Name: AP CHEMISTRYPROBLEMSET 1 For purposes consistency, of everyone shoulduseR : 0.08206L . atm / mol .

K 1-1 Element reacts X with oxygento produce XrOr. In an experiment is foundthat it g l.lXXX g of XrO3.Whatis the atomicweightof X? 1.0000 of X produces

t-2
a) A compound containsonly carbon and hydrogen. A 0.857 g sample rs burnedin oxygen to give 1.45 L of carbondioxide, measured dry at 98.0 kPa and 20.0" C. What is the compound'sempiricalformula?

b) What would be the volumeof the carbondioxideif it were collected at wet pressure). 2X.XX" C (still with the same ambient Assume that the vapor pressure wateris X.XX kPa at that temperature. of

t -3 Ferric ion reacts with sulfideaccording the reaction: to ZF+(aq) + 3 SL(aq) -' Fe,Sr(s) An iron solutionis madeby dissolving 1.25 g of ferric sulfate,Fe,(SOo)r, XXX mL of water. in (Assume volumeof the liquid remains the constant.) sample this solutioncontaining12.0 mL was A of mixedwith 18.0mL of 0.113M sodium sulfide(NES) solution. a) How many gramsof ferric sulfideare formed?

b) How many sulfur molecules(Sr) would be formed by decomposingthe ferric sulfide?

c) If the sulfur molecules (b) werevaporized in and allowedto fill a 780 mL container 550" C, what would be the pressure the sulfur (in at of atmospheres)?

L-4 A non-stoichiometric compound NaWOn, analyzed foundto contain is and TX.XXVotungsten. What is the valueof n? (Sincethe compound nonis n stoichiometric, doesnot needto be an integer.)

n -

1-5 An aspirintabletweighs2.AOg. Part of the tabletis madeof aspirin,CeH1sO3, part of the tabletis and filler. Combustion aspiringoesaccording the following reaction: unreactive of to
+ CeHroO3 10 02- 5 COz + 5 H2O "Ihe combustionof an aspirintabletproducesl.XXX L of carbondioxide, measureddry and at 100.0 kPa and 22' C. What is the percentage aspirin in of an aspirin tablet?

L-6 (CrHu)is placedin a 2.50 L container A smallamountof ethane containing oxygen(OJ to give a mixturewhich exertsa pressure 1.0XXX atm at 20' C. The mixtureis ignitedand reacts shown of as below: 2 CrHu@) 7 Ot(g) -,4 COz($ + 6 HrO(g) + After the gasmixture hascooledback to 20" C, the pressure the containeris in pressure ethane, atm., in the original 1.100atm. What is thepartial of in mixture.Note that all the wateris present a gas. as

t-7
Consider the combustionof aluminum in oxygen, 4 Al(s) + 3 Or(g) -' 2 AlzOr(s). Suppose 6.75 g of aluminumis allowed to reactwith X.XX L of oxygen, measured at25" C and 1.02 atm. What is the massof the aluminum oxide which is produced?

1-8 An evacuated steelvessel with a volumeof 10.00L is filled with 32.00 atm. of pure oxygenat is 25'. An electricdischarge passed throughthe oxygen,converting someof it to ozone. '- 2 Ot(E) 3 Or(g) insidethe vessel As a result,the pressure dropsto 30.XXX atrn. at 25" C. (a) Calculate final pressures, atm., of ozoneand in the D P orygen : r ozore of oxygenin the flask.

(b)

of Calculate the final masses ozone and oxygen in the flask.

Moro*:

Mo*yg"n:

l-9 A mixture of Ht(g), Ot(fl, and 2 mL of HzO(l) is at equilibrium in a 350 mL rigid container at 25" C. The number of moles of H, and the number of moles of O, are equal. The total pressureis IXX.X kPa. (The equilibriumvapor pressure water at25" C is 3.2 kPa.) The naixtureis ignited, and the H, of and Or react until one reactantis completely consumed.You may neglect the volume of the liquid water. (a) Identify the reactantremaining and calculatethe number of moles of the reactantremaining.

(b) Calculate total pressure the container the conclusion the in the at of reaction the final temperature 90"C. (The equilibriumvaporpressure if is o f w a t e r t 9 0 'C i s 8 1 .2kP a .) a

1.-10 A mixture containingKCIO3,KHCO3,KrCO, and KCI was heated,producing COz,Oz and HzO accordingto the following equations: 2 KCIO3 -' 2 KCI(s) + 3 O2(g) 2 KHCOr(s) -' KzO(s)+ HrO(g) + 2 COr(e) KtCOr(s) -' KzO(s)+ COr(g) T h e KC l d o e s n otre a ct. IX X .X g o f th emixtur epr oduced If I.XXXgof Hr O, 13.20 gof COr and (in 4.00 g of Or, what wasthe composition percent) the originalmixture?Fill in your answers of below.
KCIO3 : _% KHCQ: _Vo K2CO3