UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education CHEMISTRY Paper 1 Multiple Choice May/June 2006

45 minutes
Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended)

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w w w e tr .X m ap eP s er om .c

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 20. You may use a calculator.

This document consists of 18 printed pages and 2 blank pages.

IB06 06_0620_01/3RP UCLES 2006

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2 1 At room temperature, in which substance are the particles furthest apart? A 2 H2 B H2O C Mg D MgO

Which method can be used to obtain crystals from aqueous copper(II) sulphate? A B C D chromatography electrolysis evaporation neutralisation

Five elements have proton numbers 10, 12, 14, 16 and 18. What are the proton numbers of the three elements that form oxides? A B C D 10, 12 and 14 10, 14 and 18 12, 14 and 16 14, 16 and 18

The rows P, Q and R in the table show three pairs of structures.

e e 1n 2p

e e 2n 2p

key e electron

n neutron p proton nucleus

atoms of the same element

H R H C H
Which pair or pairs are isotopes? A P only B P and Q only C

H H H C H

H C H H

Q only

Q and R only

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3 5 Which numbers are added to give the nucleon number of an ion? A B C D 6 number of electrons + number of neutrons number of electrons + number of protons number of electrons + number of protons + number of neutrons number of protons + number of neutrons

In the molecules CH4, HCl and H2O, which atoms use all of their outer shell electrons in bonding? A B C D C and Cl C and H Cl and H H and O

Which change to an atom occurs when it forms a positive ion? A B C D It gains an electron. It gains a proton. It loses an electron. It loses a proton.

For which compound is the formula correct? compound A B C D ammonia carbon dioxide potassium oxide zinc chloride formula NH4 CO P2O ZnCl2

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4 9 The diagrams show the molecules of three elements.

Which of these elements are present in water? A B C D 1 and 2 only 1 and 3 only 2 and 3 only 1, 2 and 3

10 The diagram shows that two gases are formed when concentrated hydrochloric acid is electrolysed between inert electrodes.

+ ve

ve

concentrated hydrochloric acid

Which line correctly describes the colours of the gases at the electrodes? anode (+ve) A B C D colourless colourless yellow-green yellow-green cathode (ve) colourless yellow-green colourless yellow-green

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5 11 The diagram shows an electrolysis experiment to electroplate nickel with a different metal.

+ 1 2 Ni Ni

3 4 Ni Ni

aqueous copper(II) sulphate

Which nickel electrodes are plated with a metal? A B C D 1 only 1 and 3 only 2 only 2 and 4 only

aqueous sodium chloride

12 The diagram shows an experiment in which magnesium oxide powder is added to dilute hydrochloric acid. magnesium oxide powder

dilute hydrochloric acid 20 oC pH2 before Which terms describe the experiment? exothermic A B C D     neutralisation     after

aqueous magnesium chloride 22 oC pH7

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6 13 Coal, methane and hydrogen are burned as fuels. Which descriptions of this process are correct? what happens to the fuel A B C D oxidised oxidised reduced reduced type of reaction endothermic exothermic endothermic exothermic

14 Two reactions involving water are shown. X Y FeSO4 + water hydrated iron(II) sulphate Fe + O2 + water rust

Which of these reactions are reversible by heating? X A B C D     Y    

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7 15 The diagram shows a speed of reaction experiment.

hydrogen

magnesium

excess of dilute hydrochloric acid at 25 oC

Increasing the concentration of the acid and increasing the temperature both affect the speed of reaction. Which line of the table is correct? increase concentration of acid A B C D decrease speed of reaction decrease speed of reaction increase speed of reaction increase speed of reaction increase temperature decrease speed of reaction increase speed of reaction decrease speed of reaction increase speed of reaction

16 Barium hydroxide is an alkali. It reacts with hydrochloric acid.

aqueous barium hydroxide pH meter

hydrochloric acid
What happens to the pH of a solution of hydrochloric acid as an excess of aqueous barium hydroxide is added? A B C D The pH decreases from 14 but becomes constant at 7. The pH decreases from 14 to about 1. The pH increases from 1 but becomes constant at 7. The pH increases from 1 to about 14.

