Set III

Section A
Answer all questions /Jawab semua soalan 1. The body of an aeroplane is made of duralumin. What is the main metal in duralumin? Badan kapal terbang dibuat daripada duralumin. Apalah logam utama dalam duralumin? A. Iron / Besi B. copper / kuprum C. aluminium / aluminum D. magnesium/magnesium

2.

Why is ceramic used form the wall of a nuclear reactor? B. ceramic is malleable/seramik mudah dibentuk

Mengapakah seramik digunakan sebagai dinding reaktor nuclear?

A. Ceramic is very hard /seramik sangat keras

C. ceramic is inert towards chemicals/seramik lengai terhadap bahan kimia D. ceramic can withstand high temperature/seramik tahan suhu tinggi

3.

The diagram shows the stages in the production of sulphuric acid usng the contact process.

Gambarajah di bawah menunjuukkan peringkat-peringkat dalam pembuatan asid sulfuric menggunakan proses sentuh.

Sulphur Sulfur

sulphur dioxide sulfur dioksida

O2

O2 sulphur concentrated sulphuric acid trioxide sulfur asid sulfuric pekat trioksida substance X sulphuric acid oleum asid sulfuric bahan X
C. oxygen /oksigen D. sulphur dioxide/sulfur dioksida

what is substance X? /apakah bahan X? A water / air B. sulphur / sulfur

4. The diagram shows polymerization process. /gambarajah menunjukkan suatu proses pempolimeran.

Substance R Bahan R

substance S bahan S

Which of the following properties is identical for substances R and S?

Antara sifat berikut yang manakah sama bagi bahan R dan bahan S?

A. Melting point/takat lebur B. density/ketumpatan C. relative molecular mass/jisim molekul relative

D. percentage composition/peratusan komposisi

5.

The diagram shows the energy profile of a reaction. Ea is the activation for this reaction.

Gambarajah di bawah menunjukkan profil tenaga bagi suatu tindak balas. Ea ialah tenaga pengaktifan bag tindak balas itu.

What will change the activation energy from Ea to Ea1 ? /apakah yang akan mengubah tenaga pengaktifan daripada
Ea to Ea1 ?

A. Temperature /suhu B. catalyst/mangkin D. total surface area /jumlah luas permukaan 6.

C. concentration/kepekatan

Which of the following explains the meaning of effective collision?/yang manakah antara berikut menjelaskan
perlanggaran berkesan?

A. The collision where its energy is less than the activation energy
Perlanggaran yang tenaganya kurang daripada tenaga pengaktifan.

B. The collision that has a low energy /perlanggaran yang mempunyai tenaga yang rendah C. The collision which takes place before a reaction /perlanggaran yang berlaku sebelum suatu tindak balas D. The collision that causes a reaction ./perlanggaran yang menghasilkan tindak balas 7. The diagram shows energy profile of a reaction. /gambarajah menunjukkan profil tenaga untuk satu tindak balas.

Which of the following is true about the diagram? Antara berikut, yang manakah benar tentang gambarajah itu? A. The reaction is endothermic /tindak balas adalah endotermik. B. The activation energy is y kJ / tenaga pengaktifan ialah y kJ C. The heat of reaction is (y x) kJ /haba tindak balas ialah (y x) kJ D. y value increases with the presence of a catalyst / nilai y bertambah dengan kehadiran mangkin 8. The diagram shows the set up of the apparatus for an experiment to determine the rate of reaction between sodium thiosulphate and sulphuric acid.
Gambarrajah menunjukkan susunan radas bagi eksperimen untuk menentukan kadar tindak balas antara natrium tiosulfat dengan asid sulfuric.

Which of the following combinations of conditions take the shortest time for the mark X to disappear from sight?
Antara kombinasi keadaan berikut yang manakah mengambil masa paling singkat untuk tanda X hilang ?

In an experiment, the decomposition of 25 cm3 of 0.1 mol dm-3 hydrogen peroxide solution produces oxygen gas. The graph of the volume of oxygen gas against time is drawn and curve P is obtained. Dalam satu eksperimen, penguraian 25 cm3 larutan hydrogen peoksida0.1 mol dm-3 menghasilkan gas oksigen. 9.
Graf isipadu gas oksigen melawan masa dilukis dan lengkung P diperoleh.

