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1.

Principal quantum number specifies: a) the size of the orbital b) The shape of the orbital c) the way the orbital is oriented in space d)the spin of the electron that occupy an orbital 2. The maximum number of electrons that can fit into a 4d subshell is a) 4 b) 6 c) 10 d)18

3. Which of the following orbital cannot exist? a) 6S b) 3P c) 2d d) 4f 4. Which of the following neutral atom can have the largest number of unpaired electrons? a) Na b)Al c) SI d)N f)P 5. Which of the following atoms has the smallest radius a) Na b) Mg c) Al d)K f)Ca 6. Which of the following elements the largest electronegativity a) Na b)F c) Si d)N f)P 7. Which of the following molecules is planer a) SO3 b) SF4 c) CO2 d) H2O 8. Which of the following molecules are polar? a) PH3 b) CO2 c) CCl4 d) CS2 f) NH3 9. Which of the following molecules exist as resonance hybrid a) NO3 - b) NCl3 c) PCl5 d) CO2 10. In which of the following molecules central atom is in SP3d hybrid state a) SO3 b) SF4 c) CO2 d) H2O 11. Which of the following atoms has the largest radius a) K b)Ca c)Cl d)P 12. Which of the following ions has the smallest radius? a) N 3- b) F - c) Al3+ d) Mg 2+ 13. Which of the following molecules does not exist as resonance hybrid? a) SO3 b) SO2 c) CO3 2- d) CS2

14. The maximum number of electrons that can fit into a 4d orbital is a) 2 b) 4 c)6 d)14 15 The maximum number of electrons that can fit into a 4 level is a) 8 b) 18 c)24 d)32 16. Which of the following elements the smallest electronegativity a)K b) N c) O d)F 17. Which of the following is polar molecule? a) SO3 b) CO2 c) H2O d) CCl4 18. Which of the following molecules have tetrahedral shape? a) SF4 b) CCl4 c) NH3 d) BF3 19 Which of the following molecules have square pyramidal shape? a) SF6 b) IF5 c) TeCl4 d) CH4s 20. Which of the following molecules have polar covalent bonds? a) PH3 b)NaCl c) MgF2 d)NO2 21. Which of the following is colligative property of solution? a) density b)freezing point depression c)solubility d) mass 22. Which of the following is not colligative property of solution? a) freezing point depression b) vapor pressure depression c)osmosis d)density

23. Which of the following solution have the same colligative properties as 0.1M AlCl3 a) 0,1 M Na3PO4 b) 0.1M NaCl c) O.1M sugar d)0.1M NaNO3

24.Which of the following solution have the same colligative properties as 0.1M AlCl3 a) 0,2 M Na3PO4 b) 0.3M NaCl c) O.4M sugar d)0.4 M NaNO3

25. pH 0f 0.00005 M Ba(OH)2 is a) 12 b) 4 is c) 10 d)11 c) 10 d)11

26. pH 0f 0.00001 M HCl a) 5 b) 4

27. pOH 0f 0.00005 M Ba(OH)2 is a) 12 b) 4 c) 10 d)11

28. pH of HCl solution is equal to 5 . What is the [H+] concentration? a) 0.001 b) 0.0001 c)0.00001 d)0.000001

29. pH of NaOH solution is equal to 12 . What is the [OH-] concentration? a) 0.001 b) 0.01 c)0.00001 d)0.000001

30. Which of the following is only Bronsted-Lowry acid? a) NH3 b) OHc) HCO3d)H3O-

31. Which of the following is only Bronsted-Lowry base? a) NH3 b) NH2c) HCO3d)H3O-

32. Which of the following is only Lewis acid? a) BF3 b) OHc) HCO3d)NaOH

33. Which of the following is only Lewis acid? a) NH3 b) OHc) HCO3d)Al3+

34. Which of the following is not the hardness ion a) Mg 2+ b) Ca2 + c) Zn 2+

35. Which of the following is colorless and odorless gas a) CO b) O3 c) N2O3 d) NO2 36. Which of the following is colorless and odorless gas a) NH3 b) CH4 c) SO3 d) H2S 37. Which of the following is not odorless gas a) CO b) H2S c) N2O3 d) NO2 38. Which of the following is colorless gas a) Cl2 b) O3 c) N2O3 d) NO2 39. Which is the most abundant element in the earths crust a) Si b) O2 c) Al d) N2

40. Which of the following is not solid at room temperature? a) H2O2 b) Fe2O3 c) NH2OH d) CaO 41. Which of the following will react with water at room temperature? a) Mg b) Al c) Ga d) Na 42. which of the following reactions can be used for industrially receive carbon dioxide a) CH4 + O2 b) CaCO3 +HCl c) CaCO3 + heat d) C+ O2 43. Which of the following compound is able to express oxidative as well as reductive properties? a) H2S b) NO2 c) N2O5 d) NH3 44.Which of the following compound is able to express only reductive properties? a) H2S b) NO2 c) N2O5 d)SO2 45. which of the following reactions can be used for industrially receive H2 a) CH4 + H2O b) Na+ H2O c) Zn + HCl d) CaH2 + H2O 46. which one of the following elements has greater tendency to catenation a) O b) N c) S d) Cl 47. In which reaction Fe is used as a catalyst a) NO+ O2 b) N2 + O2 c) N2 + H2 d) NH3 + O2 48. The carbon monoxide is able to form covalent compound with a) Na b) Ba c) Cr d) Ca 49. Nitrogen has a reasonable oxidation number in all of following compounds and yet one of them is impossible. Which of them is impossible? a) NF3 b) NF5 c) NO2 d) NO3 - e) NO 50.Which of the following compound should not exist a) CH5 b) (NH4)3PO4 c) SF4 d) PH3 e) POCl3 51. Which of the following is polymeric phosphoric acid a) H3PO4 b) H3PO2 c) HPO3 d) H3PO3 52. Which of the following compound is desiccant? a) N2O5 b) P4O10 c) P4O6 d) N2O3

