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Thermodynamics
What is Heat?
Perception as to hot and cold defined relative to our own body temperature, i.e. object is hotter or colder than oneself Objective measurement of temperature
I feel hot
Measuring temperature
Volume
Resistance
A bimetallic strip
Most materials get bigger when they get hot (but not water 0C > 4C gets smaller!)
Thermometer
Thin tube (Gives big length change for small increase in volume)
thermometer
Example
You have a (glass) jar and you cant get the metal lid off. What should you do:
a) ask your girlfriend b) run the jar & lid under cold water c) run the jar & lid under hot water
Solution:
a) ask your girlfriend b) run the jar & lid under cold water
Because the metal has a substantially higher coefficient of thermal expansion than the glass, heating them will make both of them bigger, but the metal will be more bigger.
The mercury in the thermometer must reach the same temperature as you Thermal Equilibrium!!
Insulation
A vacuum, polystyrene, fibreglass, plastic, wood, brick (low density/foam structure, poor electrical conductors)
Most metals (but stainless steel better than copper) e.g. gold contact used within IC chips to prevent heating Gases, liquids (high density, mobile, good electrical conductors)
If A and B are each in thermal equilibrium with C then A and B are in thermal equilibrium with L each other
=Temp
=Temp?
If Alfred and the Bread are the same temperature as Cliff then Alf is the same temperature as the Bread.
=Temp
Cliff Alf
Celsius (MP 0C 100C) Degrees Kelvin (MP 273.15 K BP 373.15 K) Degree Fahrenheit (MP 32 F BP 212F)
Absolute zero
Ideal gas has zero volume Resistance of metal drops to zero
Absolute zero, 0K
Lord Kelvin
William Thompson, born Belfast 1824 Student in Natural Philosophy Professor at 22! Baron Kelvin of Largs in 1897 A giant
Kelvin to Celsius
K
= C + 273.15 C = K - 273.15
Example
Convert the following temperatures into F and K Boiling water, 100C Freezing water, 0C Absolute zero, -273.15C
Type of thermometer
Change in electrical resistance (convenient but not very linear) Change in length of a bar (bimetallic strip) Change in volume of a liquid Change in volume of gas (very accurate but slow and bulky)
Heat
Internal
Energy
Temperature is a property that determines the direction of thermal energy transfer between two bodies in thermal contact.
Absolute temperature is a measure of the average kinetic energy of the molecules of a substance.
3 KEavg kT 2
Example
Heat (Energy)
Is the flow of energy in or out of a system. Heat (energy) flows because of temperature difference
Bigger
flow Less insulation give more heat flow for the same temperature difference
Heat will not flow between two bodies of the same temperature
Equilibrium
Two objects of different temperature when placed in contact will reach the same temperature
One cal raises one gram of water from 14.5C to 15.5C 1 cal = 4.186J Joules Experiment!
1st law of thermodynamics heat and work are both forms of energy
Change in temperature proportional to work done Showing equivalence of heat and mechanical energy
Joules Experiment
Internal Energy
energy is associated with intermolecular forces. energy includes both translational and rotational motion.
Kinetic
When the kinetic energy of the molecules become comparable to the energy required for separation the molecules change there position and separate (PE increase). This is a phase transition Melting or vaporizing
Avogadro constant
One mole a any substance is that quantity of the substance whose mass in grams is numerically equal to the substances molar mass, .
The moloar mass of O2 is 32 g mol-1 NA = 6.02 x 1023 molecules mol-1
EX:
Example
How many grams are there in a quantity of oxygen gas containing 1.2 x 1025 molecules?
Since the molar mass is 32 g mol-1 The mass is 19.93 x 32 = 638 g or 0.638 kg
Example
O2 = 32 g/mole
v = 479 m/sec
3 mechanisms
Conduction
Conduction of heat
Conduction in solids
Heat energy causes atoms to vibrate, a vibrating atom passes this vibration to the next Heat energy causes electrons to gain energy, electrons travel through metal (conduction) and carry heat energy with them
Metals are good conductors of both heat and electricity
Conduction in metal
Conduction of heat
The atoms at the bottom are at a higher temperature and will oscillating more strongly than those at the top.
Temperature difference Thermal conductivity (k) k (copper) = 385 W/(m K) k (glass) = 0.8 W/(m K) k (air) =0.02 W/(m K)
TH TC Q H kA t L
TH
TC
Example
Two rods of the same cross-sectional area are joined together. The right rod is a better conductor of heat than the rod at Heat entering the joint must equal the left. The ends are kept at heat leaving the joint. (Conservation of Energy). Hence, the rate of heat fixed temperatures.
In which rod is the rate of heat transfer the largest? Is the temperature at the joining point lower are higher than 54 C?
transfer is the same. Since the second conductor is poor a much larger temperature gradient can be maintained. Thus, the temperature at the junction will be larger.
Convection of heat
Convection of heat
clouds
Convection of heat
Hurricanes Plate tectonics
Radiation of heat
Dont confuse with radioactivity Instead realize that light carries heat (e.g. the sun heats the earth) Anything above absolute zero radiates heat
Radiation of heat
involves the generation and absorption of photons. Unlike conduction or convection, however, radiation requires no intervening medium to transport the heat.
= AesT4
s = Stafans constant = 5.6x10-8 W/(m2 K4) e = emissivity of a body, 0 -1 ecopper = 0.3 ecarcoal 1
Example
Emission, P = AesT4 Area = 4pr2 = 6.2 x 1018 m2 Emissivity 1 H = 6.2 x 1018 x 5.6x10-8x70004 Suns output = 8.3 x 1026 W
Figure 16-12 The Thermos Bottle Discuss the operation of a thermos making reference to methods of heat exchange.
Assignment
Peak wavelength of light emitted depends on temperature Spectrum includes all wavelength longer than the peak but not many above
20C - peak in infrared (need thermal imaging camera to see body heat) 800C - peak in red (electric coil, fire glows reds) 3000 - peak in blue (but includes green and red light hence appears white) 2.7K peak in micro-wave (background emission in the universe left over from the Big Bang)