If the experiment is repeated using another solution, which solution will produce curve Q?
Sekiranya eksperimen diulang dengan menggunakan larutan lain, larutan manakah yang akan menghasilkan lengkung Q?

A. B. C. D.

25 cm3 of 0.15 mol dm -3 hydrogen peroxide/25 cm3 hidrogen peroksida 0.15 mol dm -3 20 cm3 of 0.15 mol dm -3 hydrogen peroxide/20 cm3 hidrogen peroksida 0.15 mol dm -3 15 cm3 of 0.15 mol dm -3 hydrogen peroxide/15 cm3 hidrogen peroksida 0.15 mol dm -3 20 cm3 of 0.25 mol dm -3 hydrogen peroxide/15 cm3 hidrogen peroksida 0.25 mol dm -3

10. The manufacturing of sulphuric acid involves several reactions. Which of the following equations represents the sulphuric acid reaction that uses a catalyst?
Pembuatan asid sulfuric melibatkan beberapa tindak balas. Antara persamaan berikut, yang manakah mewakili tindak balas asid sulfuric yang menggunakan mangkin?

A. S + O2 SO2 C. SO3 + H2SO4

H2S2O7

B. 2SO2 + O2 2SO3 D. H2S2O7 + H2O

2H2SO4

11. A. B. C.

Which of the following is not a characteristic of a catalyst?Antara yang berikut, yang manakah bukan ciri mangkin? A catalyst is specific in its reaction /mangkin adalah khusus dalam tindakannya. A catalyst influences the quantity of product of a reaction/Mangkin mempengaruhi kuantiti hasil tindak balas The chemical property of a catalyst remains unchanged at the end of the reaction
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Sifat kimia mangkin tetap tidak berubah di akhir tindak balas

D. Only a little amount of a catalyst is needed to influence the rate of reaction/

Hanya sedikit mangkin diperlukan untuk mempengaruhi kadar tindak balas.

12. The following diagram shows the structural formula of a polymer.

Rajah di bawah menunjukkan formula struktur satu polimer.

What is the structural formula of its monomer? /apakah formula struktur monomernya?

13. The diagram below shows the effect of a weight that is dropped onto a composite substance and its original component. / rajah di bawah menunjukkan kesan satu beban yang dijatuhkan ke atas bahan komposit dan komponen asalnya.

What is the characteristic of the composit substance? /apakah sifat yang dimiliki oleh bahan komposit itu? A. Strong and hard /kuat dank eras B. strong and elastic /kuat dan kenyal C Hard and ductile /keras dan mulur D. elastic and ductile /kenyal dan mulur 14. The following statements are related to the collision theory of a reaction.
Pernyataan berikut adalah berkenaan teori perlanggaran suatu tindak balas.

I.

The total surface area of the reactant particles increases.

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Jumlah luas permukaan zarah bahan tindak balas bertambah

II. III. IV.

The kinetic energy of the reactant particles increases.

Tenaga kinetic zarah bahan tindak balas bertambah

The frequency of the collision between the reactant particles increases

Frekuensi perlanggaran antara zarah bahan tindak balas bertambah

The number of reactant particles per unit volume increases

Bilangan zarah bahan tindak balas per unit isipadu bertambah

Which of the following combination is true about the effect of the rise in temperature on the reactant particles?
Yang manakah antara kombinasi berikut mengenai kesan peningkatan suhu atas zarah bahan tindak balas adalah benar?

A. I and II only / I dan II sahaja B. II and III only / II dan III sahaja C. III and IV only / III dan IV sahaja D. I and IV only / I dan IV sahaja 15. The diagram shows an electric cable supported by substance N.
Gambar rajah berikut menunjukkan kabel elektrik yang disokong oleh bahan N.