53. Which of the following compound is an effective water softener a) Na3P b) (NH4)3PO4 c) Na3PO4 d) PH3 e) POCl3 54.Which of the following is the correct equilibrium constant expression for the reaction Cl2 (g) + 3F2 (g) = 2ClF3(g) a) Kc =2[ClF3]/[Cl2]+[F2] b) Kc =2[ClF3]/[Cl2] 3[F2] c) b) Kc =[ClF3]2 /[Cl2] [F2]3 d) b) Kc =[ClF3]/[Cl2] [F2] 55. the following data were obtained for the reaction 2HI(g) =H2(g) + I2(g) trial 1 2 3. [HI] 1 10 -2 2 10 -2 3 10-2 Rate 4 10-6 8 10-6 3.6 10-5

The rate of the reaction is proportional to a) Rate = K [HI] 2 b) Rate = K [HI] c) Rate = K [HI] 3 d) Rate = K [HI] 4 56. Given the reaction PCl3 + Cl2 = PCl5 H=-21 Kcal

Which of the following increases the equilibrium concentration of PCl5 a) decreasing the concentration of PCl5 b) increasing the concentration of Cl2 c) increasing the temperature d) decreasing the volume of the reaction container 57. which of the following reaction will be faster a)H2 + Cl2 = 2HCl b)Sr 2+ + SO42- =SrSO4 c) CH4 + 2O2 = CO2 + 2 H2O d) CH4 + Cl2 = CH3Cl + HCl 58. Which of the following reaction will be faster? a)N2 +3H2=2 NH3 b)2H2+O2=2H2O

c)H+ + OH- =H2O d)C3H8 + 5O2 = 3CO2+4H2O 59. Which of the equilibrium constant expression of given reaction isnt correct a) CuO (s) + 2HCl (g) = CuCl2(s)+H2O (g) Kc = [H2O] / [HCl]2 b). SrO(s)+SO3(g)= SrSO4(s) Kc = 1/ [SO3] c)H2(g) +Cl2(g)=2HCl(g) Kc = [HCl ]/ [H2] [Cl2] d)H2(g) +S(s)=H2S(g) Kc = [H2S]/[H2][S] 60. In which of the following reaction the rate of reaction can be determined by measuring the decrease in pressure in time interval a) H2+Cl2=2HCl b) C3H8 + 5O2 = 3CO2+4H2O(g) c) CaO(s)+CO2 =CaCO3(s) d) H2(g) +S(s)=H2S(g) 61. The rate of reaction slows down with time at constant temperature because a)the energy of activation increases b)the catalyst is used up c)the concentration of reactants decreases d) the energy of activation decreases 62 The following data were obtained for the reaction A+B+2C=D+2F A B 0.02 C rate

0.2 0.1 3.6 10-4

0.01 0.01 0.01

0.4 0.1 1.8 10-4 0.2 0.2 7.2 10-4 0.2 0.1 1.8 10-4

a)rate=K(A)(C)2 b)rate=K(A)(C) c)rate=K(A)(B) d)rate=K(A)2(B)(C)2 f)rate=K(A)(B)(C)2 Which of them is correct? 63. The value of K- the rate constant, may be increased A. increasing the concentration of reactants B. increasing the pressure C. increasing the energy of activation D. increasing the temperature 64. The mechanism of reaction is given as following: AB+J=DE+F DE+G=K+C L+F=M+J

Which of the species involved in the mechanism is a catalyst a)DE b)J c)G d)L f)C 65.Given the reaction: P+N = 2C Doubling the concentration of N doesnt change the rate but doubling the concentration of P doubles the rate of the reaction. The equation is a) rate =K [N] b)rate = K[P] [N]2 c). rate = K[P] 2 d). rate = K[P]

66.Which statement is incorrect about a catalyst? A. It lowers the energy of activation B. It change the reaction mechanism C. It increases the yield of reaction D. It decreases the number of molecules with necessary energy to react 67.The following date were obtained for the reaction X+ Y = Z trial 1 2. 3. X 0,3 0,3 0,6 Y 0,2 0,4 0,4 rate of reaction 0,06 0,12 0,24

the rate of the reaction is proportional to A. rate = [X] [Y] B. rate = [Y] C. rate= [X]2 [Y] D. rate = [Y]2 E. rate=[X] [Y]2

68. Given the reaction 2NO+O2=2NO2 H= -21.6 Kcal Which of the following increases the equilibrium concentration of NO? a). increasing temperature b). Addition of O2 c)removal of NO2 d). increasing pressure

69. Which of the following procedures lead to a change in the value of the equilibrium constant of a chemical reaction? a) A change in concentration of product and reactants b) A change in the temperature c) A change in the pressure d) Replacement of the catalyst

70. Assuming equilibrium reaction 2CO (g) + O2 (g) = 2 CO2 (g) H=-135,2 Kcal. A greater equilibrium yield of carbon dioxide will best be obtained by A. raising the temperature and lowering the pressure B. lowering the temperature and pressure C. adding the catalyst and lower the pressure D. lowering the temperature and raising the pressure 71. Which of the following is not a thermodynamic state function? a) Internal energy b)Entropy c)Work d) Enthalpy 72. Which of the following is a thermodynamic state function? a) Internal energy b)Heat c)Free energy d)Entropy 73. Which of the following is not an extensive parameter of thermodynamic system state? a) concentration b)volume c) mass d)pressure

