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v
deBroglie Wavelength
mv
h
deBroglie
=
Calculate the wavelength in nanometers
associated with a 0.072 kg golf ball moving at
30 m/sec?
Quantized Energy
Energy Levels for H
where n in an integer.
2
18
Joules 10 18 . 2
E
n
n
=
Derivation of Balmer-Rydberg equation
AE = En
final
En
initial
d) (equation
J 10 18 . 2 1
10 18 . 2
c) (equation
1 1
J 10 18 . 2
b) (equation
1 1
J 10 18 . 2
a) (equation
J 10 18 . 2 J 10 18 . 2
2
18
2
18
2 2
18
2 2
18
2
18
2
18
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= A
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= A
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= A
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= A
final initial
final initial
initial final
initial final
n n
J E
n n
E
n n
E
n n
E
constant rydberg the R where
1 1 1
1 1
m 10 097 . 1
1
1 1
sec) / m 10 0 . 3 sec)( J 10 626 . 6 (
J 10 18 . 2 1
1 1
hc
J 10 18 . 2 1
1 1
J 10 18 . 2
hc
1 1
10 18 . 2
hc
h
positive is change energy - level energy higher a to promoted is electron an If
c) (equation
1 1
J 10 18 . 2
H
2 2
2 2
1 - 7
2 2 8 34
18
2 2
18
2 2
18
2 2
18
2 2
18
=
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=
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=
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=
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= = = A
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= A
final initial
H
final initial
final initial
final initial
final initial
final initial
final initial
n n
R
n n
n n
n n
n n
n n
J E
n n
E
u
R
1 1
1 1 1 1
m 10 097 . 1
1
1 1
sec) / m 10 0 . 3 sec)( J 10 626 . 6 (
J 10 18 . 2 1
1 1
hc
J 10 18 . 2 1
1 1
J 10 18 . 2
hc
1 1
10 18 . 2
hc
h
negative is change energy - level energy lower a to drops electron an If
c) (equation
1 1
J 10 18 . 2
2
H
2
2 2 2 2
1 - 7
2 2 8 34
18
2 2
18
2 2
18
2 2
18
2 2
18
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+
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=
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=
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=
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=
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=
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=
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= = = A
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= A
final initial
H
final initial
H
final initial
final initial
final initial
final initial
final initial
final initial
n n
R
n n
R
n n
n n
n n
n n
n n
J E
n n
E
u
What Next?
Light behaves like waves --- and
particles.
Particles can behave like waves.
Energy is quantized.
???????
Heisenberg Uncertainty
Principle
The first thing we would like to learn about
electrons is where they are and how they
travel.
Heisenberg Uncertainty principle says this is
impossible.
(Ax)(Amv) > h/4t (~10
34
kg m
2
/sec)
Schrodingers quantum
mechanical model of the atom
E = H
is the wave function or orbital
2
(probability function) represents the
probability of finding an electron at any
given position in an atom.
Quantum Numbers
The behavior of an electron is described
mathematically by Schrodingers wave
equation and each orbital contains as
set of three variables called quantum
numbers.
The principal quantum number
(n) --
- an integer
- determines energy level of orbital
Angular momentum quantum
number (l)--
equal to (n-1) to 0
so for n = 1, l = 0
for n = 2, l = 0, or 1
for n = 3, l = 0, 1, or 2
- determines type of subshell of an
electron
quantum number subshell type
0 s
1 p
2 d
3 f
Magnetic quantum number
(m
l
)
- equal to -l to +l in integer increments
- identifies number of orbitals within a
sublevel
describes spatial orientation orbitals
within a sublevel
Spin quantum number (m
s
)
- equal to +1/2 or 1/2
- necessary because
each orbital contains
2 electrons and each
electron needs its own
space.
s orbitals
- spherical in shape
- one spatial orientation (m
l
= 0)
- contain nodes as move to higher
quantum levels (nodes are places
probability of finding an electron goes to
zero)
- makes sense if we look at electrons as
waves, waves have nodes.
p orbitals
- dumbbell shaped
- three different spatial orientations (m
l
=1, 0, 1,)
d orbitals
- cloverleaf shaped + one dumbbell in a
doughnut
- five different spatial orientations (m
l
= 2,
1, 0, 1, 2)
f orbitals
- complex shape (8 lobes)
- seven different spatial orientations (m
l
=
3, 2, 1, 0, 1, 2, 3)