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Berrin Ylmaz Kordsa Global Endustriyel Iplik ve Kord Bezi San. ve Tic. A.S 17-19 November 2010, Mumbai - India
Financial Services
Cement
Energy
Retail
57,000 employees
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Worlds leading producer of industrial nylon 6.6, polyester yarns, tire cord fabrics and single end cords Leading supplier of textile reinforcement materials for the tire industry 36 years of expertise in reinforcement technologies Only company in the industry with a globally approved product portfolio
2010 Kordsa Global
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Industry Leader *
Nylon 6.6 Global Market Share
Kordsa Global, 34% Other, 14%
Producer A, 3% Producer B, 4% Producer C, 2% Producer D, 4% Producer E, 8% Producer H, 9% Producer I, 25% Producer G, 27%
Producer F, 31%
Only global company with a sizeable position in both industrial Nylon & PET Leading producer of Nylon 6.6 with 34% market share Worlds largest Tire Cord Fabric producer Growing in PET, 4th largest producer
* 2009 figures
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Worldwide Operations
Interkordsa GmbH Mhlhausen, Ger many
SEC
NY6.6, TCF
Kordsa China
NY6.6 TCF
Thai Indo Kordsa Ayutthaya, Thailand
NY6.6, TCF
Kordsa Argentina Buenos Aires
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Product Portfolio
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Hybrid cords
Aramide (Ar)
Rayon (Ry)
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Hybrid cords
Ply 1
Fiber A
Ply 2 Ply 3
Fiber B Fiber A or B
Ply 1
Fiber A
Ply 2 Ply 3
Fiber B Fiber A or B
RFL treatment S S
Cable
Fiber A+ Fiber B
Cable
Fiber A+ Fiber B
Hybrid cords
Hybrid cord features Combination of different materials Broad range of constructions are possible Properties can be engineered by changing Material, dtex, ply number, single and cable twist, dipping conditions PEN-NY hybrid cords Dtex PEN = 1100, 1670, 2200 Dtex NY66 = 940, 1400, 1880, 2100 Twist, tpm = 150 450 PEN ply number = 1 2 NY ply number = 1 2 Total ply number = 2 - 3 RY-PET hybrid cords Dtex RY = 1220, 1840, 2440 Dtex PET = 1100, 1440, 1670, 2200 Twist, tpm = 150 450 RY ply number = 1 2 PET ply number = 1 2 Total ply number = 2 - 3
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Ar-NY Hybrid cords Dtex Ar = 1100, 1670 Dtex NY66 = 940, 1400, 1880, 2100 Twist, tpm = 150 450 Ar ply number = 1 2 NY ply number = 1 2 Total ply number = 2 - 3 PET-NY Hybrid Cords Dtex PET = 1100, 1440, 1670, 2200 Dtex NY66 = 940, 1400, 1880, 2100 Twist, tpm = 150 450 PET ply number = 1 2 NY ply number = 1 2 Total ply number = 2 - 3
Hybrid cords
Aramide ~30 40 % loss in break str ~ 25 - 35% loss in modulus ~ 40 - 50% loss in LASE2% ~30 40% increase in brk.elongation >100% increase in EASL 66N
Nylon ~ 7-10% loss in break str ~ 30-40% loss in modulus ~ 15 - 40% loss in LASE2% ~ 7 - 30% increase in brk.elongation ~ 25 - 60% increase in EASL 66N
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Hybrid cords
Load elongation (%) curves of single ply twisted Ar and NY enables a broad range of hybrid cord structure
Contribution of aramide Tire production Running performance Low modulus at low elongations High modulus at high elongations
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Contribution of nylon
Hybrid cords
Hybrid ar dtex/ply ny dtex/ply Hybrid A 1100/2-2100/1 Hybrid B 1100/2-1880/1 Hybrid C 1100/1-1880/2 Hybrid D 1100/1-940/2 Hybrid E 1670/2-2100/1 Hybrid F 1670/2-1880/1 Hybrid G 1670/1-1880/2 Hybrid H 1670/1-940/2
Twist, tpm, ar/ny/cable 250/350/150 350/150/250 350/150/250 450/450/450 250/350/150 350/150/250 350/150/250 450/450/450
Breaking Strength, N 426 454 344 266 605 633 456 351
Elongation at 66N,% 1,1 2,8 4,3 6,6 1,0 2,8 4,8 6,4
Elongation at break,% 4,3 7,8 10,6 13,4 4,6 8,9 13,7 16,3
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Hybrid cords
Data Means
NY dtex 350 A R twist
NY dtex
AR twist
NY twist
8
300
6
250
Mean
Mean
4 940 10 1400 1880 C able twist 2100 150 250 350 A R ply 450 150 250 350 NY ply 450
940
2100
150
450
150
450
350
8
300
6
250
4
150 250 350 450 1 2 1 2
150
250
350
450
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Hybrid cords
80
60
Mean
40 940 100 1400 1880 Cable twist 2100 150 250 350 A R ply 450 150 250 350 NY ply 450
80
60
Based on Delta values and P values of response of means of %Retained Break. Str. after Fatigue
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Hybrid cords
Hybrid cords
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Hybrid cords
PET-NY hybrids
PET (based on dtex) ~10-25% loss in break str ~25-40% loss in modulus ~10-15% increase in brk.elongation ~ 40 - 50% increase in EASL 66N