74 Which of the following is not an extensive parameter of thermodynamic system state? a) mass b)volume c) Temperature d)concentration 75. Which of the following is constant when a process is isochoric a) temperature b)volume c) pressure and volume d)pressure e) temperature and pressure 76 Which of the following is constant when a process is isobaric a) temperature b)volume c) pressure and volume d)pressure e) temperature and pressure 77. Which of the following is constant when a process is isothermal a) temperature b)volume c) pressure and volume d)pressure e) temperature and pressure 78. the free energy change a) is increased when the reaction in egzergonic b)will indicate the rate and direction of the reaction c)is equal to zero at equilibrium state d)is constant at equilibrium state 79. Which of the following statement s are incorrect? a)Entropy is a measure of a system randomness b) a system is in an equilibrium state when the entropy changes in the system c) The entropy of the system remains constant in the stationary state d) The entropy of any pure substance at absolute zero is equal to zero 80. Which of the following change will produce an increase in the entropy of the system? a) an increase in T b) an increase in V c)formation of gaseous product from solid reactants d) formation of a precipitate in liquid solution 81.In stationary state a) the production of entropy system always tends to minimum b)S=0 c)G=0 d) G=H 82. Which of the following statement s are incorrect? a)In spontaneous process entropy of the system is always decreases b) In equilibrium state S=O

c) .In stationary state G=0 d) the reaction will go in needed direction if G<0 83. Which of the following has highest entropy a) NaCl b)H2O c)CO2 d)H2SO4 84. Which of the following has highest entropy a) SO2 b)H2O2 c) LiCl d) CaO 85. Which of the following has lowest entropy a)CH4 b)CH3COONa c) CH3CH2OH d)C2H4 86. Which of the following has highest entropy a) H2O2 b)CH3COONa c) CH3CH2OH d)C2H4 87. Which metal reacts with nitrogen at room temperature? a)Mg b)Na c)Li d)K e) Be 88. Which salt impart red color to a flame? a)SrCl2 b)CaCl2 c)LiF d) KCl e) BaCl2 89. Which salt impart yellow color to a flame? a)SrCl2 b)CaCl2 c)LiF d) KCl e) BaCl2 90. Which salt impart yellowish-green color to a flame? a)SrCl2 b)CaCl2 c)LiF d) KCl e) BaCl2 91.Which of the following phisical properties of a system are state functions? a.) temperature b,) enternal energy c,) enthalpy . d). pressure c,) volume f.) heat g. work

92. Which of the following changes are endothermic? a.) water boiling b). ice forming c.) water evaporating d,) snow melting e,) water condensing 93. Which of the following statement is correct? a) the second low of thermodynamics determines the direction of the process b) In isolated system the entropy always decreases for the spontaneous process

c) Processes that take place without any change in entropy are irreversible d)T S is change of the part of internal energy , that can make the work

94. Which of the following is not correct? a) G = H +T S b) E = Q- p V c) Q- T S = 0 d) E+ p V- T S = 0

95) Which of the following statement is not correct? a) Entropy is the measurement of the system randomness b) The free energy change of a system is equal to zero at equilibrium during constant P and T c) The entropy of any object will be the equal to zero at room temperature d) The reactions that take place with decrease of a free energy of system are called the egzergonic reaction 96)Which of the following orbitals cannot exist a)2S b)3f c)3P d)4d 97 Which of the following atoms has the largest covalent radius a) Na b)Mg c) Al d)Cl 98. Which of the following elements has the largest electronegativity a)N b)K c) O d) B 99 Which of the following is the nonpolar covalent bond a) C-F b)S-C c)C-N d) B-F 100. Which of the following is legitimate set of n, l, m, and s quantum numbers a) 0, 0, 0, b) 8, 4, -3, - c) 3.3, 2, d) 2, 1. -2, - e) 5, 3, 3, -1

101. The maximum number of electrons in the n=3 shell is

a) 18 b) 32 c)8 d) 48 102. which of the following orders of increasing energies is incorrect? a) 3s< 4s< 5s b) 5s< 5p< 5d c) 5s< 4d< 5p d) 6 s< 4f< 5d e) 6s< 5f< 6p 103. Which pair of quantum numbers determines the energy of an electron in an orbital a) n and l b) n and m c) n and s d) l and m 104) Which of the following ions has five unpaired electrons? a) Ti +4 b) Co+ 3 c) V+3 d) Fe+3 c) Zn+2 105. As atomic orbital are filled according to Aufbaw principle the 6p orbital are filled after which of the following orbital a) 4f b) 4d c) 6s d) 7s 106. Which of the following elements should have the largest ionization energy a) Na b) Mg c) Al d) Si c) P 107. Which of the following atoms has the largest covalent radius a) N b) O c) F d) P e) S

108. Which of the following ions has the electron configuration [ Ar] 3d4 a) Ca +2 b) Ti+2 c) Cr+2 d) Mn+2 e) Fe+2

109.Which of the following ions has the smallest radius a) K+ b) Li + c) Be+2 d) O-2 e) F-

110) Which of the following isoelectronic ions is the lagest a) Ca+2 b) P-3 c) S-2 d) K+

111. Which of the following does not contain a double bond a) N2 b) CO2 c) C2H4 d) NO2 e)SO-3

112. Which of the following molecules are planar a) SO3 b) SO -3 c) NO-3 d) PF3 e) TeF4

113. Which of the following molecules exist as resonance hybrids a) HCO2- b) PH3 c) SO4-2 d) SF4

114 Which of the following elements would form a linear compounds with the formula XO2 a) Li b) Be c) C d) F

115. Which element forms a compound with the following Lewis structure

C- X= O

a) Be b) B c) C d) N e) O f)F

116) Which element forms an ion with the formula XF6 -2 that has no lone pair electrons in the valence shell of the central atom a) Ca b) C c) Si d) S e) P

117. Which of the following molecule is polar a) PCl5 b) CO2 c) SCl4 d) PH3

118. In which of the following the central atom has SP3 hybrid orbitals a) PCl5 b) H2O c) SF2 d) NO3-

119. the shape of SF4 is a) Linear d) planar c) tetrahedral d) distorted tetrahedral

120. Which of the following molecules are arrenius bases

a) NaOH b) FeO c) Ca(OH) d) H2O e) NH3

121) Which of the following molecules can act as both a Bronsted acid and base? a) NaHCO3 b) Na2CO3 c) H2CO3 d) CO2 e) H2O