Substance N has the following properties. /bahan N mempunyai sifat berikut: Strong /kuat Can withstand erosion/tahan hakisan Can withstand weathering/tahan luluh bawa Not an electrical conductor/bukan konduktor elektrik Which of the following is substance N? /yang manakah bahan N? A. Concrete /konkrit B. marble /marmar C. ceramic /seramik D. soda lime glass/kaca soda kapur 16. If you want to cook 100 potatoes within a short time, which is the most suitable method?
Jika anda ingin memasak 100 biji kentang dalam masa yang singkat, apakah langkah yang paling sesuai dilakukan?

A. B. C. D.

Boil the potatoes in a pan /merebus kentang dalam kuali leper Boil the potatoes in a pressure cooker /merebus kentang dalam periuk tekanan Steam the potatoes in a steamer/mengukus kentang dalam pengukus Fry the potatoes in a wok /menggoreng kentang dalam kuali

17. Which of the following reactants produces the highest rate of reaction with zinc powder?
Bahan tindak balas yang manakah akan menghasilkan kadar tindak balas tertinggi dengan serbuk zink?

18. Polythene is a polymer that is formed from the combination of ethene molecules. Which of the following represents the
process of the formation of polyethene?
Polieten ialah polimer yang dibentuk daripada kombinasi molekul-molekul eten. pembentukan polieten? Yang manakah antara proses-proses berikut mewakili

19. The diagram shows the arrangement of atoms in four metals.

Rajah berikut menunjukkan sususnan atom dalam empat logam.

Arrange the metals from the most easily malleable to the most difficult?
Susun logam tersebut daripada yang paling mudah ditempa kepada yang paling sukar.

A. R, P, Q, S

B. Q, P, R, S

C. Q, S, P, R

D. S, Q, R, P

20. The diagram below shows the apparatus set up for an experiment to determine the rate of reaction.
Rajah di bawah menunjukkan susunan radas eksperimen untuk menentukan kadar tindak balas.

Which of the following techniques is the most suitable to determine the rate of reaction?
Teknik yang manakah paling sesuai untuk menentukan kadar tindak balas itu?

A. Record the time as soon as precipitate is formed./Rekod masa sebaik sahaja mendakan terbentuk B. Record the time taken to obtain the maximum temperature
Rekod masa diambil apabila suhu maksimum tercapai 6

C. Record the time as soon as the cross mark cannot be seen

Rekod masa sebaik sahaja pangkah itu tidak kelihatan

D. Record the time taken for the change of the pH value untuk a fixed value is obtained.
Rekod masa yang diambil bagi perubahan nilai pH sehingga satu nilai tetap diperoleh.

21. A decorative glassware maker encountered problem on his products which are fragile. He needs another material which is transparent but not fragile to replace the glass. What is the most suitable material?
Seorang pembuat barang hiasan kaca menghadapi masalah bahan keluarannya mudah pecah. Dia memerlukan satu bahan lain yang bersifat lutsinar tetapi tidak mudah pecah untuk menggantikan kaca. Apakah bahan yang paling sesuai?

A. Polyethene /polieten B. polypropene /polipropen C. polychloroethene/polikloroeten D. polimethylmethacrylate/polimetilakrilat 22. Which of the following is the correct match of a low rate of reaction and a high rate of reaction?
Antara padanan berikut, yang manakah betul tentang tindak balas yang mempunyai kadar tindak balas rendah dan kadar tindak balas tinggi?

A B

Low rate of reaction/kadar tindak balas rendah High rate of reaction/kadar tindak balas tinggi Neutralization between hydrochloric acid and Iron rusting /pengaratan besi sodium hydroxide solution/peneutralan antara asid
hidroklorik dan larutan natrium hidroksida

Double decomposition between lead(II) nitrate Neutralization between hydrochloric acid and solution and potassium iodide solution/penguraian sodium hydroxide solution/peneutralan antara asid
ganda dua antara larutan plumbum(II) nitrat dan larutan kalium iodida Iron rusting /pengaratan besi hidroklorik dan larutan natrium hidroksida

C D

Fermentation of glucose solution /penapaian larutan

glukosa

Fermentation of glucose solution /penapaian larutan

glukosa

Double decomposition between lead(II) nitrate solution and potassium iodide solution/penguraian
ganda dua antara larutan plumbum(II) nitrat dan larutan kalium iodida

23. The table below shows the volume of carbon dioxide gas,CO 2, collected in the reaction between limestone powder and dilute hydrochloric acid.
Jadual berikut menunjukkan isipadu gas karbon dioksida, CO2, yang dikutip dalam tindak balas antara serbuk batu kapur dan asid hidroklorik cair.

