r t o h i g h p r e s s u r e s p r a y wash system. M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e i s e x t r e m e l y e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s , w a t e r d e p o s i t s , and haze f r o m body p a r t s and w i n d s h i e l d . Rohm & Haas Low Foam: Rhone-Poulenc A n t a r o x BL-240 H i g h Foam: S h e l l Chemical Neodol 23-6.5 o r Neodol 25-7
* **
T o u c h l e s s V e h i c l e Wash B o o s t e r / A d d i t i v e L Z e r o Phosphate, L i q u i d ) Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s , road f i l m Surface-Painted metal s u r f a c e , Polymeric A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition: Wt% T u r b o b r i t e L (25 w t . % a c t i v e T u r b o b r i t e A l u m i n o s i l i c a t e S1u r r y ) 100.0 D i l u t e l i q u i d T u r b o b r i t e L a t h i g h p r e s s u r e pump w i t h w a t e r ( 1 g a l l o n d e t e r g e n t : 128 g a l l o n s w a t e r ) and d e l i v e r t o h i g h p r e s s u r e s p r a y wash system. M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e i s e x t r e m e l y e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s ( c l a y s , c a r b o n b l a c k , b r a k e d u s t ) , w a t e r d e p o s i t s , and haze f r o m body p a r t s and w i n d s h i e l d . T u r b o b r i t e L can be used as an a d d i t i v e o r b o o s t e r f o r conv e n t i o n a l t o u c h l e s s , h i g h p r e s s u r e carwash o r f l e e t w a s h d e t e r gents. O r make a d e t e r g e n t by b l e n d i n g T u r b o b r i t e L w i t h 1-2% lowfoaming n o n i o n i c s u r f a c t a n t t o make f o r b e s t c l e a n i n g r e s u l t s . D i l u t e T u r b o b r i t e L / s u r f a c t a n t b l e n d a t h i g h p r e s s u r e pump w i t h w a t e r (128: 1 ) . T u r b o b r i t e L a l s o works i n waxes, p o l i s h e s , and o t h e r d e t a i l ing p r o d u c t s .
SOURCE:
PQ C o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
17. Whitewall Tire Cleaners
202
1z e ro
Whi tena 1 1 Ti.r&C!ean.ey
.P.b-s phate -?.w&cl
Soil-Clay, p a r t i c u l a t e , o i l , grease
Surface-Whitewal 1 t i r e s Application Method-High pressure s p r a y / b r u s h / w i p e M a n u f a c t tire - D r y b 1 end/Agg 1 o m e r a t i On
c_q.m3osi t i . o n l
Nt%
35.0
2.0
Valfor 100 Zeolite A
* A c u s o l 4 4 5 N D Sodium P o l y a c r y l a t e ( 9 2 % Solids) * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cll; 6 M o l e s E D ) Sodium A l k y l a r y l S u l f o n a t e M e t s o Beads 2 0 4 8 Sodium Carbonate Rohm & Haas Rhone-Pou 1 e n c R h o d a s u r f 91 - 6
8.0
10.0
* **
35.0 12.0
wi j.t.e a -T i.r,e w n
1Pbes?batePowde.!l
C L Y C ~e 1:
Soil-Clay, p a r t i c u l a t e , o i l , g r e a s e Surface-Whi tewal1 t i r e s

Application M e t h o d s - H i g h
Manufacture-Dry blend pressure spray/brush/wipe
Cs-mmeo s.it j P.V :. .
Y!.% t
(C9-Cll; 6 nroles 0 )
45.0 5.0 10.0 10.0
*STPP
GTSP
**tiquid
Noninnic Surfactant
Sodium A l k y l a r y l Sulfonate Met50 B e a d s 2 0 4 8

* a R h o n e - P o u l e n c Rhodasurf 91 -6
30.0
FMC
WRitewal..1..Ti re,&!ea_n_er
(.Lictuj.d).
Soil-Clay, p a r t i c u l a t e , o i l , p r e a s e Surface-Whi tewall tires A p p l i c a t i o n Method-High p r e s s u r e s p r a y / b r u s h / w i p e M a n u f a c t u r e - M i x t a n k w i t h propeller s t i r r e r
C o m q . ~!.f.bn: S
flL?b
70.0 16.0 10.0 2.0 2.0
Water Potassium H y d r o x i d e 145%) N C l e a r o r S t a r Sodium Silicate

S o d i uni A 1 k y l a r y l Sulfonate ( 6 0 % ) * L i q u i d N o n i o n i c S u r f a c t a n t (CS-Cll; 6 m o l e s E O ) * R h o n e - P o u l e m R h o d a s u r f 91 - 6
S O U R C E : FQ Corp. : D e t e r g e n t F o r m u l a t i o n G u i d e
18. Miscellaneous
204
Miscellaneous
205
A i r c r a f t Cleaner (Reduced Phosphate. Powder) Soi 1 - P a r t i c u l a t e s , c a r b o n b l a c k , p e t r o l e u m o i 1 and grease Surface-Aluminum, m e t a l A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manufacture-Dry b l e n d / A g g l o m e r a t i on Composi t i on : Metso Pentabead 20 V a l f o r 100 Z e o l i t e A Ammoni u m B i f 1u o r ide TSPP *Sodi um A1 k y l naphtha1 ene Sul f o n a t e **Sodium A l k y l a r y l S u l f o n a t e Powder (90%) Use D i l u t i o n :
Wt%
30.0 30.0
8.0
20.0
8.0
4.0
1.5-6.096
bw (2-8
oz/gallon)
**
Rhone-Poulenc S u p r a g i l N K Witco
N o t e : C o n s t a n t a g i t a t i o n i s r e q u i r e d i n s t o c k t a n k t o keep V a l f o r 100 suspended i n s o l u t i o n . May use 0.25% w t Carbopol 647 (BFGoodrich) as a suspending a g e n t .
A i r c r a f t 61 eaner (Phosphate, Powder)

