Beruflich Dokumente
Kultur Dokumente
BY
DR.SUBHAS CHANDRA
PROF. AND HEAD HLC
Nature
All polymers are not plastics. Only less than 5% petroleum is consumed for plastics. Remaining petroleum is used for energy and fuel.
APPLICATION OF PLASTICS
In various walk of life
Clothing to Shelter, Transportation to Communication, Entertainment to Health Care, Agriculture to Packaging Production, Shipment and storing.
This is because of their advantageous properties, light weight high strength and use of processing and use.
APPLICATION OF PLASTICS
Rigid HDPE barrels are used for bulk chemical storage instead of steel drums.
Apart from conserving natural resources, use of plastics in these applications saves transportation fuel as plastics are substantially lighter than tin, glass or steel. Plastics is especially made use of in industries like the automobile & aviation, resulting in fuel efficiency.
APPLICATION OF PLASTICS
Safe drinking water packaged in PET bottles is a very common sight now-a-days.
They provide confidence to the consumer on the quality of water and help reduce waterborne diseases.
APPLICATION OF PLASTICS
Modern buildings and constructions use plastic doors, windows, floor and wall coverings instead of wooden ones, ultimately saving trees. In Agriculture, plastics are used in irrigation pipes, tubes, hoses to better the micro-irrigation system as well as in greenhouses, films, increasing productivity.
APPLICATION OF PLASTICS
The health care sector uses plastics in blood bags, tubing, heart catheters, IV fluid bags, disposable products (gowns, masks, syringes) because it is both hygienic as well as easier to handle than other materials.
Plastics help in conserving material resources by elimination of metal and other conventional material used in various sectors Which consumes far more energy and thus lead to greater consumption of fossil fuel.
PREFERRED MATERIAL
They are preferred material Light Weight Not expensive Not breakable Malleable for design purposes (electronics and houses) Flexible use purposes Ease of fabrications As a result growth of plastics per capita consumption is increasing every year and expected to reach 7 to 8 kg by the end of this year 2012 as against world average of 25 kg and 140 kg of advance country.
FUTURE REQUIREMENTS
CAUSE OF POLLUTION
The cause of pollution in the environment
Methane (CH4) Biogenic carbon dioxide (CO2) Non methane volatile organic compounds (NMVOCs) Small amounts of nitrous oxide (N2O), nitrogen oxides (NOx) and carbon monoxide (CO)
Simplified Landfill Methane Mass Balance Methane (CH4) produced (mass/time) = (CH4 recovered + CH4 emitted + CH4 oxidized)
CONSTRAINTS IN RECYCLING
1. Mechanical recycling Requires clean homogenous waste that can be re melted and extruded into new product. This is often used on industrial waste and scrap but far less economical on domestic waste. 2. Chemical recycling Requires expensive grinding and chemical break down to new products that may be other products or fuel. This is not cost effective and needs government supports.
3. Energy recovery The high calorie many plastics does however rendered them ideal feed stock for energy recovery. This is also a easy process can be possible through municipal incinerator or by generating fuel.
However, cost effective should be decided based on the ultimately exact LCA study, whether recycling is cost effective over energy recovery.
Plastic products also should be made by technologies which are upgraded from the view point of energy consumption regulations.
2. The
impact
of
for visible
emerging,
value across
sophisticated
addition the is plastics
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technologies prominently
material industry.
1. The important development in the material world is the introduction of inexpensive, metallocene based polypropylene with PET like properties that are set to make in roads in hot fill packaging. 2. Highly efficient PET recycling technology for converting dirty post consumer bottles into recyclable PET flakes is encouraging plastics industries to compete in PET bottle manufacturing since these flakes are less costly than virgin material. 32
The use of a poly carbonate co-polymer film that is scratch/chemical resistant and capable of with standing ten years weathering tests to form a paint less class A decorative finish is another striking innovation generating considerable excitements in the global automotive industry.
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The toughness range in vulcanized thermoplastics olefilm (TPOs) has increased considerably with the development of hi-tech ethylene propylene diene monomer (EPDM) rubber design consideration can be changed.
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Rigid rod, self reinforced polymer that eliminate the need for added fillers which providing properties considered impossible with traditional engineering plastics is another breakthrough achievement. Above all the advent of compounded, semi crystalline polyesters is creating a plethora of opportunities for plastics materials to replace metals across numerous applications.
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New generation Bimodel PE technology has allowed the development of high density PE resins, which typically exhibit an order of magnitude higher SCG (Slow Crack Growth) resistance than unimodal PE resins at lower densities. Moreover, bimodal PEs higher density allows a higher pressure rating and reduced wall thickness. More tougher pipe is possible with these materials.
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The development of halogen free plastics material for fire retardant pipe is another emerging area for exploitation.
