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AIEEE - Previous year Papers -MATHEMATICS - 2005 MATHEMATICS - 2005

1. If the angle between the line x + 1/1 = y 1/2 = z 2/2 and the plane 2x y + z+4 = 0 is such that sin = 1/3, the value of is (a) 4/3 (b) 3/4. (c) 5/3 (d) 3/5

2. If a circle passes through the point (a, b) and cuts the circle x2 + y2 = p2 orthogonally, then the equation of the locus of its centre is (a) 2ax + 2by (a2 b2 + p2) = 0 (c) 2ax + 2by (a2 + b2 + p2) = 0 (b) x2 + y2 3ax 4by + (a2 + b2 p2) = 0 (d) x2 + y2 2ax 3by + (a2 b2 p2) = 0.

3. If a vertex of triangle is (1, 1) and the mid point of two sides through this vertex are (-1, 2) and (3, 2), then the centroid of the triangle is (a) (-1, 7/3) (b) (-1/3, 7/3) (c) (1/3, 7/3) (d) (1, 7/3).

4. In a triangle ABC, let 2(r + R) equals (a) b + c

C = /2. If r is the inradius and R is the circumradius of the triangle ABC, then (c) c + a (d) a + b + c

(b) a + b

5. The differential equation representing the family of curves y2 = 2c(x + c), where c > 0, is a parameter, is of order and degree as follows (a) order 1, degree 2 (c) order 2, degree 2 (b) order 1, degree 1 (d) order 1, degree 3.

6. If C is the mid point of AB and P is any point outside AB, then (a) (c) + + +2 + = =0 (b) (d) + + = =2

7. If the circles x2 + y2 + 2ax + cy + a = 0 and x2 + y2 3ax + dy 1 = 0 intersect in two distinct points P and Q then the line 5x + by a = 0 passes through P and Q for (a) exactly two values of a (c) infinitely many values of a. (b) no value of a (d) exactly one value of a

8. A lizard, at an initial distance of 21 cm behind an insect, moves from rest with an acceleration of 2cm/s2 and pursues the insect which is crawling uniformly along a straight line at a speed of 20 cm/s. Then the lizard will catch the insect after

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(a) 1 s

(b) 24 s

(c) 20 s

(d) 21 s.

9. In a triangle PQR, if (a) b = a + c

R = /2. If tan (P/2) and tan (Q/2) are the roots of ax2 + bx + c = 0, a 0 then (c) b = c (d) a = b + c.

(b) c = a + b

10. In a frequency distribution, the mean and median are 21 and 22 respectively, then its mode is approximately (a) 20.5 (b) 25.5 (c) 22.0 (d) 24.0 + c , + and c + c +b

11. Let a, b and c be distinct non-negative numbers. If the vectors a + a lie in a plane, then c is (a) the harmonic mean of a and b (c) the geometric mean of a and b 12. ABC is triangle. Forces , ,

(b) the arithmetic mean of a and b (d) equal to zero. acting long IA, IB and IC respectively are in equilibrium, where I

is the incentre of ABC. Then P : Q : R is (a) cosA : cosB : cosC (c) sinA : sinB : sinC

(b) sinA/2 : sinB/2 : sinC/2 (d) cosA/2 : cosB/2 : cosC/2

13. limn [1/n2 sec2 1/n2 + 2/n2 sec2 4/n2+..+1/n sec2 1] equals (a) 1/2sec1 (c) 1/2tan1 (b) 1/2cosec1 (d) tan 1. x. if f(1) = - 2 and f (x) 2 for [1, 6], then (c) f(6) < 5. X )2 + ( (c) 2 . X (d) f(6) = 5 )2 + ( (d) 3 X )2 is equal to

14. Let f be the differentiable for (a) f(6) < 8 (b) f(6) > 8

15. For any vector , the value of ( (a) 4 (b)

16. of mathematical induction (a) An = 2n 1 A + (n 1)I (c) An = nA (n 1)I

then which one of the following holds for all n > 1, by the principle (b) An = 2n 1 A (n 1)I (d) An = nA + (n 1)I.

17. Suppose f(x) is differentiable at x = 1 and limh0 1/h f(1 + h) = 5, then f(1) equals (a) 6 (b) 3 (c) 4 (d) 5.

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18. If non-zero numbers a, b, c are in H.P., then the straight line x/a + y/b + 1/c = 0 always passes through a fixed point. That point is (a) (-1, -2) (b) (1, -1/2) (c) (1, -2) (d) (-1, 2)

19. If the letters of the word SACHIN are arranged in all possible ways and these words are written out as in dictionary, then the word SACHIN appears at serial number (a) 600 (b) 603 (c) 601 =2 -2 (c) 10/33 (d) 602 + 3 + ( + 4 ) and the plane .( + 5 + )=

20. The distance between the line 5 is (a) 10/9 (b) 10/3

(d) 3/10.

21. If the coefficient of x7 in [ax2 + (1/bx)]11 equals the coefficient of x-7 in [ax (1/bx2)]11 then a and b satisfy the relation (a) a b = 1 (b) ab = 1 (c) a + b = 1 (d) a/b = 1.

172. If cos-1 x cos-1 y/2 = , then 4x2 4xy cos + y2 is equal to (a) 4 (b) 2sin2 (c) 4sin2 (d) 4sin2

23. Three houses are available in a locality. Three persons apply for the houses. Each applies for one house without consulting others. The probability that all the three apply for the same house is (a) 2/9 (b) 1/9 (c) 7/9 (d) 8/9.

24. If x dy/dx = y (log y-log x + 1), then the solution of the equation is (a) log (y/x) = cx (c) ylog (x/y) = cx (b) xlog (y/x) = cy (d) log (x/y) = cy

25. {(log x 1 / 1 + (log x2)}2 dx is equal to (a) xex/1+x2 +C. (b) x/x2 + 1 +C (c) x/(log x)2 + 1 +C (d) log x/(log x)2 + 1 +C

26. An ellipse has OB as semi minor axis, F and F its focii and the angle FBF is a right angle. Then the eccentricity of the ellipse is (a) 1/4. (b) 1/2 (c) 1/3 (d) 1/2

27. Let f : (-1, 1) B, be a function defined by f(x) = tan-1 2x/1 x2, then f is both one-one-and onto when B is the interval (a) (-/2, /2) (b) [0, /2) (c) (0, /2) (d) [-/2, /2].

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28. Let A and B be two events such that P

= 1/6, P (AB) = 1/4 and P(

) = 1/4, where

stands for complement of event A. Then events A and B are (a) equally likely but not independent (c) equally likely and mutually exclusive 29. Let Then [ , = - , , =x + + (1 - x) and (b) mutually exclusive and independent (d) independent but not equally likely. = y + x + (1 + x y)

] depends on (b) only x (c) neither x nor y (d) both x and y.

