MIL-STD-101B Colour Code For Pneumatics

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MIL-STD-1OIB 3 December 1970 DEPARTMENTOF DEFlM3E Wssliington, .C. 20301 D Color Code for Pipelines end for CompressedGas ~linders
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1. This Military Standard is mandatory for use by all Departmentsand Agencies of the Department of Defsnse. 2. Recommended corrections,additions,or deletionsshould be addressed to Ccnunanding fficer, Edgewood Arsensl, ATTN: SMUEA-QAES-A,Edgsw~ O Arsened, MD 21010.
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MIL-STD-1OI.B 3 December 1970 CONTENTS
SCOPE. . . . . . . . . . . . . . . .
1.1 . . . . . .
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1.2
1.3 2. 3. 4. 4.1 4.2 4.3 5*. 5.1 5.1.1 5.1.2 5.1.3 5.1.4 5.1.5 5.2 5.2.1 5.2.2 5.2.3 5.2.4 5.2.5
Application. . . . Method . . . . . . REFERENCED DOCUMENTS DEPINTTIONS. . . . . GENERAL REQUIREMENTS Colors . . . . . . Warning colors . . Colors-havingno significantmeaning DETAIL REQUIREMENTS. . . . . . . . . . Pinin~ system identification. . . . E&ct-id-&tification . . . . . . . . Use of colors. . . ... . . . . . . . . . . . . . . . Prilllarycolors.. Arrows and secondary color warnings. Classificationof materials in piping . . @3tems. . . . . . . . . . . . . , blinder identification.. . . Assignment of colors . . . . . . . I&act identification. . Use of colors. . . . . . Painting of cylinders. . Additional information
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PIGURE
1. Piping systems. . . . . . . 2. Eottle-t~ cylinders . . . 3. Tube-type cylinders . . . . TABLES

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TABLE
I. Size of stencil letters . . systems II. Classificationof materials Titles and color codes for compressed ge9 III. cylkders. . . . . . . . . . . . .
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MIL-STD-1OIB
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3 December 1970 1. SCOPE is 1.1 Object. The object of this stancbxrd to-establisha common color code for visual warnings to accompanythe written identification of materials covered in piping systems and contained in compressedgas , a cylinders and to facilitatethe segregationof these cylinders t depots. The use of this standardwill promote greater safety snd wilJ lessen the chances of error, confusion,or inaction in times of emergency by providing a uniform color code to quickly warn personnel of outstfidinghazards inherent in the materials involved. However, this standard does not define the manner or conditionsunder which these materialsmay be used safely. 1.2 Application. This standard is applicableto all ground based piping systems and to alJ.compressedgas cylinders owned by or procured for the Department of Defense includingtype D one-ton containers (Departmentof TransportationSpecification1OGA-5OO). The applicability of this standardto industrypiping systems and cmmnercial-owned cylinders (see 5.2.5.1) is encouraged. Requirementsspecifiedherein are optional for hose linesand nozzles, ship installations,equipment intended for operationsin forward area facilities,steam plants, and method for bulk petrole~ hydroelectricplants. The identification product systems is covered in MIL-STD-161. The identificationof pipe lines for aircraft,missiles, and space vehicles is covered in MILSTD-1247.Color coding for contain&s of liquid propellantsis covered in MIL-STD-172. 1.3 Method. This standard establishes,defines, and assigns a color for recognitionto each of six classes of materials. Five classes have been selected to representuniversallyrecognizedtypes of hazards involved in the handling of dangerous gases and liquids. The sixth class is assigned for exclusiveuse of fire protectionmaterials and equipment. This standard requires the applicationof the color warnings in a distinctive manner, as a visual aid and supplementto written identification. 2. REFERENCEDDOCUMENTS 2.1 The issues of the foil.uwing ocuments in effect on the date of d invitationfor bids form a part of this standardto the extent specified herein. ( FEDERAL TANDARD 595 - Colors. S NO. AMERICAN NATIONAL STANDARD z48.1
Method of Marking Portable Compressed Gas Containersto Identifythe Material Contained.

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MIL-STD-1OU3
3 December 1970
DEPARTMENTOF TRANSFQRTATIONREGULATIONS (CUpie8 Of specifications,standards,drawings, and publicationsrequired by suppliersin connectionwith specific procurement functionsshouldbe obtained from the procuring activity or as directed by the contractingofficer.) 3. DEFINITIONS
3.1
For the purpose of this standard,the followingdefinitionsshall

