Chemistry141

Exam 1 F05 A

Name _______________________________________________
SHOW WORK for all Calculations

1. Determine the number of grams of S3O8Cl2. that contain 15.65 g of chlorine.

(8 points)

2. Calculate the number of atoms of nitrogen in 1.45x10-9 g of [Co(NH3)5Cl]Cl2 .

(8 points)

3. Determine the grams of Mg3(PO4)28H2O that contain 1.750 moles of water.

(8 points)

4. Nomenclature

(20 points)

Write names for:

Write formulas for:

Mg(IO2)2 ________________________________ lead(II) dichromate ____________________________

H2SO3(aq) _______________________________ zinc sulfate heptahydrate _______________________
BiBr3 ___________________________________ diboron tetrachloride ___________________________
Sr(NO3)2 _______________________________ tin(IV) phosphide _____________________________
UF6 ____________________________________ mercury(II) cyanide ___________________________
Au2S3 __________________________________ aluminum thiosulfate __________________________
K2O2 __________________________________

tungsten(V) oxide __________________________

(NH4)2CO3 _______________________________ sodium acetate _______________________________

CaHSO4 _________________________________ hypochlorous acid ___________________________
C3H8 ___________________________________ chromium(III) hydroxide ______________________

5. Fill in the blanks.

(28 points)

A vanadium(II) ion has ____________ electrons and __________ protons.

One phosphide ion has ___________ protons and ___________ electrons.
A single isotope of cadmium-119 has _____ protons and ______ neutrons.
Calculate and express 748563.50.00356 to correct significant figures is _______________.
Add 0.05658 + 4.111 + 7.6 and express to correct significant figures _________________.
96.0 amu of ozone, O3 , has __________ oxygen atoms and _____________ ozone molecules.
1 mole of CuSO45H2O has _______________ Cu2+ ion(s) and five _____________ of water.
1 molecule of a compound has 12.0 amu of hydrogen and 72.0 amu of carbon.
The compound has empirical formula _____________ and molecular formula__________________.

6. Circle all of the following:

which are mixtures:

(8 points)
H2O(l)

which have a positive charge:

which are halogens:
which are nonmetals:

coffee

NaCl(aq)

neon nucleus
hydrogen

sodium

argon

neutron

nitrogen

selenium

mercury

lead

K2SO4(s)

carbon monoxide gas

potassium atom
iodine
carbon

helium

cation

7. A certain compound is 85.27 % lanthanum and 14.73 % oxygen . Determine the empirical formula of the
compound.
(8 points)

8. Strontium has four naturally occurring isotopes (with mass and % abundance):
84
Sr 83.91340 amu
0.56%
86
Sr 85.90927 amu
9.86 %
87
Sr 86.90884 amu
7.00 %
88
Sr 87.90562 amu
82.58 %
Calculate the number of 84Sr isotopes in 6.00 g of naturally occurring strontium.

(8 points)

9. 0.250 pound of chromel wire costs $41.69 Also 200. meters of the wire has mass 0.873 kilograms.
Calculate the number of centimeters of wire worth $1.50
(8 points)

10. Tungsten is refined from ferberite, which is 60.54 % tungsten.

6.55 g/cm3 and is 8.49 % ferberite. Use dimensional analysis.
(ore = ferberite + rock

and

The ore containing ferberite has density

(16 points)

ferberite = tungsten + iron + oxygen )

a. Calculate the kilograms of ore in 12.0 cubic feet of the ore.

b. How many grams of the ore contain exactly 175.0 grams of pure tungsten?

1. 332.07 + 816.00 + 235.45 = 295.1

? g S3O8Cl2 = 15.65 g Cl

295.1 g S3O8Cl 2
= 65.14 g S2O8Cl2
2 35.45 g Cl

2. 58.93 + 514.01 + 151.008 + 335.45 = 250.45

? atoms N = 1.45x10-9 g cmpd

cmpd = [Co(NH 3)5Cl]Cl2

106 g
5 mol H
6.022x10 23 atoms N

= 1.74x107 N atoms
1 g 250.45 g cmpd
1 mol N

3. 324.305 + 230.97 + 816.00 + 818.016 = 407.0

? g Mg3(PO4)28H2O = 1.750 mol H2O
4. magnesium iodite
bismuth(III) bromide
uranium(VI) fluoride
potassium peroxide
calcium bisulfate

407.0 g Mg 3 (PO4)2 8H 2 O
= 89.03 g Mg3(PO4)28H2O
8 mol H 2 O

sulfurous acid
strontium nitrate
gold(III) sulfide
ammonium carbonate
propane

PbCr2O7
B2Cl4
Hg(CN)2
W2O5
HClO(aq)

ZnSO47H2O
Sn3P4
Al2(S2O3)3
NaC2H3O2
Cr(OH)3

5. vanadium(II) = V2 has 21 e and 23 p

phosphide = P3 has 15 p+ and 18 e
119
Cd has 48 p+ and 71 n0
748563.50.00356 = 2664.9 2.66x103
0.05678 + 4.111 + 7.6 = 11.76758 11.8
96.0 amu ozone, O3 = 6 O atoms + 2 O3 molecules
1 mole CuSO45H2O = 6.022x1023 Cu2+ ions and 5 moles of water
Empirical formula CH2 and molecular formula C6H12
6. coffee and NaCl(aq) are mixtures
iodine is a halogen
7. 86.27 g La
14.73 g O

1 mol La
= 0.6211
138.91 g La

0.6211
= 1.00
0.6211

1 mol O
= 0.9206
16.00 g O

0.9206
= 1.482
0.6211

8. ? atoms 84Sr = 6.00 g Sr

9. ? cm wire = $1.50

12

=2

1.4822 = 2.96 3 so La2O3

6.022x1023 atoms Sr
0.56 84 Sr atoms

= 2.31x1020 atoms 84Sr

87.62 g Sr (mixed atoms) 100 Sr mixed atoms

0.25 lb 453.6 g 1 kg
200 . m 100 cm

= 93.5 cm
$41 .69
1 lb
1000 g 0.873 kg
1m

10. a. ? kg ore = 12.0 ft

3

123 in3
1 ft

b. ? g ore = 175.0 g W
A

neon nuclei and cations have positive charges

argon and carbon are nonmetals

2.543 cm3
1 in

6.55 g ore
3

1 cm

1 kg
1000 g

= 2.23x103 kg ore

100.0 g ferberite
100 g ore

= 3405. g ore
60.54 g W
8.49 g ferberite

Fa 05