(a) only y

30. A spherical iron ball 10 cm in radius is coated with a layer of ice of uniform thickness that melts at a rate of 50 cm3/min. When the thickness of ice is 5 cm, then the rate at which the thickness of ice decreases, is (a) 1/54 cm/min. (c) 5/6 cm/min (b) 1/36 cm/min (d) 1/18 cm/min

31. Two points A and B move from rest along a straight line with constant acceleration f and f respectively. If A takes m sec. more than B and describes n units more than B in acquiring the same speed then (a) (f + f )m2 = ff n (c) (f f)n = 1/2ff m2 (b) (f f )m2 = ff n (d) 1/2(f + f )m = ff n2.

32. The system of equation x + y + z = 1, x + y + z = 1, x + y + z = 1 has no solutions, if is (a) 1 (b) -2 (c) either -2 or 1 (d) not -2.

33. If a1,a2,a3,.,an,are in G.P., then the determinant

(a) 4.

(b) 0

(c) 1

(d) 2

34. If the cube roots of unity are 1, , 2 then the roots of the equation (x - 1)3 + 8 = 0, are (a) 1, 1 2, 1 22. (c) 1, 1 + 2, 1 + 22 (b) 1, 1 + 2, 1 22 (d) 1, 1, 1

35. The area enclosed between the curve y = loge(x + e) and the coordinate axes is (a) 1 (b) 2 (c) 4 (d) 3.
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36. If A2 A + I = 0, then the inverse of A is (a) A (b) I A (c) A + I (d) A I.

37. If a2 + b2 + c2 = - 2 and

Then f(x) is a polynomial of degree (a) 1 (b) 0 (c) 2 (d) 3.

38. The value of 50C4 + r=16 56-rC3 is (a) 56C4 (b) 56C3 (c) 55C3 (d) 55C4.

39. If the equation anxn + an 1xn-1 +.+ a1 x = 0, a1 0, n > 2, has a positive root x = , then the equation nanxn-1 + (n - 1)an-1 xn-2 +.+ a1 = 0 has a positive root, which is (a) smaller than (c) equal to (b) greater than (d) greater than or equal to .

40. Let f(x) be a non-negative continuous function such that the area bounded by the curve y = f(x), xaxis and the ordinates x = /4 and x = > /4 is (sin + /4 cos + 2). Then f(/2) is (a) (1 /4 2). (c) (/4 + 2 1) (b) (1 /4 + 2) (d) (/4 2 + 1)

41. Let and be the distinct roots of ax2 + bx + c = 0, then limx 1 cos (ax2 + bx + c) / (x - )2 is equal to (a) a2/2 ( - )2. (c) 1/2 ( - )2 (b) a2/2 ( - )2 (d) 0

42. If the plane 2ax 3ay + 4az + 6 = 0 passes through the midpoint of the line joining the centres of the spheres x2 + y2 + z2 + 6x 8y 2z = 13 and x2 + y2 + z2 10x + 4y 2z = 8 then a equals (a) 2 (b) 1 (c) 1 (d) 2.

43. If f is a real-valued differentiable function satisfying |f(x) f(y)| (x - y)2, x y R and f(0) = 0, then f(1) equals (a) 0 (b) 1 (c) 2 (d) -1.
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44. Let P be the point (1, 0) and Q a point on the locus y2 = 8x. The locus of mid point of PQ is (a) y2 + 4x + 2 = 0 (c) y2 4x + 2 = 0. (b) x2 4y + 2 = 0 (d) x2 + 4y + 2 = 0

45. The sum of the series 1+1/4.2! +1/16.4! +1/64.6! + is (a) e + 1/2e (c) e+1/e (b) e 1/e (d) e 1/2e.

46. If x = n=0 an, y = n=0 bn, z = n=0 cn where a, b, c are in A. P. and |a| < 1, |b| < 1, |c| < 1 then x, y, z are in (a) Arithmetic-Geometric progression (b) HP (c) AP (d) GP. 47. If both the roots of the quadratic equation x2 2kx + k2 + k 5 = 0 are less than 5, then k lies in the interval (a) (5, 6] (b) [4, 5] (c) (6, ) (d) (-, 4).

48. The value of - cos2x/1+ax dx, a > 0, is (a) /a. (b) a (c) 2 (d) /2

49. The plane x + 2y z = 4 cuts the sphere x2 + y2 + z2 x + z 2 = 0 in a circle of radius (a) 1 (b) 2. (c) 2 (d) 3

50. The angle between the lines 2x = 3y = -z and 6x = -y = -4z is (a) 90 (b) 30 (c) 45. (d) 0

51. A random variable X has Poisson distribution with mean 2.The P(X > 1.5) equals (a) 3/e2 (b) 1 3/e2. (c) 0 (d) 2/e2

52. Let F: R R be a differentiable function having f(2) = 6, f (2) = (1/48). Then limx2 0f(x) 4t3/x 2 dt equals (a) 12. (b) 24 (c) 36 (d) 18

53. Let x1, x2,,xn be n observations such that x21 = 400 and xi = 80. Then a possible value of n among the following is (a) 9. (b) 12 (c) 18 (d) 15
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54. The parabolas y2 = 4x and x2 = 4y divide the square region bounded by the lines x = 4, y = 4 and the coordinate axes. If S1, S2, S3 are respectively the areas of these parts numbered from top to bottom; then S1 : S2 : S3 is (a) 1 : 2 : 1 (b) 2 : 1 : 2. (c) 1 : 2 : 3 (d) 1 : 1 : 1

55. The locus of a point P (, ) moving under the condition that the line y = x + is a tangent to the hyperbola x2/a2 y2/b2 = 1 is (a) a circle (b) a hyperbola (c) an ellipse (d) a parabola.

56. A real valued function f(x) satisfies the functional equation f(x y) = f(x) f(y) f(a x) f(a + y) where a is a given constant and f(0) = 1. f(2a x) is equal to (a) f(x) (b) f(x) (c) f(a) + f(a x). (d) f(x)

57. If the coefficient of rth, (r + 1)th and (r + 2)th terms in the binomial expansion of (1 + y)m are in A.P., then m and r satisfy the equation (a) m2 m(4r + 1) + 4r2 + 2 = 0 (b) m2 m(4r + 1) + 4r2 2 = 0 (c) m2 m(4r 1) + 4r2 + 2 = 0 (d) m2 m(4r 1) + 4r2 2 = 0. 58. If = z/z (1/3)i and || = 1, then z lies on (a) an ellipse (b) a straight line. (c) a circle (d) a parabola

59. If x is so small that x3 and higher powers of x may be neglected, then (1 + x)3/2 (1 + 1/2 x)3 / (1 - x)1/2 my be approximated as (a) 1 3/8x2 (b) x/2 3/8x2 (c) 3x + 3/8x2 (d) 3/8x2.