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apply: (a) C-rcial colors. Commercialcolors are the colors which may be used, in a limited arrangement on a small portion of the body and bottcxn , of a compressedgas cylinder for ccunmercial dentificationand designation i of ounership. (b) Compressed gas cylinder. A compressed &s cylinder is any tube, bottle, or other type of pressure cylinder larger than 3 inches in diameter by 6 inches in length, which contains a pressure that exceeds 104 pounds per square inch at 130 F or any liqyid flammablematerial having a vapor pressure exceeding 40 pounds per square inch absolute at 100 F. One-ton type bulk containersare included. All ammunitionis excluded.
(c) Piping systems. Piping systems consist of any pipe line or conduit used for the transport of gases, liquids, or semiliquids,but not / those used for carrying solids ti air or gas. Vslves, fittings,operating accessories,pipe coverings,and pipe installationsof any kind (including / submerged or buried pipe lines, their markers or buoys, and their points of tie-in with pumping stations sad storage or dispensing facilities) shall be consideredas parts of a piping system, Supports,brackets, or other nonoperatingaccessoriesare not consideredparts for application of warning colors. (d) Primu?y color warnin~. A primary color warning is the color assigned to the class into which a material is classifiedin accordance titllits prim- h=ard from a safety standpoint. These colors appem as a circular band on piping systems and as main body, top, or b&nd , colors on compressedgas cylinders. (e) Secondary color warning. A secondary color winning is the color assigned as a warning of a secondaryhazard possessed by a material having atype of hazard distinctlydifferent I&cm that indicatedby its primary color wzwning. These colors appew es arrows (or triangles) on piping systems and as main body, top, or band colors on compressed. gas cylinders. (f) Title. A titleis any lettered identificationrequired on a piping system or a compressed gas cylinder. Titles shall identify 2
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4. GENERALREQUIREMENTS
MIL-STD-101B 3 December 1970
the contents by completensmes, or by generallyrecognizedabbreviations, s~bols, letters, numerals, or combinationsthereof.
4.1 Colors. The colors assigned in this standard sh& conform in hue and chroma to the requirementsidentifiedby number in Fed. Std. No, 595. No change shall be made in the assigned colors without prior approval of the preparing activity of this standard.
4.2 Warning color~, The following colors are assigned for use as both prtiary and secondarywarnings:
(a) Yellow, No. 13655- flammablematerials. All materials . -.. known ordinarilyas flammablesor combustibles. (b) .hmm, No. -. . 1008o -toxic and poisonousmaterials. ~ materials extremelyhazsrdousto life or health u=r normal conditions as toxics or poisons.
(c) Blue, No. - -anesthetics and harmful materials. All 15102 .. ..... materials productiveof anestheticvapors and all liquid chemicals snd compoundshazardous to life and property but not normally productive of dangerous quantitiesof fumes or vapors. oxidizingmaterials. All materials (d) Green, No. 14187- which readily furnish o~gen for combustionand fire producerswhich react explosivelyhor with the evolutionof heat in contact with many other materials.
(e) Gray, No. 16187- physicallydangerousmaterials. All - materials, not dangerous in themselves,which are asphyxiatingin confined areas or which are generallyhandled in a dangerousphysical state of presstie or temperature.
(f) Red, No. ~05 A . - f~r~ protectionmaterisJ.s_. ll materials provided in ~iping systems or in compres~edgas cylinders exclusively for use in fire protection.
4.3
Colors having no significantmeaning.
(a) BlackLNo. 17038 snd . White, No. 17875: These colors are . assigned,without significantmeaning, for general use where specifiedin this standard except as follows: Water-pipingsystems containingwater suitable for human consumptionand installed for this purpose shall be painted White, No. 17875 throughout or shall be painted to match surroundings when not in conflictwith other color desi~ations in this standard.
MIL-STD-1OIB .3 December 1970 (b) Orange&No. 12246 and Buf~No. 13594. These colors are assigned,without significantmeaning, ~o;use as colors on selected compressed gas cylindersfor segregationof identicalmaterial requiring recognitionwithin more than one assigned class (see table III).
I 5* DETAIL REQUIREMENTS 5.1

Piping system identification.
ofmaterials in any 5.1.1 .... Ezact identification. Exact identification piping system for hazamiousmaterials and the use classificationfor fire protectionis mandatory and shtil be made only by means of titles lettered in black or white. These titles shall be prominentlydisplayed adjacent to color wmings to obviate errors by personnel. It is recommended,where the view is unobstructed,that titles be lettered on the two lower quarters of the pipe or covering. Lettering in this position is unlikely to be obscured by dust collection or mectu+nical damage. However, titles should be clearly visible from operatingpositions,especiallythose adjacent to control valves. The use of stencils with standard size letters specifiedin table I is recommended. For pipe lines smaller than 3/4 inch in diameter, the use of securely fastenedmetal tags, with lettering etched or filled in with enamel,is suggested. It is recommendedthat titles be applied by use of upper case letters and erabic numerals whenever applicable. Table I. . Size of stencil letters .-. : Outside diameter of pipeor covering, : inches .. : LeSS than 1-1/2 : : 1-1/2 to 3-1/2 : 3-1/2 to 6 .,
: 6tog
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9 to 13 Over 13
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.... _ _ : Size of stencil letters, : . inches : : 1/2 : 3/4 : 1-1/4 : 2 : 3 : 3-1/2

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5.1.2 Use of colors. The appearanceof any of the six colors specified in 4.2 on a piping system shall. provide a warning of danger from the hazard involved in the system accordingto the definitions for warning colors specifiedtherein. PiPing systems which do not require warning colors may be painted to match surrounding,if not in conflict ith other color designationsin this standard or such w systemsmay be painted aluminum,black, or remain unpainted.
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MIL-STD-1OJ.B 3 December 1970 5.1.3 Primary color warning.

color warning shall appear 5.1.3.1 Use and application. A primary on aJJ dangerous piping systems and on all fire protectionmaterials in any installationwhich is color cciied accordancewith this in standard Primary color warnings shall consist of a single color . applied as a band or bands which completelyencircle the piping system. Color bands shall be applied in conformancewith dimensional infofiationshown on fig&e 1. In lieu of color bands, all pipe and covering on an entire system, includingall encirclingor partial.Q encirclingstraps, hangers, and supports,msy be painted with the color warning. However, the use of color bands is preferred primary because they will indicate dangerous systems to color-blindpersonnel.
a 5.1.3.2 Location on piping systems. Inmediatel.ydjacent to all operating accessoriessuch as valves, regulators,flowchecks,strainers, cle=outs~ pumps, dispensingpoints, and vents, all coded piping systems shall be painted with a primary color warning. In addition, Pr_ color ~ings shall be painted throughoutthe system at convenient intervals,e.g., where branch lines join the system, where the system passes underground or through walls, and at any other conspicuousplaces where warnings &e required by safety authorities. If desired, operating accessoriesmay also be painted with the primary color warning. 5.1.4 Arrows and second ary color warnings. An arrow shape shall appear on coded piping systems in any installationwhich is color coded in accordancewith this standard. Any material system possessing an outstandinghazard of a type distinctlydifferent from that indicated by its primary color warning shall have a secondary color warning applied in the shape of an arrow. The color of the arrow shall be selected according to the definitionsfor warning colors specified in 4.2. Systems which do not involve such additionalhazards shall have arrows either the same color as the primary warning, or black or white. When bands are used for the primary warnings, the colored =rows sh~ appear adjacent to each primary color warning applied to the piping system. When the entire piping system is painted with the primary color irarning, the colored arrows shall appear in all locationsspecified in 5.1..3.2. The arrows shall indicate the normal direction(s)of flow of material in the system. A double-headedarrow shall be placed on lines subject to reverse flow. Dimensional information is shown on figure 1. Tails may be omitted on arrows, creating triangles with one corner indicatingthe normal direction of flow. Operatingaccessories~ also be painted with the secondary color warning.
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MIXATD-1OIB 3 December 1970
EXACT
ALWAYS BY NAME
IDENTIFICATION
OF THE MATERIAL CONTAINED
PRIMARY
COLOR
WARNING
WIDTH
OF I 11
BAND
OUTSIDE DIAMETER PIPE OR COVERING UNDER 3+
OF
2 6
+ TO 13 OVER 13
SECONDARY
COLOR
WARNING )
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DIRECTION
OF
FLOW
REVERSIBLE
FLOW
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a= APPROX
OF OUTSIIX
7 2a
DIAMETER OF PIPE OR COVERING. (6 MAX)
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EXAMPLE
TITLE
Figure 1. Piping systems

