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The Laws of Conservation of Energy states that: the total energy of the universe is a
constant; energy cannot be created or destroyed.
Types of Energy:
Where q is the amount of heat in J (joules), m is the mass in g (grams), c is the specific heat
capacity in J/g°C (the values for this variable are usually found in a table), and ∆T is the change
in temperature in °C (degrees Celsius). Moreover, ∆, which is called Delta, means “change in,”
and in this case: “change in” temperature.
Things to Remember:
• Energy and heat are the same.
• If mass doubles, so does heat!
q = m ∙ c ∙ ∆T m = 100 g
q = (100 g)(2.46 J/ g°C)(25°C) ∆T = 25°C
q = 6150 J c = 2.46 J/ g°C
q = ? 6150 J
2. Beaker A contains 50 g of liquid at room temperature. The beaker is heated until the liquid
gains 10°C. Beaker B contains 100 g of the same liquid at room temperature. This beaker is
also heated until the liquid gains 10°C. In which beaker does the liquid absorb the most heat?
Beaker A
q = m ∙ c ∙ ∆T m = 50 g
q = (50 g)(4.184 J/ g°C)(10°C) ∆T = 10°C
q = 2092 J c = 4.184 J/ g°C
q = ? 2092 J
Beaker B
q = m ∙ c ∙ ∆T m = 100 g
q = (100 g)(4.184 J/ g°C)(10°C) ∆T = 10°C
q = 4184 J c = 4.184 J/ g°C
q = ? 4184 J
3. How much heat is required to raise the temperature of 789 g of liquid ammonia from 25.0°C
to 82.7°C? Remember to subtract 82.7°C from 25.0°C to determine ∆T, as we usually do not use
negative temperatures, yet.
q = m ∙ c ∙ ∆T m = 789 g
q = (789 g)(4.70 J/ g°C)(57.7°C) ∆T = 57.7°C
q = 213968.91 J c = 4.184 J/ g°C
q = 214 Kj q = ? 214 Kj
melting boiling/vaporizing
Solid -----> Liquid -----> Gas
<----- <-----
solidifying/freezing condensing
Where H is the enthalpy change in Kj (kilojoules), n is the number of moles in mols, and ∆H
(vaporization, condensation, melting, freezing, etc.) is the molar enthalpy in Kj/mol. Moreover,
the value for ∆H is usually found in a table that is already provided, or easily found.
1 mol
8.2 g of H20 = = 0.46 mols of H20
18.02 g
H = n ∙ ∆H H = ? 2.77 Kj
H = (0.46 mols)(6.02 Kj/mol) n = 0.46 mols
H = 2.77 Kj ∆H = 6.02 Kj/mol
2. What mass of Diethly Ether, C4H10O, can be vaporized by adding 80.7 Kj of heat?
H = n ∙ ∆H H = 80.7 Kj
80.7 Kj = n (29 Kj/mol) n = ? 2.78 mols
80.7 Kj ÷ 29 Kj/mol = n ∆H = 29 Kj/mol
2.78 mols = n
Things to Remember:
• The values of “c” changes based on its physical state (“q”) on the curve.
• Remember that, when you are drawing/determining Total Energy Changes (Curves), use
the following formulas: q = m ∙ c ∙ ∆T & H = n ∙ ∆H.
(a) q = m ∙ c ∙ ∆T m = 532.1 g
q = (532.1 g)(4.184 J/g°C)(45.21 °C) ∆T = 45.21°C
q = 100651.312 J c = 4.184 J/g°C
q = 100.7 Kj q = ? 100.7 Kj
H = n ∙ ∆H H = ? 177.7 Kj
H = (29.52 mol)(6.02 Kj/mol) n = 29.52 mol
H = 177.7 Kj ∆H = 6.02 Kj/mol
1 mol
532.1 g of H2O = = 29.52 mols of H2O
18.02 g
(b)
Etotal = q + H
Etotal = 100.7 Kj + 177.7 Kj
Etotal = 278.4 Kj
2. Calculate the total heat released when 200 g of water vapor at 300.0°C is cooled until it
reaches -20.0°C. The specific heat capacity of ice is 2.01 J/g°C. The specific heat capacity of
water vapor is 2.01 J/g°C.
(a) Draw a heating curve.