60. If I1 = 01 2x dx, I2 = 01 2x dx, I3 = 12 2x and I4 = 12 2x dx then (a) I3 > I4 (b) I2 > I1 (c) I3 = I4. (d) I1 > I2

61. Let R = {(3, 3) (6, 6), (9, 9), (12, 12), (6, 12), (3, 9), (3, 12), (3, 6)} be a relation on the set A = {3, 6, 9, 12}. The relation is (a) reflexive and symmetric only (c) reflexive and transitive only. (b) an equivalence relation (d) reflexive only

62. The line parallel to the x-axis and passing through the intersection of the lines ax + 2by + 3b = 0 and bx 2ay 3a = 0, where (a, b) (0, 0) is (a) below the x-axis at a distance of 2/3 from it (b) above the x-axis at a distance of 3/2 from it. (c) below the x-axis at a distance of 3/2 from it (d) above the x-axis at a distance of 2/3 from it

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63. A particle is projected from a point O with velocity u at an angle of 60 with the horizontal. What it is moving in a direction at right angles to its direction at O, its velocity then is given by (a) u/3 64. If [( + , , )2 (b) u/3 (c) u/2 (d) 2u/3.

are non-coplanar vector and is a real number then ]=[ + ] for

(a) no value of (b) exactly one value of (c) exactly two values of (d) exactly three values of 65. Area of the greatest rectangle that can be inscribed in the ellipse x2/a2 + y2/b2 = 1 is (a) ab (b) 2ab (c) a/b (d) ab

66. The normal to the curve x = a(cos + sin), y = a(sin cos) at any point is such that (a) it passes through (a/2, -a). (b) it is at a constant distance from the origin (c) it passes through the origin (d) it makes angle /2+ with x-axis 67. If the pair of lines ax2 + 2(a + b)xy + by2 = 0 lie along diameters of a circle and divide the circle into four sectors such that the area of one of the sectors is thrice the area of another sector then (a) 3a2 + 2ab + 3b2 = 0 (b) 3a2 10ab + 3b2 = 0 (c) 3a2 2ab + 3b2 = 0 (d) 3a2 + 10ab + 3b2 = 0. 68. A and B are two like parallel forces. A couple of moment H lies in the plane of A and B and is contained with them. The resultant of A and B after combining is displaced through a distance (a) H/A + B (b) 2H/A B (c) H/A B (d) H/2 (A + B).

69. If z1 and z2 are two non-zero complex numbers such that |z1 + z2| = |z1| + |z2|, then argz1 argz2 is equal to (a) (b) 0. (c) /2 (d) /2

70. The value of a for which the sum of the squares of the roots of the equation x2 (a 2)x a 1 = 0 assume the least value is (a) 0 (b) 3 (c) 1 (d) 2

71. The resultant R of two forces acting on a particle is at right angles to one of them and its magnitude is one third of the other force. The ratio of larger force to smaller one is

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(a) 2 : 1

(b) 3 : 22

(c) 3 : 2

(d) 3 : 2.

72. A function is matched below against an interval where it is supposed to be increasing. Which of the following pairs is incorrectly matched? Interval (a) (, ) (b) (, 1/3] (c) [2, ] (d) (,4] Function x3 3x2 + 3x + 3 3x2 2x + 1 2x3 3x2 12x + 6 x3 + 6x2 + 6

73. If in a ?ABC, the altitudes from the vertices A, B, C on opposite sides are in H.P., then sinA, sinB, sinC are in (a) A.P. (b) G.P. (c) H.P. (d) Arithmetic-Geometric progression

74. If the roots of the equation x2 bx + c = 0 be two consecutive integers, then b2 4c equals (a) 1 (b) 2 (c) 3 (d) 2.

75. A circle touches the x-axis and also touches the circle with centre at (0, 3) and radius 2. The locus of the centre of the circle is (a) a parabola (b) a circle (c) an ellipse (d) a hyperbola.

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AIEEE - Previous year Papers -PHYSICS - 2005


1. A smooth block is released from rest on a 45 incline and then slides a distance d. The time taken to slide is n times as much to slide on rough incline than on a smooth incline. The coefficient of friction is (a) s = 1 1/n2 (b) s = 1 1/n2 (c) k = 1 1/n2 (d) k = 1 1/n2.

2. Which of the following is incorrect regarding the first law of thermodynamics? (a) It introduces the concept of entropy (b) It introduces the concept of the internal energy (c) It is not applicable to any cyclic process (d) It is a restatement of the principle of conservation of energy 3. The electrical conductivity of a semiconductor increases when electromagnetic radiation of wavelength shorter than 2480 nm is incident on it. The band gap in (eV) for the semiconductor is (a) 0.5 eV (b) 1.1 eV (c) 0.7 eV (d) 2.5 eV

4. In a full wave rectifier circuit operating from 50 Hz mains frequency, the fundamental frequency in the ripple would be (a) 100 Hz (b) 70.7 Hz (c) 25 Hz (d) 50 Hz

5. An annular ring with inner and outer radii R1 and R2 is rolling without slipping with a uniform angular speed. The ratio of the forces experienced by the two particles situated on the inner and outer parts of the ring, F1/F2 is (b) 1 (a) R1/R2 (c) R2/R1 (d) (R1/R2)2

6. Consider a car moving on a straight road with a speed of 100 m/s. The distance at which car can be stopped is [k = 0.5] (a) 100 m (b) 400 m (c) 1000 m (d) 800 m

7. A car, starting from rest, accelerates at the rate f through a distance S, then continues at constant speed for time t and then decelerates at the rate f/2 to come to rest. If the total distance traversed if 15S, then (a) S = 1/4f t2 (b) S = 1/2f t2 (c) S = ft (d) S = 1/6f t2

8. The relation between time t and distance x is t = ax2 + bx where a and b are constants. The acceleration is (a) 2av2 (b) 2av3 (c) 2av2 (d) 2bv3 . 9. A gaseous mixture consists of 16 g of helium and 16 g of oxygen. The ratio CP/CV of the mixture is (a) 1.4 (b) 1.54 (c) 1.59 (d) 1.62
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10. The moment of inertia of a uniform semicircular disc of mass M and radius r about a line perpendicular to the plane of the disc through the center is (a) 1/4 Mr2 (b) Mr2 (c) 2/5 Mr2 (d) 1/2 Mr2