S o i l - P a r t i c u l a t e s , c a r b o n b l a c k , p e t r o l e u m o i l and grease Surface-Metal A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) M a n u f a c t u r e - D r y b l end/Aggl o m e r a t i on Composi t i on : Metso Pentabead 20 *STPP Ammonium B i f l u o r i d e *TSPP **Sodium A1 k y l n a p h t h a l e n e S u l f o n a t e ***Sodi u A1 k y l a r y l Sul f o n a t e Powder (90%) m Use D i l u t i o n : 1 . 5 - 6 . 0 % bw ( 2 - 8 o z / g a l l o n )
Wt%
30.0 30.0
8.0
20.0 8.0 4.0
* **
*%Xc
F C M DeSoto, Witco
Inc.
OURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
206
A u t o Care:
I n t e r i o r / E x t e r i o r Rubber B V i n y l P r o t e c t a n t
F u n c t i ons 8 Benef it s : Pemul an 1622 : *Primary e m u l s i f i e r f o r s i l i c o n e o i l *NO s u r f a c t a n t s and no s o l v e n t s r e q u i r e d e q u a l s z e r o VOC *Imparts y i e l d value f o r v e r t i c a l c l i n g * E x c e l l e n t w e t t i n g f o r " s p r a y and no-wipe" a p p l i c a t i o n s *Improved d u r a b i l i t y and w a t e r - r e s s t a n c e Good-Rite K-752: * R e d u c t i o n i n emu1s i on v i s c o s i t y w t h o u t l o s s i n s t a b i l i t y I n q r e d ient : D I water Pemulen 1622* 1000 c S t s i l i c o n e o i l * * DC Q2-5211*** T r i e t h a n o l a m i n e (99%) Good-Rite K-752 (63%)**** * E m u l s i f i e r : BFGoodrich * * P r o t e c t a n t : DC 200 F l u i d : Dow C o r n i n g * * * S u p e r - w e t t i n g a g e n t : DC (12-5211: Dow C o r n i n g * * * * V i s c o s i t y r e d u c t i o n : BFGoodrich Physical Properties: B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 150 CP P r o d u c t pH: 5.5-6.0 P r o d u c t C l a r i t y : Opaque Procedure: 1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Pemulen r e s i n i n t o t h e D I w a t e r . Mix t h e s l u r r y f o r appr o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2. Add t h e s i l i c o n e f l u i d w i t h good a g i t a t i o n . 3. Add t h e DC Q2-5211 s u p e r - w e t t i n g a g e n t w i t h moderate a g i t a t i o n 4 . Add t h e t r i e t h a n o l a m i n e w i t h moderate a g i t a t i o n . 5 . Reduce a g i t a t i o n and add t h e Good-Rite K-752 p o l y m e r . The v i s c o s i t y w i l l d r o p f r o m a b o u t 3,000 CP t o <200 CP w i t h t h i s addition. 6. A d j u s t t h e pH w i t h a d d i t i o n a l t r i e t h a n o l a m i n e , i f n e c e s s a r y . 7 . Add f r a g r a n c e and c o l o r , as d e s i r e d .
Wtl
78.55 0.20 20.00 0.50 0.25 0.50
DET-512
Miscellaneous
207
Boat Polish I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase separa t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s . Inqredi ent :
Wt%
37.80 0.20 2.50 2.00 1.50 2.50 10.00 6.00 5.00 1.50 8.50
#I Water
Carbopol EZ-2 ( 1 ) Morphol ine SF96 S i l i c o n e F l u i d (350) ( 2 ) V i s c a s i l F l u i d (10,000) ( 2 ) Oleic Acid Mineral S p i r i t s Hoechst Wax E (3) M i n e r a l Spi r i t s SF1 706 React ive A m i ne Polymer Kaopolite kaolin clay (4) Physical P r o p erties: B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 7,200 cps P r o d u c t pH: 9.00 P r o d u c t C l a r i t y : Opaque Raw M a t e r i a l S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) General E l e c t r i c ( 3 ) Hoechst Celanese (4) Kaopolite, Inc.
Procedure: 4 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r by s i m p l y "dumping" i t i n . The polymer w i l l wet o u t i n a few m i n u t e s . 2 . Add t h e m o r p h o l i n e , m i x w i t h good a g i t a t i o n . Heat t o 60-65C. 3 . I n a s e p a r a t e v e s s e l , combine t h e s i l i c o n e f l u i d , V i s c a s i l , o l e i c a c i d , and t h e wax i n t h e m i n e r a l s p i r i t s . Heat t o 90-95C u n t i l t h e wax m e l t s and t h e m i x t u r e appears homogeneous. Add to t h e above m i x t u r e w i t h good m i x i n g . 4 . When homogeneous, c o o l t o 60-65C. 5. I n a s e p a r a t e v e s s e l , combine t h e m i n e r a l s p i t i t s and t h e r e a c t i v e amine p o l y m e r . Add t o t h e above m i x t u r e w i t h h i g h shear m i x i n g . 6. S l o w l y add i n t h e c l a y . M i x u n t i l homogeneous. Total Actives: 1.50 T o t a l Wax : Total Silicone Fluid: 4.50 R e a c t i v e A m i ne Polymer : 2.00 Mineral S p i r i t s : 13.00 Abrasive: 12.00
$ ~ BFGoodrich ~ p e c i a l t y Chemicals: ~ S ~ ~ :
DET-520
208
C o n c r e t e Cleaner/Deqreaser I n g r e d ie n t s : Water, D . I . Sodium T r i p o l y p h o s p h a t e T r i s o d i u Phosphate m Varami de A-83 V a r o n i c DM55
WtB
81 . O 2.0
1.o
6.0 10.0
B l e n d i n g Procedure: Add i n g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t ion. T y p i c a l P r o p e r t i es : V i s c o s i t y , cps: 0 S o l i d s : 19.0% Formula 937 Garage F l o o r C1eaner I n s r e d ie n t s : Water T r i s o d i u Phosphate m Emphos PS-236 W i t c o n a t e 45 L i q u i d
Wt%
82.0 8.0 4.0 6.0
B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . A l l o w f o r complete b l e n d i n g between a d d i t i o n s . Formula 941 A c i d Rust Remover I n q r e d ients: Water, D . I . Phosphoric A c i d , C i t r i c Acid Varox 365
\Me%
86%
81 . O 15.0 3.0 1.o
B l e n d i n g Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n .
T y p i c a l P r o p e r t ies : V i s c o s i t y , cps: 4 S o l i d s : 16.2% pH: 1.3 Formula 1116
Miscellaneous
209
Concrete/Driveway
Cleaners
F o r l e a f and o t h e r t a n n i n s t a i n s - u s e as i s . Wet s p o t . S p r i n k l e FB Sodium P e r c a r b o n a t e o n t o s p o t . S c r u b i n and r i n s e w i t h hose when s p o t i s removed.
For O t h e r S t a i n s
Component: Soda Ash (Dense) B r i t e s i 1 H-24 TSP Anhydrous B u r c o s p e r s e AP Powder Dry S u r f a c t a n t * FB-Sodi um P e r c a r b o n a t e
Wt%
25 15 20 5 5 30
Wet s p o t . S p r i n k l e c l e a n e r o n t o a r e a . S c r u b i n and a l l o w t o s t a n d . R i n s e w i t h hose. *Sodium L a u r y l S u l f a t e , Sodium Dodecylbenzene S u l f o n a t e o r Sodium Cocoyl T a u r a t e s can b e used.
SOURCE:
B u r l i n g t o n Chemical C o . :
Suggested F o r m u l a t i o n
Neavv D u t y C o n c r e t e C l e a n e r ( P h o s p h a t e F r e e ) F o r m u l a 1C
Wt%
Water, D . I . EDTA, 38% Sodium M e t a s i l i c a t e , P e n t a h y d r a t e Sodium C a r b o n a t e (Soda Ash) W i t c a m i d e S-780 W i t c o n o l NP-120 B u t y l Cel l o s o l v e Mineral S p i r i t s KOH, 45% W i t c o n a t e SXS L i q u i d Pine O i l Blending Procedure: Blend i n g r e d i e n t s i n order l i s t e d , addition. Typical Properties: S p e c i f i c G r a v i t y : 1 .022 Wt./Gal. I b s . : 8.52 pH, as i s : 1 3 . 1 8 3 Freeze/Thaw C y c l e s : Passed 1 Week @ 52C: Passed 4 Weeks Room Temp: Passed S o l i d s : 13.5% Use D i l u t i o n : As s t r o n g as needed,
SOURCE:
75.0 0.5 2.0 1.5 6.5 1.5 3.0 4.0 2.5 1.5 2.0
m i x i n g w e l l a f t e r each
d e p e n d i n g on t y p e o f s o i l .
Witco Corp.:
F o r m u l a 949
210
__ n y l Dressing Vi
I g r e d i& n Part A: M a s i l EM 250 C Dei o n i zed Water
~Wt%
30.0 30.0
P a r t 8: M a c o l NP 9 . 5 G1 y c e r i n e D e i o n i z e d Water Sodium B e n z o a t e
1.5 1.5 36.9 0.1
Procedure: 1 . To a m i x i n g v e s s e l , c h a r g e t h e M a s i l E 250 C and s t a r t M g e n t l e a g i t a t i o n . S l o w l y add t h e w a t e r s o a s n o t t o b r e a k t h e emu1 s i o n . 2 . I n a s e p a r a t e m i x i n g v e s s e l , c h a r g e t h e Macol NP 9 . 5 a n d g l y c e r i n e t o t h e water. Mix w i t h g e n t l e a g i t a t i o n u n t i l a l l components a r e d i s s o l v e d , and t h e s o l u t i o n i s f r e e o f " f i s h e y e s " . Charge t h e sodium b e n z o a t e a n d m i x u n t i l d i s s o l v e d . 3 . Under g e n t l e a g i t a t i o n , c h a r g e P a r t B t o P a r t A . C o n t i n u e m i x i n g g e n t l y t o a v o i d a i r e n t r a p m e n t . NOTE: T h i s f o r m u l a i s d e s i g n e d t o be u s e d " a s i s " as a d r e s s i n g f o r r u b b e r and v i n y l p r o d u c t s . I f d e s i r e d , UV a b s o r b e r s a n d o t h e r components may be added t o t h e f o r m u l a t i o n . F o r m u l a t i o n SV-101
Inqredient: M a s i l EM 1 0 , 0 0 0 M a s i l EM 2 5 0 C Macol NP 9 . 5 Glycerine B a r q u a t MB-50 Water
& % 10.0 18.0
2.0
1.5 0.1 68.4
Procedure: Add t h e s i l i c o n e e m u l s i o n t o a b l e n d e r . S l o w l y a d d a p o r t i o n o f t h e w a t e r and a g i t a t e . Add t h e M a c o l NP 9 . 5 and g l y c e r i n e . M i x f o r 10 m i n u t e s . Add t h e b a l a n c e o f t h e w a t e r a n d m i x f o r 15 minutes.
SOURCE:
Inc.:
Section Ill demarked Raw Materials
211
212
RAW MATERIAL
A-C
617A
CHEMICAL DESCRIPTION Polyethylene Cationi c surfactant P o l y a c r y l a t e (40%) Tall o i l f a t t y acid Sodium p o l y a c r y l a t e (92% s o l i d s ) Sodium p o l y a c r y l a t e Anti-static agent
SOURCE
Allied Tomah
Acid Thickener A c r y s o l AS-108 Actinol FA-I
Rohm&
A r i zon
A c u s o l 445ND Acusol 479ND
Rohm& RohmB
Witco
Adogen 66 A 1 ip a l CO-128 A1 ip a l CO-436 Alkylaryl Alpha-Step
Anionic surfactant Anionic surfactant
Rho ne RhoneWitco
S u l f o n i c A c i d (98%) MC-48 Alpha s u l f o methyl e s t e r Alpha s u l f o methyl e s t e r Amine o x i d e A m i nomethyl p r o p a n o l Amphoteric s u r f a c t a n t A m p h o t e r i c (35% a c t i v e ) Hydrotrope Amphoteric s u r f a c t a n t L i q u i d nonion c s u r f a c t a n t L i q u i d nonion c s u r f a c t a n t Surfactant (37%)
Stepan Stepan Stepan Angus Zschim
A 1 p h a - S t e p ML-40 Ammonyx LO AMP-95 A m p h o t e n s i d 84 A m p h o t e r i c SC A m p h o t e r i c TC A n t a r o n FC-34 A n t a r o x BL-240 A n t a r o x BL-330 A n t a r o x LF-330 Aquamoll i n BC Powder Aristonate M A r i s t o n a t e M-LF A r o m a t i c 150
Tomah Tomah
RhoneRhoneRhoneRhone-
P e t r o l e u m s u l f o n a t e (61%) Petroleum s u l fonate
Pi l o t
Pilot
Sol v e n t
Exxon
Trademarked Raw Materials
213
RAW MATERIAL Autopoon GK4004 Autopoon GK4008 A u t o p u r WK4332 Avanel S-30 Avanel S-70 Avanel S-74
CHEMICAL DESCRIPTION Blend o f s u r f a c t a n t s Blend o f s u r f a c t a n t s Blend o f s u r f a c t a n t s Anionic surfactant Sodium l i n e a r a l k y l p o l y e t h e r Anionic surfactant
SOURCE
Zschim Zschim Zschim PPGMaz PPGMaz PPGMaz
5;mrlOX
12
Amine o x i d e (30%) Q u a t e r n a r y ammonium compound
Lonza Lonza
B a r q u a t NIB-50 BiQSOft D-62 B i o s o f t s-100
Sodium a l k y l benzene s u l f o n a t e ( 6 0 % ) Stepan Alkylbenzene s u l f o n i c a c i d , linear Stepan Stepan Stepan PO
B i o t e r g e AS-40
B i o t e r g e PAS-8S 83-120
Sodium o l e f i n s u l f o n a t e (40%) P r i m a r y a l k a n e s u l f o n a t e (40%)
b q u i d Sodi um S i 1 ic a t e
Surfactant Hydrous sodium p o l y s 1 i c a t e Hydrous sodium p o l y s 1 ic a t e Hydrous sodium p o l y s 1 i c a t e
B r i j 96 B r i t e s i 1 c20 B r i t e s i I H20
B r i t e s i 1 H24
ICI
PQ
PQ
PQ
Burcene I00 Burco BSGH-270 Burco WCS-SONF NPS-225