122) Which of the following compound cannot be Bronsted bases? a) H3O+ b) MnO4- c) BH4- d) CN- e) S-2

123 Which of the following is not a conjugate acid- base pair a) NH4+/NH3 b) H2O /OH- c) H3O+/ OH- d) CH4/CH3-

124) Which of the following ions is the conjugate base of a strong acid a) OH- b) HSO4- c)NH2- d) S2- e) H3O+

125) Which of the following is the strongest Bronsted base a) NH2 - b) PH2 - c) CH3 - d) SiH3 -

126) Which of the following solutions is the most acidic a) pH-2.9 b) pH- 4.1 c) pH-8.4 d) pH 11.2

127) pH of 0. 0005 M Ba(OH)2 solution is a) 12 b) 10 c) 3 d) 9

128) Which of the following compound would be the most soluble in nonpolar solvent such as CCl4 a) H2O b) CH3OH c) CH3(CH2)2OH d) CH3(CH2)4OH

129) Which of the following compound would give the largest freezing point depression when 100g are dissolved in 1Kg of water? a) NaCl b) NH4NO3 c) (NH4)2SO4

130) Which of the following mixtures would make the best buffer a) HCl and NaCl b) NH4OH and NH4Cl c) NH4Cl and CH3COOH d) Na OAc and NH3 131, Which of the following is the hardness ion a) Mg 2+ b) Na+ c) Ba 2+ d) Zn 2+ 132. Which of the following is colorless and odorless gas a) CO2 b) O3 c) N2O3 d) NO2 133. which is the most abundant element in the earths crust a) Si b) O2 c) Al d) N2 134. Which of the following is not solid at room temperature? a) H3PO4 b) Fe2O3 c) NH2OH d) NH3 135. Which of the following will react with oxygen at room temperature? a) Mg b) Al c) Ga d) Li 136) which of the following reactions can be used for industrially receive carbon dioxide a) CH4 + O2 b) CaCO3 +HCl c) CaCO3 + heat d) C+ O2 137) Which of the following are able to express oxidative as well as reductive properties a) HCl b) HClO c) HClO2 d) HClO4 138) which of the following reactions can be used for industrially receive CO a) CH4 + H2O b) HCHO+ H2SO4 c) C+O2 d) CaC2 + H2O 139) which one of the following elements has the greatest tendency to catenation a) C b) N c) S d) Se 140. In which reaction is used Pt as catalyst a) NO+ O2 b) N2 + O2 c) N2 + H2 d) NH3 + O2 141.The following data were obtained for the reaction X+Y+2Z=K+2L

rate

0.02 0.2 0.1 3.6 10-4

0.01 0.4 0.1 1.8 10-4 0.01 0.2 0.2 7.2 10-4 0.01 0.2 0.1 1.8 10-4 A. B. C. D. E. rate=K(x)(z)2 rate=K(x)(z) rate=K(x)(y) rate=K(x)2(y)(z)2 rate=K(x)(y)(z)2

Which of them is correct? 142.The following date were obtained for the reaction X+ Y = Z

trial 1 2. 3.

X 0,2 0,2 0,4

Y 0,2 0,4 0,4

rate of reaction 0,06 0,24 0,24

the rate of the reaction is proportional to A. rate = [X] [Y] B. rate = [Y] C. rate= [X]2 [Y] D. rate = [Y]2 E. rate=[X] [Y]2

143.Which of the following has general formula CnH2n+2 O2?

a)Dihydric alcohols

b)ether c) aldehyde d) ester

144. Which of the following is secondary alcohol? a) 2, methyl 1 butanol b) 2 methyl 2 butanol c) 2 butanol d) 1 butanol

3. Which of the following compound is gas at room temperature? a) methanol b) ethane c)hexane d)acetaldehyde 145. The compound X is with formula C3H6O gives on oxidation the compound with formula C3H6O2. X is most likely to be a) an aldehyde b) a ketone c) a tertiary alcohol d) a secondary alcohol e) an ether 146. Which of the following compound will react with CH3OH? a) CH3CHO b) CH3OCH3 c) NaOH d) CH3ONa 147. Which of the following compound is polyhydric alcohol? a) 1,2,3 ethantriol b) 2 ethanol c) butanal d) 2. Methoxy propane 148. Which of the following compound will react with HCl? a) Aniline b) diethylether c) 2 butanon d) butanal 149 Which of the following compound is tertiary amine? a) (CH3)2NH b) CH3CH2NH2 c) (CH3)3N d) HCN 150. Which of the following reaction is possible? a)CH3OH +NaOH b) CH3CHO +HCl c) (CH3)2CH-OH +HCl d) (CH3)3C-OH +[O] 151. The following data given for alcohols : I. a Aldehyde formed when it oxidized in the present of suitable catalyst. II. 0.5 mol of H2 is liberated when 1. Mol alcohol is react with Na. Which one of the following is this alcohol a) 1.2 butanediol b) 2 butanol c) 2methyl 2 butanol d) 1. Butanol e) 1.3 butanediol 152Which of the following has general formula CnH2n O? a)Dihydric alcohols b)ether c) aldehyde d) ester 153. Which of the following is tertiary alcohol? butanol c) 2 butanol d) 1 butano a) 2, methyl 1 butanol b) 2 methyl 2