11. If I0 is the intensity of the principal maximum in the single slit diffraction pattern, then what will be its intensity when the slit width is doubled? (a) I0/2 (b) I0 (c) 2I0 (d) 4I0

12. A magnetic needle is kept in a non-uniform magnetic field. It experiences (a) a force but not a torque (b) neither a force nor a torque (c) a torque but not a force (d) a force and a torque 13. A block is kept on a frictionless inclined surface with angle of inclination . The incline is given an acceleration a to keep the block stationary. Then a is equal to

(a) g

(b) g/tan

(c) g tan

(d) g cosec

14. The resistance of hot tungsten filament is about 10 times the cold resistance. What will be the resistance of 100 W and 200 V lamp when not in use? (a) 200 (b) 400 (c) 20 (d) 40

15. A fully charged capacitor has a capacitance C. It is discharged through a small coil of resistance wire embedded in a thermally insulated block of specific heat capacity s and mass m. If the temperature of the block is raised by ?T, the potential difference V across the capacitance is (a) 2mC T/s (b) ms T/C (c) 2ms T/C (d) mC T/s

16. The temperature entropy diagram of a reversible engine cycle is given in the figure. Its efficiency is

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(a) 1/4

(b) 1/3

(c) 1/2

(d) 2/3

17. If S is stress and Y is Youngs modulus of material of a wire, the energy stored in the wire per unit volume is (a) 2Y/S (b) S2/2Y (c) S/2Y (d) 2S2Y

18. A body A of mass M while falling vertically downwards under gravity breaks into two parts; a body B of mass 1/3 M and body C of mass 2/3 M. The center of mass of bodies B and C taken together shifts compared to that of body A towards (a) body B (b) does not shift (c) depends on height of breaking (d) body C

19. Out of the following pair, which one does not have identical dimensions is (a) work and torque (b) moment of inertia and moment of a force (c) angular momentum and Plancks constant (d) impulse and momentum 20. Two thin long, parallel wires, separated by a distance d carry a current of i A in the same direction. They will (a) attract each other with a force of 0i2/(2d) (b) repel each other with a force of 0i2/(2d2) (c) attract each other with a force of 0i2/(2d2) (d) repel each other with a force of 0i2/(2d) 21. The diagram shows the energy levels for an electron in a certain atom. Which transition shown represents the emission of a photon with the most energy?

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(a) II

(b) I

(c) III

(d) IV

22. A moving coil galvanometer has 150 equal divisions. Its current sensitivity is 10 divisions per milliampere and voltage sensitivity is 2 divisions per millivolt. In order that each division reads 1 volt, the resistance in ohms needed to be connected in series with the coil will be (a) 9995 (b) 103 (c) 99995 (d) 105

23. A charged particle of mass m and charge q travels on a circular path of radius r that is perpendicular to a magnetic field B. The time taken by the particle to complete one revolution is (a) 2qB/m (b) 2m/qB (c) 2mq/B (d) 2mq/B

24. When two tuning forks (fork 1 and fork 2) are sounded simultaneously, 4 beats per second are heard. Now, some tape is attached on the prong of the fork 2. When the tuning forks are sounded again, 6 beats per second are heard if the frequency of fork 1 is 200 Hz, then what was the original frequency of fork 2? (a) 200 Hz (b) 204 Hz (c) 202 Hz (d) 196 Hz

25. The self inductance of the motor of an electric fan is 10 H. In order to impart maximum power at 50 Hz, it should be connected to a capacitance of (a) 8 F (b) 1 F (c) 4 F (d) 2 F

26. A parachutist after bailing out falls 50 m without friction. When parachute opens, it decelerates at 2 m/s2. He reaches the ground with a speed of 3 m/s. At what height, did he bail out? (a) 182 m (b) 91 m (c) 293 m (d) 111 m

27. When an unpolarized light of intensity I0 is incident on a polarizing sheet, the intensity of the light which does not get transmitted is (a) I0 (b) zero (c) 1/2 I0 (d) 1/4 I0

28. A bullet fired into a fixed target loses half its velocity after penetrating 3 cm. How much further it will penetrate before coming to rest assuming that it faces constant resistance to motion?

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(a) 1.0 cm

(b) 3.0 cm

(c) 1.5 cm

(d) 2.0 cm

29. The block of mass M moving on the frictionless horizontal surface collides with the spring of spring constant K and compresses it by length L. The maximum momentum of the block after collision is

(a) MK L

(b) KL2/2M

(c) zero

(d) ML2/R

30. A Youngs double slit experiment uses a monochromatic source. The shape of the interference fringes formed on a screen (a) circle (b) hyperbola (c) straight line (d) parabola

31. A coil of inductance 300 mH and resistance 2 is connected to a source of voltage 2V. The current reaches half of its steady state value in (a) 0.1 s (b) 0.3 s (c) 0.15 s (d) 0.05 s

32.A body of mass m is accelerated uniformly from rest to a speed v in a time T. The instantaneous power delivered to the body as a function of time is given by (a) 1/2 mv2/T2 t (b) mv2/T2.t (c) 1/2 mv2/T2 t2 (d) mv2/T2.t2

33. A particle of mass 10 g is kept on the surface of a uniform sphere of mass 100 kg and radius 10 cm. Find the work to be done against the gravitational force between them to take the particle far away from the sphere. (you may take G = 6.67 x 10-11 Nm2/kg2) (a) 13.34 x 10-10 J (b) 6.67 x 10-9 J (c) 6.67 x 10-10 J (d) 3.33 x 10-10 J

34. A photocell is illuminated by a small bright source placed 1 m away. When the same source of light is placed 1/2 m away, the number of electrons emitted by photocathode would (a) decrease by a factor of 4 (b) decrease by a factor of 2 (c) increase by a factor of 2 (d) increase by a factor of 4 35. The figure shows a system of two concentric spheres of radii r1 and r2 and kept at temperatures T1 and T2, respectively. The radial rate of flow of heat in a substance between the two concentric spheres is proportional to

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(a) (r2 r1) / r1r2 (c) r1r2 / (r2 - r1)

(b) (r2 r1) (d) ln [r2/r1]

36. If a simple harmonic motion is represented by d2x/dt2 + ax = 0, its time period is (a) 2 (b) 2 (c) 2/ (d) 2/

37. A projectile can have the same range R for two angles of projection. If t1 and t2 be the time of flights in the two cases, then the product of the two time of flights is proportional to (a) R2 (b) 1/R (c) 1/R2. (d) R

38. The phase difference between the alternating current and emf is /2. Which of the following cannot be the constituent of the circuit? (a) L alone (b) LC (c) C alone (d) R, L

39. One conducting U tube can slide inside another as shown in figure, maintaining electrical contacts between the tubes. The magnetic field B is perpendicular to the plane of the figure.