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Table II. -- Classificationof .. . materialsin~~ng .
MIL-STD-1OIB 3 December 1970
5.1.5 C&ssificati~of material. pi~i~_systems. The classifiin cation of materials in a piping system shall be as specified in table II. IV.O.S. refers to materials of like neme and hazardous propertiesbut %ot otherwise specified. .Whenno secondary color wsrni~is specified, the sxrow m~ be the same color as the primary warning or black or white, as preferred.
systems
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.-.. - . . . .._. ..__ -.--. ---- .. -..

: :
Material ----
: Primary : Secondary : : color warning : color warn=n-:

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Acetaldehyde : Acetic acid, aqueous solution : Acetic acid, glacial . : : Acetic anhydride Acetone : Acetone oils : Acetyl chloride : Acetylene : Acid, liquid, N.O.S. : : Acrolein Acrylonitrile : Aerosol insecticide : Air, compressed : Alcohol, allyl, liquid Alcohol, ~1, butyl, ethyl; propyl,: N.O.S. : Alcohol, methyl : Alkaline corrosive liquids,.N.O.S. : Aluminum borohydride : Ammonia, anhydrous : : Amyl acetate : Aniline (oil), liquid Argon : : Argon-oxygenmixture Arsenic trichloride : .
Yellow Blue Blue Blue Yellow Yellow Blue Yellow Blue Brown Yellow Gray Gray Yellow Yellow Yellow Blue Yellow Brown Yellow Brown Gray Green Brown
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Blue Yellow Yellow Ye~ow

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: : :
Yellow Brown ----Green Brown

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: Blue Brown : Yellow

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Yellow : --: -----
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: Blue .
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MIL-STD-1OI-B
3 December 1970
,TableII. . Classificationof materials in~i~i~ . . . . , . .. .

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8ystems (continued) .
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Material .
: Primary ; Secondary : : color wsrni~ . color : --. warning: . ..-

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: : : : : : : . . : : : : : : : : : : : : .: : : : .
acids and liquids, N.O.S. : Brown Benzaldehyde : Yellow Benzene (benzol,coal tar light oil : Yellow 13enzine (petroleumether, petroleum : naphtha) : Yellow : Blue Benzoyl chloride Benzyl chloride : Blue Boron hydrides (al.kyl decaborane, : al@l pentaborane,diborane, : dihydrotetraborane ,hexaborane, : pentaborane,and N.O.S.) : Brown Boron trichloride : Brown Boron trifluoride : Brown Bromine : Brown Bromine pentafluoride : Brown Bromine trifluoride : &own Bromoacetone : Brown Bromobenzene : Yellow Bromochloromethane : Brown Bromochloromethane, fire : Red Bromotrifluoromethane : Gray Bromotrifluoromethane, fire : Red Butadiene : Yellow Butane (see petroleumgas) : Yellow Butyl acetate : Yellow Butyl ether : Yellow Camphor oil : Yellow Carbon bisulfide (carbon disulfide) : Yellow Csrbon dioxide : Gray Csrbon diox$de, fire : Red Carbon monoxide s Yellow Carbon tetrachloride : Brown Caustic potash, liquid (potassium : , hydroxide) : Blue Caustic soda, liquid (sodium : hydroxide) : Blue Chloroacesyictiori& : Blue Chlorine : Brown Chlorine trifluoride : Brown
Arsenical
: Blue : --: Brown : : --: ----: Yellow : : : : Yellow : --: Gray : Green : Green : Green : ----: ----: Gray : Brown : --: -: ----: ----: ----. -. : ----: Brown : --: ----: Brown : Blue : : ----: : --: ----: Green : Green
: : : : : : : : : : : : : : : . . : : : : : : : : : : : : : : : : : : : : : : : .
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MIL-STD-101B 3 December 1970 Table II. Classificationof . materials in ~~ -.. .. .

- : : . .- . . Mat erial . : :
systms ~continued)
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:
: : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :
: Primary : Secondary : color warniny : color warni~ : ,- .. . . .. _

: :
: -
: : : : : : : : : : N.o.s. : Brown Cyanogengas : Brown Cyclopropane : Yellow Decalin (decahydronaphthalene) : Yellow Dibromodifluoromethane : Gray Dibromodifluoromethane, ire f : Red Dichloropentane : Yellow Diethanolamine : Yellow Diethylenetrismine : Yellow Difluorochloroethdne : Gray Difluoroethane : Gray Diisobutylketone : Blue Dimethylamine,snhydrous : Yellow Dimethyl ether : Yellow Dimethyl sulfate : Brown Dimethyl sulfide : Yellow Diphenyl-diphenyl oxide : : Gray (DowthermA) Dispersant (dichlorodifluoromethane-: difluoroethane mixture) : Gray : Blue Electrolyteacid, N.O.S. Ethane : Yellow Ethers, anesthetic: diethyl, ethyl,: isopropyl,sulfuric,N.O.S. : Yellow Ethyl acetate : Yellow Ethyl benzene : Yellow Ethyl bromide : Yellow
Chloroacetone Chlorosulfonicacid Chloropicrin Chloropropane Chromic acid solution Coal gas (see manufacturedgas) Coal tar distillates,N.O.S. Crotonaldehyde Crude oil, petroleum Cyanide, liquid (potassium solutions,sodium solutions),
Brown Blue Brown Yellow Blue Yellow Yellow Blue Yellow
: :
Yellow : Green
: --: Blue
: Green : Brown : Brown : Yellow : ----: : : ----: Yellow
: Blue : --: : : : ---------------
: -r--: Yellow : Yellow : Yellow : Blue : Brown : Blue : Blue : : ----:
: : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :
: . -.. : . . .. .. ... ..: .