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Improvement in barrier properties of polyethylene by introducing optimum level of long chain branching is drawing much attention of the scientists and technocrats now a days. This is done with the help of peroxides other layer can be avoided.
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Should be designed to breakdown for complete assimilation by micro organism in a disposal infrastructure such as composting
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BIODEGRADABLE PLASTICS
1. Smart compostable and bio-degradable plastic (PLA) from corn is getting popularized in advanced countries like USA for packaging strawberries and tomatoes. It is claimed by some company that this package from corn will save the equivalent of 800,000 gallons of gasoline and reduce 11 million pounds of green house gas emissions. This switch over is being convinced, to the consumer because of skyrocketing cost of plastics made from oil. In order to remain competitive in this front since 2000 DuPont has been slowly replacing petrochemicals with ingredients like corn. Today about 83 percent of its products use petrochemicals. Another company in USA is commercializing a family of polymers PHA natural plastics made from renewable resources such as sugar and vegetable oils. The material can be palletized and compounded into formulations suitable for a broad range of applications.
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2.
3. 4. 5. 6.
7.
BIODEGRADABLE PLASTICS
1. Scientists at the university of Dublin have found a way to breakdown Styrofoam, the base of recyclers/ composters everywhere. Bacteria have been found that eat Styrofoam and turn it into usable plastics. (Fig. 1) 2. A few companies in Japan designed a substitute of
Fig. 1 Styrofoam
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DEVELOPMENT OF BIO BASED PLASTICS In bio based plastic materials significant portion of the carbon is derived from a renewal resources like corn, soybens or other plant mass
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DEVELOPMENT OF NANOSTRUCTURED MATERIALS (APPLICATIONS) 1. The application of nano fillers based plastics can be extended to the rotational moulded product where the strength is less.
2. The lightweight structure of high strength can be produced for products like rotational moulded tanks. 3. The other applications include processing of interior and exterior trim for the transportation industry, packaging liners, housings for appliances and power tools, closures, containers, pipes conduits, fittings and fascia used in the construction industry and consumer goods.
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Micro cellular nanocomposite foam for the structural and insulation market is the another area where new product applications are yet to be developed in order to take the advantages of much higher structural strength and thermal insulation performance of the nano composite over the existing materials.
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DEVELOPMENT OF NANOSTRUCTURED MATERIALS 1. Development of antiballistic material from nanocomposite is slowly penetrating the market
Another area of processing would be related to development of polymer based nanocomposite with advanced FR properties that delay ignition, reduce smoke emissions and eliminate slumping and dripping of the molten polymer by the formation of a strong stable char.
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application
particularly
where
thin
wall
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Fig. 2 Nano composite materials for thin wall components (Light, stiff and tough attributes well suited to a broad range applications)
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Fig. 3 Drops of water on superhydrophilic multi layer surface patterned with hydrophilic regions.
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TECHNOLOGY REQUIREMENT
Technologies are basically being developed based on following requirements for making plastic products Energy Efficient and environment friendly plastic product Efficient manufacturing process for minimizing energy of production well engineered design reducing waste material cost as well as facilitating recycling
2.
3.
4.
1. Plastic processing is costly step in plastic product manufacturing. 2. Therefore, if some kind of innovation is introduced in the step of its manufacturing then cost can be controlled without much change in property value of the product. 3. Many companies at present adopted this technique and achieved a significant cost saving due to power used in the production process.
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3. This additives can offer performance and cost advantages over comparable loading of other processing aids.
4. The processing aids in the new formulations eliminate melt fracture, can reduce extruder torque, and increase output. 5. It improves clarity and gloss in film products.
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2. 3. 4.
5.
2. This is low pressure injection moulding processing. In this process virtually any type of thermoplastics can be moulded.
3. Even unsorted, uncleaned mixed plastic waste can be injection moulded into CD panels and used in a variety of exciting and imaginative new applications like, concrete forms, roofing material, furniture, office environments.
4. Green houses, animal confinement structures, marine, steam houses, swimming pool decks, panels for toilets, irrigation channels and items used in transportation. (Fig. 4) 61
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EXTRUSION TECHNOLOGY FOR MIXING RECYCLED PLASTICS WITH VIRGIN PLASTICS 1. Extrusion technology for mixing recycled plastics with virgin studies indicated that a blend of 25% flake provided a product of acceptable physical and visual quality. 2. The mix of flakes and pellets could be processed on the existing equipment without any modifications in equipment or process parameters. Some additional equipment would be required to mix the flakes of a higher ratio.
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ii. Mold cavity condition is checked iii. Part length and inner diameter and outer diameter tolerances for medical molding applications are seen. iv. Compatibility with 21 CFR part 11 for medical GMP compliance is observed (Fig.6) v. Overload, preprinted logos and their positioning and contaminates are checked.