If each tube moves towards the other at a constant speed V, then the emf induced in the circuit in terms of B, l and V where l is the width of each tube, will be (a) 2BlV (b) BlV (c) Zero (d) BlV

40. The function sin2(t) represents (a) a simple harmonic motion with a period 2/ (b) a periodic, but not simple harmonic, motion with a period 2/ (c) a simple harmonic motion with a period / (d) a periodic, but not simple harmonic motion with a period /

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41. Two simple harmonic motions are represented by the equation y1 = 0.1 sin (100t + /3) and y2 = 0.1 cos t. The phase difference of the velocity of particle 1 with respect to the velocity of particle 2 is (a) /3 (b) /3 (c) /6 (d) /6 . 42. A circuit has a resistance of 12 ohm and an impedance of 15 ohm. The power factor of the circuit will be (a) 1.25 ANS: b 43. A 20 cm long capillary tube is dipped in water. The water rises up to 8 cm. if the entire arrangement is put in a freely falling elevator the length of water column in the capillary tube will be (a) 20 cm (b) 4 cm (c) 10 cm (d) 8 cm (b) 0.8 (c) 0.4 (d) 0.125

44. A uniform electric field and a uniform magnetic field are acting along the same direction in a certain region. If an electron is projected along the direction of the fields with a certain velocity then (a) it will turn towards right of direction of motion (b) its velocity will decrease (c) its velocity will increase (d) it will turn towards left of direction of motion 45. A charged ball B hangs from a silk thread S, which makes an angle with a large charged conducting sheet P, as shown in the figure. The surface charge density of the sheet is proportional to

(a) tan

(b) cos

(c) cot

(d) sin

46. A fish looking up through the water sees the outside world contained in a circular horizon. If the refractive index of water is 4/3 and the fish is 12cm below the surface, the radius of this circle in cm is

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(a)36/7

(b) 367

(c) 365

(d) 45

47. If radius of the 2713 Al nucleus is estimated to be 3.6 fermi then the radius of 12552Te nucleus be nearly (a) 5 fermi (b) 4 fermi (c) 6 fermi (d) 8 fermi

48. Two sources of equal emf are connected to an external resistance R. The internal resistance of the two sources are R1 and R2 (R2 > R1). If the potential difference across the source having internal resistance R2 is zero then (a) R = R1R2 / R1 + R2 (c) R = R1R2/R2 R1 (b) R = R2 R1 (d) R = R2(R1 + R2) / (R2 R1) U1 and U2 are the

49. A system goes from A to B via two processes I and II as shown in figure. If changes in internal energies in the processes I and II respectively, then

(a) (b) (c)

U2 < U1 = U2 >

U2 U2 U1 U1 and U2 can not be determined

(d) relation between

50. Two voltmeters, one of copper and another of silver, are joined in parallel. When a total charge q flows through the voltmeters, equal amount of metals are deposited. If the electrochemical equivalents of copper and silver are z1 and z2 respectively the charge which flows through the silver voltmeter is (a) q/1+z1/z2 (b) q/1+z2/z1 (c) qz2/z1 (d) qz1/z2

51. The intensity of gamma radiation from a given source is I. On passing through 36 mm of lead, it is reduced to I/8. The thickness of lead which will reduce the intensity to I/2 will be

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(a) 12 mm

(b) 18 mm

(c) 6 mm

(d) 9 mm

52. Two thin wire rings each having a radius R are placed at a distance d apart with their axes coinciding. The charges on the two rings are +q and q. The potential difference between the centers of the two rings is (a) Q/20 [1/R 1/R2 + d2] (b) Q/40 [1/R 1/R2 + d2] (c) QR/40d2 (d) zero 53. A thin glass (refractive index 1.5) lens has optical power of 5 D in air. Its optical power in a liquid medium with refractive index 1.6 will be (a) 1 D (b) 25 D (c) 25D (d) 1 D

54. A T shaped object with dimensions shown in the figure, is lying on a smooth floor. A force is applied at the point P parallel to AB, such that the object has only the translational motion without rotation. Find the location of P with respect to C.

(a) 3/4 l

(b) 3/2 l

(c) l

(d) 4/3 l

55. A mass m moves with a velocity v and collides inelastically with another identical mass. After collision the first mass moves with velocity v/3 in a direction perpendicular to the initial direction of motion. Find the speed of the 2nd mass after collision

(a) v

(b) 2/3v

(c) v/3

(d) 3v

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56. Two point charges +8q and 2q are located at x = 0 and x = L respectively. The location of a point on the x axis at which the net electric field due to these two point charges is zero is (a) 8L (b) 2L (c) L/4 (d) 4L

57. A spherical ball of mass 20 kg is stationary at the top of a hill of height 100 m. It rolls down a smooth surface to the ground, then climbs up another hill of height 30 m and finally rolls down to a horizontal base at a height of 20 m above the ground. The velocity attained by the ball is (a) 34 m/s (b) 40 m/s (c) 10 m/s (d) 20 m/s

58. If the kinetic energy of a free electron doubles, its deBroglie wavelength changes by the factor (a) 1/2 (b) 1/2 (c) 2. (d) 2

59. A heater coil is cut into two equal parts and only one part is now used in the heater. The heat generated will now be (a) halved (b) doubled (c) four times (d) one fourth

60. A nuclear transformation is denoted by X(n, )73 Li. Which of the following is the nucleus of element X? (a) 95B (b) 105B (c) 114Be (d) 126C

61. Two concentric coils each of radius equal to 2 cm are placed at right angles to each other. 3 ampere and 4 ampere are the currents flowing in each coil respectively. The magnetic induction in weber/m2 at the center of the coils will be (0 = 4 x 10-7 Wb/A-m) (a) 7 x 10-5 (b) 5 x 10-5 (c) 12 x 10-5 (d) 10-5

62. The change in the value of g at a height h above the surface of the earth is the same as at a depth d below the surface of earth. When both d and h are much smaller than the radius of earth, then which of the following is correct? (a) d = h (b) d = 2h (c) d = h/2 (d) d = 3h/2

63. Two point white dots are 1 mm apart on a black paper. They are viewed by eye of pupil diameter 3 mm. Approximately, what is the maximum distance at which these dots can be resolved by the eye? [Take wavelength of light = 500 nm] (a) 1 m (b) 5 m (c) 3 m (d) 6 m

64. An observer moves towards a stationary source of sound, with a velocity one-fifth of the velocity of sound. What is the percentage increase in the apparent frequency? (a) Zero (b) 20% (c) 5% (d) 0.5%