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: ----: ----: Blue : : Blue : ----: ----: Blue
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MIL-STD-101B 3 December 19?0 classificationof materials --in~i~~~stems (continued) Table II. .- - -- .-. -,--- -- -- .-.
. : -- . . -: -- --. - -- : :
: : :
. . :
:
:
: : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : ; -
: Secondary : : Primary : color warnin~ : color warning: ----.. - .--- -.. .-.. . : : : : : ----: Yellow Ethyl butyl acetate : : --: Yellow Ethyl butyrat e : -.--: : Yellow Ethyl chloroacet ate : Blue : : Yellow Ethyl chloride : Blue : : Yellow Ethylenediamine : ----: Yellow Ethyl hexaldehyde :, ----: : Yellow 13t41 lactate : Blue : : Yellow Et@l methyl ketone : Blue : : Yellow Ethyl nitrate : ----: : Yellow Ethyl nitrite : ----: : Yellow Ethyl silicate : Blue : : Yellow Ethylamine : Blue : : Yellow Ethylene : : -----: Yellow Ethylene chlorohydrin : Blue : : Yell,ow Ethylene dichloride : ----: : Yellow Ethylene glycol : Blue : : Yellow Ethylene oxide : Green : : Brown Fluorine : Brown : : Yellow Formaldehyde : Yellow : : Blue Formic acid : ----: : Yellow Fuel oil, N.O.S. : : ----Fuels: JP, RP, RS, diesel, N.O.S. : Yellow : : Fumigant, carbon dioxide - ethylene : : : Blue : Gray oxide mi+ture : : Yellow : Blue Furfural : ----: : Yellow Gasoline (motor fuel) : ----: : Gray Helium : : Yellow : Brown Hydrazine : : : Hydrocarbons,heavy: hexsnes, : : ----: Yellow heptanes, octanes, N.O.S. : : ----: Blue Hydrochloricacid : : --: Brown Hydrocyanicacid : : ----: Brown Hydrofluoricacid :. : ----: Blue Hydrofluorosilicacid : ----: : Yellow Hydrogen : : ----: Brown Hydrogen bromide Material
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Table II.. Classificationof materials inyi~~stems .- (continued) . ... ..- . ..-. - : : . .. . . . . - - .-. : - -. : :
:
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Material . ..--. .-.
: Primary : Secondary : : color warning : color warnin~: . .. . ..

: : : ----: Green : : : : : : : : : : : : :, : : : : : : : : : : : : :
:2.. : : : : : : : : : : : .
Hydrogen chloride,snhydrous : Brown Hydrogen cyanide, anhydrous : Brown Hydrogen fluoride, anhydrous : Brown Hydrogen, liquid : Yellow : Green Hydrogen peroxide Hydrogen sulfide : Yellow Hydroxyaceticacid (glycolicacid), : : Blue aqueous solutions : Yellow Ink (solventtype), N.O.S. : Brown Insecticide,liquid, N.O.S. : Brown Iodine heptafluoride : Yellow Isopentane Jet f%el (ti grties) . : Yellow Kerosene : Yellow Krypton : Gray : Yellow Lacquer : Manufacturedgas (coal, oil, pintsch, producer,water, and : N.O.S.) : Yellow Mercaptans (thioalcohols, N.O.S.) : Yellow Mercury componds (solutions),N.O.S.: Brown : Yellow Methane : Yellow Methylsmine : Yellow Methyl acetate : Yellow Methyl acetone Methyl acetylenepropadiene mixture : (MAPP) : Yellow : Yellow acetate Methyl ~1 : Yellow Mel@l amyl ketone : Brown Methyl bromide : Red Methyl bromide, fire : Yellow Methyl chloride : Brown Methyl cyanide (acetonitrile) : Yellow Methyl formate : Brown Methyl hydrazine Methyl mercaptan : Yellow Methyl sulfide : Yellow Methylene chloride : Blue .
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: Green : Gray : Blue : Brown : : ----: -----: Yellow : Green : Blue : ----: ----: ----: --: : : Brown : ------: --: ----: Brown : ----: --: ----:. : ----: --: ----: Brown : Brown : Yellow : Blue : Yellow : Brown : Brown : Gray .
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MIL-STD-1OI.B 3 December 1970 Classificationof materials in pipi~ systems (continued) Table II. -
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Material .
:
: : : ,. . : : : : : : : : : : : : : : : : : : :
: : : : : : : : : : : : : : .
: Primary : color waining .

:
: Secondary : : color warning:

: :
-.
: Yellow Natural gas, fortified,N.O.S. : Gray Neon : Brown Nickel carbonyl : Brown Nicotine compounds : Blue Nitrating acid (mixed acid) : Blue Nitric acid : Brown Nitric acid, fuming : Brown ,. Nitrobenzene : Gray Nitrogen : Brown Nitrogen dioxide : Brown Nitrogen peroxide : Brown Nitrogen tetroxide : Gray Nitrogen-helium mixture : Gray Nitrogen-oxygen mixture : Blue Nitrogen trifluoride Nitromethane : Yellow : Brown Nitrosyl chloride : Blue Nitrous oxide : Yellow Oil, hydraulic : Yellow Oil, lubricating,N.O.S. Oil; fish, vegetable, edible, N.O.S.: Yellow : Green Qxygen Oxygen-carbondioxidemixture : Gray Oxygen, electrolytic : Green : Brown Oxygen fluoride . : Green Oxygen, liquid (IOX) : Green Ozone : Yellow Paint : Yellow Paraldehyde : Yellow Pentane Perchloricacid : Green l-Pentene : Yellow Petroleum gas (acetogen,butane: : propane mixture, l-butene, cyclopropane,isobutane,neo: : Yellow pentane, and N.O.S.) .
.-
: Brown
: ----: Yellow : ----: Green
:
: : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : =
: Green : Green : Yellow, : --: Green : Green : Green : ----: Green : Green : Blue
: ----: ----: Gray
: ----: ----: ----: Green : ----: Green : Gray : Brown : ---.: ----: --: Blue : ----: : : : -----
:, . .. ...- .--
..- -...
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MIL-STD-101B 3 December 1970 Table 11. . Classificationof materials in piping systems (continued) .. e . .-. ._
: : . . : : :
Material
: .. . . . : Perchloroethylene : Perchl.oryl fluoride : Phenylcarbylamine chloride : Phosgene : Phosphorus oxychloride : Phosphorustribromide : Phosphorustrichloride s : Potassium permaaga.nate olution : Propylene : n-propyl nitrate : Propyne : Pyrosulfurylchloride : R-n , Trichlorofluoromethane : R-12, Dichlorodifluoromethane : R-14 , Tetrafluoromethane : R-21 , Dichlorofluoromethane : R-22 , Chlorodifluoromethane : R-112, Tetrachlorodifluoroethane : R-113, !!?richlorotrifluoroethme : R-114, Dichlorotetrafluoroethane Chl.oropentafluoroetha,ne : R-11.5, R-124A, ChlorotetrafluoroetWne : R-C-316, Dichlorohexafluoro: cyclobutane : R-C-317, Chlcroheptafluoro: cyclobutane : R-C-318, Octafluorocyclobut~e : Shellac : Solvents, I?.O.S. : Steam : Stoddard solvent : Sulfur dichloride : Sulfur dioxide : Sulfur hexafluoride : Sulfur monochloride : Sulfur trioxide : Sulfuric acid : Sulfuric acid, fuming (oleum)
: -
: F&imary : Secondary : : color warning : color warning~

