Beruflich Dokumente
Kultur Dokumente
GEOCHEMISTRY
DR HARVIR SINGH
Source Rock Lab, KDMIPE
Geochemistry-What It Is
Geochemistry is the study of
distribution and migration of
elements in the earth crust
Geochemistry deals with the question
of origin, migration, accumulation
and alteration of petroleum and
related substances
Petroleum Geochemistry
Integrate geochemistry
with:
• Seismic
• Geology
• Production data
of Producible Hydrocarbons
Probability (P) =
(Source rock)(Temperature)
(Time)
(Reservoir)(Seal)(Trap)
(Expulsion)
(Timing)(Migration path)
P=0 If any risk element is zero
GEOCHEMISTRY DIVISION KDMIPE
Capabilities
Surface Prospecting
Source Rock Evaluation
Fluid Characterization
Oil to oil, oil to source correlations
Genetic modeling
Laboratory Simulation of Hydrocarbon
Generation
Stratigraphic correlations
Reservoir Geochemistry
Exploration of unconventional energy
resources (CBM and Gas Hydrates)
Source Rock Lab
Source Rock Identification and
Characterisation
Mapping of
Organic content
Maturity
Biopolymers
Geopolymers (kerogen)
Petroleum
Preservation
In an oxygen deficient
environment
▪ Stagnant basins
▪ Oxygen minimum layer : Concn. Of O2 in
seawater of many coastal areas decreases
to
minimum at depth 100-500m. OML occure
worldwide wherever consumtion of O2 for
OM
degradation exceed the available supply of
O2
▪ Restricted circulation : Anoxic
environment is
Density stratification Stagnant basins
O2
O2 minimum layer
Reduced sediments
(O2<0.2 ml/l)
Slightly reduced to
oxidised sediments
Sea level
ANOXIC OML
OXIC
Dilution
Dependence of TOC on sedimentation rate
100
Calcareous
Siliceous
10 Black shale
TOC(%)
0.1
0.01
1 10 100 1000
Sediment Accumulation rate (m/MY)
Free HC directly from dead
organism plus HC formed by
bacterial activity & low
Temp. reaction in Recent
unconsolidated sediments
No free HC until
kerogen is heated to
enough temp. to crack
it & release HC
REC
Organic content of recent
sediments
Organic matter is incorporated with
sediments during deposition
OM in Recent sediments is not same as
Kerogen
in lithofied rocks. 40-60% Recent OM is
soluble in acid, base & organic solvents as
compared <20% of kerogen in lithified
rocks
High concentrations of OM favored by:
High productivity
Petroleum Formation:
The Source Rock Concept
GENERATION MIGRATION
ACCUMULATION
Source Reservoir
rock rock
Oil
100-
>150oC
150oC
Refra
ctory
Gas
>150oC
Inert Graphit
Very high T+P >250oC e
Kerogen
Kerogen is the disseminated
organic matter in sedimentary
rock that is insoluble in
organic solvents, non-
oxidizing acids and bases.
Kerogen is a macro-molecule,
or polymer-like substance,
that forms in a three-
dimensional network.
A schematic parallel-reaction model of
kerogen breakdown to oil on primary
cracking
Kerogen Types
A source rock is a kerogen-rich rock
that has experienced sufficient
catagenesis to generate oil or gas
(petroleum). The amount of oil or gas
that has been or will be generated
depends on the amount and type of
kerogen present in the source rock.
The familiar type I, II, and III kerogens are
based solely on hydrogen content and not on
morphology (terrigenous, marine, and
lacustrine).
Kerogen Maturity
▪Aquatic and terrestrial organic matter
that is
preserved in sediments is converted to
kerogen
by biological and very low temperature
▪ As sediments
processes are diagenesis
termed more deeply buried,
kerogen is
converted into oil and gas by thermal
processes
▪known
Under as catagenesis
extreme thermal stress, organic
matter is
meta-morphised into methane and
graphite by a
process called metagenesis
The organic
matter(OM)
in
sediments
generates
hydro-
carbons on
application
of thermal
stress
Maturity Assessment
Vitrinite reflectance
Tmax
TAI
Molecular parameters
Depth and temperature for the onset of
petroleum generation in rocks of different
ages
[Tissot and Welte, 1984]
Oil Window
The depth interval in which a petroleum source rock
generates & expels most of its oil is called oil window
( 60-160oC ) or VRo~ 0.6-1.30%
Type
Maturity
To identify
sediment
The oxygen content of bottom waters
palaeoecology
PYROLYSIS TECHNIQUE
RC CO % weight S 4CO ×
12
28
Residual Carbon org.
10 (CO)
RC CO2 % weight S 4CO2 ×
12 Residual Carbon org.
44
10 (CO2)
RC % weight RC CO + RC CO2 Residual Carbon org.
TOC % weight PC +RC Total Organic Carbon
HI mgHC/gTOC S 2 × 100
TOC
Hydrogen Index
S 3×100
OI mgCO2/gTOC Oxygen Index
TOC
S 3CO × 100
TOC
OI CO mg CO/gTOC Oxygen Index CO
Derived Parameters from RE
Data
The ratio S1/(S1+S2), called production
index (PI) is also a maturity indicator
like Tmax. Value of 0.1 represents
onset of generation, while values in the
neighborhood of 0.4 are characteristic
of peak oil generation.
