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MATERIALS SCIENCE
CHAPTER 1
• Composite Materials
- Mixture of two or more materials.
- Consists of a filler material and a binding material.
- Materials only bond, will not dissolve in each other.
Examples : Fiber Glass ( Reinforcing material in a polyester or epoxy matrix).
Concrete ( Gravels or steel rods reinforce
in cement and sand).
Applications : Aircraft wings and engine, construction.
ATOM
Basic Unit of an Element
Diameter : 10 –10 m.
Neutrally Charged
Proton Neutron
Mass : 1.673 x 10 –24 g Mass : 1.675 x 10 –24 g
Charge : 1.602 x 10 –19 C Neutral Charge
Rasdi Deraman, FKM UiTM NPP 8
What does an ATOM look like?
•Atoms are made of a nucleus that contains protons, neutrons and
electrons that orbit around the nucleus at different levels, known as shells.
+
- -
+
Electrons
move
around the
nucleus
Electron
Shell @ Orbital @ Energy level
Rasdi Deraman, FKM UiTM NPP 9
ATOMIC NUMBER and ATOMIC
MASSusing :
Atom can be described
SYMBOL
ATOMIC MASS , A =
no. of protons (Z) + number of neutrons (N)
Hydrogen 3 1 2 3
(tritium)
s 2
p 6
d 10
f 14
1s2, 2s2, 2p6, 3s2, 3p6, 4s2,
3d10 , 4p6, 5s2, 4d10 , 5p6, 6s2,
4f14 , 5d10 , 6p6, 7s2, 5f14 , 6d10 ,
7p6
Rasdi Deraman, FKM UiTM NPP 15
Each orbital holds a max. of 2 electrons.
Electrostatic
Cation Attraction Anion
+ve charge -ve charge
Chlorine
Sodium Atom
Atom Cl=17
Na=11
I
O
N
I Chlorine Ion
C Cl -
B
O
N
Rasdi Deraman,DFKM UiTM NPP 20
b) Covalent Bonding
• Large interatomic forces are created by the sharing of
electrons to form directional bonds.
• In Covalent bonding, outer s and p electrons are shared
between two atoms to obtain noble gas configuration.
• Takes place between elements
with small differences in
electronegativity and close by
in periodic table.
• In Hydrogen, a bond is formed between 2 atoms by
sharing their 1s1 electrons Electron Overlapping
Pair Electron Clouds
H +H H H
1s1 Hydrogen
Electrons Molecule
Rasdi Deraman, FKM UiTM NPP 21
Covalent Bonding - Examples
• In case of F2, O2 and N2, covalent bonding is formed by
sharing p electrons
• Fluorine gas (Outer orbital – 2s2 2p5) share one p electron to attain
noble gas configuration.
F + F F F F F
Bond Energy=160KJ/mol
O + O O O O=O
Bond Energy=28KJ/mol
HH N + N N N
Rasdi Deraman, FKM UiTM NPP
N 22
N
Bond Energy=54KJ/mol
Covalent Bonding in Benzene
•• Chemical composition
Chemical composition of
of Benzene
Benzene is
is C
C6H .
6H66.
•• The Carbon
The Carbon atoms
atoms are
are arranged
arranged in
in hexagonal
hexagonal ring.
ring.
•• Single and
Single and double
double bonds
bonds alternate
alternate between
between the
the atoms.
atoms.
H
H C H
C C
C H
H
C
Structure ofRasdi
Benzene
Deraman, FKM UiTM NPP
Simplified Notations
23
Covalent Bonding in Carbon
• A carbon atom can form symmetrically
toward the corners of a tetrahedron.
•Different
Polycrystalline lattice
orientation for
•Completely ordered each grain
•In segments
Rasdi Deraman, FKM UiTM NPP 30
The Space Lattice and Unit Cells
• An imaginary network of lines, with atoms at
intersection of lines, representing the arrangement of
atoms is called space lattice.
Face centered
• Tetragonal
a =b ≠ c
α = β = γ = 900
Rasdi Deraman, FKM UiTM NPP Body Centered32
Simple
Types of Unit Cells (Cont..)
• Orthorhombic
a≠ b≠ c
α = β = γ = 900
Body Centered
Face Centered
• Rhombohedral
a =b = c
α = β = γ ≠ 900
Simple
Simple
• Monoclinic
a≠ b≠ c
α = β = γ = 900
Base
Centered
Simple
• Triclinic
a≠ b≠ c
α = β = γ = 900 Simple
• Represented as one
atom at each corner
of cube. a
• Each atom has 8
nearest neighbors. R=0.5a
• Therefore,
coordination close-packed directions
number is 8. contains 8 x 1/8 =
1 atom/unit cell
(8x1/8 ) + 1 = 2 atoms
ρ = nA
Volume/unit cell Vc NA Avogadro's number
(cm3/unit cell) (6.023x 1023 atoms/mol)
4R 4 × 0.1278nm
a= =
2 2
Volume of unit cell = V= a3 = (0.361nm)3 = 4.7 x 10-29 m3
FCC unit cell has 4 atoms.
Long
Transvers
e
Short Transverse
M. I of a DIRECTION
Miller Indices
M. I of a PLANE
Rasdi Deraman, FKM UiTM NPP 45
MILLER INDICES OF A DIRECTION
How to determine crystal direction
i)indices?
Determine the length of the vector projection
on each of the three axes, based on :
Clear fractions by
Fractions?
multiplying by an integer
Place a ‘bar’ over the to determine smallest set
Negative indices of whole numbers
Example:
• Metals have relatively high melting points and
remain in the liquid state over a wide temp.
range.
• Metals conduct electricity and heat.
• Metals are usually shiny when polished.
Rasdi Deraman, FKM UiTM NPP 52
MECHANICAL PROPERTIES
Generally, the common mechanical properties of
metals are as follows:
Toughness - the ability to resist / withstand repeated
bending.
Ductility – a property of material which can be easily
drawn into wires
Brittle – a property of material which easily
breaks when subjected to impacts.
Hardness - resistance to scratching or indentation.
Elasticity - ability to return to its original shape.
Plasticity - does not return to its original shape.
Rasdi Deraman, FKM UiTM NPP 53
STRESS-STRAIN CURVE
A stress–strain curve is a graph derived from
measuring load (stress – σ) versus extension
(strain – ε) for a sample of a material tested
using tensile machine.
Knoop A very small rhombic pyramidal diamond. Between 1 and 1000 g •Measure the hardness of small specimen,
(HK) very hard brittle materials (ceramic), very thin
sections and small elongated areas.
Vickers A very small square pyramidal diamond. Between 1 and 1000 g •Measure the hardness of small specimen, thin
(HV) materials and small rounded areas.
•More sensitive to measurement errors than
Knoop test
•Less sensitive to surface conditions than
Knoop test
Brinell Hardened steel or tungsten carbide ball. Use much higher loads than •Steel parts.
(HB) Rockwell.
Hardness-Width of indentation.
Rockwell Conical diamond or hardened steel balls. An initial minor load (10kg) •Measuring many materials from soft bearing
(HR) followed by a larger major load metals to carbides.
Hardness-Depth of penetration. (60, 100 or 150 kg)
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