154. Which of the following compound is gas at room temperature?

a) methanol b) formaldehyde c)hexane d)acetaldehyde 155. the compound X is with formula C3H8O gives on oxidation the compound with formula C3H8O. X is most likely to be a) an aldehyde b) a ketone c) a tertiary alcohol d) a secondary alcohol e) an ether 156 Which of the following compound will react with CH3OH? a) CH3CHO b) CH3OCH3 c) CH3CH2OH d) CH3ONa 167. Which of the following compound is polyhydric alcohol? a) 1,2 ethandiol b) 2 ethanol c) butanal d) 2. Methoxy propane 158. Which of the following compound will react with HCl? a) methylamine b) diethylether c) 2 butanon d) butanal 159. Which of the following compound is secondary amin? a) (CH3)2NH b) CH3CH2NH2 c) (CH3)3N d) HCN 160. Which of the following reaction is not possible? a)CH3OH +Na b) CH3CHO +H2 c) (CH3)2CH-OH +HCl d) (CH3)3C-OH +[O] 161. The following data given for alcohols : I. a keton formed when it oxidized in the present of suitable catalyst. II. 0.5 mol of H2 is liberated when 1. Mol alcohol is react with Na. Which one of the following is this alcohol a) 1.2 butanediol b) 2 butanol c) 2methyl 1 butanol d) 1. Butanol e) 1.3 butanediol
162. The distance between carbon-carbon atoms in Alkenes is equal to a) 0.120 b) 0.130 c) 0.134 d) 0,140 162. The distance between carbon-carbon atoms in Alkanes is equal to a) 0.120 b) 0.130 c) 0.134 d) 0,140 163. Which of the following compounds will react with HCl a). CH2=CH-CH3 b). CH3-CH2- CH2-CH3 c)CH3- CH3 d). CCl4

164. Which of the following equation is correct a) CH4+Cl2 - CH3Cl +HCl b) CH3-CH=CH2 + HBr--- CH3-CH2-CH2Br

d) HCHO + Na->CH3ONa

e). CCl4+ O2----CO2 + Cl2O7

165.Which of the following compounds are isomers 1) 3-methyl-1 butene 2) 2,3 dimethyl butane 3) cyclopentane 4) 2,2 dimethylpentane

166 Which of the following has general formula CnH2n-2 1) Alkene 2) Alkadiene 3) cycloalkane 4) Alkyne

167. Which of the following is isopropyl radical a) CH3- CH2- CH2- b) CH3-CH- CH3 c) CH3-C- CH3 d) CH3-CH-CH2

168 When a 3 liter mixture containing equal moles of ethane ethane and ethyne is burned . How many many liters of CO2 is produced a) 2 b) 3 c) 4 d) 6 c) 9

169 Which of the following Alkenes has cis- trance isomers 1) 1- butane 2) 2,2 dimethyl butane 3) 2-methyl-1 butene 4) 2- butane

170. Which of the following compounds will react with H2O 1) 2-methyl-1 butene 2) 1- propyne 3) 2-pentene 4) cyclobutane

171 CH2=CH-CH3 + HBr----X1 +Na------X2 a) propane b)propyne c) hexane

X2 is:

d) 2,3 dimethylbutane

172. Which of the following compounds does not have the same moleculer formuler as others a) cyclopetene b) 1- pentene c) methylcyclobutane d) 1,1- dimethylcyclopropane e) pentane 173. Which of the following have cis- trance isomers

a) FClC=CFCl b) CHCl3 c) F2C=CF2 d) Cl2=CHCH3 e) H2C=CHF

174 Which of the following is the product of the reaction between chlorine and ethylene a) CH3-CHCl2 b) CH3-CH2Cl c) ClCH2- CH2Cl d) Cl2CH=CHCl2

175 Which of the following does not rapidly react with Br2 dissolved in CCl4 a) pentane b) 1- pentene c) 1- pentyne d) 2- pentene e) 2- pentyne 176 Which of the following is the product of the reaction between water and ethyne a) CH3CH2OH b) CH2=CH2 c) CH3C=O d) CH3C=O 177. Which of the following is five member ring heterocyclic compound with two hetero atoms? a) pyran b) furan c)imidasole d)pyridine 178. Which of the following is five member ring heterocyclic compound with one hetero atoms? a) pyran b) indole c)imidasole d)pyridine 179 Hydrolysis of maltose will yield a) glucose only b) galactose+glucose d) manose+glucose e) fructose+galactose 180. d galactose and d glucose are a) enantiomaers b) anomers c)epimers 181. Which of the following is not a polysaccharide? a) starch b) lactose c) cellulose d) clycogen 182. Which of the following statements is not correct regarding the predominant form d galactose a)It is hemiacetal b)It is a reducing sugar c)It is a C-4 epimer of glucose d)It contains five asymmetric carbon atom 183. Which of the following statements is correct for fructose a) is a reducing sugar b) is hemiacetal c) is optically active d)is aldose

184Which of the following carbohydrate is sweeter than sucrose? a)glucose b) fructose c)maltose d)none of above 185. Dextran is a) a long chain polymer of sucrose b) used as a substituent for plasma in cases of blood loss c) a long chain polymer of fructose 186. Which of the following substances will not react with Ag2O a) fructose b) formic acid c) glucose d)formaldehyde 187Which of the following is not a dicarboxylic acid a)succinic acid b) oxalic acid c) malonic acid 4)citric acid 188. Which one of the following is dihydroxyacetone CH3-CH(OH)-CO-CH2OH b)HOCH2-CO-CH2OH c) HOCH2-CH2-CO-COOH d)HOCH2CH2-CO-CH2OH 189 How many structural isomers corresponds to butene a)1 b) 2 c) 3 d) 4 190. Which of the following is chiral a) CH3-CHCl-CH3 b) CH3-CH(NH2)-CH2CH3 c) HOCH2-CO-CH2OH d) HOCH2-CH2-CO-CH2OH 191. Which of the following is gas at room temperature 1. haxane 2. methanal 3) acetic acid 4) butandiol 192. Which of the following substance is hemyacetal a) b)

a)

d)

193. Which of the following has Z configuration a) b)

c)

d)

194. Which of the following has the carbon atom in both Sp3 hybrid and Sp2 hybrid state a) ethene b) toluene c) propane d) 1.3butadiene

