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Acids
An acid is a substance that produces hydrogen ions when dissolved in water. All acids contain hydrogen. But not all substances with hydrogen contains acids (Water). The hydrogen ions produced are responsible for the properties of an acid. A strong acid is one that is completely ionized in water (eg HCl) whereas a weak acid is only partially ionized in water
Strong acids: Sulphuric acid, Nitric acid, Hydrochloric acid, Carbonic acid, Sulphurous acid, Phosphoric acid o Weak acids: Ethanoic acid, Methanoic acid, Lactic acid, Citric acid
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Properties of Acids
Acids have a sour taste eg vinegar Acids are electrolytes because they dissolve in water to form ions which conduct electricity. Acids turn blue litmus paper red. pH value < 7. If concentrated they can be corrosive
Natural
Hydrochloric Acid (HCl) Sulphuric Acid (H2SO4) Nitric Acid (HNO3) Ethanoic Acid (Found in vinegar)
Unreactive metals (copper and silver) Concentrated nitric acid reacts with metals but it does not give hydrogen (gives nitrogen dioxide) Lead does not react as a coating is formed once lead is placed inside the acid.
Uses of acids
Sulphuric Acid:
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Sulphur
Sulphur exists as S8 molecule in which 8 atoms of sulphur join together by covalent bonding
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Weak van der Wals forces between sulphur molecules so sulphur has low melting and boiling point
Volcanic regions Natural gas and crude oil Minerals
Sources of sulphur
Oxides of sulphur
Sulphur dioxide SO2 S (s) + O2 (g) -- > SO2 (g) An acidic gas with choking smell o Sulphur trioxide SO3 2SO2 (g) + O2 (g) < --- > 2SO3 (g)
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Bases
Bases are metal oxides and hydroxides Soluble bases are known as alkalis A base is a substance that reacts with an acid to give salt and water only --- neutralization reaction Acid + Base Salt and Water Similar to: Acid + Metal Oxide/Hydroxide Salt and Water. Ionic Equation for this is always: OH- + H+ H2O (l)
Common Bases
Sodium Oxide Zinc Oxide Copper (II) Oxide Magnesium Hydroxide Aluminum Hydroxide
Family of Bases
Alkalis
An alkali is a base that is soluble in water. Some examples include:
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Sodium Hydroxide Potassium Hydroxide Calcium Hydroxide Barium Hydroxide Aqueous Ammonia
Properties of Alkalis
Alkalis have a bitter taste and soapy feel. Alkalis turn red litmus paper blue. pH value > 7.
Neutralization
All alkalis react with acids to form salt and water only.
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In neutralization, the hydrogen ions from the acid react with the hydroxide ions of the alkali
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The salt depends on the acid used. The ionic equation for this is standardized.
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H2O (l).
Applications of Neutralization
1. Soil treatment farming
Most plants grow best at pH 7. If the soil is acidic or alkaline the plant may grow badly. Therefore, chemicals can be added to the soil to change its pH. If the soil is too acidic - the most common complaint - it is treated with a base (chemicals opposite to an acid) in order to neutralize it. Common treatments use quicklime (calcium oxide) or chalk (calcium carbonate).
Applications of Neutralization
2. Indigestion
We all have hydrochloric acid in our stomach - it helps breakdown food However, too much acid leads to indigestion. Therefore, to cure this ailment we need to neutralize the acid with a base such as, sodium hydrogen carbonate (baking soda), or an indigestion tablet.
Applications of Neutralization
3. Insect stings
A bee sting contains acid. To relieve the painful symptoms of the sting we need to neutralize the acid. By rubbing on calamine lotion (zinc carbonate) or baking soda the acid can be neutralized. Wasp stings are alkaline, hence acid is needed to neutralize and remove the painful sting. Vinegar (ethanoic acid) is used.
Milk of magnesia Magnesium oxide MgO Verdigris Copper(II) oxide CuO Rust Iron(III) oxide Fe2O3
Uses of alkalis
Ammonia Solution:
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Sodium Hydroxide:
Uses of Ammonia
Ammonia is important in
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Manufacture nitric acid which is made by the catalytic oxidation of ammonia over heated platinum Producing fertilizers to supply nitrogen that is essential for plant growth
Eg ammonium sulphate, ammonium nitrate, urea To reduce acidity of soil, better not to add calcium hydroxide to soil as it can cause the loss of nitrogen from nitrogenous fertilisers
Haber Process
Haber Process mass produces ammonia by passing nitrogen gas and hydrogen gas through iron catalyst Reversible reaction:
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Temperature
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Raising temperature of the system will favor the backward reaction Lowering temperature will favor ammonia production However, at low temperature, the reaction will be very slow which is not economical, so temperature is kept optimum at 540oC
Concentration
Concentration tells us how much of a substance is dissolved in 1dm3 of a solution. It can be changed by either adding more solute or more solvent.
