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Operations in packed towers:
Mass transfer theories
Liquid
m
o
l
e
f
r
a
c
t
i
o
n
x
Gas
y
Liquid
m
o
l
e
f
r
a
c
t
i
o
n
x
Gas
y
i
x
i
y
Mass transfer of A
B A
Operations in packed towers:
Mass transfer theories
Liquid
m
o
l
e
f
r
a
c
t
i
o
n
x
Gas
y
i
x
Mass transfer of A
Two film theory:
resistance to the overall mass transfer is viewed as a combined
resistance of liquid and gas films at the interface
i
y
Operations in packed towers:
Mass transfer theories
Mass transfer rate (per unit area)
Liquid
m
o
l
e
f
r
a
c
t
i
o
n
x
Gas
y
i
x
i
y
| |
i
y
y y k r =
| | x x k r
i
x
=
x
(mole fraction of A in L)
(mole fraction of A in V)
y
equilibrium line
i
y
i
x
y
x
Operations in packed towers:
Mass transfer theories
Mass transfer rate (per unit area)
Liquid
m
o
l
e
f
r
a
c
t
i
o
n
x
Gas
y
i
x
i
y
| |
i
y
y y k r =
| | x x k r
i
x
=
x
(mole fraction of A in L)
(mole fraction of A in V)
y
equilibrium line
i
y
i
x
y
x
Operations in packed towers:
Mass transfer theories
Mass transfer rate (per unit area)
| | x x K r
x
=
*
| |
*
y y K r
y
=
x
(mole fraction of A in L)
y
equilibrium line
i
y
i
x
y
x
*
y
*
x
Operations in packed towers:
Mass transfer theories
Liquid
m
o
l
e
f
r
a
c
t
i
o
n
x
A
C
Gas mixture C is in equilibrium with the liquid system A:
x T H y ) (
*
= (in Henrys law regime)
*
y
Operations in packed towers:
Mass transfer theories
Liquid
m
o
l
e
f
r
a
c
t
i
o
n
x
i
x
Gas
y
B A
C
*
y
Mass transfer rate (per unit area)
| | x x K r
x
=
*
| |
*
y y K r
y
=
x
(mole fraction of A in L)
y
equilibrium line
i
y
i
x
y
x
*
y
*
x
Operations in packed towers:
Mass transfer theories
Liquid
m
o
l
e
f
r
a
c
t
i
o
n
x
i
x
Gas
y
B
A
C
*
y
Mass transfer rate (per unit area)
| | x x K r
x
=
*
| |
*
y y K r
y
=
x
(mole fraction of A in L)
y
equilibrium line
i
y
i
x
y
x
*
y
*
x
Operations in packed towers:
Mass transfer theories
x
(mole fraction of A in L)
y
equilibrium line
i
y
i
x
y
x
*
y
*
x
y
i
x
i
y
k x x k
y y
K
1
) (
1
*
+
=
y x y
k k
m
K
1 1
+ =
Resistance of gas film
Resistance of liquid film
Overall gas resistance m
Operations in packed towers:
Mass transfer theories
x
(mole fraction of A in L)
y
equilibrium line
i
y
i
x
y
x
*
y
*
x
y x x
mk k K
1 1 1
+ =
Resistance of gas film
Resistance of liquid film
Overall liquid
resistance
Operations in packed towers:
Mass transfer theories
y x y
k k
m
K
1 1
+ =
Resistance of gas film
Resistance of liquid film
Overall gas resistance
- when coefficients k
y
and k
x
are of the same order of
magnitude and m is much greater then 1 the liquid phase
resistance is controlling
- in the opposite situation when solubility is very high, the
gas film resistance is controlling
Consider an absorption column;
For diluted gases the change in flow rates is neglected
Consider a mass transfer process in a section of
the column dZ (cross-section of the column is S)
L
a
,x
a
V
a
,y
a
V
b
,y
b
L
b
,x
b
Z
dZ
SdZ y y a K Vdy
y
*) ( =
Integration leads to:
} }
= =
b
a
y
y
y
Z
y
y y
dy
Z
V
aS K
dZ
V
aS K
*
0
S
Absorption in packed towers
L
a
,x
a
V
a
,y
a
V
b
,y
b
L
b
,x
b
Z
S
}
=
b
a
y
y
y
y y
dy
a K
S V
Z
*
/
}
b
a
y
y
y y
dy
*
change in the concentration divided
by driving force. This property is
called the number of transfer units
(NTU)
a K
S V
y
/
This property has units of length, is
constant for constant L/V and is called
the height of transfer units
(HTU)
Absorption in packed towers
L
a
,x
a
V
a
,y
a
V
b
,y
b
L
b
,x
b
Z
S
Oy Oy
b
a
y
N H
y y
dy
a K
S V
Z =
=
}
*
/