Time/min 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Masa/min Volume of gas /cm3 0.0 4.5 7.5 10.0 12.5 14.5 16.0 17.0 Isipadu gas /cm3 What is the average rate of reaction during the second minute?/Berapakah kadar tindak balas purata dalam minit kedua?

24. Which of the following shows the arrangement of the atoms in an alloy? Antara yang berikut, yang manakah menunjukkan
susunan atom dalam aloi?

25. A. B. C.

Which of the following is a characteristic of a catalyst? Yang mana antara berikut ialah sifat suatu mangkin? It changes the amount of products in the reaction.Ia mengubah amaun hasil tindak balas Chemically unchanged at the end of the reaction Tidak berubah secara kimia pada akhir tindak balas Equal amount of catalyst and reactants are needed for the reaction

Amaun yang sama bagi mangkin dan bahan tindak balas diperlukan untuk tindak balas

D. The amount of the catalyst decreases at the end of the reaction

Kuantiti mangkin berkurang pada akhir tindak balas.

Answers to multiple choice questions.

1 11 21 2 12 22 3 13 23 4 14 24 5 15 25 6 16 7 17 8 18 9 19 10 20

Section B 1. (a) write the chemical equation for the reaction used in Haber process for the industrial production of ammonia.
Tulis persamaan kimia bagi tindak balas yang digunakan dalam proses Haber bagi penghasilan ammonia secara industry.

[2 markah] (b) the graph below shows the percentage of ammonia production from Factory P and its competitor, Factory Q.
Graf berikut menunjukkan peratusan penghasilan ammonia daripada Kilang P dan persaingnya, Kilang Q.

(i) Based on the above graph, compare the percentage of ammonia produced at the pressure of 200 atm from each factory.
Berdasarkan graf tersebut, bandingkan peratusan ammonia yang dihasilkan pada tekanan 200 atm daripada setiap kilang itu.

[1 markah] (ii) Based on your comparison in (b)(i) above, what is the effect of temperature on the percentage of ammonia produced?
Berdasarkan perbandingan anda dalam (b) (i) di atas, apakah kesan suhu atas peratusan ammonia yang dihasilkan?

.[1 markah] (iii) One method of increasing the percentage of ammonia is by increasing the pressure. State one problem that may arise from this method.
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Satu kaedah untuk menambah peratusan ammonia ialah dengan menambahkan tekanan. Nyatakan satu masalah yang mungkin dihadapi dalam kaedah ini.

[1 markah] (iv) How may the problem in (b)(iii) be overcome?/Bagaimanakah masalah dalam (b)(iii) boleh diatasi? [1 markah] (c) Ammonia from the Haber process can be used to manufacture ammonium nitrate fertilizer, NH4NO3.
Ammonia dari proses Haber boleh digunakan untuk menghasilkan baja ammonium nitrat, NH4NO3 .

(i) State one other use of ammonium nitrate. /nyatakan satu lagi kegunaan ammonium nitrat. (ii) Complete the chemical equation below for the preparation of ammonium nitrate fertilizer.
Lengkapkan persamaan kimia berikut bagi penyediaan baja ammonium nitrat.

.[1 markah]

.. + NH4NO3 [2 markah] (iii) The apparatus below is used to make ammonium nitrate solution. Next to the arrow, draw a diagram of the set-up of the apparatus used in the preparation of ammonium nitrate crystals.
Radas di bawah digunakan untuk membuat ammonium nitrate. Selepas anak panah, lukis satu susunan radas yang digunakanj dalam penyediaan hablur ammonium nitrat.

2.

[2 markah] The diagram below shows two experiments to investigate one factor that influences the rate of a reaction.