NPS-816
Burl i n Proprietary t e x t i l e auxiliary Proprietary t e x t i l e auxiliary Proprietary t e x t i l e auxiliary Proprietary t e x t i l e auxiliary Proprietary t e x t i l e auxiliary Proprietary t e x t i l e auxiliary Burl i n Burl i n Burl i n Burl i n Burl i n Burl i n
SZS
LAF-6
21 4
RAW M A T E R I A L
B u r c o l 117 B u r c o l i t e BSGH-255 B u r c o s o l v TM B u r c o s p e r s e AP Powder B u r c o s p e r s e LP B u r c o s p e r s e SP-60 B u r c o t a s e LL-100 B u r c o t a s e EP-60 B u r c o t a s e SL-160 B u r c o t e r g e DG-40 B u r c o TME B u r c o t r o p e 1250 B u r c o w h i t e BBH-20 Burdac-114 Butyl Carbi t o 1 Butyl Cellosolve
CHEMICAL D E S C R I P T I O N
Proprietary t e x t i l e auxiliary
SOURCE Burli n
Burlin
Water s o l u b l e s o l v e n t m i x t u r e S o d i um p o l y a c r y l a t e Sodium p o l y a c r y l a t e s o l u t i o n Sodium p o l y a c r y l a t e P r o p r i e t a r y d e t e r g e n t enzyme P r o p r i e t a r y d e t e r g e n t enzyme P r o p r i e t a r y d e t e r g e n t enzyme Detergent concentrate Proprietary t e x t i l e a u x i l i a r y
Burli n B u r l in Burli n B u r l in Burl i n B u r l in Burli n Burlin Burl i n Burlin B u r l in
I n d u s t r i a1 s o l v e n t Ethylene g l y c o l monobutyl e t h e r
UnCarb UnCarb
Calamide C C a l a m i d e CW-100 Calamide C T W C a l a m i d e SM C a l f a x DB-45
C o c o n u t d e r i v e d ami de Coconut d i e t h a n o l a m i d e 100% Super ami de Non-DEA 1 iq u i d ami d e Sodium a l k y l ( b r a n c h e d ) d i p h e n y l o x i d e d i s u l f o n a t e 45% S o d i um a1 k y l ( 1 in e a r ) d i p h e n y l o x i d e d i s u l f o n a t e 45% Liquid detergent
Pilot
Pilot Pilot
Pilot
Mona
C a l f a x 1OL-45
Mona
C a l foam EA-603
Pilot
215
RAW MATERIAL Cal foam ES-303