:
: Blue : Brown : Brown : Brown : Blue : Blue : Blue : Green : Yellow : Yellow : Yellow : Blue : Gray : Gray : Gray : Gray : Gray : Gray : Gray : Gray : Gray : Gray : : Gray Gray : Gray : Yellow : Yellow : Gray : Yellow : Brown : Brown : Gray : Blue : Brown : Brown : Brown
._____
: : -----
; . .,
: Green : Gray : ----: Green : Green : Green : ---
: : :
: : :
:Gray : Brown : Gray : --: : : : : : : : : : ----------------------------------------
. . :
: ----: : ----: --------: ----: ----: ----: ----: Gray
: : : : : : : : : : : : : : : : : : : : : :
:
:
: ----: ----: Green
. .
: Green : Green : -.-.-.
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FIIL-STD-1OM 3 December 1970 Table 11. Classificationof materials inflipi~ systems (continued) ..
. : -. . - - : -- : :
: :
: : : : : : : : : : : : : : : : : : : : : : : : : : : .
Material .
I I
: Primary : color warning ..- - -.. .

. :
: Secondary : : color warning ~

: : ----: ----: Green : : : : : : : : : : : : : : : : : : : : : : : : : :
Tetraethyl lead Tetrafluoroethylene, inhibited Thionyl chloride Tin tetrachloride,anhydrous Titanium tetrachloride Toluene Tri~lsmine ltributylamine Triethanolsmine Triethylsmine Trimethylamine,anhydrous Turpentine Unsymmetricaldimethyl hydrazine Vacuum (noncontaminated) Varnish Vinyl bromide Vinyl chloride Vinyl methyl ether Waste acid (spent nitrating acid) Water, over 50 p.s.i.g. or 150F Water, fire Water, potable Waxes, liquid Xenon Xylene Xylidine
Brown : Gray : Brown : Blue : Blue : Yellow : Brown : Yellow : Blue : Brown : Brown : Yellow : Brown : Gray ;Yellow : Blue : Yellow : Yeliow : Blue : Gray : Red : White : Yellow : Gray : Yellow : Brown
.
: ----: -----
: Brown : Yellow : Blue : Yellow : Yellow : Yellow : ----: Yellow : ----: ----: : : : : : : : : ----------Yellow -------------------,.-
: Brown : Yellow
.
5.2 Cylinder identification. ent of colors. The use of color coding for compressedgas 5.2.1 Assignm cylinders covered by this stmdard is mandatov. The assignment of colors to extend coverage of material handled in compressedgas cylinders shall be made only after approval of the preparing activity of this standsrd. Requests for color coding of additionalmaterials not covered by this standard should include technical details of the material, primary and secondary hazards of the material, aud technical details of the cylinder, includi~ the type of cylinder valve used. .
14
*
5.2.2 Exact identification. Exact identificationof any material .. contained in a compressedgas cylinder is msndatory and shall be made only by means of the written title as specified in table III. The title shall appear in two locations diametricallyopposite smd parallel to the longitudinalaxis of the cylinder. It is recommendedthat the titles be applied by use of upper case letters and arabic numerals whenever applicable. On cylinders4 inches in diameter and larger, the title shall be in approximately2-inc~ high letters. On cylinders less than 4 inches in diameter, letters may be reduced in size. Where a title includes a modifier, such as lmedical[t l;oil-free,l or the modifier shall follow the chemical designationand should be shown in letters approximtel.ythree-foufihsas high. Cylindershaving a background color of yellow, orange, or buff shall have the title painted with black letters. Cylindershaving a background color of red, brown, blue, gray, green, or black shall have the title painted with white letters. Mixtures of two or more gases shall show the percent of each gas as part of the title.
5.2.3 . of - Use colors.
5.2.3.1 . Color warn~~: The appearanceon the body, top, or as a baud(s) on compressedgas cylindersof any of the six colorsspecified in 4.2 shall provide a warning of danger from the hazsrd involved in handling the type of material contained in the cylinder accordingto the definitionsfor warning colors in 4.2. ,.
j.2.3.2 Qylinder colcnr band(s). Cylinder color bands appear upon the cylinder body and serve aa color warnings when they are yellow, brown, blue, green, or gray. The bands also provide color combinations to sepsxate and distinguishcylinders for conveniencein handling, storage, and shipping. Colorbands for segregationpurposes will not be specifiedfor new materials not presently covered by this standard when new color codes for them are assigned.
5.2.4 Painting of~linders. All cylinders shall be painted in accordancewith table 111 and figures 2 and 3 to provide uniform recognitionthroughoutthe Department of Defense.
15
MIL-STD-1OI.B 3 December1970
,,
c. .8 ~A
--
+-d + *A
1111, I I
r TO
81
P
THRE/U)S
NOT
BE PAINTED
TITLE
\
I I
:;
II II
;
I t Y
i
I
LOCATION
OF COLORS ON GOVERNMENT- OWNED CYLIND=S * ,1:
OF A,A ORA
-~i
LOCATION OF COLORS ON COMMERCIAL-
I ,, ,.
OWNED CYLlhJOE~ LOCATION OIMENSIOIUSm

