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1.2 Relevant identified uses of the substance or mixture and uses advised against Product use : For research use only. Not for use in diagnostic procedures. 1.3 Details of the supplier of the safety data sheet AB SCIEX Pte. Ltd. 110 Marsh Drive Foster City, CA USA 94404 1-877-740-2129 e-mail address of person responsible for this SDS : msds.inquiry@absciex.com
1.4 Emergency telephone number National advisory body/Poison Centre Telephone number : Chemtrec : 1-800-424-9300 (24H) Supplier Telephone number : 1-877-740-2129 (8:30A PT - 5:00P PT)
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
: Danger : Highly flammable liquid and vapour. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. : Wear protective gloves. Wear eye or face protection. Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Avoid breathing vapour. Wash hands thoroughly after handling. : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Response
: Store locked up. Store in a well-ventilated place. Keep cool. : Dispose of contents and container in accordance with all local, regional, national and international regulations. : Not applicable.
Special packaging requirements Containers to be fitted : Not applicable. with child-resistant fastenings Tactile warning of danger : Not applicable.
2.3 Other hazards Substance meets the criteria for PBT according to Regulation (EC) No. 1207/2006, Annex XIII
Substance meets the : Not available. criteria for vPvB according to Regulation (EC) No. 1207/2006, Annex XIII Other hazards which do not result in classification : Not available.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
See section 16 for the full text of the Rphrases declared above
There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the substance and hence require reporting in this section. Type [A] Constituent [B] Impurity [C] Stabilising additive Occupational exposure limits, if available, are listed in Section 8.
Ingestion
Protection of first-aiders
4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Date of issue/Date of revision : 10/30/2010. 3/13
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
4.3 Indication of any immediate medical attention and special treatment needed Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment.
5.2 Special hazards arising from the substance or mixture Hazards from the : Highly flammable liquid and vapour. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The substance or mixture vapour/gas is heavier than air and will spread along the ground. Vapours may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Hazardous combustion products : Decomposition products may include the following materials: carbon dioxide carbon monoxide
: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. 4/13
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
6.3 Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. : See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
Derived effect levels No DELs available. Predicted effect concentrations No PECs available. 8.2 Exposure controls Appropriate engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts.
Skin protection
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
Body protection
Respiratory protection
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
: Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. : Reactive or incompatible with the following materials: oxidizing materials. peroxides acids alkalis Ammonia.
: Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Conclusion/Summary : Not available. Sensitiser Conclusion/Summary : Not available. Mutagenicity Conclusion/Summary : Not available. Carcinogenicity Conclusion/Summary : Not available. Reproductive toxicity Conclusion/Summary : Not available. Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Product/ingredient name ethanol Category Category 3 Route of exposure Not determined Target organs Respiratory tract irritation and Narcotic effects 8/13
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
Potential acute health effects Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Ingestion : Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach. Skin contact : No known significant effects or critical hazards. Eye contact : Causes serious eye irritation. Symptoms related to the physical, chemical and toxicological characteristics Inhalation : Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness Ingestion Skin contact Eye contact : No specific data. : No specific data. : Adverse symptoms may include the following: pain or irritation watering redness
Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects Not available. Conclusion/Summary General Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Other information : Not available. : No known significant effects or critical hazards. : No known significant effects or critical hazards. : : : : : No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Not available.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
12.2 Persistence and degradability Conclusion/Summary : Not available. 12.3 Bioaccumulative potential Product/ingredient name ethanol 12.4 Mobility in soil Soil/water partition coefficient (KOC) Mobility LogPow -0.32 BCF Potential low
12.5 Results of PBT and vPvB assessment PBT : No. P: Not available. B: Not available. T: No. vPvB : Not available. vP: Not available. vB: Not available. 12.6 Other adverse effects : No known significant effects or critical hazards.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user Additional information
II No.
II Yes.
II No.
II No.
Not available.
Not available.
Not available.
Not available.
Hazard identification number 33 Limited quantity LQ4 CEFIC Tremcard 30S1170 Special provisions 144 601 Tunnel code D/E
Passenger and Cargo Aircraft Quantity limitation: 5 L Packaging instructions: 305 Cargo Aircraft Only Quantity limitation: 60 L Packaging instructions: 307 Limited Quantities Passenger Aircraft Quantity limitation: 1 L Packaging instructions: Y305
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
: Not available.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
: : : :
This material is listed or exempted. Not listed Not listed Not listed
: Not listed
: Not listed
: Not listed
: Not listed
: Not available.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ETHANOL
Full text of classifications : F - Highly flammable [DSD/DPD] Date of printing : 10/30/2010. Date of issue/ Date of : 10/30/2010. revision Date of previous issue : No previous validation Version : 1 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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