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65. The upper half of an incline plane with inclination is perfectly smooth while the lower half is rough. A body starting from rest at the top will again come to rest at the bottom if the coefficient of friction for the lower half is given by (a) 2 sin (b) 2 tan (c) tan (d) 2 cos

66. In a potentiometer experiment the balancing point with a cell is at length 240 cm. On shunting the cell with a resistance of 2 , the balancing length becomes 120 cm. The internal resistance of the cell is (a) 4 (b) 0.5 (c) 2 (d) 1

67. The bob of a simple pendulum is a spherical hollow ball filled with water. A plugged hole near the bottom of the oscillating bob gets suddenly unplugged. During observation, till water is coming out, the time period of oscillation would (a) First decrease and then increase to the original value (b) remain unchanged (c) increase towards a saturation value (d) first increase and then decrease to the original value 68. Staring with a sample of pure 66Cu, 7/8 of it decays into Zn is 15 minutes. The corresponding halflife is (a) 10 minutes (b) 14 minutes (c) 7 1/2 minutes (d) 5 minutes

69. In a common base amplifier, the phase difference between the input signal voltage and output voltage is (a) /4 (b) 0 (c) /2 (d)

70. In the circuit, the galvanometer G shows zero deflection. If the batteries A and B have negligible internal resistance, the value of the resistor R will be

(a) 200

(b) 100

(c) 500

(d) 1000

71. A parallel plate capacitor is made by stacking n equally spaced plates connected alternatively. If the capacitance between any two adjacent plates is C then the resultant capacitance is (a) C (b) nC (c) (n - 1)C (d) (n + 1)C

72. An energy source will supply a constant current into the load if its internal resistance is (a) non-zero but less than the resistance of the load

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(b) zero (c) equal to the resistance of the load (d) very large as compared to the load resistance 73. A particle is moving eastwards with a velocity of 5 m/s. In 10 s the velocity changes to 5 m/s northwards. The average acceleration in this time is (a) 1/2 ms-2 towards north-west (b) 1/2 ms-2 towards north-east (c) 1/2 ms-2 towards north (d) zero 74. A particle of mass 0.3 kg is subjected to a force F = - kx with k = 15 N/m. What will be its initial acceleration if it is released from a point 20 cm away from the origin? (a) 5 m/s2 (b) 15 m/s2 (c) 3 m/s2 (d) 10 m/s2

75. Average density of the earth (a) does not depend on g (b) is inversely proportional to g (c) is directly proportional to g (d) is a complex function of g

AIEEE - Previous year Papers -CHEMISTRY - 2005


1. Which one of the following types of drugs reduces fever? (a) tranquiliser (b) antipyretic (c) analgesic (d) antibiotic

2. Calomel (Hg2Cl2) on reaction with ammonium hydroxide gives (a) HgO (b) HgNH2Cl (c) NH2 Hg Hg Cl (d) Hg2O

3. The structure of diborane (B2H6) contains (a) four 2c-2e bonds and four 3c-2e bonds (b) four 2c-2e bonds and two 3c-2e bonds (c) two 2c-2e bonds and two 3c-3e bonds (d) two 2c-2e bonds and four 3c-2e bonds 4. Equimolar solutions in the same solvent have

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(a) same boiling and same freezing points (b) same boiling point but different freezing point (c) same freezing point but different boiling point (d) different boiling and different freezing points 5. If is the degree of dissociation of Na2SO4, the vant Hoffs factor (i) used for calculating the molecular mass is (a) 1 2 (b) 1 (c) 1 + 2 (d) 1 +

6. Which one of the following species is diamagnetic in nature? (a) H2+ (b) He2+ (c) H2 (d) H2-.

7. For a spontaneous reaction the ?G, equilibrium constant (K) and Ecell will be respectively (a) ve, < 1, ve 8. In silicon dioxide (a) each silicon atom is surrounded by two oxygen atoms and each oxygen atom is bonded to two silicon atoms (b) there are double bonds between silicon and oxygen atoms (c) each silicon atom is surrounded by four oxygen atoms and each oxygen atom is bonded to two silicon atom (d) silicon atom is bonded to two oxygen atoms 9. The decreasing order of nucleophilicity among the nucleophiles (b) ve, > 1, ve (c) ve, > 1, +ve (d) +ve, > 1, ve

(a) (4), (3), (2), (1)

(b) (3), (2), (1), (4)

(c) (1), (2), (3), (4)

(d) (2), (3), (1), (4)

10. Aluminium oxide may be electrolysed at 1000C to furnish aluminium metal (At. Mass = 27 amu; 1 Faraday = 96, 500 Coulombs). The cathode reaction is Al3+ + 3e- Al0 The prepare 5.12 kg of aluminium metal by this method would require (a) 5.49 x 107 C of electricity (b) 5.49 x 104 C of electricity (c) 1.83 x 107 C of electricity (d) 5.49 x 1010 C of electricity 11. p-cresol reacts with chloroform in alkaline medium to give the compound A which adds hydrogen cyanide to form, the compound B. The latter on acidic hydrolysis gives chiral carboxylic acid. The structure of the carboxylic acid is

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12. In both DNA and RNA, heterocyclic base and phosphate ester linkages are at (a) C2 and C5 respectively of the sugar molecule. (b) C5 and C1 respectively of the sugar molecule. (c) C1 and C5 respectively of the sugar molecule. (d) C5 and C2 respectively of the sugar molecule. 13. Acid catalyzed hydration of alkenes except ethane leads to the formation of (a) primary alcohol (b) secondary or tertiary alcohol (c) mixture of secondary and tertiary alcohols (d) mixture of primary and secondary alcohols 14. The reaction

is fastest when X is (a) NH2 (b) Cl (c) OC2H5 (d) OCOR

15. What is the conjugate base of OH-? (a) O(b) O2(c) O2 (d) H2O

16. Hydrogen ion concentration in mol/L in a solution of pH = 5.4 will be (a) 3.98 x 108 (c) 3.88 x 106 (b) 3.68 x 10-6 (d) 3.98 x 10-6
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17. Amongst the following the most basic compound is (a) aniline (c) acetanilide (b) p-nitroaniline (d) benzylamine