195. Which is the number of possible isomers for the compound C3H5Br a)1 b) 2 c) 3 d) 4 e) 5 196 Which of the following is the dihydroxydicarboxylic acid a)succinic acid b)tartaric acid c) malonic acid d)lactic acid 197. What would you expect to receive while acting by sodium hydroxide on

198 Which of the following compound will not react with H2O a) ethylamine b) aniline c) benzene 4) ethyne 199 The distance between C-C atoms is aromatic compound is equal to a) 0.120 b) 0.130 c) 0.134 d) 0.140 200. Which of the substance given below provides disodium derivatives under the action of NaOH solution a) CH3-CH2-COOH b) HOCH2CH2COOH c) HO-C6H4-COOH d)HOCH2CH2OH

201 Which pairs of the compounds given bellow are not diastereomers

202. Which of the following is thiol a) CH3-S- CH3 b) CH3-CH(SH)-CH3 c) CH3-CH(NH2)-CH2-CH3 d)H2S 203 Which of the following substituent has lowest priority a) CH2OH b) -CH2-NH2 c) CH2-CH3 d) -CH-C(CH3)3 204 Which of the following is acetosalicilic acid

205. Which of the following statement is not correct about TNT a) Its explosive b) it contains two methyl groups c) NO2 group is in meta positin d) it contains OH and methyl groups 206 Which of the following is not a tricarboxylic acid a)succinic acid b) oxalic acid c) malonic acid 4)citric acid 207 Which one of the following is dihydroxyacetone

a) CH3-CH(OH)-CO-CH2OH b)HOCH2-CO-CH2OH c) HOCH2-CH2-CO-COOH d)HOCH2-CH2-CO-CH2OH 208 How many structural isomers corresponds to pentane a)1 b) 2 c) 3 d) 4 209. Which of the following is not chiral a) CH3-CHCl-CH2-CH3 b) CH3-CH(NH2)-CH2OH c) HOCH2-CH(OH)-Cl d) HOCH2-CHBr--CH2OH 210. Which of the following substance is hemyacetal a) b)

b)

d)

211. Which of the following has Z configuration a) b)

c)

d)

212. Which of the following has the carbon atom only in Sp2 hybrid state a) ethane b) benzene c) propanal d) butanol 213Which of the following is not a hydroxydicarboxylic acid a)succinic acid b) oxalic acid c) malonic acid d)lactic acid 214. What would you expect to receive while acting by sodium hydroxide on HO-C6H4-COOH a) HO-C6H4-COOH b) Na-C6H4-COOH c) Na-C6H4-COONa 215. Which of the following compound will react with hydrogen chloride a) ethylamine b) aniline c) benzene 4) ethyne 216. The distance between C-C atoms is aromatic compound is equal to a) 0.120 b) 0.130 c) 0.134 d) 0.140 217. Which of the substance given below provides disodium derivatives under the action of NaOH solution a) CH3-CH2-COOH b) HOCH2CH2COOH c)HOOC-C6H4-OH d)HOCH2-C6H4-CH2OH

218. Which pairs of the compounds given bellow are not diastereomers

219. Which of the following substituent has highest priority a) CH2COOH b) -CH2CHO c) CH2CH3 d) CH2C(CH3)3 220. Which of the following is hydroquinone

221 Which of the following statement is correct about xylene a) Its explosive b) it has two methyl groups c) NO2 group is in meta positions d) it contains OH group 222. Which definition is wrong a) Most carboxylic acids exist as cyclic dimmers b) Carboxylic acids are slightly dissociated in aqueous solution c) acetic acid is much more stronger than nitric acid d) Carboxylic acids are much more stronger than alcohols 223. Which of the following acid is stronger a) CH2Cl-COOH b)CH2F-COOH c) CH2Cl-CH2-COOH d)CH3COOH 224. Which of the following substituent has highest priority a) CH2COOH b) CH2CHO c)-CH2-CH2Cl d)-CH2CH(NH2)

225Which of the following compounds has the R absolute configuration

226. How many stereoisomers are possible HOCH2-CO-CHOH-CHOH-CHOH-CH2OH a) 9 b)4 c)6 d)8 e) none of above 227. Which of the following is the lactic acid a) CH3-CH(OH)-COOH b)CH3-CH2-COOH c)HOOC-COOH d)HOOC-CH2-COOH 228. Which of the following compound is ester a)CH3-CH2-O-CH3 b)CH3COOCH3 c)CH3OH d)CH3CHO 229. Saponification reaction is characteristic for

a) ethers b) aldehydes c) carbocsilic acids d)fats 230 Which of the following substances will react with Ag2O a) ethane b)formic acid c) methanol d) citric acid 231. oxidation of which compound will give benzoic acid a) benzene b) phenol c)aniline d) toluene 232Which of this acids also have aldehyde properties a) malic acid b) propanoic acid c)formic acid d) benzoic acid 233. Which of the followinghas cis trans isomers a)2,3 dimethyl -2 butene b) 3,4 dimethyl 3-hexene c) 1.butene d) 2 methyl 2 pentene 224 Which of the following will deduce Cu2O at high t? a) aniline b)formaldehyde c) acetic acid d) ethanol 225. In the production of hexane by Wurts reaction butane and octane are produced as by products Which alkyl chlorides do you expect to be used a) CH3CH2Cl+CH3CH2CH2CH2Cl b)CH3Cl+CH3(CH2)2Cl c) 2CH3(CH2)2Cl d) 2C2H5Cl 226 Which of the following is the same for two structuerl isomers a) molecular formula b) physical properties c)chemical properties d) molecular weight 227 Which of the following is cleaning agent a)Waxes b) detergents c)steroids d) prostaglandins 228 Which of the following compound liberates the same amount of hydrogen when reacted with eater one of Zinc and sodium metal a)CH3CH2OH b) HOOC-CH2OH c)HOOC-COOH d) CH3CHO 229 Which of the following statements is not correct about cholesterol? Cholesterol is a) a secondary alcohol b)an unsaturated alcohol c) a cyclic alcohol d) a.polyhydric alcohol 230 Which of the following forms a ketone when oxidized a) 2-butanol b)1-butanol c) 2methyl 2 butanol d) 2methyl 1 butanol 231 Which of the following statements is not correct about fructose? a)Is optically active b) is hemiacetal c) is redusing sugar d) is pentose 232. Which of the following statements is not correct about ketone a) contains carboxylic group b) is oxidation product of secondary alcohol c)is reducing agent d)reacts with carboxylic acids 233. Which of the following statements is not correct about glycogen a) is polymer of fructose b)is an unbranched molecule c)There are 1,4 1nd 1,6 linkages d) Iodine test gives blue color 234.When monohydric alcohol and organic acid which have equal MW reacts an ester with molecular weight of 102g is obtained. What is the formula of alcohol a)CH3OH b)C3H5OH c) C3H7OH d)CH3CH2OH 235 Which of the following is obtained from the acid catalyzed hydrolysis of sucrose? a)glucose +fructose b)mannose c) galactose d) Glucose+ mannose 236. Which of the following compound is formed if one of the isomer of ethylacetate is redused by one step