Strength of acid/alkali
Strength refers to how easily an acid or alkali dissociates when dissolved in water. A strong acid like hydrochloric acid dissociates easily in water (almost 100% of the acid dissociates) A weak acid like ethanoic acid does not fully dissociate when dissolved in water. The strength of an acid cannot be changed. No matter how concentrated ethanoic acid is, it is still a weak acid. The strength of an acid of an alkali can be shown using the pH scale.
Oxides
4 types of oxides
Acidic oxides Amphoteric oxides Oxides of non-metals Dissolve in water to give acids React with bases to give a salt and water Eg. carbon dioxide, sulphur dioxide, phosphorus(V) oxide
Oxides of metals react with both acids and alkalis to form salt and water Eg zinc oxide, aluminium oxide, lead(II) oxide Oxides of metals Some dissolve in water to give alkalis React with acids to give a salt and water Eg. ammonia, calcium oxide, sodium oxide, potassium oxide
Oxides of non-metals Do not react with acids or bases Eg carbon monoxide, nitrogen oxide, water
pH indicators
Indicators are substances that turn to different colors in acidic and alkali solutions The pH of a solution is a number that shows how acidic or alkaline a solution is
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A neutral solution like ethanol has a pH of 7 An acidic solution like HCl has a pH of 2 An alkaline solution like NaOH has a pH of 14
The lower the pH, the more acidic; the higher the pH, the more alkaline the substance is Farmers neutralize excess acidity in the soil by adding calcium hydroxide (slaked lime) to the soil
pH indicators
Indicator Litmus paper Universal Methyl orange Screened methyl orange Phenolphthalein
Salts
A salt is obtained from an acid when the hydrogen ion of an acid is replaced by a metal or ammonium ion Solubility of salts
Soluble salts Oxides Carbonates Hydroxides Chlorides Group I metals, Ammonium All the rest Insoluble salts All the rest
Lead(II), Silver
Nitrates
Sulphates
All
All the rest
None
Barium, Calcium, Lead(II)
Preparation of Salts
1. Insoluble salts are prepared using the precipitation method
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2. Soluble salts are prepared using acid + excess metal/insoluble metal oxide/carbonate (if reacting with insoluble substance) or titration (acid + alkali reaction) 3. After getting the salt solution, saturate it and then let it crystallize to get the salt
Titration
Preparation of NaCl Titrate NaOH against HCl
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Pipette 25.0cm3 of HCl into a conical flask Add a few drops of indicator (phenolphthalein) Add NaOH dropwise to the conical flask until end point (when 1 drop of NaOH turns permanent pink) NaCl is stable to heat
Precipitation
Preparation of Barium Sulphate Mix two soluble salt to obtain the insoluble salt
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Filter the mixture Wash the precipitate with distilled water Dry using filter paper
Identification of cations
Aqueous cation
Addition of dilute NaOH Few drops Excess White precipitate White precipitate White precipitate White precipitate Blue precipitate Precipitate dissolves Colorless solution Precipitate dissolves Colorless solution Precipitate dissolves Colorless solution Precipitate insoluble Precipitate insoluble
Green precipitate
Brown precipitate
Precipitate insoluble
Precipitate insoluble
Green precipitate
Brown precipitate
NH4+
Ammonia gas produced on warming No reaction with dilute NaOH. Gas has a pungent smell and turns damp red litmus blue
No reaction
Identification of cations
Aqueous Anion Test NO3CO32ClIAdd dilute NaOH and a little aluminium power Add dilute HCl Add dilute nitric acid and then silver nitrate Add dilute nitric acid and then lead(II) nitrate solution Add dilute nitric acid and then barium nitrate solution Observation Ammonia gas produced Effervescence occurs A white precipitate of silver chloride is formed A yellow precipitate of lead(II) iodide is formed A white precipitate of barium sulphate is formed
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