Cal foam SLS-30 Gal i mu1 se PRS Caloxylate M-9 C a l s o f t F-90 C a l s o f t L-40 C a l s o f t L-60 Cal s o f t LAS- 99 C a l s o f t T-60 Calsuds A Calsuds CD-6
CHEMICAL DESCRIPTION Sodium l a u r y l e t h e r s u l f a t e (30%) Sodium l a u r y l s u l f a t e 30% Emu1s i f ie r
SOURCE
Pilot Pi l o t
Pilot
Nonyl p h e n o l e t h o x y l a t e ( 9 M o l e EO) P i l o t L i n e a r a1 k y l a t e s u l f o n a t e Sodi u 1 inear a1 k y l benzene m s u l f o n a t e 1 i q u i d 40% Sodi u 1 inear a1 k y l benzene m s u l f o n a t e p a s t e 60% L i n e a r a1 k y l benzene s u l f o n a c i d 99%
C
Pilot Pilot Pilot Pi l o t Pilot Pilot
TEA l i n e a r a l k y l benzene su f o n a t e 60%

Conc. b l e n d o f a n i o n i c d e t e r g e n t s and amides
M o d i f i e d c o c o n u t diethanolamidelOO% P i l o t Conc. b l e n d o f a n i o n i c d e t e r g e n t s and amides I n d u s t r i a l solvent T h i c k e n i n g agent T h i c k e n i n g agent T h i c k e n i n g agent Suspension a i d Thickening agent Thickening agent T h i c k e n i n g agent Resin v i scosi t y m o d i f i e r Resin v i s c o s i t y m o d i f i e r Pilot UnCarb BFGood BFGood BFGood BFGood BFGood BFGood BFGood BFGood BFGood
Calsuds 8 1
Carbi t o 1 Solvent Carbopol 672 Carbopol 674 Carbopo 1 676 Ca r b o p o l 69 1 Ca rbopo 1 934 Carbopol 940 Carbopol 941
Carbopol ETD 2623

Ca rbopol ETD 2691
216
RAW MATERIALS Carbopol EX-473

Carbopol EZ-2 C a r d i s 36 Wax
CDB C l e a r o n
CHEMICAL DESCRIPTION
(30%)
V i s c o s i t y modi f i e r
SOURCE:
BF600d
V i scosi t y
modi f ie r
BFGood
Petrol
O x i d i z e d m i c r o c r y s t a l l i n e wax C h l o r i n a t e d is o c y a n u r a t e P o l y a c r y l a t e (40%) P o l y a c r y l a t e (40%) G l y c o l e t h e r defoamer
0 in 1
RAOPa@
C o l l o i d 225/35 Col 1o i d 226/35 Contraspum 300 Cublen D50
Rhone Zschi e
DC (22-5211
S u p e r - w e t t i n g agent
DowCor
Decanol Dequest 2000 DeSonic LFD-97 DeSonic 5N DeSonic 9N DeSonic 11N DeSonic 81-6 DeSophos 5AP Diatomaceous E a r t h Organophosphorous p r o d u c t Nonionic s u r f a c t a n t Nonioni c s u r f a c t a n t Detergent/degreaser Nonionic s u r f a c t a n t Nonionic s u r f a c t a n t Phosphate e s t e r
I\iiCN7san
DeSoto DeSoto DeSoto DeSoto
DeSoto
DeSoto Kaopol PQCorp Dow or Arc0
D L i q u i d Sodium S i l i c a t e
D i p r o p y l e n e G l y c o l Monoethyl E t h e r S o l v e n t Dodigen 226 Dowanol DPM Dowanol DPnB Glycol ether Glycol ether
Dow
Bow
21 7
RAW MATERIAL Dowanol EB

Dowanol P M Dowanol PnB Dowanol TBA Dowanol TPM
CHEMICAL DESCRIPTION Ethylene glycol n-butyl ether P r o p y l e n e g l y c o l methy Glycol ether Glycol ether T r i p r o p y l e n e g l y c o l me ether ether
SOURCE
Dow Dow Dow Dow Dow DowCor Dow
Dow C o r n i n g 20 R e l e a s e C o a t i n g Dowfax 382 S o d i um n - d e c y l d i p h e n y l o x d e d i s u l f o n a t e (45%) Sodium o - P h e n y l p h e n a t e
Dowicide A
Dow DowCor Dow
Dow 200 S i l i c o n e F l u i d ( 1 0 0 0 c S t ) Dowfax 2A1 S o d i um d o d e c y l d i p h e n y l o x i de d i s u l f o n a t e (45%) Anionic surfactant R o s i n soap
Dowfax 382 D r e s i n a t e 91
Dow Hercul
E L i q u i d Sodium S i l i c a t e
Emcol 4500 Emcol 6744 E m e r s o l 213 Emphos PS-236 Emphos PS-331 Emphos 5AP E m u l s i f i e r F o u r HF W e t t i n g agent Surface-active Oleic acid Phosphate e s t e r s u r f a c t a n t Phosphate e s t e r s u r f a c t a n t Phosphate e s t e r s u r f a c t a n t
D i a1 k y l q u a t e r n a r y ( 7 5 % a c t i v e )
PQ W itco
agent
Witco
Henkel
Witco W itco
Witco
Tomah Tomah Tomah

PQ
Emul s i f ie r 827
Emul s i o n C340 Epsom S a l t
Mixed d i a l k y l
q u a t e r n a r y (75% a c t )
218
RAW MATERIAL Ethylene G l y c o l n-Butyl

