Beruflich Dokumente
Kultur Dokumente
Done by : 1.Billa Manasa Reddy 2.Kavya sharma 3. Mainowshree Boro 4. Shamma Anna Jacob
OBJECTIVES
To investigate the efficiency of coconut coir pith for the removal of Rhodamine B dye from waste water. To investigate the effects of contact time, adsorbent dosage, pH on dye removal efficiency. To investigate the adsorption mechanisms through kinetic models. To quantify the adsorption equilibrium through Langmuir and Freundlich isotherms.
Introduction
Materials used Adsorbate: Rhodamine B dye Adsorbent: Coconut Coir Pith What is Rhodamine B? What are its uses? Why the removal of Rhodamine B?
Ref: Wikipedia.org
Unsieved
Sieved
Work Done
Performed Trials for phosphate removal by adsorption using various adsorbents . Removal Efficiency not sufficient . Started new project on Removal of Rhodamine B dye from aqueous solution using adsorption by coconut coir pith. Experiments performed : Effect of contact time Effect of Dosage Kinetic models for contact time
Experimental Procedure
Preparation of stock solution: Take 1g of Rhodamine B and add it to 1000 ml of distilled water. A solution of concentration 1000 mg/l is obtained. Preparation of Reference samples: Take 10 ml of 1 g/l solution and dilute it to 100 ml. This solution has a concentration of 100 mg/l. Further take 50 ml of this solution and dilute it to 500 ml. A solution of 10 mg/l is obtained. Similarly, samples of concentration 2,4,6,8 mg/l are prepared and a calibration curve is obtained.
CALIBRATION CURVE
Effect of dosage
Removal efficiency increases with the increase in Coir pith dosage. Optimum dosage : 2.5 gm/L with Removal efficiency of 98%.
ADSORPTION KINETICS
In order to clarify the adsorption process, adsorption models were applied to evaluate the experimental data. Adsorption Models : 1. Lagergrens pseudo first order kinetic model 2. Lagergrens pseudo second order kinetic model. The pseudo first order equation is generally expressed as : log(Qe-Qt) = log Qe (k1/2.303)t Where Qe and Qt are the adsorption capacity at equilibrium and at time t, respectively(mg/g), k1 is the rate constant of pseudo first order.
The pseudo second order equation is expressed as : (t/Qt) = (1/(k2Qe) + (t/Qe) Where k2 is the rate constant of pseudo second order.
Kinetic Models
Kinetic Constants
Dye Pseudo 1st order coefficients Pseudo 2nd order Coefficients Qe exp (mg/g)
Qe (mg/g)
Rhoda 19.7 mine B
k (1/min)
0.0368
Qe (mg/g)
18.4
k (g/mg/m in )
0.021
0.914
0.999
17.61
Future Plans
Experiments to be conducted : Effect of pH Adsorption Isotherms Properties of Adsorbents : 1. Zero point charge 2. Specific gravity 3. Particle size
REFERENCES
1. Residual oil and suspended solid removal using natural adsorbents chitosan, bentonite and activated carbon: A comparative study by A.L. Ahmad, S. Sumathi, B.H. Hameed. 2. Removal and Recovery of the Hazardous Azo Dye Acid Orange 7 through adsorption over Waste Materials: Bottom Ash and De-Oiled Soya by Alok Mittal, Vibha Gajbe, and Jyoti Mittal. 3. Adsorption of basic dye (methylene blue) onto activated carbon prepared from rattan sawdust by B.H. Hameed*, A.L. Ahmad, K.N.A. Latiff. 4. A novel agricultural waste adsorbent for the removal of cationic dye from aqueous solutions by B.H. Hameed, R.R. Krishni, S.A. Sata.
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