ANO BAND G ARE BANDS B OR 6CYLINOER COLOR BAND (S) A B B B
f
ON CYLINOERS FOR MEOICAL OAS MIXTURES# ~

LOCATED iMMEDIATELY 9ELW SHOULDER COLOR (S) A L/5 A
FOR
LENGTH L
COMMERCIAL IDENTIFICATIW
c
3
D L/6
MEOICALGN5 MIXTURES OTHER GASES
OVER 30
3&
3
2
~LESS%
L/5 L/5 L/5
L/6
US L/6i
ME DtCAA 30 QAS ANA) WXTllRES Uuolm

OTHER GASES
ALESS A 2
2
FROM XI
SPACE TO BE OMITTED
IF BANDS B
CYLINDER TOP TO BOTTOM OF NECK RING a c ARE oF .mFFEi3ENT COLORS
Figure Bottle type cylinders 2. 16
..--- ---
. . ..
MIL-STD-1OI.B 3 December1970
q. I
\\
\
tl
CB
F1
t
\
I
1 ,1
I
TITLE I I
II
11 A
LOADING
/ [ BoDyL:~~,L
r t :~ END
LOCATION OF COLORS ON GOVERNMENT-OWNED

S<RVICE OWNERSlilP OR
CYLINDERS
\ I , t
q
1
LOCATION OF COLORS ON COMMERCIMO OWNED CYLlhUIERS
LOCATION OVERALL LENG7H L

OVER 30 304V$D UNDER @ l SPACE TO, BE OM17TE0 ~ ~OFL
IF SAhiOS BM C
DIMENSIONS
CAP AND SHOULDER COLOR A

OF L
c;#mR
BAND(S) B~C
3 2
COMMERCIAL IDENTIFICATION 1)
~6 OF )60FL COLORS. L
ARE
OF
OIFFERENT
Figure Tube type cylinders 3. 17
q
MIL-STD-1OIB 3 December 1970 Table III. Titles and color codes for compressedgas cylinders Location on cylinder : Top A :Band B: Band C: Body
: : :
:
: : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :
Title
: :
:
: Yellow : Yellow : Yeld.ow: Yellow : Acetylene : Yellow : Brown : Black :Brown : Acrolein :. Buff : Buff : Buff : Buff : Aerosol insecticide : Black : Greeh : Black : Black : Air, compressed,breathing : Black : Green : Black : Black : Air, dry, special purpose : Black : Green : Black : Black : Air, oil-free : Black : Green : Green : Black : Air, oil-tolerant : Yellow : : Yellow : Brown : Br~ Al@l decaborane : Yellow : Brown : Brown : Yellow : A3kyl pentabarane : Brown : Yellow : Orange : Orange : Ammonia : Gr~ : White : Gray : Gray : Argon; oil-free : Gray : White : White : Gr~ : Argon, oii-tolersnt : Green : White : Gray : : Gray Argon-oxygenmixture : Brown : : Brown : Gray Boron trichloride : Gray : Gray : Brown : Brown : Brown : Boron trifluoride : Brown : Black : Black : Brown : Bromoacetone : Buff : Buff : Buff : : Grsy Bromochloromethane : Red : Gr~ : Red : Red : Bromochl.oromethane (Fire only) : Orange : : Orange : White : Gray Bromotrif luoromethane : Red : : White : Gray Bromotrif luoromethane(Fire only): Red : Buff : : Yellow : White : Buff Butadiene : Gray : : Gray : Gr~ : Gray Csrbon dioxide : Red : Red :Red : Red : Carbon dioxide (Fire only) : Yellow : Brown : Brown : Brown : Carbon monoxide : Black : Brown : Black : Brown : Chloroacetone : Brown : Brown : Brown : Brown : Chlorine : Brown : Green : Brown : Brown : Chlorine trifluoride : Brown : Orange : Orange : Brown : Chl.oropicrin : Yellow : Brown : Yellow : Brown : Cyanogen : Blue : : Orange : ~el.low: Blue @lopropane, medical : Orange : chromium plated : ~clopropane, medical : Yellow : Brown : Brown : Yellow : Diborane : Buff : : Buff : White : Buff Dibromodif luoromethane : Dibromodifluorcnnethane (Fire : : : : : Red : : Red : White : Red only) Difluorochloroethane : Gray : Yellow : Yellow : Or:ange: Difluoroethane : Gray : Yellow : Orange : Orange : Dihydrotetraborane : YelJ.ow: Brown : Brown : Yellow : : : White : Buff Dimethylamine,anhydrous : Yellow : Blue : Buff : Dimethylether : Yellow : Brown : Buff
: : : : :
18
MIL-STD-1OIB 3 December 1970 Table III. Titles and color codes for compressed fire cylinders (continued)
:
: :
: : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :
,:
Location on cylinder : : Top A : Band B :Band C:Body : : : : : : Dispersant,dichlorodifluoro: : : : : mthmediflumath~etitiwe : Buff : Buff : : Gr~ : Gr~ Ethane : Yellow : Blue : Yellow : Yellow: Ethyl chloride . .,. . : Buff : .Blue : Yellow : Buff : Ethyl nitrite ,, : Yellow : Buff : Buff : Buff : Et@lamine, anhydrous : Blue : YeUow : Blue : Buff : : Blue Ethylene, industrial . . . : Buff : : .Yellow: Buff Ethylene,nm?dical ~.., : Blue : Yellow : Blue : Blue : Ethylene oxide : Buff : Yellow : Blue : Buff : Fluorine : Brown : Green : Green : Brown : Fumigant, carbon dioxide: : : : : ethylene oxide mixhre : Buff : Buff : Blue : Buff : Fumigant,ethylene oxide: : : : dichlorodifluoromethaneixture~ Buff m : Buff : Buff : Buff : Helium, oil-free or medical : Buff : Grsy : Gray : Grqr : Helium, oil-tolerant : Grqy : Orange : Gr~ :Gr~: Helium~gen niixture : Buf~ : White**:, Green : Green : Hydrogen : Yellow : Black : Yellow : Yellow: : Black : Brown : Brown : Brown : Hydrogen bromide Hydrogen chloride, anhydrous : Brown : White : Brown : Brown : Hydrogen cyanide, anby~ous : YeUow : Brown : White : Brown : Hydrogen fluoride, anhydrous : Green : Brown : Brown : Brown : @3rogen sulfide : Brown : Yellow : Brown : Brawn : i&ypton, oil-free : Grsy : Buff : Gray : Gr~ : Krypton, oil-tolerant : Buff : Grqy : Buff :Gray: Manufacturedgas: coal, oil, : : : : : water, producer, etc. : Brown : Yellow : Yellow : Yellow: Methane : Yellow : White : Yellow : Yellow: Methyl acetylerie ropadiene p : : : : (MAPP) mixture ~ : Yellow : Orange : Yellow : Yellow~ Msthylsmine : Yellow : Br@& : Yellow : Buff : Methyl braide : Brown : Black : Brown : Brown : Methyl bromide (Fire only) : Red : Brown : Red : Red : Met@l chloride : Yellow : Brown : Orange : Orange: Methyl mercaptan : Brown : Yellow : Yellow : Brown : Methyl sulfide : Brown : : Yellow : Brown : Buff Methylene chlpride : Blue : Orange : Orange: : Gray
:
Title
. .
q 1 or At t (see figure 2) for medical gas mixtures. A **Bt or B 1t (see figure 2) for medical gas mixtures.
19
.
M&sTD-lolE 3 December 1970
..
Table III. Titles and color codes for compressed cylinders (continued) : :
: : : : :
Title
: Location on cylinder :ToPA : Band B :Band C: Body