E u p e r l a n PK-771
CHEMICAL DESCRIPTION SOURCE Ether Solvent Dow or Union @ a r b P e a r l iz i ng a g e n t (47%) Henkel
Foam B o o s t e r 14
Def oamer
Tornah
Gafac RE-40 Gafamide CDD 518 Genagen LAB Genapol OA-80 Genapol UD-030 Genapol UD-080 Genapol ZRO l i q u i d Genapol 2908
Anionic surfactant Ethanolamide C12C14 a l k y l d i m e t h y l b e t a i n e Alcohol ethoxylate C11 0x0 e t h o x y a t e ( 3 moles EO) A l c o h o l ethoxy a t e Alkyltriglycol ether sulfate soln
Rhone
Rhone
Hoechs Hoechs H Q ~ C ~ S Hoechs Hoechs Hoechs GaMarb Ashlan Henkel
Alcohol ethoxylate
G e o r g i a M a r b l e W h i t e #8 c a l c i u m c a r b o n a t e G l u c o n i c A c i d S o l u t i o n (50%) G ucopon 425CS 1 G l y c o l E t h e r DPM Glycol Ether P M Good-Ri t e K-752 Good-Rite K-7058 GP-RA-159 V i s c o s i t y reducer 5800 MW p o l y a c r y l i c a c i d C8-16 a l k y l p o l y g l y c o s i d e (50%)
BFGood
BFGood
Genes Genes Genes
S i 1 icone P o l ish A d d i t i v e
GP-121 S i l i c o n e P o l i s h A d d i t i v e GP-227 S i l i c o n e S u r f a c t a n t S o l u t i o n
219
RAW MATERIAL H-7892 d-Limonene

Hampene 100 Hexyl C a r b i t o 1 H i t e c E-515 Hoe S3924 Hoechst Wax E Hoechst Wax S Hostapur Wax Wax
CHEMICAL D E S C R I P T I O N T e t r a s o d i u EDTA m
SOURCE A r y l es
Grace UnCarb Ethyl Hoechs Hoechs Hoechs Hoechs
I n d u s t r ia1 s o l v e n t
0s
Liquid Secondary a l k a n e s u l f o n a t e Q u a t e r n a r y ammonium compound Secondary h y p o c h l o r i t e , 10% s o l n
Hostapur SAS6O Hyamine 1 O X Hypure N
Hoechs Lonza
I g e p a l CA-520 I g e p a l CA-620 Pgepal CA-630 I g e p a l CA-720 I g e p a l CO-430 I g e p a l CO-530 I g e p a l 60-630 Pndopol H-100 I n h i b i t o r 4000 Isopar K Isopar
O c t y l p h e n o x y p o l y e t h o x y e t h a n o l . 5 EO RhoneO c t y l p h e n o x y p o l y e t h o x y e t h a n o l , 8 EO RhoneO c t y l p h e n o x y p o l y e t h o x y e t h a n o 1 , g EO RhoneOctylphenoxy p o l y e t h o x y e t h a n o l , 12-13 moles EO Nonionic ethoxylat e s u r f a c t a n t A1 k o x y l a t e d 1 in e a r a1 coho1 n o n i o n i c s u r f a c t a n t (low foam) Nonylphenoxy p o l y e t h o x y e t h a n o l , 9-10 moles 0 Viscous polybutene A1 kanolami ne b o r a t e I s o p a r a f f i n solvent I s o p a r a f f i n solvent RhoneRhoneRhoneRhone-
Amoco
Zschim Exxon Exxon
220
RAW MATERIAL Kaopol it e

K a o p o l i t e SF Kaopol it e 1 152 K a s i l #1 K a s i l #6 K a t h o n CG K e l zan
CHEMICAL DESCRIPTION Kaolin clay A n h y d r o u s a l u m i num s i 1 ic a t e A n h y d r o u s a l u m i n u m s i 1i c a t e P o t a s s i um s i 1 i c a t e P o t a s s i um s i 1 ic a t e Fungicide (biocide) Xan h a n gum
SOURCE Kaopol Kaopol Kaopol

PQ
PQ
Rohrn& Kel co Kerr-
Kerr-McGee M i n e r a l S e a l O i K o m p e r l a n KD
L a r o s t a t 88 L a r o s t a t 264A L a r o s t a t 519 L a u n d r y A d d i t i v e LA-5 Lonzabac-1230 Lumo WW 75 Lumorol 4154 L u m o r o l 4192 L y t r o n 295
Ant s t a t Antistat Anti stat
PPGMaz PPGMaz PPGMaz Tomah Lonza Zschim
Surfactant blend Surfactant blend Opacifier. Polystyrene emulsion
Zschirn Zschim Morton
Macol NP 9 . 5 & NP-11 & P o l y o x y e t h y l e n e f a t t y e t h e r OPlOSP & TD-3 & T D - 1 2 & 2LF & 48 & 5100 M a f o CSB M a f o 13 MOD 1 Amphoteric s u r f a c t a n t Amphoteric s u r f a c t a n t
PPGMaz
PPGMaz PPGMaz
221
RAW MATERIAL Makon 10 Makon 12 Maphos 58 Maphos 60A Maphos 8135
CHEMICAL DESCRIPTION A l k y l phenol e t h e r A l k y ? pheno7 e t h e r Phosphate e s t e r Phosphate e s t e r Phosphate e s t e r
SOURCE
Stepan Stepan PPGMaz PPGMaz PPGMaz PPGMaz
M a s i l EM250C & Silicone fluids EM10,OOOC & SF-10 & SF-100 & SF-1,000 & 123 M a s l i p 500 & 501A & 501 Base Mazamide SS-10 80 & 1281 Mazawet 77 Mazon R I 4A & R I 6 & RI 8A & R I 88 & 98 Mazox LDA
Mazu DF 210 SX
Synthetic lubricant additives S p e c i a l t y alkanolamides Surfactant Specialty proprietaries F a t t y amine o x i d e Def oamer
PPGMaz PPGMaz
PPGMaz
& 65 &
PPGMaz PPGMaz PPGMaz
M e d i a l a n KA Conc. Metso Beads 2048 Metso Pentabead 20

M i r a n o l CPM-SF Conc.
Anhydrous sodium m e t a s i l i c a t e Sodium m e t a s i l i c a t e p e n t a h y d r a t e D i s o d i u cocoamphodi p r o p i o n a t e m
PQ PQ
RhoneRhoneMona Mona Mona
M i r a n o l J E M Conc.(34%) Sodium mixed C8-amphocarboxylate Monacor BE Corrosion i n h i b i t o r Corrosion i nhi bi t o r
Monacor 4000
Monalube 110 & 205 & Synthetic lubricants 210 & 215 & 220 & 225 & 310 & 315 & 320 & 325 Ik 605 & 610 Monamid 150-ADD Cocamide DEA
Mona
222
RAW MATERIAL Monamine CF-100M & 1-76

Monamulse dL-1273 Mona NF-10 & N F - 2 0 Monamulse TRP & 653-83D Monaquat I S I E S
CHEMICAL DESCRIPTION
2 : 1 f a t t y a1 k a n o l a m i d e s
SOURCE Mona
P r o p r i e t a r y emu1 s i f ie r / s o l u b i 1 iz e r s Mona Surfactants L i q u i d e m u l s i f i e r and s o l u b i l i z e r I s o s t e a r y l e t h y l d i m o n i urn e t h o sulfate Q u a t e r n a r y p h o s p h o l i p i d compound Mona Mona
Mona
Monayuat TG M o n a s i l PCA M o n a t e r g e ALX-100s
Mona Mona
Cocami de DEA & DEA-Dodecyl benzenes u l f o n a t e & diethanolamine DEA-Laureth s u l f a t e Sodium c o c o a m p h o a c e t a t e

