SWANA SCIENCE ACADEMY

Intermediate Part I
Test: Chemistry: Chapters 6,7,8 Time Allowed: 3:00 Hours Name: ____________________

Date: 29-03-10
Total Marks: 85 Roll No._______

INSTRUCTIONS Please write your Roll no. in space provided above. Overwriting, cutting, erasing, selecting more than 1 answer choices will result in score loss.

SECTION I

Q: 2. Each question has four possible answers. Choose correct & encircle it. (17) 1. As compared to single bonds, multiple bonds are (a) Weaker (b) Stronger (c) Longer (d) Polar 2. One Debye is equal to (a) 3.34 Cm (b) 3.34 x 10-10 Cm (c) 3.34 x 10-20 Cm (d) 3.34 x 10-30 Cm 3. SO3 molecule is (a) Tetrahedral (b) Triangular (c) Hexagular (d) Pentangular 4. The geometry of NH4+ ion is (a) Square planer (b) Tetrahedral (c) Trigonal planer (d) Pyramidal 5. Which of the following is a stronger acid (a) HF (b) HCl (c) HBr (d) HI 6. NH4Cl has (a) Covalent bond (b) Ionic Bond (c) Coordinate Bond (d) All these 7. The value of Kw depends upon (a) Amount of water (b) Temperature (c) Pressure (d) None 8. HCl has a very small pKa value, it indicates (a) Its Stronger acid (b) Its weaker acid (c) Its base (d) None 9. When a solid melts there is (a) Increase in enthalpy (b) Decrease in enthalpy (c) No change (d) All possible 10. For the state of matter H= E, the state is (a) Gas (b) Liquid (c) Solid (d) Both b & c 11. Conc. Of H2SO4 is 10-3 moles dm-3, its pH is (a) 3.0 (b) 2.7 (c) 2.0 (d) 1.5 12. Solubility of KClO3 salt in water is decreased by adding (a) NaClO3 (b) NaCl (c) KMnO4 (d) KCl 13. pH of 1 molar NaOH is (a) 7 (b) Zero (c) 14 (d) 10 14. Which of following solutions will have highest pH (a) 0.01M H2SO4 (b) 0.01M HCl (c) 0.01M NaOH (d) 0.01M NH4OH 15. pH of milk is (a) 7 (b) 7.5 (c) 4.0 (d) 6.5 16. Value of pOH of pure water at 250C is (a) 14 (b) 7 (c) 1x10-7 (d) 10-14 17. Number of bonds in C2H2 molecule is (a) 4 (b) 2 (c) 3 (d) 1

SECTION II
Q: 1. Attempt any EIGHT (08) questions from the following. 1. Differentiate between atomic orbital & molecular orbital 2. Why H-bonding is not regarded as true chemical compound
3. Differentiate between sigma & Pi bond

(22x2) =44
19. 20. 21. 22. 23. What is role of catalyst in reversible reactions Why water is called as weak electrolyte Explain term buffer capacity What is Lowry Bronsted concept of acid base Differentiate solubility & solubility product 24. Calculate pH of 10-4 moles dm-3 of Ba(OH)2 25. Calculate solubility of Ag2CrO4 whose Ksp value is 2.6x10-2 at 250C 26. How we can predict extent of reaction from its Kc value 27. Prove that pH+pOH=14 28. What is lattice energy. By which method it is determined? 29. Differentiate between internal energy & enthalpy 30. Draw & label figure of bomb Calorimeter 31. Why physical state of substances must be mentioned in thermo chemical equations 32. Calculate bond energy of H-Br while bond energies of H2 & Br2 are 43b & 193 Kj mol-1 33. Define enthalpy of neutralization

4.

SECTION III Attempt any THREE (03) from following questions

What is difference between heat and temp 5. Prove that qv= E 6. Define term solubility product 7. Define Kc & Kp. How these are related 8. State Le-chateliers principle 9. Define common ion effect with one example 10. How buffer solution can be prepared 11. Explain the term state function 12. What is Lewis theory of bonding (Octet-rule) 13. Why N2 molecule less reactive then O2 molecule 14. Why dipole moment is vector quantity 15. Why ionic reactions are fast & covalent reaction slow 16. How is % ionic character of polar bond determined 17. Why NaCl is soluble in water not in benzene 18. Differentiate between reversible & irreversible reaction

(8x3)=24

Q: 3. a) Write note on Born-Huber cycle b) Define (i) Enthalpy of atomization (ii) Bond order (4,2,2) Q: 4. a) How pH of buffer solution is calculated b) Explain Para magnetism of O2 by MOT (4,4) Q: 5 a) Define Orbital hybridization & explain shapes of H2C=CH2 & HC=CH (5,1.5,1.5) b) Define (i) Hesss Law (ii) Law of Mass Action Q: 6 a) Explain formation of and bond by VBT (b) What effect of change of pressure on gaseous (4,4)

equilibrium system Q: 7 a) Derive Kc & Kp expression for reversible reaction b) Give postulates of VSEPR theory. What is importance of this theory.

(4,4)