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Over the past two three decades the problem of yellowing of textiles has become progressively more widespread. It would be wrong to regard yellowing as a phenomenon arising from a single cause. There are more than 20 different ways in which white or pale-coloured textiles can undergo this undesirable change in appearance.
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The critical factors identified are: Access to hindered phenol Access to air and NOx pH Auxiliaries Moisture Packaging In the case of indigo-dyed textiles there is the risk of the dyestuff being destroyed due to environ ental influences! "his irreversible destruction of the dyestuff is caused# a ongst others# by an interaction of ultraviolet radiation# o$one % nitrogen oxide -&photoche ical s og'! Ho(ever# noxious gases ay effect a destruction of the dyestuff even (ithout ultraviolet radiation being involved! "he degradation products of the indigo are usually yello() therefore (e also speak of yello(ing during storage of the indigo! Powerpoint Templates Page 3

The critical factors identified are: "his pheno enon is# for instance# observed (hen looking at the folded edges of ade-up *eans! In a pile of folded *eans# the folded edges are particularly affected since they are especially exposed to light % air! "he interior of the pile is protected against detri ental influences by its relative inaccessibility! +ue to the extre e ring dyeing of the (arp yarn# the indigo dyestuff situated on the surface is highly accessible to noxious gases# such as NOx and O,!
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O'one O( : O$one is the strongest oxidi$ing agent after fluorine! In organic che istry it serves to detect --- double bonds! "he general bleaching effect of o$one on indigo is (ellkno(n! "herefore the indigo dyestuff is also used as an indicator dyestuff in detection syste s .e!g! +rager/ (hich serve to easure the o$one concentration! #itrogen oxides #ox : Nitrogen oxides are also referred to as &nitrous gases'! Nitrogen oxides are ainly co posed on nitrogen onoxide % nitrogen dioxide! "hey are kno(n to be highly aggressive agents!

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)*O+,%-& ! .&%/0 -O#$&T OT1%*&0 +2 #O3IO.& $ &%& : 0ello(ing of optical brighteners due to nitrogen oxides 1 o$one! +estruction of natural rubber by o$one -hanges of shade caused by nitrogen oxides 0ello(ing of polyurethane fibres due to nitrogen oxides % sulphur dioxide /estruction of indigo by o'one and nitrogen Powerpoint Templates Page 6

!O.#T%* - -% &.*%& 2torage of the textiles in a controlled environ ent! Opti u ventilation of the store roo s .circulating air/! Nox is heavier than air and accu ulates on the ground! Packing e!g! in polyethylene foil that does not contain any igrating# light-inhibiting stabili$ers! +o not expose goods to sunlight!
)rotective finishing with

4. &O*+-O5 6 )owersil-#O5

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-%!1 #I&- O7 2%,,O8I#$ O7 I#/I$O-/2%/ T%3TI,%& /.% TO I* )O,,.T #T&0 &.!1 & O5O#% 6 #IT*O$%# O3I/%& 3ltraviolet radiation .9 2hort (avelength portion partly for ed of the sunlight by 34 % Nox e!g! fro the co bustion of fossil fuels o$one O( nitrogen oxides #ox!

photoche ical s og for ation of aggressive radicals

5adical attack against the double-bonded# con*ugated indigo syste Powerpoint Templates

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H O N

N H O Indigo

6or ation of peroxide % other radicals destruction of the --- double bond for ation of ostly yello( degradation products are

!OO1

O N
Phenylglycine .-olourless/

H
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It is a co plex a ido a ine phosphate used to protect indigo dyed fabrics and gar ents against o$one % NOx fading ! 7cono ical % 7co-friendly!

Hybrid silicone i parts pre iu softness I parts pre iu softness! 2oftening better than conventional a ino silicone e ulsion Protects indigo dyed fabrics and gar ents fro O$one and NOx fading 7nhances colour depth 7co friendly
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