1 - H y d r o x y e t h y l e n e - 2 - c a p r y l im i d a z o l i fie ( 5 0 % a c t iv e )
M i I d amphoteric detergent/emulsifier
Mona
Monaterge 779 M o n a t e r i c CM-36s M o n a t e r i c CyNa-50
Mona Mona Mona
M o n a t e r i c EH
Mona
Monat r o p e 1 2 5 0 M-Pyrol M u l s i f a n K326 S p e z i a l M u l s i f a n RTI n-Methyl-2-pyrrolidone Emulsifier for solvents Fatty acid ethoxylate. Emulsifier.
Mona
ISP
Zschim Zschim
Nacconol 9 0 G
Linear alkylbenzene sulfonate(LAS)
Stepan PQ RhoneShell
N C l e a r Sodium S i l i c a t e Sodium m e t a s i l i c a t e
N e k a l WT-27 Neodol 1 . 5
A n i o n i c w e t t i n g agent Ethoxylate. Linear primary alcohol
223
RAW MATERIAL Neodol 23-6.5 Neodol 25-3 Neodol 25-7 Neodol 25-12 Neodol 91-6 N i n o l 11-CWI N i n o l 30-LL N i n o l 40-CO
CHEMICAL DESCRIPTION C12-13 l i n e a r a l c o h o l . 6 . 5 Cf2-15
moles EO
SOURCE Shel 1
Shel 1 Shel 1 Shel 1 Shel 1 Stepan Stepan Stepan
l i n e a r a l c o h o l . 3 moles EO
C12-15 l i n e a r a l c o h o l . 7 moles EO Linear primary alcohol Linear primary alcohol. Ethoxylate Coconut d i e t h a n o l a m i d e , A1 k y l o l a m i d e Cocamide DEA modified
P a r o i l 160 Pemulen 1622 P e t r o BW L i q u L i q u i d & BAF LBA L i q u i d & ULF L i q u i d & P h o s f e t a l 201 Phosphol ip i d EFA P i l o t SXS-40 P l u r a f a c C-17 P l u r a f a c 0-25 P o l y t e r g e n t S-305LF
PQ Epsom S a l t
Chlor nated p a r a f f i n Resin d & BAF A n i o n c s u r f a c t a n t / d s p e r s a n t Powder & LBA Powder & 22 Powder Phosphoric a c i d e s t e r L i ndeamidopropyl PE-Dimoni u m c h l o r i d e phosphate Sodi u x y l e n e s u l f o n a t e 40% m A1 k o x y l a t e d f a t t y a1 coho1 Linear alcohol ethoxylate. MW:930
Dover BFGood DeSoto
Zschi m Mona Pilot BASF BASF
Alkoxylated l i n e a r alcohol nonionic O l i n s u r f a c t a n t ( l o w foam)

PQ
P r i f a c 2922 P r o d u k t 2058 P r o p e t a l 99
Lauric acid Fatty alcohol f a t t y acid ester A1 k y l p o l y a l k y l e n e g l y c o l e t h e r
Uni che Zschi m Zschi m
224
RAW MATERIAL P r o p e t a l 241 P r o p e t a l 281 P u r t o n CFD

PVP K-15
CHEMICAL DESCRIPTION A1 k y l p o l y a l k y l e n e g l y c o l e t h e r A1 k y l p o l y a l k y l e n e g l y c o l e t h e r F a t t y a c i d alkanolamide P o l y v i n y l p y r r o l i d o n e polymer
SOURCE
Zschirn
Eschirn Zschi m Rhone-
Renex 2 0 R e w o t e r i c AM 8-14 R e w o t e r i c AM B-15 & AM D L 35 & AM HC & M AM KSF 40 & AM TEG & AMV Rhodafac RA-600 Rhodafac RE-600 Rhodafac RE-61 0 Rhodasurf A-24 Rhodasurf LA-7 Rhodasurf LA-9 Rhodasurf LA-12 Rhodasurf 91 -6 Rhodaterge S C M Rhodopol 23 Rhodopol 50MD
R i chami de 5725
Surfactant Grease c u t t e r & foam b o o s t e r Surfactants
ICI
Wi t c o
w i eco
Linear alcohol ethoxylate Phosphate e s t e r Phosphate e s t e r L i q u i d nonionic surfactant. moles EO L i q u i d nonionic surfactant. moles EO L i q u i d nonionic surfactant. moles EO L i q u i d nonionic surfactant. moles EO Liquid nonionic surfactant. moles EO Cleaner c o n c e n t r a t e Xanthan gum Xanthan gum 2.5 7-9
RhOneRhOn@-
RhoneRhoneRhone-
9
12
6
Rhone-
Rhone-
RhoneRhoneRhoneRichar
RU L i q u i d Sodium S i l i c a t e c o r r o s i o n i n h i b i t o r
PO
225
RAW M A T E R I A L
SF96 S i l i c o n e F l u i d
CHEMICAL DESCRIPTION Polydimethyl s i l i c o n e f l u i d
SOURCE GE
GE
S F I 705 R e a c t i ve S i 1 icone Polymer
S F I 706 R e a c t i v e S i 1icone Polymer

S h e l l f e x 213 S h e l l S o l 135 Rubber p r o c e s s o i l Solvent
GE
Shel 1 Shel 1 GE
GE
SM2133 S i 1 icone Emu1s i on SM2135 S i l i c o n e Emulsion SMA-2625 R e s i n S-Mar Cop01ymer r e s i n Sorbitan f a t t y ester M i n e r a l f i 1l e r
Arco PPGMaz
80
Snow F l o s s
JM
W itco
Sodium A l k y l a r y l S u l f o n a t e Powder (99%) Sodium A l k y l n a p h t h a l e n e S u l f o n a t e Sodium B i c a r b o n a t e (Grades 1 & 5 ) Sodium Carbonate Sodium D i c h l o r o i s o c y a n u r a t e , 2H20 Sodi u T r ipol yphosphate m Sodium Xylene S u l f o n a t e (40%) Sokalan CP5 B HP22 Standamid PD Standapol A Standapol ES-3 Star Cocamide DEA A n i o n i c s u r f a c t a n t . Ammonium l a u r y l s u l f a t e (30%) A n i o n i c s u r f a c t a n t . Sodium l a u r y l e t h e r s u l f a t e (30%) Sodium s i 1 i c a t e 4QBe' L i q u i d sodium s i l i c a t e Alcohol ether s u l f a t e
DeSoto Church F C M Olin F C M Stepan, W i t c o
Hen k e l Stepan Stepan

PQ
Starso
PO Stepan
Steal CS-330
226
RAW MATERIAL S t e p a n o l WA-Extra Stoddard S o l v e n t STPP S u l f e t a l 4069 S u l f e t a l 4105 Sul f o n a t e OA5 Super F l o s s S u p r a g i l NK S u r f o n i c N-150
CHEMICAL DESCRIPTION Hydrotrope
SOURCE Stepan
Exxon
FMC
Fatty alcohol s u l f a t e . Anionic surfactant Fatty alcohol s u l f a t e . Anionic surfactant W e t t i n g agent Diatomaceous e a r t h Sodium a l k y l n a p h t h a l e n e s u l f o n a t e S u r f a c e a c t i v e agent
Zschim Zschim Tennes

JM
RhoneTexaco
TEA L a u r y l S u l f a t e
RhoneNonoxynol UnCarb Hoechs Hoechs F l u o r e s c e n t w h i t e n i n g agent

