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Industry Standard Welding Procedures Software AWS, ASME and API Welding Codes
CWA Welding Symposium, October 22, 2002 Toronto CWA Welding Symposium, October 22, 2002 Toronto
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Content Introduction Design Criteria Weld Metal Grades Slag Systems Properties Applications / Procedures
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Estimated Stainless Consumables Potential North America & Canada Europe 14.8 x 103 ton 23.8 x 103 ton
s les n tai S
400 300
Steel total
200 100 0
Introduction Share of consumables per process Process SMAW GMAW FCAW SAW Total Welding Stainless Steel Market Only 22 % 60 % 57 % 35 % 15 % 5% 6% <1 %
Weld Metal Grades Stainless Steel Base Materials Regular stainless steel
Austenitic, with up to 12 FN
Non N-alloyed Base Metal N-alloyed Base Metal Weld Metal Identification Supermartensitic EN / AWS X80-11Cr2Ni 22 9 3 NL / 2209 B X80-13Cr4.5Ni1.5Mo / X80-13Cr6Ni2.5Mo 25 9 4CuWNL / 2553 A (Super)Duplex X2CrNiMoN 22-5-3 22 9 3 NL sion 2209 / B corro ess A resistan 25-7-4 tr 25 9 4CuWNL / 2553 d X2CrNiMoNce to s Increase X2CrNiMoCuWN 25-7-4 25 9 4CuWNL / 2553 A Regular stainless steel X2CrNi18-9 X2CrNiN18-9 19 9 L / 308L C X6CrNiTi18-10 19 9 Nb / 347 D X2CrNi17-12-2 X2CrNiMoN17-12-2 19 12 3 L / 316L E X6CrNiMoTi17-12-2 19 12 3 Nb / 318 F X2CrNiMo18-14-3 X2CrNiMoN17-13-5 18 16 5 NL / (4439) G 20 16 3 MnNL / (4455) H Fully Austenitic X1NiCrMoCu25-20-5 20 25 5 CuNL / 385 J X1CrNiMoN25-22-2 and 25eneral cor310Mo n K g 22 2 NL / rosio g sistance to pittin X1NiCrMoCu31-27-4e 27 31 4 CuL / 383 L Increased r X1CrNiMoCuN20-18-7 Ni6059 / NiCrMo-13 M 6 Ni6625 / NiCrMo-3 N
Ferrite Number FN
20
FA
30 40
15
50 60
E
13
F B
70 80 90
100
D C
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Weld Metal Design Criteria Controlled Ferrite content A controlled weldmetal ferrite content requires a balanced chemical composition Controlled ferrite for an E(R)316L type implies a ferrite content of 4 - 10 FN Too low ferrite increases the risk of hotcracking Too high ferrite increases the risk of embrittlement and/or preferential corrosion attack of the ferrite
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Among investigated European and US suppliers, 6 out of 14 comply for -17 grades 10 out of 12 comply for -16 grades
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Weld Metal Design Criteria Horses for Coarses! The type of slag system to be used, depends on the required combination of: Weldability, Mechanical Properties, Corrosion Resistance AND Specific Application
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Weld metal adapted to match or exceed base metal MECHANICAL properties. Free of detrimental phases
Carbides, sigma, etc.
Weld Metal Design Criteria Flux types & Slag systems Vertical down
Fast freezing High rutile
Downhand fillets
Wettability Rutile / Silicate
All position
Weldability Mechanical properties Rutile / Basic Basic
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15
Appreciation
PA
PB
PF
PF
PG
Horizontal fill
Vertical fill 16
Vertical up fillet
Nickel
Austenite
Carbon
Austenite
Nitrogen
Austenite
Manganese
Molybdenum
Continued . . .
Titanium Aluminum
Copper
Sulfur Phosphorus
AWS A5.4
EN 1600
As an indicator for the corrosion resistance we can use the PITTING RESISTANCE EQUIVALENT, being: PREN = %Cr+3.3x%Mo+16x%N
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Elements C Si
Mn
negative
S Cr
negative positive
Mn rich sulphides act as initiation points for pitting. Mn may destabilize the passive film Sulphides (except Cr- and Ti-) tend to initiate pitting Cr stabilizes the passive film
Max. 2,0%, dueto its effect on structural stability and on nitrogen solubility Max. 2%, as high amounts might increase the risk for precipitation of intermetallics Max. 0,02% Max 25-28%, depending on Mo content. Higher contents increase the risk for precipitation of intermetallics Nickel is primarely ised to control the austenite content
Ni
negative
Mo
positive
With other elements constant, nickel dilutes the austenite with regard to N, which in turn decreases the PRE. When the alloy is very sensitive to precipitation of Cr-nitrides, nickel can have a positive effect. Mo stabilizes the passive film.