18. Heating an aqueous solution of aluminium chloride to dryness will give (a) AlCl3 (b) Al2Cl6 (c) Al2O3 (d) Al(OH) Cl2

19. Which of the following oxides is amphoteric in character? (a) CO2 (b) CaO (c) SnO2 (d) SiO2

20. Which of the following is a polyamide? (a) teflon (b) bakelite (c) terylene (d) nylon-66

21. The IUPAC name of the coordination compound K3 [Fe(CN)6] is (a) potassium hexacyanoferrate (III) (b) potassium hexacyanoferrate (II) (c) potassium hexacyanoiron (II) (d) tripotassium hexacyanoiron (II) 22. Heating mixture of Cu2O and Cu2S will give (a) Cu2SO3 (b) Cu + SO2 (c) CuO + CuS (d) Cu + SO3

23. Two solutions of a substance (non electrolyte) are mixed in the following manner. 480 ml of 1.5 M first solution + 520 mL of 1.2 M second solution. What is the molarity of the final mixture? (a) 1.20 M (b) 1.344 M (c) 1.50 M (d) 2.70 M

24. Based on lattice energy and other considerations which one of the following alkali metal chlorides is expected to have the highest melting point? (a) LiCl (b) RbCl (c) NaCl (d) KCl

25. Which of the following compounds shows optical isomerism? (a) [Cu(NH3)4]2+ (b) [Co(CN)6]3- (c) [Cr(C2O4)3]3(d) [ZnCl4]226. The number and type of bonds between two carbon atoms in calcium carbide are (a) two sigma, one pi (b) one sigma, two pi (c) one sigma, one pi (d) two sigma, two pi 27. Electrolyte KCl KNO3 HCl NaOAc NaCl 2 -1 (S cm mol ) 149.9 145.0 426.2 91.0 126.5 Calculate using appropriate molar conductances of the electrolytes listed above at in finite dilution in H2O at 25C.

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(a) 517.2

(b) 552.7

(c) 217.5

(d) 390.7

28. Benzene and toluene form nearly ideal solutions. At 20C, the vapour pressure of benzene is 75 torr and that of toluene is 22 torr. The partial vapour pressure of benzene at 20C for a solution containing 78 g of benzene and 46 g of toluene in torr is (a) 37.5 (b) 25 (c) 53.5 (d) 50

29. A schematic plot of ln Keq versus inverse of temperature for a reaction is shown in the figure. The reaction must be

(a) exothermic (b) one with negligible enthalpy change (c) endothermic (d) highly spontaneous at ordinary temperature 30. The oxidation state of chromium in the final product formed by the reaction between KI and acidified potassium dichromate solution is (a) +4 (b) +6 (c) +2 (d) +3

31. The lanthanide contraction is responsible for the fact that (a) Zr and Nb have similar oxidation state (b) Zr and Hf have about the same radius (c) Zr and Y have about the same radius (d) Zr and Zn have the same oxidation state 32. The correct order of the thermal stability of hydrogen halides (H - X) is (a) HCl < HF > HBr < HI (b) HF > HCl > HBr > HI (c) HI > HCl < HF > HBr (d) HI > HBr > HCl > HF 33. Among the following acids which has the lowest pka value? (a) HCOOH (b) CH3COOH (c) (CH3)2 CHCOOH (d) CH3CH2COOH

34. The oxidation state of Cr in [Cr(NH3)4Cl2]+ is (a) +3 (b) 0 (c) +2 (d) +1


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35. In which of the following arrangements the order is NOT according to the property indicated against it? (a) I < Br < F < Cl increasing electro gain enthalpy (with negative sign) (b) B < C < N < O increasing first ionization enthalpy (c) Al3+ < Mg2+ < Na+ < F - increasing ionic size (d) Li < Na < K < Rb increasing metallic radius 36. Of the five isomeric hexanes, the isomer which can give two monochlorinated compounds is (a) n-hexane (c) 2, 2-dimethlybutane (b) 2,3-dimethlybutane (d) 2-methlypentane

37. The volume of a colloidal particle, VC as compared to the volume of a solute particle in a true solution VS could be (a) 10-3 (b) 1023 (c) 1 (d) 103

38. t1/4 can be taken as the time taken for the concentration of a reactant to drop to 3/4 of its initial value. If the rate constant for a first order reaction is k, the t1/4 can be written as (a) 0.75/k (b) 0.10/k (c) 0.69/k (d) 0.29/k

39. Which one of the following cyano complexes would exhibit the lowest value of paramagnetic behaviour? (a) [Fe(CN)6]3(b) [Mn(CN)6]3(c) [Cr(CN)6]3(d) [Co(CN)6]3H

40. Consider the reaction: N2 + 3H2 2NH3 carried out at constant temperature and pressure. If and U are the enthalpy and internal energy changes for the reaction, which of the following expressions is true? (a) H=0 (b) H= U (c) H< U (d) H> U

41. A reaction involving two different reactants can never be (a) unimolecular reaction (b) first order reaction (c) second order reaction (d) bimolecular reaction 42. The highest electrical conductivity of the following aqueous solutions is of (a) 0.1 M fluoroacetic acid (b) 0.1 M difluoroacetic acid (c) 0.1 M chloroacetic acid (d) 0.1 M acetic acid

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43. An organic compound having molecular mass 60 if found to contain C = 20%, H = 6.67% and N = 46.67% while rest is oxygen. On heating it gives NH3 along with a solid residue. The solid residue gives violet colour with alkaline copper sulphate solution. The compound is (a) CH3CONH2 (b) CH3NCO (c) (NH2)2 CO (d) CH3CH2CONH2

44. The exothermic formation of ClF3 is represented by equation: Cl2(g) + 3F2(g) 2ClF3(g); H = - 329 kJ Which of the following will increase the quantity of ClF3 in an equilibrium mixture of Cl2, F2 and ClF3? (a) increasing the temperature (b) adding F2 (c) removing Cl2 (d) increasing the volume of the container 45. Consider an endothermic reaction X Y with the activation energies Eb and Ef for the backward and forward reactions, respectively. In general (a) Eb > Ef (c) Eb < Ef (b) there is no definite relation between Eb and Ef (d) Eb = Ef

46. The best reagent to convert pent-3-en-2-ol into pent-3-en-2-one is (a) pyridinium chlorochromate (b) acidic permanganate (d) acidic dichromate (c) chromic anhydride in glacial acetic acid 47. For the reaction 2NO2(g) 2NO(g) + O2(g) (KC = 1.8 X 10-6 at 184C) (R = 0.0831 kJ/m(mol. K)) When KP and KC are compared at 184C it is found that (a) KP is greater that KC (b) KP is less than KC (c) Whether KP is greater than, les than or equal to KC depends upon the total gas pressure (d) KP = KC 48. Which one of the following statements is not true about the effect of an increase in temperature on the distribution of molecular speeds in a gas? (a) the fraction of the molecules with the most probable speed increases (b) the distribution becomes broader (c) the area under the distribution curve remains the same as under the lower temperature (d) the most probable speed increase 49. 2-Methylbutane on reacting with bromine in the presence of sunlight gives mainly (a) 2-bromo-2-methylbutane (b) 1-bromo-2-methylbutane