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8 17 Element X is at the left-hand side of the Periodic Table. Which line in the table shows the correct type and property of the oxide of X? type of oxide A B C D metallic metallic non-metallic non-metallic property of oxide acidic basic acidic basic

18 The diagram shows the positions of some elements in the Periodic Table.
Z W X Y

Which elements form ionic bonds with oxygen? A B C D W only W and X only Y only Y and Z only

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9 19 The diagrams show three experiments using dilute sulphuric acid. Three different powders are added to the acid.

Cu powder

Cu(OH)2 powder

CuCO3 powder

H2SO4(aq)

H2SO4(aq)

H2SO4(aq)

1
The mixtures are stirred. Which test-tubes then contain Cu2+(aq) ions? A B C D 1 and 2 only 1 and 3 only 2 and 3 only 1, 2 and 3

20 The equation shows the reaction between a halogen and aqueous bromide ions. X2 1 + 2Br(aq) 2 2X(aq) + Br2 3

Which words should be written in gaps 1, 2 and 3? 1 A B C D chlorine chlorine iodine iodine 2 brown colourless brown colourless 3 colourless brown colourless brown

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10 21 The diagram shows an outline of part of the Periodic Table.

W X Y Z

Which two elements could form a covalent compound? A W and X B W and Y C X and Y D X and Z

22 A student is asked to complete two sentences. Metallic and non-metallic elements are classified in the 1. This can be used to 2 the properties of elements. Which words correctly complete the gaps? gap 1 A B C D Periodic Table Periodic Table reactivity series reactivity series gap 2 measure predict measure predict

23 The diagram shows three balloons held by children.

P carbon dioxide Q helium R hydrogen

Which of the balloons float up into the air when the children let go? A B C D P only P and R only Q only Q and R only

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11 24 Three mixtures are made. 1 2 3 C + Fe2O3 Cu + Fe2O3 Mg + Fe2O3

The mixtures are heated strongly. Which of the elements C, Cu and Mg are reactive enough to reduce the iron oxide to iron? A B C D C and Cu only C and Mg only Cu and Mg only C, Cu and Mg

25 Which property do all metals have? A B C D Their densities are low. Their melting points are high. They act as catalysts. They conduct electricity.

26 Copper, iron and zinc are all used to make things. Which of these three metals are also used in the form of alloys? copper A B C D     iron     zinc    

27 Which diagram shows a common use of stainless steel?

A B C D

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12 28 The diagram shows stages in the purification of water. Which stage uses chlorine? water at pH9 + bacteria + large solids + fine solids A water at pH9 + bacteria + fine solids B

water at pH9 + bacteria C

pure water at pH7

water at pH7 + bacteria

29 In experiments on rusting, some students are each given two metal objects to study. One student set up his apparatus as shown.

nitrogen

air

chromeplated keyring brass screw water

Which objects rusted? brass screw A B C D     chrome-plated keyring    

30 Which substance is not a pollutant of clean air? A B C D argon carbon monoxide nitrogen dioxide sulphur dioxide

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13 31 Which metallic element is needed in a complete fertiliser? A B C D calcium magnesium potassium sodium

32 A newspaper article claims that carbon dioxide is formed as follows. 1 2 3 during respiration when calcium carbonate reacts with hydrochloric acid when methane burns in air

Which statements are correct? A B C D 1, 2 and 3 1 and 2 only 1 and 3 only 2 and 3 only

33 The diagram shows an experiment.

damp litmus paper gas given off

mixture of ammonium chloride and sodium hydroxide heat

What is the name of the gas and the final colour of the litmus paper? gas A B C D ammonia ammonia chlorine chlorine colour blue red white red

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14 34 The diagram shows the pH values of the soil in X and Y, two parts of the garden of a house.

X pH 7.0

Y pH 5.5

The house owner wishes to use lime to neutralise the soil in one part of the garden. To which part should the lime be added, and why? part of garden A B C D X X Y Y because lime is acidic basic acidic basic

35 In the molecule shown, the two OH groups are numbered.

H H 1 O C H H C H H C H C O 2 H O

Which of these OH groups react with aqueous sodium hydroxide?

1 2

A B C D

   

   

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15 36 When a suitable catalyst is used, ethene reacts with steam. What is the structure of the compound formed? A H H C H H C H O H H O H C H B H C H O H

C H H C H C O H H O O C O

D O C O H

37 The diagram shows the separation of crude oil into fractions.

petrol

X Y crude oil Z

bitumen

What could X, Y and Z represent? X A B C D diesel lubricating oil lubricating oil paraffin Y lubricating oil diesel paraffin diesel Z paraffin paraffin diesel lubricating oil

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16 38 Which of the compounds shown are used as fuels?