a) ethanol b) propanol c) butanol d) pentanol 237. The oxidation of 6-6 atom of glucose yields a) sorbitol b) mannitol c) glucinic acid d) sacharic acid e) glucoronic acid 238. What is the name of compound given bellow? HO-CH2-CH2 NH2 a) ethanolamine b) cephalin c) choline d) serine 239 What is the name of compound given bellow? HOCH2-CH2N(CH3)3 a) ethanolamine b) cephalin c) choline d) serine .240. What is the name of compound given bellow? HO-CH2-CH(NH2)-COOH a) ethanolamine b) cephalin c) choline d) serine 241Which of the following statements is correct about sphingosine? a) is unsaturated alcohol b)contains 6 carbon atom c) contains two amino group d) is saturated alcohol 242. Which of the following statements is not correct? a) Rancidity is due to tipe s of reaction hydrolysis and oxidation b) Soaps are produced by saponification of fats c) Cephalins are good emulsifying agents d) Lecithins are good emulsifying agents 243. Which of the following is phospholipid? a) cholesterol b) Lecithin c) inositol d) prostaglandin 243. Which of the following is phosphosphingosides? a) cholesterol b) Lecithin c) inositol d) spingomyeline 244. Which of the following is glycolipid? a) cholesterol b) cerebron c) inositol d) prostaglandin 245. Which of the following compound is polysaccharide? a)starch b) lactose c) glucose d) proline 246 Which of the following compound is monosaccharide? a)starch b) lactose c) glucose d) proline 247. 246 Which of the following compound is monosaccharide? a)starch b) lactose c) glucose d) proline 248Which of the following compound is steroid? a)projesterone b) lactose c) glucose d) proline 249 Which of the following compound is phospholipide? a)fat b) oil c) cephaline d) proline 250. Which carbohydrate is sweeter than sucrose? a)starch b) lactose c) glucose d) fructose 251. Common name of 1,2-dimethyl benzene is

a)toluene b) 0-xylene c)p-xylene d) o-crezole 252 Common name of 1,4-dimethyl benzene is a)toluene b) 0-xylene c)p-xylene d) o-crezole 253. Common name of methyl benzene is a)toluene b) 0-xylene c)p-xylene d) o-crezole 254. Pyrrol undergoes electrophilic aromatic substitution predominantly at the position a) 1 b) 2and5 c)3 and4 255 Which of the following statements is not correct about indole? a) is solid at room temperature b)has intence fecal odor c) indole structure can be found in amino acid tryptophane d) it contains 2 N atoms in the five member ring 256.A useful synthetic intermediate is produced via a Mannich reaction of indole with a)CH3NH2 and HCHO b) (CH3)2NH and HCHO c)CH3CHO and CH3CH2NH2 d)(CH3)3N and HCHO 257. 255 Which of the following statements is not correct about pyridine? a) is solid at room temperature b)it is structurally related to benzene c) undergoes protonation d)pyridine behaves as primary amine 258Which of the following is not aromatic compound a)pyrrol b) imidazole c)tetrahydrofuran d)pyrimidine 258Which of the following is not bicyclic aromatic compound a)purine b) naphtalinec)Indole d)pyrimidine 259. substituted Indole is not structural element of a) serotonine b) tryptophan c) indometacin d)aspirine 260. Which of the following compound is not alkaloid a)caffeine b) epinephrine c)phenantrane d) dopamine 261. Anomers are a)Diatsereomers of each other b) structural isomers c) cis- trans isomers d)enantiomers 262.Galactose is a) 4- epimer of glucose b)3 epimer of glucose c) 2- epimer of glucose d) 3- epimer of galactose

1. Secondary quantum number specifies: a) the size of the orbital b) The shape of the orbital c) the way the orbital is oriented in space d)the spin of the electron that occupy an orbital

2. The maximum number of electrons that can fit into a 4p subshell is a) 4 b) 6 c) 10 d)18

3. Which of the following orbital cannot exist? a) 6S b) 3P c) 5d d) 2f 4. Which of the following neutral atom can have the largest number of unpaired electrons? a) B b)S c) Si d)N f)P 5. Which of the following atoms has the smallest radius a) N b) Mg c) Al d)O f)C 6. Which of the following elements the largest electronegativity a) Na b)Li c) Si d)N f)P 7. Which of the following molecules is planer a) SO2 b) SF4 c) BF3 d) H2O 8. Which of the following molecules are polar?