positive
Cu W Ferrite
Slight positive effect Similar effect as Mo Increased ferrite increases the N, Cr and Mo content of the austenite Precipitates with accompanying depletion of alloying elements Cr carbides and nitrides cause Cr depleted zones, which are selectively attacked in certain corrosive environments 21
Max. 4-5%, depending on Cr content. Mo enhances the precipitation of intermetallics Max. 0,15% in Mo-free DSS. Max 0,3 in 25Cr high Mo SDSS, and max 0,4% in 25%Cr SDSS with high Mn and Mo Max 2%, due to undesired hardenability Increases tendency to precipitation of intermetallics Too high ferrite content may cause precipitation of Cr carbides and nitrides
negative negative
120 100
GTAW
80 60 40 20 0 0 200 400
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600
800
1000
Stick Electrodes
General Corrosion Resistance 304L, 308L and 347 range
Arosta, Limarosta, Jungo, Vertarosta
Increased Pitting and General Corrosion Resistance 316L and 318 range
Arosta, Limarosta, Jungo, Vertarosta
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Stick Electrodes
Dissimilar Joints, Buffer Layers and Difficult Weldable Metals 308MoL, 309L, 309Nb, 309MoL, 329 and 312 range
Arosta, Limarosta, Jungo, Vertarosta
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Stick Electrodes
High Temperature Applications, Highly Oxidation Resistant 308H, 309H, 310 range
Arosta, Intherma
Highly Stress Corrosion Resistant in 22%Cr and 25%Cr (super) Duplex Stainless Steels and Supermartensitic Steels 2209, 2553 range
Arosta, Jungo, Zeron100
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Stick Electrodes
Special Corrosion Resistant Steels, with Increased Pitting Resistance in Oxidizing and Reducing Media
Pitting-, Intergranular-, Stress Corrosion , Chemical Tankers Arosta / Jungo 4439 Cryogenic, Non-magnetic Jungo 4455 Urea, Nitric Acid,Strong Oxidizing and Slightly Reducing Jungo 4465 Phosphoric, Sulphuric Acids, Paper Mill Plants Jungo 4500
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Applications / Procedures
Process Type of joint Filler material Coated electrodes 2,0 - 2,5 mm Comments Only when acceptable to have slag on inside
SMAW
Purging or welding on Cu or ceramic backing Good weld pool control Manual or mechanized Risk of overheating when manual In closed joints, addition of filler metal is required
GMAW-STT
5G : mechanized 1G: Manual or mechanized low HI, improved corrosion resistance Only mechanized Requires solution annealing
PAW
No filler
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29
30
Base material 22Cr DSS (UNS 31803), consumables SMAW E2209-15, Jungo 4462
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32
33
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STT.008 2 95.048
Welding procedures
All-weld-me tal tension test Yield point [MPa] : 15 12 - 15 Tensile strength [MPa] : Elongation, A5 [% ] : Reduc tion, Z [% ] : B end t est s Root Fa ce Side Impact t ests 20 x 15 20 x 15 10 x 15 ISO - V Former diameter: 180 180 180 [Joule] 3 xt + 3.8 xt No remar k s No remar k s No remar k s Test temp [ C]: . see below Requir ed 40 J oule av.
Flow Flow
CTO D testing Notc h lo cation Temp. [C] C TOD value [mm] Frac tur e mode
Req. 30 - 99 WM 65 - 62 - 66 56 - 56 - 56 70 - 71
Joint D et ail
Load : 20 k g HAZ 256 - 257 - 268 - 269 255 - 266 - 263 - 274 277 - 288 - 264 - 274
Req. < 325 WM 245 - 261 - 258 252 - 249 - 254 278 - 260
Fa ce C entre Root
Corrosion test s Modified ASTM G48a 24 hours C PT > 30C We the under s igned, certify that the statementsin this r e cor d ar e correct. Manufactur er or C ontr actor Autho riz by ed Issued b y 35 D ate Linc oln Smitweld bv Nijmegen L.van Na ssau Fred N eessen 23 September 1995
WPAR: Rev. :
Ref. WP Q :
Test Results
Acc eptable
Cross Tensile Tes t (reduced section) a t + 20C Tens s ile trength [MPa] Full cro s s s ection: 30 x25 mm 784 MPa All weld metal Tension tes t Yield point [MPa] : 15 15 Tens s ile trength [MPa] : Elongation, A5 [% ] : Reduction, Z [%] : Guided B end Tes ts Forme r diameter: Root satis facto ry, no defe cts Face satis facto ry, no defe cts Side -Impact Tes ts ISO-V [Joule] 3xt Fractu re location base material
Welding procedures
2: LNM 4462
N.A. 1: EN12072: G 25 9 4 N L 2: EN12072: G 22 9 3 N L 98Ar + 2% CO Argon 4.0 N.A. DC + RT ma x 100 . N.A. Arie van der Sluis & Dirk Rits ema BR 96 B STT - I Po w erwave 450
