THERMODYNAMIC:The chemical-reaction is controlled by 2-factor; 1) Enthalpy; 2) Entropy; When these both factor( Enthalpy+Entropy) Joined together so it Produced new

factor that is FREEENERGY;Bio-Physic,P.g#1 FREE-ENERGY:The Free-Energy is formed by Adding enthalpy+Entropy; 1) Enthalpy:The Enthalpy is defined as,the change in heat contact of a system,is called Enthalpy;Its denoted by reaction in Enthalpy-occurs; ;On the
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Base of EnthalpyThere are 2-Types of a) Exothermic-Reaction:If any system release some energy is called ExothermicReaction,If any system release some energy so,its Enthalpy is negative; Enthalpy;

b) Endothermic-Reaction:If any system Absorbed some energy is called EndothermicReaction;& then the Enthalpy of this system is Positive;Enthalpy= ; First-Law-Of-Thermodynamic:In the 1thLaw-Of-ThermodynamicThe Energy (Heatenergy)-can never be created nor be destroyed,but it can change its formed;the total energy in the Universe(system) remain constant;
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Entropy:Its define as,The measure of disOrder(or Random-ness) of a system,Entropy is denoted by 2-Types; 1. +ve Entropy:The +ve Entropy are those Entropy in which reactants have greater( ) Order then the Products; ice freaze water no-order in-order; ,It has

2. ve Entropy:The ve Entropy are those entropy in which a chemical-reaction whose has greater order of Product then Reactants;

In ve Entropy,its has decrease the Entropy of a system;

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Free-Energy:The change in free energy is calculated by amount of energy required to the system to Performed some-worked at a constant temperature & Pressure;Its denoted by Free-Energy= =

where, energy; enthalpy;

=change in free =change in =change in

entropy;T=Absolute-Temperature in [Co+273=k];There are 2-types of free-energy(i-e) a) +ve Free-Energy:When [

Bio-Physic,P.g#5

],then

there will be net gain in energy of system & due to this the reaction will not run forward;(e.g)
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b) ve Free-Energy:When run forward;(e.g) c)

then

system will lose energythen reaction will

No-Change-In-Free- Energy:When then system will neither gain nor lose any energy so, the reaction will not run in any direction,This is called an Equilibrium-state;(e.g) ;

 Second-Law-Of-Thermodynamics:All Physical & Chemical reaction run in such a manner that the entropy(Random-ness)of a system increase( ) to the maximum Untill equillibrium is achived;

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