The hydrogen index (HI=S2 x 100/TOC)
and oxygen index (OI=S3 x 100/TOC)
show good correlation with atomic
ratios H/C and O/C respectively and can
be used as proxies for atomic ratios in
the van Krevlin diagram.
General Scheme of Kinetic Model of
Hydrocarbon Generation
K = A e-E/RT
C1
Kerogen C2-C5 C1
C6-C14 Coke
C15+
n- Parallel
primary reactions
Optimization of kinetic
parameters (for realistic charge
estimates)
Assumptions
Generation follows 1st order kinetics
Mature
Early .6-.65 435-445 .1-.15 2.6-2.7 .05-.10
3
Kamalapuram
Depth (Km)
Portonovo
Nannilam
4
Kudavasal
Bhuvanagiri
Sattapadi
Andimadam
5 (0-10) (0-10) (0-300) (420-460) (0-2) (0-1)
Geochemical Source Rock Log of
Chintalapalli#1
Geochemical Source Rock Log of
Chintalapalli#8
Geochemical Source Rock Log of MDP#19HR
Geochemical Source Rock Log of Sarepalli#1 HR
Geochemical Source Rock Log of
Sitarampuram#1 HR
Effective Source Rock of World
91.5% of world’s discovered original reserve of petroleum
came from SRs of following six stratigraphic intervals
(Klemme et al., 1991)
Geology Geophysics
Stratigraphy Seismic
Petroleum Geochemistry
Understanding of Processes
Comparison
Go to with
A input real system
B Conceptual
Model
Unsuccessful Successful
Model Model
ogical concept organization in mode
logical
-DEPTH & AGES OF STRATIGRAPHIC
BOUNDARIES
-AGE & AMPLITUDE OF EROSION/ HIATUS - GEOMETRY OF SEDIMENTARY COLUMN
THROUGHOUT THE BASIN HISTORY
IF ANY
BACK -BURIAL HISTORY OF EACH SOURCE ROCK
-LITHOLOGY OF EACH SEDIMANTARY
STRIPPING - POROSITY EVOLUTION
LAYER
- SUBSIDENCE CURVES
-POROSITY/ PERMEABILITY DATA
- PALEOBATHEMETRY
- DIAPIRISM
- DIGITAL DATA FOR SEISMIC LINES
40 30 200 10 a l
g ic m s
l o e u t
0Paleozo
0 Mesozo 0
Cenoz e o e o l n
G Tim e tr eve
ic J
D MicP P TR K oic
P N P
e m
s t
y
RockSUnit
Source Rock
Reservoir Rock
Seal
Overburden
Rock
Trap
Rock
Formation
Gen/Mig/Accu
m.
Preservation
Critical
moment
Cross Section of a Petroleum
System
Geographic extent of petroleum
system in section view drawn at
critical moment (250 MA)
Petroleum System
A Dynamic Entity
1) Early Generation Spill Point
Spill Point
Seal Rock
Reservoir Rock (Mudstone)
Migration from (Sandstone)
‘Kitchen’
Gas beginning to
2) Late Generation displace oil
Displaced oil
accumulates
Gas displaces all
oil
Well State Vitrinite Reflectance (#
A)
Subsidence and Maturation
History of well Gandhar-A
Source Rock Generated
Hydrocarbons(#SWN)
Source Rock Expelled Hydrocarbons
(#SWN)
GENETIC CLASSIFICATION OF Petroleum
System
Depends on three factors
Petroleum charge available for trapping
H(S1+S2)*ρ
SPI = -----------------
1000
Migration drainage style
-Long distance lateral migration typical
of For
foreland basins is less efficient than
vertical
The entrapment style
GENETIC CLASSIFICATION OF
PETROLEUM SYSTEMS
1 Charge factor Migration-
Drainage style
-Super charged
-Normal charged -Vertically drained
-Under charged -Laterally drained
Entrapment Style
-High impedance
-Low impedance
PETROLEUM SYSTEM
Vertical drainage petroleum system
SPI > 5 under
charged
5 ≤ SPI > 15 moderate
charged
LateralSPI
drainage
> 15 petroleum system
super
charged SPI > 2 under
charged
2 ≤ SPI > 7 moderate
charged
Oil& Gas provinces based on their
petroleum system
Drainag Vertical Lateral
e style
Entrapm High Low High Low
ent
Super Los angels San joaquin N. Slope E. Vanezuela
charged N.Sea(UK) Iraq FTB C.Arabia
r
a Tr
vu
m am
ja
Andimadam-Nannilam
tin
n
(.) t
Ta
a
gap
Na
y
Ba
alk Andimadam-Niravi (.)
P
–
d
na
m
Ra
0
Scale
50km
Map Showing
Hydrocarbo
n Generated
(solid lines)
and
expelled
(colored
contours) in
a basin
Maturity modeling and computation of
critical moments in an Indian Basin
(Cauvery Basin)
1.2
Ariyalur-Pondicherry
1 Tranquebar
Nagapattinam
Ramnad
0.8 Tanjavur
0.7 %
VRo, %
VRo
0.6
0.4
0.2 50
3 15 25
0
0 50 100 Age, mybp
Benefits of Petroleum
SystemModeling
3-D modeling enables :
1. Understanding of petroliferous basins
in a
comprehensive manner
accumulation
Suggested Readings
Geochemistry in
Petroleum Exploration by
D. W. Waples, IHRDC,
Boston, 1984
Petroleum Geochemistry
and Geology by J. M.
Hunt, W. H. Freeman and
Co., New York, 1996
Thank you