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Objective i) Describe the principles of production of x-ray from an x-ray tube ii) Understand and analyse the x-ray spectra iii) Explain line spectrum and continuous spectrum
Principle of production
X-RAY
Cutoff Wavelength
min = hc/eV f Z2
2dsin = n
Moseleys Law
Braggs Law
13.1 Introduction X-rays is one of electromagnetic wave with wavelength between 10-12 until 10-8 m which is shorter than light wavelength. X-rays were discovered by Wilhelm C. Roentgen (1845 1923), a dutch who performed much of his work in Germany.
The electrons are produced by thermionic emission from a hot filament. The electrons are accelerated with high voltage and then bombard the target on the anode.
Only about 1% of the kinetic energy of the electrons is converted into x-ray and 99% of the kinetic energy is changed into heat. The target must be metal of high of melting point.
The electron which is produced by therminonic emission knock out one of the electrons from the innermost shell of a target atom-the K shell electron.
The K-series of x-ray line is due to movement of electrons of the target atom from the L (K line) or M (K line) shells to the K shell.
The kinetic energy of the bombarding electrons is also lost in the form of the electromagnetic radiation or various energies as E = hc/.
Summary
Objective i. Derive and use min = hc/eV equation ii.Explain Moseleys Law, f Z2 iii.Derive and use the Bragg equation 2d sin = n
If the energy of the bombarding electron, E = eV is completely absorbed by the atom, then by Quantum Theory the x-ray quantum has maximum energy.
The frequency f of the characteristic x-rays from metals is proportional to the atomic number Z of the metal.
= Wavelength of x-ray d = Distance between atoms = The glancing angle n = Order of difraction
If the path difference between two rays = 2dsin = n, constructive interference occurs when 2dsin = n, where n = 1, 2, 3.
Uses of Braggs law : i) To determine the separation of atom in a crystal ii) To determine the wavelength of the x-ray iii) To identify a given crystal
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The intensity of the reflected xrays from a crystal, I at various glancing angles, can be measured by an ionization chamber.
Example A potential difference of 40 kV is applied across a x-rays tube. What is the minimum wavelength of the x-ray radiated?
8 h(310 )
(1.61019)(40103) = 3.1010-11m
Summary
Question i)When a beam of x-ray of wavelength 2.010-10 m is incident on a crystal, a third order diffraction occurs with an angle 60. What is the separation between the two adjacent atoms in the crystal. (3.4610-10 m).
The maximum frequency and the minimum wavelength of the x-ray emitted from this -11 tube. (6.2110 m)
The velocity of the electron that will produce the x-ray with maximum frequency. (8.38107 ms-1)
iii) An x-ray of wavelength 0.2510-10 m is diffracted at an angle 4.6 by a crystal placed in a spectrometer. If the diffraction occurs at the first order, what is the distance between two adjacent atomic -10 planes. (1.5610 m)
iv) An x-ray is diffracted by a crystal. If the glancing angle is 8 for first order and the separation between two atomic -10 planes is 2.6510 m, calculate the wavelength of the incident x -11 ray. (7.3810 m)
v) If the voltage applied across 5 the tube is 10 V, what is the minimum wavelength of the x-ray emitted. (1.2410-11 m)