C i ba-
T e r g i t o l NP Thermphos Thermphos N W T i n o p a l 5BM
Tomah A l k a l i S u r f a c t a n t Amphoteric Tomah Amphoteric Tomah AO-14-2 Tomah A0-728 Tomah Q-14-2 Tomah Q-17-2 T r i l o n A Liquid T r i t o n DF-16 & N-101 & x-45 Special L
(35% a c t i v e )
Toma h
Tomah Tomah Tomah Toma h Tomah Zschim
M i I d surfactant
E t h e r amine o x i d e (50% a c t i v e Amine o x i d e - h i g h foaming (50% a c t 1 Quaternary Quaternary
Nonionic surfactants
Rohm
227
R A W MATERIAL Tur b o b r i t e
Turbobrite L Tween 40 T y l o s e CBR 10000 U b a t o l TR1138 V a l f o r 100
CHEMICAL DESCRIPTION Aluminosilicate Aluminosilicate slurry P o l y s o r b a t e 40
SOURCE
PO
PQ
ICI
Zeolite A builder
PQ
Van Gel B & C & ES & 0 Magnesium aluminum s i l i c a t e s Vanseal NACS-30 Vanseal NALS-30 Varami de A-1 0 & A - 1 2 & A-83 & MA-1 V a r o n i c DM-55 & K205 8 T202 & T202SR Varox 365 8 1770 V a r q u a t 50MC Veegum & Veegum T Versene 100 & 220
V i scasi
RTVan RTVan RTVan
Sodi u 1a u r o y l s a r c o s i n a t e m
D e t e r g e n t a1 kanolami des Nonionic w e t t i n g agents W e t t i n g agents S p e c i a l t y quaternary, germicide
W itco
witCO
W itco
w itco
RTVan Dow
GE
Magnesi um a1 umi num s i 1 ic a t e s C h e l a t i n g agents
F l u i d ( 1 0 , O O O ) S i 1 icone
Wachsemulsion 1864 Witcamide S-780 & 128T A l k a n o l a m i d e s u r f a c t a n t s

& 6445
Zschim
W i tco
W i t c o 12986 W i t c o 1298SA W i t c o l a t e ES-3 & LES-6OA & LES-6OC & S E - 5 & WAC-LA & 2310
W itco
Soft acid
Sulfated surfactants
W i tco
witco
228
RAW MATERIAL W i t c o n a t e AOS & SXS & 30DS & 45 L i q u i d & 60T L i q u i d & 1240 & 1260 S l u r r y
W i t c o n o l NP-100
CHEMICAL D E S C R I P T I O N Surfactants
SOUWGE
\Mi ~ C O
Detergents & degreasers Zeolith P Pine o i l Fatty alcohol ether s u l f a t e Fatty alcohol ether s u l f a t e A1 k y l p o l y e t h y l e n e g l y c o l e t h e r Alkyl polyethylene glycol ether
w i tco
& NP-120
Wessalith P Ya rmor 3 02 Z e t e s o l 2056 Z e t e s o l NL Zusol a t 1005/85 Zusol a t 1008/85
Hercul Zschim Pschi I Zschim Zschi rn

PQ
2 . l r Potassium s i l i c a t e (39%) 2 . 4 r Sodium s i l i c a t e (52%)
BQ
Section IV pliers' Addresses
230
A1 1 ied-Si g n a l , I n c . P . O . Box 2332R M o r r i s t o w n , NJ 07962
Dover Chemical Corp

W15 & D a v i s
(201)-455-2000/(800)-526-0717
Amoco Chemical Co. 200 E. Randolph D r . Chicago, I L 60601
P.O. Box 40 Dover, OH 44622
(800)-321 -8805
Dow Chemical USA M i d l a n d , M I 48674 (8 0 0 )-2 5 8 - C H E M Dow C o r n i n g Corp. Box 0994 M i d l a n d , M I 48686
(312)-856-3200/(800)-621-8888
Angus Chemical Co. 2211 Sanders Rd. N o r t h b r o o k , I L 60062
(708)-498-6700/(800)-323-6209
A r c o Chemical Co. 3801 West C h e s t e r P i k e Newtown Square, PA 19073
(517)-496-4000
E t h y l Corp. 451 F l o r i d a Baton Rouge,
(215)-359-2000
A r izona Chemical Co. 1001 E . B u s i n e s s Hwy 98 Panama C i t y , FL 32401
LA 70801 (504)-388-7556/(800)-535-3030
Exxon Chemical Americas 13501 K a t y Frwy Houston, TX 77079
(904)-785-6700/(800)-526-5294
Ash1 and Chemical Co. P . O . Box 2219 Columbus, OH 43216
(713)-870-6000/(800)-231-6f333
F C Corp. M
2000 Market S t .
Philadelphia, P 19103 A (215)-299-6000/(800)-526-3649
(614)-889-3333/(800)-848-7485
BASF Corp. 100 C h e r r y H i l l Rd. P a r s i p p a n y , N J 07054
GE S i l i c o n e s 260 Hudson R i v e r Rd. W a t e r f o r d , NY 12188
(201)-316-3000/(800)-526-1072
B u r l i n g t o n Chemical Co. P . O . Box 1 1 1 615 Huffman M i l l Rd. B u r l i n g t o n , NC 27215
C i ba-Gei gy Corp. 7 Skyline Drive Hawthorne, NY 10532
(518)-237-3330/(800)-255-8886
Genesee Polymers Corp. Fenton Rd./P.O. Box 7047 F l i n t , M I 48507
Inc.
(313)-238-4966
Georgia Marble Co. 1201 R o b e r t s B l v d . Kennesaw, GA 30144
(919)-584-0111/(800)-672-5888
(404)-421-6500
B.F. G o o d r i c h G o .
(914)-374-4700/(800)-431-1900
DeSoto I n c . 1700 S . M t . P r o s p e c t Rd. Des P l a i n e s , I L 60018
991 1 B r e c k s v i 1 1 e Rd , B r e c k s v i l l e , OH 44141 (216)-447-5000/(800)-331-1~44
(312)-391-9000
Suppliers' Addresses
231
W.R.
Grace 8 Co. 55 Hayden Ave. L e x i n g t o n , MA 02173 ( 6 1 7 )-861 -6600 Henkel Corp. 5325 S . N i n t h Ave. LaGrange, I L 60525
Mona I n d u s t r i e s I n c . 76 E . 24 S t . P . O . Box 425 P a t e r s o n , N3 07544 (201)-345-8220/(800)-553-6662 Monsanto Chemical Co. 800 N. L i n d b e r g h B l v d . S t . L o u i s , MO 63167
(708)-530-7300/(800)-543-7370
blercul es I n c . H e r c u l e s P1aza W i l m i n g t o n , DE 19894 (800)-247-4372 Woechst Celanese Corp. 801 Water S t . Portsmouth, V A 23704 (804)-393-3100/(800)-368-2822
I C I Specialties Concord P i k e & New Murphy Rd. W i 1m i n g t o n , DE 19897 (302)-886-3000/(800)-822-8215
(314)-694-1000/(800)-325-43
Morton I n t e r n a t i o n a l 100 N. R i v e r s i d e P l a z a Chicago, I L 60606
(312)-807-2000/(800)-367-33
O l i n Corp. 120 Long Ridge Rd. P . O . Box 1355 Stamford, C 06904 T (203)-356-2000/(800)-243-9171 P e t r o l i t e Corp. 6910 E. 1 4 S t . T u l s a , OK 74112 (918)-836-1601 P i l o t Chemical Co. 11756 Burke S t . Santa Fe S p r i n g s , CA 90670 (310)-723-0036 PPG/Mazer One PPG P l a c e P i t t s b u r g h , PA 15272 (412)-434-3131/(800)-243-6774 P Corp. Q P . O . Box 840 V a l l e y Forge, PA 19482 (215)-293-7200 Quest I n t e r n a t i o n a l Fragrances 400 I n t e r n a t i o n a l D r i v e Mount O l i v e , NJ 07828 (201 )-691-7100
Johns-Manvi 11e Ken C a r y l Ranch Denver, CO 80217 Kaopolite, Inc. 2444 M o r r i s Ave. Union, W J 07083 (9081-789-0609 Kel c o D i v i s i on Merck & Co., I n c . 8355 Aero D r i v e San Diego, CA 92123 (61 9)-292-4900 Kerr-McGee Chemical Corp. Kerr-McGee C t r . P . O . 80x 25861 Oklahoma C i t y , OK 73125 (405)-270-1313/(800)-654-3911 Lonfa I n c . 1717 R t a 208 F a i r Lawn, NJ 07410 (201)-794-2400/(800)-777-1875
232
Rhone-Poul enc P r o s p e c t P l a i n s Rd. Cranbury, N J 08512 (609)-860-4000/(800)-626-2613 Richardson Co. 2400 East Devon Ave. Des P l a i n e s , I L 60018 Rohm & Haas Co. Independence M a l l West P h i l a d e l p h i a , PA 19105 (215)-592-3000 S h e l l Chemical Co. P . O . Box 2463 Houston, TX 77252 (713)-241-6161 Stepan Co. 22 W . F r o n t a g e Rd. N o r t h f i e l d , I L 60093 (708)-446-7500/(800)-745-7837 Tennessee Chemical Co. 3400 Peachtree Rd NE A t l a n t a , GA 30326
Tomah P r o d u c t s , I n c . 1012 T e r r a D r i v e M i 1t o n , W I 53563
(608)-868-68ll/(800)-441-0708
Uni chema Chemicals I n c . 4650 S . Racine Ave. Chicago, I L 60609 (312)-376-9000/(800)-833-2884 Union C a r b i d e Corp. 39 O l d Ridgebury Rd. Danbury, CT 06817 (203)-794-2000 R . T . V a n d e r b i l t Co., P . O . Box 5150 30 W i n f i e l d S t . Norwalk, CT 06856 W i t c o Corp. 520 Madison Ave. New York, NY 10022 Inc.
(203)-853-1400/(800)-243-6084
(212)-605-3941/(800)-634-4010
Zschimmer & Schwarz Max-Schwarz-Strabe 3-5 D-56112 L a h n s t e i n/RH D 26 21/120
(404)-239-6700/(800)-241-1912
Texaco Chemical Co. 3040 Post Oak 8 l v d . Houston, T X 77056 (713)-961-3711 3 M 3 Center M S t . P a u l , MN 55144 (612)-733-5454

