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Nanotechnology is the exploitation of the ability to control matter at dimensions between 0.1 and 100 nm, resulting in unique functionalities
10-9 m 10-8 m 10-7 m 10-6 m 10-4 m 10-3 m 10-2 m
Scale of Things
10-10 m
0.1 nm
1 nanometer (nm)
0.01 mm 10 nm
0.1 mm 100 nm
0.01 mm 10 mm
DNA ~2-1/2 nm diameter Atoms of silicon spacing 0.078 nm ATP synthase ~10 nm diameter
Ant ~ 5 mm Red blood cells (~7-8 mm) Fly ash ~ 10-20 mm Dust mite 200 mm
Sol-Gel Technology
The main idea of the sol-gel process is the spontaneous formation of a dual phase material (gel), prepared from the solution (sol), containing inorganic precursors ( ) and stabilizing agents with hydrolysis() & condensation() reaction. Further transformation of the gel phase is driven by the evaporation of the solvent, and the subsequent formation of the xerogel phase.(aging). Drying of the xerogel completely removes solvent molecules, leading to further aggregation of inorganic clusters and the formation of solid materials.
Hydrolysis Reaction
Condensation Reaction
3
Control Parameters
Precursors Concentration of Metal Salts Temperature Catalysts pH Hydrolysis & Condensation Advantages Low temperature route (below 200oC) Uniform particle size distribution Provides good homogeneity Concentration of metals in the coatings can be controlled with ease Chemical purity of nanocomposites Drawbacks high cost for the majority of alkoxide precursors long processing times
Applications
Anti-Abrasion
Hydrophobic
Anti-Rusting
Anti-Glare
Sol-Gel Method
uses an aqueous solution to apply on the metal to form a organic-inorganic hybrid thin film.