2
Flo w Flo w
- 40 av . 0 0 0 0
Siz of s e pecimen: 10 x10 x 55 mm Cap av . Clw 121 121 116 119 Fl Fl + 2 Fl + 5 CTOD testing 0 0 0 Temp. [C] CTOD v alue [mm]
Welding Procedure
Pas s No. 1 2 3+4 5+6 7 - 11 12 -14 Consumable index [mm] A1 1,0 B2 B2 B2 B2 B2 1,0 1,0 1,0 1,0 1,0 Welding Cu rrent Ampe re Volts BC: 75 14 - 16 PC: 275 145 145 145 145 150 24 - 26 24 - 26 24 - 26 24 - 26 24 - 26
Speed H.I. Notch [mm/min] [k J/mm] location 120 (0,6 -0,8) 139 236 231 227 260 1,6 0,9 1,0 1,0 0,9
Fr actu re mode
see sketch
WM 36 32
HAZ
BM 46 45
Joint De tail
Hardness Survey Te s type: t Vic k rs e BM Face Root 256 259 HAZ 250 262
Sketch
We ce rtify that the data in this report are actual te s re s t ults. Project Clarification test welding equipment Manufactu rer or Contra ctor Lin coln Smitweld b v Autho rized b y Issued by Date Mr. Ir. Leo van Nassau Fred Neessen 27 July 1999
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Welding procedures
676 805 30 47
St 2 626 773 26
St 3
51 51 Former diameter:
P 2000, batc h F3053 LNT 4462, batc h 51469429 LNS 4462, batc h 51467032 W elded under fully r estr aint conditions
Clw 100 104 102 92 100 90 106 108 106 138 132 134
Fl + 0- 0.5 294 298 293 136 120 121 131 87 136 256 224 243
Fl + 0- 0.5 86 83
99 100 79 72
Ferrit e Cont ent (FN ) BM HAZ Fac e 1 Mid Root Fac e 2 H ardness Test ty pe : Fac e 1 Mid Root
WM
Joint D et ail
see sketch
Vicker s WM
Load : HAZ
270-264-270-264-258
10 kg BM
236-236-236 228-232-232 236-233-232
258-264-258-262-268-264 285-285-279-279-274
Sket ch
W e the undersigned, c ertify that the statements in this r ec or d ar e c orrec t. Manufac tur er or C ontr ac tor Linc oln Smitweld and MPS/DSM Authoriz by ed Issued b y D ate
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13Cr-018b 0
Test Results
No defects, A cceptable
11 Cr-2,5 N s i upermart.s tainl.s teel A: GMAW - STT B: SAW SAW Manual and ma chine
Visual Examination: Good, smooth surf aces Cross Tensile Tes t (reduced section) Fractu re location 20,1 x19,0 mm 20,0 x19,3 mm Ten s strength [Mpa] ile 689 694 base me tal base me tal
Welding procedures
STT 1 Welding position 1G (PG / PA); STT at 2h pos. 20 -V60 -STT 5 Filler me t l (trade ) 1: LNM Zeron 100X 2: LNS SD2509 a Flux Filler metal cla s sific. Shielding ga s[l/min] Ba c k (gas) [l/min] ing Pu rging gas SAW Cu rrent / polarity Preheat temp. [C] Inte rpass temp. [C] Po s theat treatment Welde r's name Laborato ry Tes No. t Rema rks: Specification-code: BIL 13Cr project P2000 EN 760: A AF 2 63 DC 1: EN12072: G 25 9 4 N L 2: EN12072: S 25 9 4 N L 98Ar + 2% CO STT: Ar 99.99% N 2 dry DC + RT ma x 140 . N.A. D. R ema and T.Bou w its man s
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All-weld-metal tension test Yield point Rp0,2[MPa] : 15 12 - 15 Tens s ile trength [MPa] : Elongation, A5 [% ] : Reduction, Z [%] : Bend tests Root Face Side Impact tests 680 871 27 54 678 869 29 49
Flo w Flo w
Forme r diameter:
ISO - V [Joule] Te te [C]: st mp. seebelo w Siz of s e pecimen: 10 x10 x 55mm Required 40 Joule n.loc./T WCL avg. FL avg. -20 face 61 65 65 64 51 61 50 54 root 57 51 52 53 51 54 40 48
Welding Procedure
Pas s No. 1 Consumable index [mm] A1 1.2 Welding Cu rrent Ampe re Volts BC: 95 PC: 260 2+3 4+5 6 -13 14 -16 B2 B2 B2 B2 2.4 2.4 2.4 2.4 200 300 350 300 30 30 30 30 650 600 600 600 0,6 0,9 1,1 0,9 N.D. Speed [mm/min] 90 - 150 H.I. [k J/mm] 0.5 - 1.0
CTOD testing Notch location WCL Temp. [C] -20 CTOD v alue [mm] 0,26 0,24 0,24 Fr actu re mode m
Joint De tail
Mn
1, 0 2
Si
Cr
0, 6 21, 2 8 0
Ni
8, 7 0
Mo
2, 9 0
Cu
0, 2 0
V
0, 0 5
N
0, 2 2
We the undersigned, ce rtify that the s tatementsin this rec or d are co rre ct. Manufactu rer or Contra ctor Autho rized b y Issued by Date Lin coln Smitweld b v Nijmegen L.van N assau '21 -03 -2000
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SUMMARY SMAW is still a popular welding process Depending on the application, various slag systems can be applied, such as rutile, rutile-silicate, rutile-basic or true basic Weldmetal chemical composition must be related to the required corrosion and in some applications, mechanical properties Mo is vital for corrosion resistance and should have a decent minimum value Ferrite content must be controlled
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