01.

NH 4 HS dissociates as follow NH 4 HS ( s ) = NH 3 ( g ) + H 2 S ( g ) . At 250 C the dissociation

pressure of pure solid is 500 mm of Hg. Calculate K P . If the flask contains 300 mm of NH3 along with solid NH 4 HS which undergo dissociation at 250 C . Calculate total pressure at equilibrium.

02.

For the equilibrium H 2 + I 2 = 2 Hl when 1 mole of H 2 and 3 mole of I 2 are introduced in a flask of volume V and at temp. T, then x moles of Hl are formed. On introducing two additional mole of H 2 the amount of Hl formed becomes 2x. Calculate Kp for the reaction 7 gm sample of IBr in 0.2 lit. flask is heated to 227 0 C to decompose as 2IBr(g) = I 2 (g) + Br2 ( g ). If partial pressure of Br2 ( g ) is 3 atm. Calculate K C and K P .

03.

04.

The equilibrium constant ( K p ) for the reaction 2 SO2 ( g ) + O2 ( g ) = 2 SO3 ( g ) is 0.13 at 830 0 C. In one experiment 2 mole of SO2 and 2 mole of

O2 were initially present in a flask. What must be the

total pressure at equilibrium be in order to have an 80 % (by mole) yield of SO3 . 05. An equilibrium mixture at 300 0 K contains N 2 O4 and NO4 at 0.28 atm and 1.1 atm pressure respectively. If the volume of the container is doubled. Calculate the new equilibrium pressure of two gases. 06. 16 moles of hydrogen and 4 moles of nitrogen are sealed in a one litre vessel. The vessel is heated at a constant temp. until equilibrium is established, when it is found that the pressure in the vessel has fallen to 9/10 of its original value. Calculate K C for the reaction N 3 + 3H 2 = 2 NH 3. 07. Ammonia under a pressure of 15 atm at 27 0 C is heated to 347 0 C in a closed vessel in the presence of catalyst. Under these conditions NH 3 is partially decomposed according to the eq.

2 NH 3 = N 2 + 3H 2 . The vessel is such that the volume remains effectively constant whereas
pressure increases to 50 atm. Calculate the % NH 3 decomposed. 08. A mixture of SO2 and O2 at 1 atm in the mole ratio 2:1 is passed through a catalyst at 1170 0 C at a rate sufficient for attainment of equilibrium. The existing gas, suddenly chilled and anolysed, is found to the contain 87% of SO3 by mole. Calculate K P for the reaction SO2 + 1 / 2 O2 = SO3 . 09. The decomposition of ammonium carbamate at 30 0 C is represented as
NH 2 COONH 4 ( s ) = 2 NH 3 ( g ) + CO2 ( g ) K P = 2.9 x10 5 what is the total pressure of gases in equilibrium with

NH 2 COONH 4 ( s ).
10. A mixture of one mole of CO2 and one mole of H 2 attains equilibrium at a temp. of 250 0 C and a total pressure of 0.1 atm for the change CO2 ( g ) + H 2 ( g ) = CO ( g ) + H 2 O( g ) . Calculate K P if the analysis of final reaction mixture shows 0.16 volume percent of CO .