Beruflich Dokumente
Kultur Dokumente
Hesss Law
Some enthalpy changes can not be measured directly in the lab. Hesss Law is used to calculate these enthalpy changes Use the information provided to calculate Hf CH4
C(gr) + 2H2(g)
2 x Hc H2 2 x -286 = -572
Hf CH4
CH4(g)
Hc C
-394
+ 2O2(g) Hc CH4
-890
CO2(g) + 2H2O(g)
Hf CH4 =
-1 -76kJmol
C(gr) + 2H2(g)
2 x Hc H2 2 x -286 = -572
Hf CH4
CH4(g)
Hc CH4 -890
Hc C
-394
Hesss Law
Hesss Law states In a reaction the total enthalpy change is independent of the route
CaO(s) + H2 O(l)
Hf H2O -286
Hr
Ca(OH)2(s)
Hf CaO
-635
Hf Ca(OH)2 -986
Hesss Law
Hesss Law states In a reaction the total enthalpy change is independent of the route Draw a Hesss Law diagram to calculate the Hr of the decomposition of NaHCO3(s) 2NaHCO3(s) Na2CO3(s) + CO2(g) + H2O(l)
2NaHCO3(s)
Hr
2 x Hf NaHCO3
2 x -948
Hf CO2
-394
Hesss Law
Draw a Hesss Law diagram to calculate the following : Hr of the formation of propane C3H8(g) 3C(gr) + 4H2(g) C3H8(g) Hr of photosynthesis 6CO2(g) + 6H2O C6H12O6(aq) + 6O2(l)
3C(gr) + 4H2(g)
4 x Hc H2 4 x -286 = -1144
Hf C3H8
C3H8(g) + 3O2(g)
3 x Hc C
3 x -394 = -1182
Hc C3H8 -2220
6CO2(g) + 6H2O(l)
Hr
6 x Hf CO2
6 x -394
6 x Hf H2O
6 x -286
-1273