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Fig. 6 Ascertaining Quality within the 6-s range in good manufacturing practices
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It has been said that the robot installed for reduction of waste verification of quality, improve manufacturing efficiencies which does not involve creative judgment but merely require a repetitive process. (fig. 7)
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4. These equipments are interfaced with robot of such quality that are easy to programme and use, and having more speed to reduce cycle time, cost and labour.
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(USE
1. It has been seen that manual placement of inserts that takes 80 sec. cycle can be operated at 45 sec. by automatic operation. 2. The 6-axis robot is inter faced with the machine for material handling, machine tending and secondary operation such as
Fig. 9 Vision system is a multiple camera Injection Moulding Robot/Work cell vision inspection system that enables the verification of part quality at the point of manufacture
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In order to reduce the no. of man working on the extruder a swing control system is mounted.
This helps operators to work at die area while simultaneously programming the high out put extruder.
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100 90 80 70 60 50 40 30 20 10 0
Loss in transportation : - loss of pressure in pipes and hoses - losses in valves - losses through flow restrictor Loss in transformation : efficiency rate of motors - mechanical losses - leakage of hydraulic pump
-
Fig. 10. Comparison of servo electric molding machine with conventional machine
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1. Recycling (most plastics are recyclable ) 2. Composting / organic diversion Based on these development of engineered life cycle plastic products should be focused
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MECHANICAL RECYCLING
In order to get standard recycled plastic materials the waste material should be processed as per following steps.
1. 2. 3. 4. Collection Storage Conveyance Size reduction unit
5.
6. 7. 8. 9.
Sorting
Washing Drying Conditioning Process (chopping / shearing / rotating to achieve better flow properties) Re-granulation by extruder (plastication, homogenization , stabilization , melt filtration , re-granulation
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1. Automatic separation has been successfully practised in many advanced countries. (for post consumer materials such as plastics bags, beverage carton and tin can ) 2. Machinery for recycling of plastics such as film, carves and bottles is already developed in advanced countries as well as India. 3. PET bottles are collected and sorted by hand or machine and recycled.
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CHEMICAL RECYCLING OF PLASTICS WASTE HAS BEEN ALREADY ADOPTED BY MANY COUNTRIES
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They are designed in such way that they can be broken down for complete assimilation by micro organization in a disposal infrastructure such as composting
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BIODEGRADABLE PLASTICSThe
Chemistry
Oxo-Biodegradable
Carbon-chain polymers Peroxidation Carboxylic acids, alcohols, hydroxycarboxylic acids
Hydro-biodegradable
2. Environmental group across the globe are resisting waste incineration and are insisting that government put a stop to the deadly practice of burning waste. 3. It has been reported that burning waste of any kind causes the emission of present organic pollutants like Dioxins and Furans. 4. Dioxin exposure is linked to a variety of health problems such as impairment of the nervous system, the endocrine system, and the reproductive system. 5. Thus a zero waste approach is becoming popular and recycling is getting a priority in the light of conservation strategy of precious plastics material.
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AVOIDING DIVERSION
If we have to avoid diversion then we must maximize the life of plastics for mechanical recycling by taking innovative steps for value addition
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WELL ENGINEERED DESIGN FOR REDUCING MATERIALS IN THE PRODUCT FOR FACILITATING RECYCLING Today design of plastic products is done in a way that would facilitate the followings: a) Retrieval of valuable material. b) Removal of contaminants. c) Collection and reuse of components with longer useful life.
TAX BENEFITS
More than 95% of the firms in the industry are partnership, proprietorship & private limited companies. These small companies get significant advantages in tax benefits. Thus these firms despite their size provide significant level of competition to organized sector companies which as a group making losses. Due to liberalization, globalization and privatization there has been a constant charge in petrochemical industries in India - facing tough competition.
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GROWTH POTENTIAL
The consumption of plastics in India is about 7-8kgs. Which is much lower than the global average of 25 kgs. and 30 kgs. in China. The projected growth rate for polymer consumption in India the will be 15 % which will consume 18.9 million tonnes of plastics by 2015. Whereas worldwide the plastics and polymer consumption will have an average growth rate of 5% and it will touch the figure of 227 million tonnes by 2015.
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COMPETITIVE MARKET
Growth and opening up of the market, entry of foreign players investment and unorganized and fragmented nature of the plastic industries put them in a critical situation. In one hand they have to produce product which should be at par with global players. On the other hand the sector is lacking structure that would boost competitiveness and professionalism at global level.
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Managari al 2% Supervisory 3%
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60% of the work force is employed at low end (i.e. machined operator, technician and supervisor levels.) Out of the remaining 40%, 1% is involved in R&D activities the rest is involved in managerial, marketing and trading activities.
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TO INCREASE GROWTH OF THE SECTOR (contributing more than 6% towards 6000 products of MSME)
1.4 million for 2011-12 . 0.9 million for low end. 10000-15000 per year (at present). Demand is much more.
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CONCLUSION
The technologies discussed above and the