Absorption in packed towers
To understand the meaning of these
definitions consider a specific case when
both the equilibrium and operating lines are
straight and parallel
The driving force is then constant
throughout the process and can be
moved outside the integral, leading to:
* y y
y y
N
a b
Oy
=
x
(mole fraction of A in L)
y
equilibrium line
b
x
b
y
a
x
a
y
operating line
Absorption in packed towers
To understand the meaning of these
definitions consider a specific case when
both the equilibrium and operating lines are
straight and parallel
The driving force is then constant
throughout the process and can be
moved outside the integral, leading to:
* y y
y y
N
a b
Oy
=
x
(mole fraction of A in L)
y
equilibrium line
b
x
b
y
a
x
a
y
operating line
Similar to the number of stages in
the tray process
Absorption in packed towers
* y y
y y
N
a b
Oy
=
x
(mole fraction of A in L)
y
equilibrium line
b
x
b
y
a
x
a
y
operating line
Similar to the number of stages in
the tray process
a K
S V
y
/
HTU (H
oy
) is the height
of packing required to achieve
one separation step
Oy Oy
b
a y
N H
y y
dy
a K
S V
Z =
=
}
*
/
Absorption in packed towers
Oy Oy
b
a y
N H
y y
dy
a K
S V
Z =
=
}
*
/
y
y y
dy
y
dy
y y y y
dy
y y
dy
N
a b
y
y
y
y
y
y
y
y
Oy
b
a
b
a
b
a
b
a
A
=
A
=
=
}
} } }
1
*
1
* *
*
*
* *
ln
] [ ] [
a a
b b
a a b b
y y
y y
y y y y
y
= A
Simplification using
average driving force
notion
Average driving force
calculated as logarithmic
mean of driving forces at
the top and bottom of the
column
Absorption in packed towers
Example: A gas stream of 3.0% A is passed through a packed column to
remove 99% of A by absorption in water. The absorber operates at
25C and 1 atm, V/S=20mol/h/ft2, L/S=100mol/h/ft2
y*=3.1x
k
x
a=60mol/h/ft3
k
y
a=15mol/h/ft3
Find N
oy
, H
oy
Z
T
neglecting changes in the gas and liquid flow
Absorption in packed towers: Example
effect of pressure
x
(mole fraction of A in L)
y
equilibrium line
Consider the effect of pressure on
the equilibrium distribution of the
volatile component:
P x T H y / ) ( = Henrys law
P=1bar
P=2bar
Absorption in packed towers:
x
(mole fraction of A in L)
y
b
x
b
y
a
x
a
y
Consider the effect of pressure on
the equilibrium distribution of the
volatile component:
P x T H y / ) ( = Henrys law
P=1bar
P=2bar
*
b
x
If the L/V ratio remains the same
- at higher pressure we need fewer
stages
effect of pressure
Absorption in packed towers:
x
(mole fraction of A in L)
y
b
x
b
y
a
x
a
y
Consider the effect of pressure on
the equilibrium distribution of the
volatile component:
P x T H y / ) ( = Henrys law
P=1bar
P=2bar
*
b
x
If the L/V is changed
- lower L/V ratio
- less solvent required
- higher pressure leads to more
efficient absorption
- lower pressure leads to more
efficient desorption (stripping)
effect of pressure
Absorption in packed towers:
Absorption processes
Multicomponent absorption
- separate equilibrium and operating
lines
- for dilute mixtures, L/V constant ->
the slope of the operating lines
for all components is the same
Absorption processes
Multicomponent absorption
- separate equilibrium and operating
lines
- for dilute mixtures, L/V constant ->
the slope of the operating lines
for all components is the same
Absorption processes with chemical reactions
- Can be used to obtain a more complete removal of a component from the
mixture
NH3 from air by using dilute acid solution
CO2 from natural gas by using dilute basic solution
} }
= =
=
b
a
b
a
y
y a
b
y
y
Oy
y
y
y
dy
y y
dy
N ln
*
Irreversible reaction