Nylon ~7-10% loss in break str ~30-40% loss in modulus ~7 - 30% increase in brk.elongation ~ 25 - 60% increase in EASL 66N
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Hybrid cords
Effect of twist level on 1 ply PET-1 ply NY hybrid cord tensile, thermal and adhesion properties
PET-NY hybrids
Hybrid ny dtex/ply pet dtex/ply Hybrid I 1400/1-1670/1 Hybrid J 1400/1-1670/1 Hybrid K 1400/1-1670/1 Hybrid L 1400/1-1670/1 Nylon cord 1400/2 Polyester cord 1670/2
Elongation Elongation Shrinkage, at 66N,% at break,% % 5,6 7,1 9,1 7,9 9,9 4,0 15,1 18,6 21,2 15,5 25,0 12,6 1,8 2,3 2,6 2,3 3,3 1,5
Ref: Aye Ayta, Design of Nylon6.6/Polyester Hybrid cords and their properties, The Degree of Doctor of Philosophy, Kocaeli University, Kocaeli-2007 Strictly Confidential
Hybrid cords
Effect of twist level on 1 ply PET-1 ply NY hybrid cord fatigue properties - High twist level contributes
more to the fatigue performance
PET-NY hybrids
Fatigue behavior of polyester nylon hybrids changes based on twist level of the components and dtex. -1400*2 NY cords , twist range 270 470 tpm; breaking strength retention is above 80 95 %. - 1670*2 PET cords, twist 160, 310; breaking strength retention 20, 40%, twist 430 tpm strength retention 80 - 90 %. - PET-NY hybrid cords breaking strength retention 40 90 %.
Ref: Aye Ayta, Design of Nylon6.6/Polyester Hybrid cords and their properties, The Degree of Doctor of Philosophy, Kocaeli University, Kocaeli-2007
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Hybrid cords
Effect of NY and PET ply number on 2 ply PET-1 ply NY and 1 ply PET-2 ply NY hybrid cord tensile, thermal and adhesion properties
Hybrid ny dtex/ply pet dtex/ply Hybrid M 1100/2-1400/1 Hybrid N 1100/1-1400/2 Hybrid O 1100/2-1880/1 Hybrid P 1100/1-1880/2 Hybrid R 1670/2-1400/1 Hybrid S 1670/1-1400/2
Shrinkage, Thickness, % mm 2,0 2,5 2,1 3,0 1,9 2,4 0,70 0,68 0,72 0,88 0,84 0,82
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Hybrid cords
Effect of NY and PET ply number on 2 ply PET-1 ply NY and 1 ply PET-2 ply NY hybrid cord fatigue properties
- High NY content increases breaking strength retention
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Hybrid cords
Finite Element Analysis; Load distribution;
-one ply NY fiber in NY-PET hybrid carries more load and absorbs more energy compared to the one ply of two ply NY cord with same twist levels. -one ply PET fiber in NY-PET hybrid carries less load and absorbs less energy compared to the one ply of two ply PET cord with same twist levels. - The difference between NY and PET fibers lateral rigidness and modulus, PET resist more to the lateral deformation due to tension. Fracture Energy distribution; - PET contributes to fracture energy more than that of NY - Balance twist of single ply and cable donot effect the distribution - Same distribution was calculated for different balanced twist levels. - Unbalance twist levels may effect the load and breaking energy distributions.
Ref: Doan Sevim, Kordsa Global, Finite Element Analysis of Nylon-Polyester Hybrid Cords, Tire Strictly Confidential Technology
Hybrid cords
PET-NY hybrids
Hybrids vs 100%nylon66
Lower shrinkage/lower growth Lower raw material cost due to PET Reduced flat spotting contribution Good comfort
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Hybrid cords
Comparision of PEN-NY and PET-NY hybrid cord tensile, thermal and adhesion properties
- PEN-NY hybrids have lower breaking strength and breaking elongations -PEN-NY hybrids have higher modulus (autoyoung) - PEN-NY hybrids 70 g/denier , - PET-NY hybrids 60 g/denier. - PEN-NY hybrid have lower partial load elongation (66N) - PEN-NY and PET-NY have the same thermal shrinkage - PEN-NY and PET-NY have acceptable adhesion levels
Hybrid ny dtex/ply pet or pen dtex/ply Hybrid T 1400/1-1670/1 nypet Hybrid U 1400/1-1670/1 nypen
Adhesion, N 188
200/350/350
188
5,3
12,2
2,2
0,72
168
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Hybrid cords
Hybrid cords
RY-PET hybrids
In summary; Ar- NY hybrids provide a big mechanical property range between aramid and nylon. Better breaking strength, variable modulus, moderate shrinkage, good adhesion and optimized fatigue are achievable. PET-NY hybrids provide comparable breaking strength, variable modulus between polyester and nylon, controlled shrinkage, optimized dimensional stability. PEN-NY hybrid provides higher modulus compared to PET-NYhybrids. RY-PET hybrid provide better breaking strength, dimensional stability, less moisture sensitivity.
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Hybrid cords
Thank you
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