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Introduction
Crystallization is the formation of solid particles within a homogeneous phase For crystallization to occur, solution must be supersaturated Supersaturation means that at a given temperature, the actual solute concentration exceeds the saturation concentration A supersaturated solution is metastable and contain clusters of molecules. Clusters grow large with time. Eventually will grow large enough for nucleation to occur.
Supersaturation
Supersaturation can be achieved by several methods:
a) Cooling b)Evaporation c) Solvent addition
Steps in Crystallization
Nucleation Birth of a new crystal Crystal Growth growth of existing crystal Ratio of rate of nucleation to growth controls the size distribution of product obtained General factors that affect nucleation and growth kinetics
Supersaturation Solvent Temperature Impurities Solution viscosity, surface tension
Objectives of Crystalization
Yield Purity Crystal strength Nonaggregation Uniformity in size
Kelvin Equation
Sequence of stages in the evolution of crystal Solubility of substance is related to particle size as
Rate of Nucleation
Rate of Nucleation is given as
Types of Nucleation
Homogeneous Nucleation Heterogeneous Nucleation Secondary Nucleation
Fluid Shear Nucleation Contact Nucleation
Crystal Growth
Equation for mass transfer
Equation for surface reaction Overall resistance for the two steps
MSMPR Model
An idealized crystallizer model Served well as a basis for identifying the kinetic parameters and showing how knowledge of them can be applied to calculate the performance of such a crystallizer
Population Density
Basic quantity in the theory of the Crystal Size Distribution The population density nis defined as the slope of the cumulative distribution curve (N/V vs. LN/L) at size L N = no of crystals of size L and smaller in the magma V = volume of mother liquor in the magma L = crystal size At L=0, N=0 and L=LT, N=NT
at L=0, n=n0 at L=LT, n=0 n = function of L and invariant in both time and location in the magma Dimensions of n: Number/Volume-Length
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