Advanced Cleaning Product Formulations Volume5

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ADVANCED CLEANING RODUCT FORMULATIONS

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ADVANCED CLEANING PRODUCT FOR MULATlONS

NOYES PUBLICATIONS WILLIAM ANDREW PUBLISHING, LLC

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IV. Main office addresses of the suppliers of trademarked raw materials.

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ntents and Subject Index

Contents and Subject Index

Contents and Subject Index

Contents and Subject Index

All Purpose Cleaner Concentrate

Contents and Subject Index

Contents and Subject Index

103 104 104 1104

Contents and Subject Index

Contents and Subject Index

135 136 B6 3 137 138

Rinse Aid. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rinse Aid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

RUG. FLOOR, CARPET. UPHOLSTERY SHAMPOOS AND CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

155 155 155

Contents and Subject Index

Contents and Subject Index

15 AUTO CLEANERS AND POLISHES

1 198 19 7 180 181

Contents and Subject Index

Contents and Subject Index

SECTION III: TRADEMARKED RAW MATE SECTION IV: SUPPLIERS' ADDRESSES

Household and Industrial Cleaners and Polishes

BFGoodrich Dowfax 2A1

i2j Stepan Co.: B i o s o f t 5-100

Advanced Cleaning Product Formulatioris

5.00 2.75 0.25 3.00

Ingredients: Veegum T , Magnesium Aluminum S i l i c a t e T e t r a s o d i u m P y r o p h o s p h a t e (TSPP) Water

8 : Sodium H y p o c h l o r i t e , 5 . 2 5 % Sodium M e t a s i l i c a t e , Anhydrous

Advanced Cleaning Product Formulations

17.6 13.5 0.5 1.o between

I n qr e d D I Water Carbopol 676 ( 1 ) P o t a s s i um h y d r o x i d e ( 4 5 % ) 2 . l r P o t a s s i u m s i l i c a t e (39%) ( 2 ) Potassium carbonate Sodium h y p o c h l o r i t e ( 1 2 . 5 0 % ) Amine O x i d e (30%) ( 3 )

Wt% 60.75 1.25 5.00 5.00 5.00 8.00 10.00

2. Dairy, Food and

General Industrial Cleaner

D a i q , Food and General Industrial Cleaners

A c i d I n d u s t r i a l and Household C l e a n e r s O x a l i c A c i d Gel

Inqredients: Water Van Gel B Rhodopol 2 3 O x a l i c A c i d D i h y d r a t e , 12.59n Aqueous S o l u t i o n P o l y s o r b a t e 40 (Tween 4 0 )

53.70 2.50 0.80 40.00 3.00

50% Aqueous Sol u t ion

Advanced Cleaning Product Formulations

I n s ed ien t s : water P h o s p h o r i c a c i d (85Oh) S u l p h u r i c a c i d (98%) P r o p e t a l 241 Dodigen 226 F o r m u l a CT 06-06-01

wts/, 48.0 24.0 5.0 3.0 20.0

6.0 3.0 0.5 4.0 0.5

Zschimmer & Schwarz GmbH 8, C o . :

Dairy, Food and General Industrial Cleaners

FMC Rhone P o u l e n c I g e p a l C A - 6 3 0 Destai ner (Reduced Phosphate,

% & 10.0 25.0 8.0 2.0 2.0 15.0 38.0

Advanced Cleaning Product Formulations

30.0 20.0 12.0 30.0 3.0

Wt% 35.0 12.0 3.0 50.0

Dairy, Food and General Industrial Cleaners

Water TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) E t h y l e n e G l y c o l Monobutyl E t h e r C a l s u d s 81 NH40H, 28%

Weight% 89.00 1.oo 3.00 4.00 3.00

Co. : Suggested Formul a t i ons

Advanced Cleaning Product Formulations

Compo_sition STPP M e t s o Beads 2048 Sod1 u m C a r b o n a t e +Sod1 um D i c h l o r o i s o c y a n u r a t e , 2H20 * * S o d i u m A1 k y l a r y l S u l f o n a t e Powder,