a) PCL5 b) CO2 c) CCl4 d) SF4 9. Which of the following molecules exist as resonance hybrid a) H2O b) SO3 c) PCl5 d) CO2 10. In which of the following molecules central atom is in SP3d hybrid state a) SO3 b) SF2 c) CO2 d) PCl5 11. Which of the following atoms has the smallest radius a) Li b)Ca c)Cl d)P 12. Which of the following ions has the largest radius? a) N 3- b) F - c) Al3+ d) Mg 2+ 13. Which of the following molecules does not exist as resonance hybrid? a) CF4 b) SO2 c) CO3 2- d) O3 14. The maximum number of electrons that can fit into a 4f orbital is a) 2 b) 4 c)6 d)14 15 The maximum number of electrons that can fit into a 3 level is a) 32 b) 18 c)24 d)8 16. Which of the following elements the smallest electronegativity a)B b) N c) O d)F 17. Which of the following is polar molecule? a) PH3 b) NH3 c) NCl3 d) CCl4 18. Which of the following molecules have tetrahedral shape? a) CF4 b) SCl4 c) NH3 d) BF3 19 Which of the following molecules have octahedral shape? a) SF6 b) IF5 c) TeCl4 d) CH4 20. Which of the following molecules have polar covalent bonds? a) SO2 b)NaCl c) MgF2 d)NCl3 21. Which of the following is colligative property of solution?

a) density b)boiling point elevation c)solubility d) mass 22. Which of the following is not colligative property of solution? a) density b) vapor pressure depression c)osmosis d) boiling point elevation

23. Which of the following solution have the same colligative properties as 0.2M glucose a) 0,1 M Na3PO4 b) 0.1M NaCl c) O.1M sugar d)0.1M NaNO3

24.Which of the following solution have the same colligative properties as 0.8M fructose a) 0,2 M Na3PO4 b) 0.3M NaCl c) O.4M sugar d)0.4 M NaNO3

25. pH 0f 0.0005 M Ba(OH)2 is a) 12 b) 4 is c) 10 d)11 c) 10 d)11

26. pH 0f 0.0001 M HCl a) 5 b) 4

27. pOH 0f 0.0005 M Ba(OH)2 is a) 12 b) 4 c) 3 d)11

28. pH of HCl solution is equal to 4 . What is the [H+] concentration? a) 0.001 b) 0.0001 c)0.00001 d)0.000001

29. pH of NaOH solution is equal to 11 . What is the [OH-] concentration? a) 0.001 b) 0.01 c)0.00001 d)0.000001

30. Which of the following is only Bronsted-Lowry acid? a) NH3 b) OHc) HCO3d)NH4

31. Which of the following is only Bronsted-Lowry base? a) CH3COOH b) NH2c) HCO3d)H3O-

32. Which of the following is not Lewis acid? a) BF3 b) Fe3+ c) AlCl3 d)NaOH

33. Which of the following is only Lewis acid? a) FeBr3 b) OHc) HCO3d)SO4 2-

34. Which of the following is not the hardness ion

a) Na+ b) Ca2 +

c) Fe2+

35. Which of the following is colorless and odorless gas a) NO2 b) H2S c) N2O3 d) NO 36. Which of the following is colorless and odorless gas a) NH3 b) CH4 c) HCHO d) N2O3 37. Which of the following is not odorless gas a) CO b) PH3 c) N2O3 d) NO2 38. Which of the following is colorless gas a) F2 b) CO2 c) N2O3 d) NO2 39. Which is the most abundant element in the earths crust a) Si b) O2 c) Al d) N2 40. Which of the following is not solid at room temperature? a) H2O b) Fe2 c) NH2OH d) CaO 41. Which of the following will react with water at room temperature? a) Mg b)Cl2 c) Ga d) N2 42. which of the following reactions can be used for Laboratory receive carbon dioxide a) CH4 + O2 b) CaCO3 +HCl c) CaCO3 + heat d) C+ O2 43. Which of the following compound is able to express oxidative as well as reductive properties? a) H2S b) N2O5 c) N2O d) NH3 44.Which of the following compound is able to express only reductive properties? a) KMnO4 b) NH3 c) N2O5 d)SO2 45. which of the following reactions can be used for laboratory receive H2 a) CH4 + H2O b) Na+ H2O c) Zn + HCl d) CaH2 + H2O 46. which one of the following elements has greater tendency to catenation a) C b) N c) S d) Cl 47. Which of the following is Haber process

a) NO+ O2 b) N2 + O2 c) N2 + H2 d) NH3 + O2 48. The carbon monoxide is able to form covalent compound with a) Na b) Mn c) Li d) Ca 49. Nitrogen has a reasonable oxidation number in all of following compounds and yet one of them is impossible. Which of them is impossible? a) NF3 b) NI5 c) NO2 d) NO3 - e) NO 50.In which of following C has the oxidation number equal to 0 a)CH4 b)CH3COOH c)CH3CHO d) HCOH 51. Which of the following is diprotic acid a) H3PO4 b) H3PO2 c) HPO3 d) H3PO3 52. Which of the following compound is anhydride of phosphoric acid? a) N2O5 b) P4O10 c) P4O6 d) N2O3 53. Which of the following compound is an Phosporylchloride a) Na3P b) (NH4)3PO4 c) Na3PO4 d) PH3 e) POCl3 54. In which of the complex ions given below the metal ion has not oxidation number equal to 3+ a)[Fe(CN)6]3- b) )[Fe(CN)6]4- c)[Cr(OH) 6]3- d)[Al(NH3)6]3+ 55. Which of the following is not monodentate ligand a)water b) ammonia c)hydroxide ion d)EDTA 56. Which of the following is polydentate ligand a)EDTA b)OH- c) en d) NH3 57. Which of the following is not neutral ligand a)water b) ammonia c)hydroxide ion d)EDTA 58. In which of the complex ions given below coordination number is equal to 4 a)[Fe(CN)6]3- b) )[Fe(CN)6]4- c)[Cr(OH) 6]3- d)[Al(OH) 4]59 In which of the complex ions given below coordination number is equal to 4 a)[Fe(CN)6]3- b) )[Cu(en)2]4- c)[Cr(OH) 6]3- d)[Al(OH) 6]360.