: : : : :
: :
:
Yellow: Brown : Yellow : Yellow : Natursl gas : B@f : White : Buff : : Gr~ Neon, oil-free : Gr~ : : White : Buff : Grqf Neon, oil-tolerant Nickel c&.rbonyl : Yellow: White : Yellow : Brown : : Brown : Buff : Brown : Bruun : Nitric oxide : : Nitrogen, oil-free. : Gray : Black : Black : Grqy : : : Gray : Grsy : Black : Gr~ Nitrogen, oil-tolerant : : Brown : Buff : Buff : Brown : Nitrogen dioxide : : Black : Orange : Gray : Gr~ Nitrogen-heliummixture : : : Black : White : Green : Green : Nitrogen-o~gen mixture : : Brown : White : Wh$te : Brown : Nitrosyl chloride : : Blue : Blue : Blue Nitrous oxide : Blue : : : Green : : Green : Green : .Green O~gen : : Green : White : Green Oxygen, aviators : : Green : : Green : White : White : Green : O~gen, electroyltic : : White : Green : Green Oxygen, medical : Green : : : Gray~ : White**: Green : Green Oxygen-carbondioxide mixture : : : Green : Brown : Green : Brown : Oxygen fluoride : : Brown : Green : Green : Green : : Ozone : Yellow: Brown : Brown : Yellow : Pentaborane,stable : : Petroleum gas: acetogen,butane, : : : : butane-propane,butene-1, : : : : : : : cyclopropane,isobutsne, : : : : : . : . isobutylene,neopentane, : : : :Yellou; Orenge : Yellow : Yellow : propane, etc. : : Brown : Grsy : Grw Phenylcarbyl.emine chloride. : Brown : : :Brown: Orange : Brown : Brown : : Phosgene : Yellow: GrW : Buff : : l?ro~lene : Buff : Propyne ~ : GrW : Yellow : Yellow : Yellow : l?richlorofluoromethane : Orange: Orange : Orange : Orange : : R-1.1, : Orange: Orange : Orange : Orenge : Dichlorodifluoromethane .: R-I.2, : Orange: Orange : orange : Orange : : R-13, Chlorotrifluoromethaue : Orange: Orsnge :. Orange : Orange : : R-21, Dichlorofluoromethane : Orange: orange : Oran~ : Orenge : R-22, Chlorodifluoromethane : : R-1.13, !l!ric~orotrifluoroethane : Ormge: Orange : Orange : Orange : : R-ilk,Dichlorotetrafluoroethane : Orange: Orange : Orenge : Orange : : R-I.24A, Chlorotetrafluoroethane : Orange: orange : Orange : Orange : : : : : R-500, Dic~orodifluoromethene/ : : : Orange: Orange .:Orange : Orange : : Difluoroethane m ~.502,Monochlorodifluoromethane :, / : : : +-entafluoroethane %++ : Orange1 Orange : Orange : Orange :
-... ..
A
&
*AI or Art (see figure 2) for udical gas tifiures. **Bt or B1t (see figure 2) for =dical gas mixtures.
20
NICL-STD-1OD 3 December 1970 Table 111. Titles and color codes for compressed gss cylinders (continued)
:
: : : : : : : : : : Sulfur
Title dioxide Sulfur hexafluoride Tetrafluoroethylene, inhibited Trimethylamine,anhydrous Vi~l bromide Vinyl chloride Vinyl methyl ether, inhibited Xenon, oil-free Xenon, oil-tolerant
: Top A
:
Location on cylinder : : Band B :Band C: Body:

: : : :
: Brown : Gray : Buff : Yellow : Buff : Yellow : Yellow : White : White
: Gray ; White : White : Blue : Blue : Orange : Black : Black : Black
: Brown : Black : White : Orange : Blue : Buff : Buff : Gr~ : Black
: Brown: : Gray : : Buff : : Buff : : Buff : : Buff : : Buff : : Gray : : Gray :
5.2.5
Additionalinformation.
5.2.5.1 Commercial-owned cylinders. Commerical-owned cylindersare those not owned by or procured for the U.S. Government. Commerci~. owned cylindersare contractor-owned supplier-ownedcylinders in or which compressedgas is supplied to the Government. When Departmmt of Defense activitiesprocure compressedgases in commercial-owned cylinders,it is not maudatory that the cylindersbe color coded in accordancewith this standard. When such commercial-owned cylinders are not color coded in accordancewith this standard,they shall be marked in accordancewith Department of Transportationregulations and American National Standard z48.1. If the using Department of Defense activity requires that this standard apply to commercial-owned cylinders,the bottom and lower portion of the cylinderbody opposite the valve end may be used for commercialidentification. In this area, which shall not exceed one-sixth of the overall length of the cylinder,the use of a solid color other than the body color will not be permitted. 5.2.5.2 Decalcomanias. Two decalcomsniasmay be applied on the shoulder of each cylinder diametricallyopposite at right angles to ;titles. They should include the title of the gas, precautionsfor handling, and use. A background color correspondingto the primary warning color of the contents should be used. 5.2.5.3 Shatterproofdesignation. Shatterproofcylinders shall be stenciledwith the phrase Non-Shatlongitudinally90 degrees from the titles. Letters shall be black or white and approximately1 inch in size. 21
q
MIL-STD-1OU3
3 December 1970 ownership. Chrcylindersowned by or procured for the Department of Defense, the bottom and the lower portion of the ~ cylinder body opposite the valve end may be used for Service ownership titles. 5.2.5.5 Internationalstandardization a~ements. This standard shall .... . . be used to implementNATO ST=AG 2121, C!ENTO STAGNAG 2121, and SEATO STAGNAG 2121, subject: Medical Gas Cylinders. Custodians:
Army-Mu
5.2.5.4
service
Navy - SH Air Force - 68 Review activities:

