CHM151 Practice Test 6

Name: _____________________________

A. TRUE or FALSE: 1. The strength of dispersion forces increases as the molar mass increases. 2. All molecular substances exhibit dispersion forces. 3. Instantaneous dipoles are formed due to unequal electron distribution within the molecules. 4. Hydrogen bonding occurs when hydrogen forms a covalent bond with O, N, or F. 5. CH3OH is more soluble/miscible in water than in CCl4 primarily because it attracts water via hydrogen bonding. 6. Vapor pressure increases as the strength of attractive forces increases. 7. The amount of heat needed to vaporize one mole of liquid at a constant temperature and pressure is called its molar heat of fusion.

B. Determine the types of intermolecular forces that are present in the following liquid samples: 1. CHCl3 2. H2Se 3. I2
H H

O H O

4.

H3C

O O

CH3

5.

Useful information: q = mCsT q = nH Cs of ice = 2.09 J/gC Cs of liq water = 4.18 J/gC Cs of steam = 2.01 J/gC Hfus = 6.02 kJ/mol Hvap = 40.7 kJ/mol PV = nRT K = C + 273.15 R = 0.08206 L atm/mol-K 1 atm = 760 mmHg = 760 torr = 14.7 psi = 101.325 kPa PA = XA Ptotal AN = 6.022 x 1023 particles/mol

CHM151 Practice Test 6

Name: _____________________________

C. For the following homogeneous solutions, determine the strongest type of intermolecular forces of attraction involved between: 1. C6H14 and C4H10 molecules 2. Br2 and CCl4 molecules 3. KCl and H2O molecules 4. H3C-O-CH3 and CH3OH molecules 5. H3C-O-CH3 and CH3CN molecules D. Of each pair of molecules, which one has: 1. Higher boiling point? 2. Higher vapor pressure? 3. Lower melting point? CH3OH NH3 CH4 or or or CS2 PH3 C2H6

E. The graph below represents the heating curve for 20.0 g of H2O at 1 atm pressure.

105 (g) ? (a) (f) Temp (C) (d) ? (b) (c) -12.0 (e)

Useful information: q = mCsT q = nH Cs of ice = 2.09 J/gC Cs of liq water = 4.18 J/gC Cs of steam = 2.01 J/gC Hfus = 6.02 kJ/mol Hvap = 40.7 kJ/mol PV = nRT K = C + 273.15 R = 0.08206 L atm/mol-K 1 atm = 760 mmHg = 760 torr = 14.7 psi = 101.325 kPa PA = XA Ptotal AN = 6.022 x 1023 particles/mol

CHM151 Practice Test 6

Name: _____________________________

1. What does (a) represent? _________ 2. What does (b) represent? _________ 3. Identify the state/s of water at each labeled segment: Segment (c) ___________ Segment (d) ___________ Segment (e) ___________ Segment (f) ___________ Segment (g) ___________ 4. Calculate the total energy required to convert 20.0 g of ice at -12C to steam at 105C.

F. How much heat (in kilojoules) is released when 10.0 g of steam is cooled from 100C to 80C?

Useful information: q = mCsT q = nH Cs of ice = 2.09 J/gC Cs of liq water = 4.18 J/gC Cs of steam = 2.01 J/gC Hfus = 6.02 kJ/mol Hvap = 40.7 kJ/mol PV = nRT K = C + 273.15 R = 0.08206 L atm/mol-K 1 atm = 760 mmHg = 760 torr = 14.7 psi = 101.325 kPa PA = XA Ptotal AN = 6.022 x 1023 particles/mol

CHM151 Practice Test 6

Name: _____________________________

G. Consider the phase diagram (axes not to scale) of substance XYZ shown here and answer each of the following questions.

Pc

1 atm

0.3 atm

290 K 350 K

800 K

Tc

1. What is the normal melting point for XYZ? 2. What is the boiling point of XYZ at 1 atm? 3. What state/s is/are present at room temperature and normal atmospheric pressure? 4. What state/s is/are present at 900 K and 0.3atm?

H. Multiple Choice. 1. The volume of a gas is proportional to number of moles is known as a) Boyles Law b) Charless Law c) Avogadros Law d) Ideal Gas Law e) Daltons Law
Useful information: q = mCsT q = nH Cs of ice = 2.09 J/gC Cs of liq water = 4.18 J/gC Cs of steam = 2.01 J/gC Hfus = 6.02 kJ/mol Hvap = 40.7 kJ/mol PV = nRT K = C + 273.15 R = 0.08206 L atm/mol-K 1 atm = 760 mmHg = 760 torr = 14.7 psi = 101.325 kPa PA = XA Ptotal AN = 6.022 x 1023 particles/mol

CHM151 Practice Test 6

Name: _____________________________

2. What volume will a balloon occupy at 1.0 atm, if the balloon has a volume of 7.6 L at 3.8 atm? a) 35 L b) 5.0 L c) 17 L d) 29 L e) 2.0 L 3. To what temperature must a balloon, initially at 25C and 2.00 L, be heated in order to have a volume of 6.00 L? a) 993 K b) 75 K c) 403 K d) 894 K e) 655 K 4. What pressure (in atm) will 0.44 moles of CO2 exert in 2.6 L container at 25C? a) 4.7 atm b) 4.1 atm c) 3.6 atm d) 8.6 atm e) 0.35 atm 5. How many molecules of CO2 are contained in a 10.0 L tank at 7.53 atm and 485 K? a) 4.89 x 1024 molecules b) 1.89 x 1024 molecules c) 8.32 x 1024 molecules d) 3.63 x 1024 molecules e) 1.14 x 1024 molecules 6. A mixture of 0.220 moles CO, 0.350 moles H2 and 0.640 moles He has a total pressure of 2.95 atm. What is the pressure of CO? a) 1.54 atm b) 0.536 atm c) 0.649 atm d) 1.86 atm e) 0.955 atm 7. A gas mixture contains CO, Ar and H2. What is the total pressure of the mixture, if the mole fraction of H2 is 0.35 and the pressure of H2 is 0.58 atm? a) 0.20 atm b) 2.1 atm c) 0.60 atm d) 1.7 atm e) 0.49 atm 8. Determine the volume of O2 (at STP) formed when 50.0 g of KClO3 decomposes according to the following reaction. (MM of KClO3 = 122.55 g/mol) 2 KClO3 (s) a) 9.14 L b) 8.22 L

2 KCl (s) + 3 O2 (g) d) 13.7 L e) 14.6 L

c) 12.3 L

Useful information: q = mCsT q = nH Cs of ice = 2.09 J/gC Cs of liq water = 4.18 J/gC Cs of steam = 2.01 J/gC Hfus = 6.02 kJ/mol Hvap = 40.7 kJ/mol PV = nRT K = C + 273.15 R = 0.08206 L atm/mol-K 1 atm = 760 mmHg = 760 torr = 14.7 psi = 101.325 kPa PA = XA Ptotal AN = 6.022 x 1023 particles/mol