Rajah di bawah menunjukkan dua eksperimen untuk menyiasat satu faktor yang mempengaruhi kadar tindak balas.

Experiment I

Experiment II

(a) What is the factor that influeces the rate of reaction in both experiments?
Apakh factor yang mempengaruhi kadar tindak balas dalam kedua-dua eksperimen itu?

[1 markah] (b) The reaction in the experiment is represented by the following equation:
Tindak balas eksperimen diwakili oleh persamaan berikut:

CaCO3 + 2HCl CaCl2 + CO2 + H2O (i) Among the products stated in the equation, which is the most suitable to be chosen to determine the rate of reaction?
Antara hasil tindak balas yang dinyatakan dalam persamaan, yang manakah paling sesuai dipilih untuk menentukan kadar tindak balas?

.[1markah] (ii) State one reason for choosing the product in (b)(i)./Nyatakan satu sebab bagi pemilihan anda dalam (b)(i). [1 markah] (c) State two controlled variables in both experiments. /nyatakan dua pemboleh ubah yang dimalarkan dalam kedua-dua eksperimen
itu.

1. 2. . [2 markah] (d) The results for both experiments are represented by the graph below.
Keputusan bagi kedua-dua eksperimen ditunjukkan oleh graf di bawah.

Based on the above graph /berdasarkan graf di atas, (i) Experiment II has a higher rate of reaction. How does the graph show this? Eksperimen II mempunyai kadar yang lebih tinggi. Bagaimanakah graf itu menunjukkan keadaan ini? .[1 markah] (ii) What has happened to the reaction at time x?Apa yang berlaku kepada tindak balas pada masa x? .[1 markah] (iii) Why are both curves at the same level after time x?
Mengapakah kedua-dua lengkung pada paras yang sama selepas masa x?

.[1 markah] / (d) What is the conclusion for both experiments? Apakah kesimpulan bagi kedua-dua eksperimen itu?
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..[1 markah] (f) Another experiment is carried out using excess calcium carbonate powder and dilute hydrochloric acid with different concentrations. Satu lagi eksperimen dijalankan dengan menggunakan serbuk kalsium karbonat berlebihan dan asid hidroklorik
cair dengan kepekatan berlainan.

Sketch the curve of concentration of dilute hydrochloric acid against time taken to collect a fixed quantity of the product.
Lakarkan satu lengkung bagi kepekatan asid hidroklorik cair lawan masa untuk mengutip suatu quantity yang tetap hasil.

Section C 1. A student carried out an experiment to investigate the rate of reaction between marble chips and hydrochloric acid. The table below shows the data obtained from the experiment.
Seorang murid menjalankan eksperimen untuk menyiasat kadar tindak balas antara ketulan marmar dengan asid hidroklorik. Jadual berikut menunjukkan data yang diperoleh daripada eksperimen.

Time/s Burette reading / cm3 Volume of gas evolved / cm3 3 Masa/s Bacaan buret/cm Isipadu gas terbebas /cm3 0 50.00 0.00 30 38.00 12.00 60 30.50 19.50 90 120 150 19.50 30.50 180 18.50 31.50 210 18.00 32.00 240 18.00 32.00 The diagram below shows the burette readings at 90 seconds and 120 seconds.
Rajah di bawah menunjukkan bacaan buret pada 90 saat dan 120 saat.

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(a) Based on diagram above, record the burette readings and volume of gas evolved at 90 seconds and 120 seconds in the table above.
Berdasarkan rajah di atas, rekod bacaan buret dan isipadu gas terbebas pada 90 saat dan 120 saat dalam jadual di atas. [3 markah]

(b) Based on the above table, state how the volume of gas evolved changes when the marble chips react with hydrochloric acid.
Berdasarkan jadual di atas, nyatakan bagaimana isipadu gas terbebas berubah apabila ketulan marmar bertindak balas dengan asid hidroklorik.

...........................................................................................................................................................................[3 markah] (c) based on this experiment, what is the meaning of the rate of reaction? Berdasarkan eksperimen ini, apakah maksud kadar tindak balas? [3 markah]

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