H1 = n ∙ ∆H H1 = ? 451.77 Kj
H1 = (11.1 mols)(40.7 Kj/mol) n = 11.1 mols
H1 = 451.77 Kj ∆H = 40.7 Kj/mol
q2 = m ∙ c ∙ ∆T m = 200 g
q2 = (200g)(2.01 J/g°C)(200 ∆T = 100°C
q2 = 40200 J c = 2.01 J/g°C
q2 = 40.2 Kj q1 = ? 40.2 Kj
H2 = n ∙ ∆H H2 = ? 66.82 Kj
H2 = (11.1 mols)(6.02 Kj/mol) n = 11.1 mols
H2 = 66.82 Kj ∆H = 6.02 Kj/mol
q3 = m ∙ c ∙ ∆T m = 200 g
q3 = (200g)(2.01 J/g°C)(-20.0°C) ∆T = 45.21°C
q3 = -8040 J c = 4.184 J/g°C
q3 = -8.04 Kj q3 = ? -8.04 Kj
q3 = + 8.04 (we are only using + right now)
1 mol
200 g of H2O = = 11.1 mols of H2O
18.02 g
Etotal = q1 + h1 + q2 + h2 + q3
Etotal = 80.4 Kj + 451.77 Kj + 40.2 Kj + 66.82 Kj + 8.04 Kj
Etotal = 647.23 Kj
Things to Remember:
• For questions such as the one featured above, repeat “q = m ∙ c ∙ ∆T & H = n ∙ ∆H” until
there are no more “q#” or “H#” to solve for. Moreover, remember that the values of “c”
changes based on its physical state (“q”) on the curve.
Where n is the number of moles in mols, and ∆H (vaporization, condensation, melting, freezing,
etc.) is the molar enthalpy in Kj/mol, m is the mass in g (grams), c is 4.184 J/g°C, and ∆T is the
change in temperature in °C (degrees Celsius).
Things to Remember:
• Simple Calorimeters always involves water. Any talk of water (warming or cooling) in your
question means you are using a Simple Calorimeter.
• You are usually always solving for “n” or “∆H”.
Bomb Calorimeter:
Hsystem = qcal
n ∙ ∆H = C ∙ ∆T
Where n is the number of moles in mols, and ∆H (vaporization, condensation, melting, freezing,
etc.) is the molar enthalpy in Kj/mol, C is the specific heat capacity of the calorimeter in Kj/°C,
and ∆T is the change in temperature in °C (degrees Celsius).
Things to Remember:
• Bomb Calorimeters never involve water.
• You are usually always solving for “n” or “∆H”.
• Always include Hsystem = qcal above your formula.
• Combustion is usually involved with Bomb Calorimeters.
1 mol
4.6 g of LiCl = = 0.11 mols of LiCl
42.4 g
2. The molar enthalpy of combustion for a gasoline assumed to be octane (C8H18) is -1.3
Mj/mol. A particular engine has a heat capacity of 105 Kj/°C. What is the minimum mass of
octane that must be burned to change the temperature of an engine from 18°C to 120°C?
114.26 g
8.24 mols of C8H18 = = 941.50 g of C8H18
1 mol
Things to Remember:
• Exothermic Gives off heat (Increase Temp)(Increase T) – ∆H is negative
Things to Remember:
• You are trying to obtain an overall formula that is the same as your “Target”.
• You may need to multiply or divide one of your “Givens”.
• You may need to reverse one of your “Givens,” but if you do, be sure to change the sign of
the “∆H°r”. For example: if it is +50 Kj, you must change it to -50 Kj, and vice-versa.
• Be sure to watch what state each compound is in ((g), (l), (s)). The question you are being
asked may try to trick you!
Where ∆H°rxn is the reaction and is in Kj, ∑ simply means the “Sum of”, n is the number of mols
from the balanced chemical equation, ∆H°f products is the standard heat of formation for each of
the products listed in Kj/mol, and ∆H°f reactants is the standard heat of formation for each of the
reactants listed in Kj/mol.
Things to Remember:
• The values of both “∆H°f products” and “∆H°f reactants” are found in tables. If “∆H°f
products” or “∆H°f reactants” are listed in the Periodic Table, then the value is automatically
zero!
Endothermic Reaction
Products must have a higher energy (Kj)
than reactants (low).
Things to Remember:
• If the products are below the reactants, then your value of ∆H°rxn will be negative. If the
products are above the reactants, then your value of ∆H°rxn will be positive.