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(c) 1-bromo-3-methylbutane (d) 2-bromo-3-methylbutane 50. The solubility product of a salt having general formula MX2, in water is 4 x 10-12. The concentration of M2+ ions in the aqueous solution of the salt is (a) 1.6 x 10-4 M (b) 2.0 x 10-6 M (c) 1.0 x 10-4 M (d) 4.0 x 10-10 M

51. Hydrogen bomb is based on the principle of (a) nuclear fission (c) nuclear fusion ANS: c 52. Of the following sets which one does NOT contain isoelectronic species? (a) PO43, SO42, ClO4 (b) SO32, CO32, NO3 (c) BO33, CO32, NO3(d) CN, N2, C22, 53. If we consider that 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic mass unit, the mass of one mole of a substance will (a) remain unchanged (b) increase two fold (c) decrease twice (d) be a function of the molecular mass of the substance 54. Alkyl halides react with dialkyl copper reagents to five (a) alkenyl halides (c) alkanes (b) alkyl copper halides (d) alkenes (b) natural radioactivity (d) artificial radioactivity

55. Reaction of one molecule of HBr with one molecule of 1, 3-butadiene at 40C gives predominantly (a) 1-bromo-2-butene under kinetically controlled conditions. (b) 3-bromobutene under thermodynamically controlled conditions (c) 1-bromo-2-butene under thermodynamically controlled conditions (d) 3-bromobutene under kinetically controlled conditions 56. Reaction of cyclohexanone with dimethylamine in the presence of catalytic amount of an acid forms a compound if water during the reaction is continuously removed. The compound formed is generally known as (a) an imine (b) an enamine (c) an amine (d) a Schiffs base

57. If the bond dissociation energies of XY, X2 and Y2 (all diatomic molecules) are in the ratio of 1 : 1 : 0.5 and Hf for the formation of XY is 200 kJ mol-1. The bond dissociation energy of X2 will be
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(a) 400 kJ mol-1

(b) 200 kJ mol-1

(c) 100 kJ mol-1

(d) 300 kJ mol-1

58. Lattice energy of an ionic compound depends upon (a) size of the ion only (b) charge and size of the ion (c) packing of the ion only (d) charge on the ion only 59. The number of hydrogen atom (s) attached to phosphorus atom in hypophosphorous acid is (a) two (b) zero (c) one (d) three

60. In a multi-electron atom, which of the following orbitals described by the three quantum numbers will have the same energy in the absence of magnetic and electric fields? (i) n = 1, l = 0, m = 0 (ii) n = 2, l = 0, m = 0 (iii) n = 2, l = 1, m = 1 (iv) n = 3, l = 2, m = 1 (v) n = 3, l = 2, m = 0 (a) (ii) and (iii) (b) (i) and (ii) (c) (iii) and (iv) (d) (iv) and (v)

61. Which of the following statements in relation to the hydrogen atom is correct? (a) 3s, 3p and 3d orbitals all have the same energy (b) 3s and 3p orbitals are of lower energy than 3d orbital (c) 3s orbital is lower in energy than 3p orbital (d) 3p orbital is lower in energy than 3d orbital 62. The disperse phase in colloidal iron (III) hydroxide and colloidal gold is positively and negatively charged, respectively. Which of the following statements in NOT correct? (a) coagulation in both sols can be brought about by electrophoresis (b) maxing of the sols has no effect (c) sodium sulphate solution causes coagulation in both sols (d) magnesium chloride solution coagulates, the gold sol more readily than the iron (III) hydroxide sol 63. Which types of isomerism is shown by 2, 3-dichlorobutane? (a) geometric (b) optical (c) diastereo (d) structural

64. Elimination of bromine from 2-bromobutane results in the formation of (a) predominantly 1-butene (b) equimolar mixture of 1 and 2-butene (c) predominantly 2-butyne (d) predominantly 2-butene

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65. An amount of solid NH4HS is placed in a flask already containing ammonia gas at a certain temperature and 0.50 atm. Pressure. Ammonium hydrogen sulphide decomposes to yield NH3 and H2S gases in the flask. When the decomposition reaction reaches equilibrium, the total pressure in the flask rises to 0.84 atm. The equilibrium constant for NH4HS decomposition at this temperature is (a) 0.30 (b) 0.17 (c) 0.18 (d) 0.11

66. The molecular shapes of SF4, CF4 and XeF4 are (a) the same with 1, 1 and 1 lone pair of electrons on the central atoms, respectively. (b) different with 1, 0 and 2 lone pairs of electrons on the central atom, respectively. (c) the same with 2, 0 and 1 lone pairs of electrons on the central atom, respectively. (d) different with 0, 1 and 2 lone pairs of electrons on the central atom, respectively. 67. An ionic compound has a unit cell consisting of A ions at the corners of a cube and B ions on the centres of the faces of the cube. The empirical formula for this compound would be (a) AB3 (b) AB (c) A2B (d) A3B

68. Which of the following factors may be regarded as the main cause of lanthanide contraction? (a) poor shielding of one of 4f electron by another in the subshell (b) poorer shielding of 5d electrons by 4f electrons (c) effective shielding of one of 4f electrons by another in the subshell (d) greater shielding of 5d electrons by 4f electrons 69. The value of the spin only magnetic moment for one of the following configurations is 2.84 BM. The correct one is (a) d5 (in strong ligand field) (b) d4 (in strong ligand field) (c) d4 (in weak ligand field) (d) d3 (in weak as well as in strong fields) 70. A photon of hard gamma radiation knocks a proton out of 2412 Mg nucleus to form (a) the isobar of 2311 Na (b) the isotope of parent nucleus (c) the nuclide 2311 Na (d) the isobar of parent nucleus 71. Which one of the following methods is neither meant for the synthesis nor for separation of amines? (a) Hinsberg method (b) Hofmann method (c) Wurtz reaction (d) Curtius reaction

72. During the process of electrolytic refining of copper, some metals present as impurity settle as anode mud. These are (a) Ag and Au (b) Pb and Zn (c) Sn and Ag (d) Fe and Ni

73. Which of the following is fully fluorinated polymer?

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(a) Teflon

(b) Thiokol

(c) Neoprene

(d) PVC

74. Tertiary alkyl halides are practically inert to substitution by SN2 mechanism because of (a) steric hindrance (b) insolubility (c) instability (d) inductive effect

75. Due to the presence of an unpaired electron, free radicals are (a) chemically inactive (b) cations (c) anions (d) chemically reactive

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