H H C H 1 H C H H H H C H 2 H C H O H H H C H 3 C O H O

1 A B C D    

2    

3    

39 Which set of diagrams shows three substances that are all in the same homologous series?

H A H C H H H

H C H O H H C

O O H

H B H C H

H C H H

H C H C

H H H C C H

H C H C C

H H H

H C H

H C C

H H H

H C H

H C H

H C C

H H

H D H C H C

O H H

H C H

O C

H C H H H

H C H

H C H O

H C H

H C H H

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17 40 The diagram shows the structure of a small molecule.

CH3 C H C H H

Which chain-like molecule is formed when these small molecules link together?
A CH3 H C C CH3 H C C CH3 H C H C H B CH3 H C H C H C CH3 CH3 CH3 CH3 C C C C CH3 H C H C D CH3 H C C CH3

CH3 H

CH3 H

CH3 CH3 CH3 CH3

CH3 H

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18 BLANK PAGE

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19 BLANK PAGE

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DATA SHEET The Periodic Table of the Elements

Group III
1

I H
Hydrogen

II

IV

VI

VII

0
4

He
Helium

1 11 12 14 16 19

2 20

Li
Boron Carbon

Be
5 27 28 6 7

N
Nitrogen

O
Oxygen

F
Fluorine

Ne
Neon

Lithium

Beryllium

8 31 32

9 35.5

10 40

23

24

Na
Aluminium

Mg
13 51 52 55 56 59 59 64 65 70

Al
14

Si
Silicon

P
Phosphorus

S
Sulphur

Cl
Chlorine

Ar
Argon

Sodium

Magnesium

11

12

15 73 75

16 79

17 80

18 84

39

40

45

48

K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc

Ca
23 93 96 101 103 106 108 112 24 25 26 27 28 29 30

Sc

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn
31

Ga
Gallium

Ge
Germanium

As
Arsenic

Se
Selenium

Br
Bromine

Kr
Krypton

Potassium

Calcium

Scandium

Titanium

19

20

21

22

32 115 119

33 122

34 128

35 127

36 131

20

85

88

89

91

Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver

Sr
41 181 184 186 190 192 195 197 42 43 44 45 46 47

Zr

Nb

Mo

Tc

Ru

Rh

Pd

Ag
48

Cd
Cadmium

In
Indium

Sn
Tin

Sb
Antimony

Te
Tellurium

I
Iodine

Xe
Xenon

University of Cambridge International Examinations is part of the University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
49 201 204 50 207 51 209 52 53 54

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity.

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Rubidium

Strontium

Yttrium

Zirconium

37

38

39

40

133

137

139

178

Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum

Ba
73 77 74 75 76 78

La Ta W Re Os Pt

Hf

Ir

Au
Gold

Hg
Mercury

Tl
Thallium

Pb
Lead

Bi
Bismuth

Po
Polonium

At
Astatine

Rn
Radon

Caesium

Barium

Lanthanum

Hafnium

55

56

57

72

79

80

81

82

83

84

85

86

226

227

Fr
140 141 144 150

Ra

Ac
152 157 159 162 165 167 169 173 175

Francium

Radium

Actinium

87

88

89

*58-71 Lanthanoid series 90-103 Actinoid series Ce

Cerium Praseodymium Neodymium Promethium

Pr
59 60 238 61

Nd

Pm
62

Sm
Samarium

Eu
Europium

Gd
Gadolinium

Tb
Terbium

Dy
Dysprosium

Ho
Holmium

Er
Erbium

Tm
Thulium

Yb
Ytterbium

Lu
Lutetium

58 232

63

64

65

66

67

68

69

70

71

a = relative atomic mass

Key Th
Thorium Protactinium Uranium

X Pa
91 92

X = atomic symbol
90

U
93

Np
Neptunium

Pu
Plutonium

Am
Americium

Cm
Curium

Bk
Berkelium

Cf
Californium

Es
Einsteinium

Fm
Fermium

Md
Mendelevium

No
Nobelium

Lr
Lawrencium

b = proton (atomic) number

94

95

96

97

98

99

100

101

102

103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).