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phases:
liquids and
solids
7.1 Liquids
• In a liquid, intermolecular forces are
strong enough to confine the
molecules to a specific volume
• Molecules are able to move freely
within a liquid
• Liquids are fluid
• Liquids cannot expand or contract
significantly
7.1 Liquids
• Properties of liquids
– Surface tension
• Measure of the resistance of a liquid to an
increase in its surface area
• There is a net attractive force on molecules
at the surface that pulls them towards the
interior of the liquid
• Cohesive forces attract molecules in the
liquid to one another
• Adhesive forces attract molecules in the
liquid to the walls of the container
7.1 Liquids
7.1 Liquids
– Capillary action
• The upward movement of water against the
downward force of gravity
7.1 Liquids
– Viscosity
• A liquid’s resistance to flow
• The greater the viscosity, the more slowly the
liquid pours
• A measure of how easily molecules slide by
one another
• This is affected by a combination of molecular
shape and the strength of the intermolecular
forces
• Viscosity is affected by temperature
7.1 Liquids
• Vapour pressure
– The distribution of molecular energies
guarantees that some of the molecules
in any liquid have enough kinetic energy
to overcome the intermolecular forces
that confine the liquid
– Whenever a liquid has an exposed
surface, some of its molecules will
escape into the vapour phase
7.1 Liquids
– The number of molecules of a liquid that have
enough energy to escape into the vapour
phase depends on:
• The strength of intermolecular forces
• The temperature
7.1 Liquids
– Vapour pressure is the pressure at which
dynamic equilibrium is achieved in a
closed container
7.2 Solids
• Magnitudes of forces
– Forces in solids range from very small to
extremely large
– Ions, atoms or molecules in solids can
be bound together by various attractive
forces:
• Intermolecular forces
• Metallic bonding
• Covalent bonds
• Ionic interactions
7.2 Solids
7.2 Solids
• Molecular solids
– Aggregates of molecules bound together
by intermolecular forces
– The forces can be dispersion, dipolar,
hydrogen bonding or a combination
– Many larger molecules have sufficient
dispersion forces to exist as solids at
room temperature
– Eg naphthalene
7.2 Solids
7.2 Solids
– Dimethyl oxalate is an example of a molecular
solid with dipolar interactions
– Interstitial impurities
occupy the spaces
between regular
atoms
7.8 Modern ceramics
• Ceramics are materials composed of
inorganic components that have been
heat-treated
• Many manufactured ceramics are
made from inorganic minerals such as
clay, silica (sand) and other silicates
• In recent times, advanced ceramics
have been prepared by chemists
7.8 Modern ceramics
• Properties of ceramics
– Almost all ceramics are very hard
– They have very high melting points
– Are often used as refractories
– Most ceramics do not conduct electricity
– Generally contain metals with high
positive oxidation states, combined with
small nonmetals with high negative
oxidation states
7.8 Modern ceramics
7.8 Modern ceramics
• Applications of advanced ceramics
– Thin ceramic films are used as
antireflective coatings on optical surfaces
– Partially stabilised zirconia is used to
make portions of hip-joint replacements
– Boron nitride powder is used in cosmetics
– Silicon nitride is used to make engine
components for diesel engines
7.8 Modern ceramics
• High-temperature superconductors
– A superconductor is a material which
offers no resistance to the flow of
electricity
– They can be levigated by a magnetic field
Summary
• Liquids are fluids, but cannot expand
or contract significantly
• Viscosity, surface tension and
capillary action depend mostly on the
strengths of intermolecular attractions
within the liquid
• Vapour pressure is the pressure at
which the number of molecules
escaping the liquid exactly matches
the number being captured
Summary
• Solids are rigid
• Solids may be classified as molecular,
metallic, network or ionic solids
• A phase change occurs when a
substance undergoes a transition
from one phase to another
• Temperatures and pressures at which
equilibria can exist between phases
are shown in a phase diagram
Summary
• Approximating atoms as spheres allows
us to determine their possible close-
packed arrangements
• The overall structure of any crystalline
solid can be described in terms of a
repeating three-dimensional array of
lattice points, which is called a lattice
• X-ray diffraction can be used to
determine the structure of crystalline
solids
Summary
• Amorphous solids do not have a
regular arrangement of atoms, ions or
molecules
• The most important example is glass
• Crystalline defects can significantly
alter the properties of a solid
• Ceramics are composed of inorganic
components that have been heat-
treated