Beruflich Dokumente
Kultur Dokumente
Production of Acrylonitrile
Project Advisor :
HASSAN JAVAID NAQVI
Co-advisor:
SHAFAQ MUZAMMIL
Presented by :
MUHAMMAD IRFAN ZUNAIRA MUNIR BASSAM HAMEED NAJAM ZIA BUTT M. SALMAN BARI 05-CHEM-09 05-CHEM-25 05-CHEM-33 05-CHEM-67 05-CHEM-105
Material Balance
Energy Balance
Production of Acrylonitrile
CH2=CHCN
PROPERTY
VALUE
Molecular weight
Boiling point, 0C (at 103.3 kPa) Density, g/L (at 250C) Freezing point, 0C Heat capacity, kJ/(kg-K) Viscosity at 25C, mPa-s (=cP)
53.06
77.3 800.4 -83.55 2.094 0.34
Production of Acrylonitrile
Production of Acrylonitrile
Barrier Resins, 1.2% Miscellaneous, 4% Nitrite Elastomers, 2.9% Acryl amide, 3.1%
Exports, 21.3%
Production of Acrylonitrile 9
From Propionitrile From Propionaldehyde From Acetaldehyde Nitric Oxide with Propylene
Production of Acrylonitrile 11
Selection Basis:
Production of Acrylonitrile
12
Production of Acrylonitrile
14
Production of Acrylonitrile
15
FBR-01 Q-01
D-01
C-01 A-01 M-01 DC-01,02,03
Production of Acrylonitrile
Decanter
Compressor Absorber Mixer Distillation columns
16
0.027
0.107
0.032
Production of Acrylonitrile
17
Acrylic Staple Fibre )DEWAN SALMAN FIBRE LIMITED( In 1999 the demand of ASF was 40000 tpa and increasing 10 % Annually ABS (Acrylonitrile Butadiene Styrene) Appliance covers Crisper trays Instrument panels
Production of Acrylonitrile
20
Material Balance
Basis:
Production of Acrylonitrile
23
Material Balance
24
kg/hr 14280 __ __ __ __ __
kg/hr __ __ __ 6936 __ __
AN
ACR ACN H 2O
Production of Acrylonitrile
__
__ __ __
__
__ __ 558
__
__ __ __
14461
515 440 18742
TOTAL
14280
7494
93024
114528
Material Balance
QUENCHER
25
INLET Stream #
Components
OUTLET 10 kg/hr __ __ __ 5737 __ __ __ __ __ __ 11 kg/hr __ __ 6440 956 __ __ 7 145 5 4 13387 20944 12 kg/hr 243 843 __ __ 72352 4806 736 14317 510 436 742 112981
8 kg/hr 243 843 __ __ 72352 4802 744 14461 515 440 18742 114809
13387 19124
TOTAL
Material Balance
DECANTER
26
#
Components
kg/hr 243
kg/hr __
kg/hr 243
C 3H 6
O2
N2 CO2 HCN
843
72352 4806 736
__
__ __ 74
843
72352 4802 662
AN
ACR ACN H2O TOTAL
Production of Acrylonitrile
14317
510 436 18753 112981
7159
255 218 11251 18957
7158
255 218 7501 94035
Material Balance
ABSORBER
27
#
Components
kg/hr __ __ __
kg/hr __ __ __
C 3H 6 O2 N2
CO2
HCN AN ACR ACN H 2O
4802
662 7158 255 218 7501
__
__ __ __ __ 90194
4802
__ 6 154 __ 1036
__
662 7153 101 28 96661
TOTAL
Production of Acrylonitrile
94035
90194
79435
104794
28
INLET
St ream #
Components
OUTLET
23 kg/hr 26 kg/hr
20 kg/hr
HCN
AN ACR ACN H 2O TOTAL
Production of Acrylonitrile
736
14310 356 436 107911 123750
736
2 2 1 1 742
__
14308 354 435 107910 123007
29
OUTLET 32 kg/hr 14302 342 434 1 15079 31 kg/hr 7 12 0.5 107909 107928
30
OUTLET 38 kg/hr 7 __
ACN
H 2O TOTAL
Production of Acrylonitrile
434
1 15079
1
__ 14638
433
1 441
BASIS:
Energy Balance
33
OUTLET
4
473
5
473
6
523
7
673
223 3.7106
223 3.3109
203 5.9107
Energy Balance
QUENCHER
Production of Acrylonitrile
34
OUTLET 11
338 101 1106 2.0106
8
493 172
10
278 173
12
358 132 8.9106
2.7107 5105
Energy Balance
ABSORBER
Production of Acrylonitrile
35
INLET
OUTLET
Stream # Temperature(K)
16
317 172
17
277 101
2.3106
18
283 101
1.3106
19
313 162
Pressure(kPa)
Enthalpy (KJ/hr)
7.6105
4105
Energy Balance
HEAT EXCHANGERS
Production of Acrylonitrile 36
Heat Exchahger 1
Stream # Temperature(K) Pressure )kPa) Heat Duty )kJ/hr(
Heat Exchanger 2
Stream # Temperature(K) Pressure )kPa) Heat Duty )kJ/hr(
Production of Acrylonitrile
37
Stream #
21 306 125
2.6103
22 299 101
1.4105
26 388 152
2.0106
Temprature (K)
Pressure (kPa) Enthalpy (KJ/hr)
2.3104 2.1103
38
INLET 26
388 152
2.0106
OUTLET 32
364 132
1.2106
27
369 148
3.6107
28
364 132
1.7106
31
413 162
2.6107
5.3106 5.4105
Production of Acrylonitrile
39
INLET
Stream #
Temprature
OUTLET
35 350 111
1.0106
32 364 132
1.2106
34 350 111
1.6105
33 359 131
3.1105
38 370 152
5104
(K)
3.2105 4.8105