Army - AV, ~, MI, MU(FA), WC Navy - AS, MC, MS, SH, YD Air Force - 12, h3, 68, 70
DSA-CS,
GS
User activities: Navy - CG Air Force -19,

Preparing
--
71
activity:
MU(EA)
No. 8120-0130
Project
o
I
...:....,., i.
,. ...,
STANDARDIZATION
1. DOCUMENT NUMBER
1
DOCUMENT
IMPROVEMEN+
pQ~~2-.
I
I
I
2. .00 CUMENT TITLE 4
M. NAME OF SUBMITTING
ORGANIZATION
14. TYPE OF ORGANIZATION
(Mark one)
In
L AOORE& (Shad, City, Stotw, ZIP Codd c1
VENOOR
I I I
I
0..
yER
MANUFACTURER .,. .
u
L PROBLEM AREAS
OTHER ,Spd/y,:
I I
a P@rqr.ph Number qnd Wording:
I I
\ .
b. Rocommond.d Wording:
D
c. R-_/Rotlonalo for R.comm.ndmien:
I I
I
, REMARKS
.,.:,.....
I t I I
I
I
i
s. NAME OF SUBMITTER
hat,
First, Ml) - OptlM~
b. WORK TELEPHONE co&) -optloit.l
NUMBER
(hCtU6
A?uo
~~
I
I
MAILING
AOORESS (Stmec City, Sta&, ZIP Co&) - Optional
S. DAT~OF. SUBMISSION (YYMMDD) .. . . ,, $ -... :,
B
b
Df)
S2 MAR
FORM
1426
REVIOUS EoITfON
l~~oLC.&.
... ~, r, ... . W, ,..,,
,,,,.,,~,
,.

MIL-STD-101B Colour Code For Pneumatics

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MIL-STD-1OI.B 3 December 1970 CONTENTS

1. Piping systems. . . . . . . 2. Eottle-t~ cylinders . . . 3. Tube-type cylinders . . . . TABLES

Method of Marking Portable Compressed Gas Containersto Identifythe Material Contained.

For the purpose of this standard,the followingdefinitionsshall

MIL-STD-101B 3 December 1970

the contents by completensmes, or by generallyrecognizedabbreviations, s~bols, letters, numerals, or combinationsthereof.

Colors having no significantmeaning.

I 5* DETAIL REQUIREMENTS 5.1

.... _ _ : Size of stencil letters, : . inches : : 1/2 : 3/4 : 1-1/4 : 2 : 3 : 3-1/2

MIL-STD-1OJ.B 3 December 1970 5.1.3 Primary color warning.

MIXATD-1OIB 3 December 1970

OUTSIDE DIAMETER PIPE OR COVERING UNDER 3+

DIAMETER OF PIPE OR COVERING. (6 MAX)

Figure 1. Piping systems

MIL-STD-1OIB 3 December 1970

.-.. - . . . .._. ..__ -.--. ---- .. -..

: Primary : Secondary : : color warning : color warn=n-:

& & &

Blue Yellow Yellow Ye~ow

Yellow Brown ----Green Brown

: Blue Brown : Yellow

Yellow : --: -----

,TableII. . Classificationof materials in~i~i~ . . . . , . .. .

: Primary ; Secondary : : color wsrni~ . color : --. warning: . ..-

MIL-STD-101B 3 December 1970 Table II. Classificationof . materials in ~~ -.. .. .

: Primary : Secondary : color warniny : color warni~ : ,- .. . . .. _

Brown Blue Brown Yellow Blue Yellow Yellow Blue Yellow

: Green : Brown : Brown : Yellow : ----: : : ----: Yellow

: Blue : --: : : : ---------------

: -r--: Yellow : Yellow : Yellow : Blue : Brown : Blue : Blue : : ----:

: . -.. : . . .. .. ... ..: .

: ----: ----: Blue : : Blue : ----: ----: Blue

MIL-STD-101B 3 December 1970

Material . ..--. .-.

: Primary : Secondary : : color warning : color warnin~: . .. . ..

: Primary : color waining .

: Secondary : : color warning:

: F&imary : Secondary : : color warning : color warning~

: Green : Gray : ----: Green : Green : Green : ---

:Gray : Brown : Gray : --: : : : : : : : : : ----------------------------------------

: ----: : ----: --------: ----: ----: ----: ----: Gray

: ----: ----: Green

: Green : Green : -.-.-.

: Primary : color warning ..- - -.. .

: Secondary : : color warning ~

5.2.3 . of - Use colors.

OF COLORS ON GOVERNMENT- OWNED CYLIND=S * ,1:

LOCATION OF COLORS ON COMMERCIAL-

OWNED CYLlhJOE~ LOCATION OIMENSIOIUSm

ON CYLINOERS FOR MEOICAL OAS MIXTURES# ~

MEOICALGN5 MIXTURES OTHER GASES

L/5 L/5 L/5

ME DtCAA 30 QAS ANA) WXTllRES Uuolm

CYLINDER TOP TO BOTTOM OF NECK RING a c ARE oF .mFFEi3ENT COLORS

Figure Bottle type cylinders 2. 16

LOCATION OF COLORS ON GOVERNMENT-OWNED

LOCATION OF COLORS ON COMMERCIMO OWNED CYLlhUIERS

LOCATION OVERALL LENG7H L

CAP AND SHOULDER COLOR A

Figure Tube type cylinders 3. 17

M&sTD-lolE 3 December 1970

: Location on cylinder :ToPA : Band B :Band C: Body